Can be found as a random lootable item that can be looted from corpse.

Can be bought from the little girl at the dark brotherhood for 670 (which is really cheap considering the other alternatives )

You can also find another Daedra Heart near Riverwood. To find it look at Bleak Falls Barrow from the sawmill cross the river and follow the river up till you see a stone tower on your left (this will act as landmark if you get lost) keep following the river until you reach the tower. A small wooden shack should be within range of you enter the shack and sharply turn left and next to the bed will be a trap door (you will need to pick the lock on the door) enter the trap door and look for a satchel. It only contains one Daedra Heart but its free. Get ready to fight when you leave the room the hag outside will say "So you know my secret now." and will attempt to kill you she will also send thugs to kill you even if you kill her first then steal the heart either way. The heart may respawn again in a week (I'm not 100% sure if this is true just a hunch if any want free easy hearts)