Put simply, yes, metals can get so hot that they will evaporate. Of course,
it takes a very large amount of heat. The melting point of copper is
roughly 1100°C, but its boiling point is just under 3000°C! The boiling
point of iron is also very high, at about 2681°C.
There is one metal, called Mercury, which is a liquid at room temperature,
and boils into a gas at only 356°C.
Hope that answers your question.