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For water or aqueous solutions, the term relating to ξ is essentially unity. A hygroscopic particle in humid air should begin to take up water when the relative humidity β of the ambient air exceeds / . A droplet of solution should evaporate to a dry particle if the relative humidity falls t o / . In reality, however, a drying droplet tends to become supersaturated and the relative humidity must fall well below/before the particle crystallizes out [62]. This hysteresis effect is shown in Fig. 13.

D is its diameter, and ξ is its dielectric constant. For water or aqueous solutions, the term relating to ξ is essentially unity. A hygroscopic particle in humid air should begin to take up water when the relative humidity β of the ambient air exceeds / . A droplet of solution should evaporate to a dry particle if the relative humidity falls t o / . In reality, however, a drying droplet tends to become supersaturated and the relative humidity must fall well below/before the particle crystallizes out [62].

Moreover, while polydispersity must increase the rate of thermal coagulation [48], its effect on ordinary size distributions does not appear to be very great [49]. When all particles carry charges of the same polarity, their mutual repulsion causes the coagulation rate to decrease. If the charge on the aerosol is symmetrical with respect to polarity, as is so frequently the case in practice, the rate of coagulation is increased, but the effect does not appear to be large [27]. If the charges are very large or there is an impressed electric field in the space 48 Properties of Aerosols 2 confining the aerosol, then coagulation may be greatly enhanced, with the formation of long chain aggregates [27].