A novel replication technique for the production of open-celled aluminium foam has recently been devised and is undergoing commercial development by the company Constellium. The technique allows close control over the pore size and shape; a feature that is uncharacteristic of metal foam production methods in general and control to such an extent is unprecedented. The method provides an excellent pathway for the exploration of pore geometry/heat transfer behaviour relations, which is the objective of this study. This also aligns with the commercial goals of Constellium as heat transfer applications have been identified as a key market for their foams. Based on the technique; the focus of this work was the development of a laboratory protocol to allow the production of aluminium foam samples with a range of different mesostructures. The heat transfer behaviour, including permeability, of foams with differing matrix metal, pore size, pore aspect ratio and pore shape were examined under forced convection conditions. Decreasing pore size was found to provide enhanced heat transfer, although for pores < 3mm the benefit was outweighed by a large decrease in permeability. Small changes in pore shape as a result of preform compaction during processing may be exploited to provide improved heat transfer without reducing permeability. Elongation of pores provided no enhancement of heat transfer or permeability.