metal

metal

metal, chemical element displaying certain properties by which it is normally distinguished from a nonmetal, notably its metallic luster, the capacity to lose electrons and form a positive ion, and the ability to conduct heat and electricity. The metals comprise about two thirds of the known elements (see periodic table). Some metals, including copper, tin, iron, lead, gold, silver, and mercury, were known to the ancients; copper is probably the oldest known metal.

Physical Properties

Metals differ so widely in hardness, ductility (the potentiality of being drawn into wire), malleability, tensile strength, density, and melting point that a definite line of distinction between them and the nonmetals cannot be drawn. The hardest elemental metal is chromium; the softest, cesium. Copper, gold, platinum, and silver are especially ductile. Most metals are malleable; gold, silver, copper, tin, and aluminum are extremely so. Some metals exhibiting great tensile strength are copper, iron, and platinum. Three metals (lithium, potassium, and sodium) have densities of less than one gram per cubic centimeter at ordinary temperatures and are therefore lighter than water. Some heavy metals, beginning with the most dense, are osmium, iridium, platinum, gold, tungsten, uranium, tantalum, mercury, hafnium, lead, and silver.

For many industrial uses, the melting points of the metals are important. Tungsten fuses, or melts, only at extremely high temperatures (3,370°C;.), while cesium has a melting point of 28.5°C;. The best metallic conductor of electricity is silver. Copper, gold, and aluminum follow in the order named. All metals are relatively good conductors of heat; silver, copper, and aluminum are especially conductive. The radioactive metal uranium is used in reactor piles to generate steam and electric power. Plutonium, another radioactive element, is used in nuclear weapons and nuclear reactors as well as in pacemakers. Some of the radioactive metals not found in nature, e.g., fermium and seaborgium, are produced by nuclear bombardment.

Some elements, e.g., arsenic and antimony, exhibit both metallic and nonmetallic properties and are called metalloids. Furthermore, although all metals form crystals, this is also characteristic of certain nonmetals, e.g., carbon and sulfur.

Chemical Properties

Chemically, the metals differ from the nonmetals in that they form positive ions and basic oxides and hydroxides. Upon exposure to moist air, a great many undergo corrosion, i.e., enter into a chemical reaction; e.g., iron rusts when exposed to moist air, the oxygen of the atmosphere uniting with the metal to form the oxide of the metal. Aluminum and zinc do not appear to be affected, but in fact a thin coating of the oxide is formed almost at once, stopping further action and appearing unnoticeable because of its close resemblance to the metal. Tin, lead, and copper react slowly under ordinary conditions. Silver is affected by compounds such as sulfur dioxide and becomes tarnished when exposed to air containing them. The metals are combined with nonmetals in their salts, as in carbides, carbonates, chlorides, nitrates, phosphates, silicates, sulfides, and sulfates.

The Electromotive Series

On the basis of their ability to be oxidized, i.e., lose electrons, metals can be arranged in a list called the electromotive series, or replacement series. Metals toward the beginning of the series, like cesium and lithium, are more readily oxidized than those toward the end, like silver and gold. In general, a metal will replace any other metal, or hydrogen, in a compound that it precedes in the series, and under ordinary circumstances it will be replaced by any metal, or hydrogen, that it follows.

Metals in the Periodic Table

Metals fall into groups in the periodic table determined by similar arrangements of their orbital electrons and a consequent similarity in chemical properties. Groups of similar metals include the alkali metals (Group 1 in the periodic table), the alkaline-earth metals (Group 2 in the periodic table), and the rare-earth metals (the lanthanide and actinide series of Group 3). Most metals other than the alkali metals and the alkaline earth metals are called transition metals (see transition elements). The oxidation states, or valence, of the metal ions vary from +1 for the alkali metals to as much as +7 for some transition metals.

Sources and Uses

Although a few metals occur uncombined in nature, the great majority are found combined in their ores. The separation of metals from their ores is called extractive metallurgy. Metals are mixed with each other in definite amounts to form alloys; a mixture of mercury and another metal is called an amalgam. Bronze is an alloy of copper and tin, and brass contains copper and zinc. Steel is an alloy of iron and other metals with carbon added for hardness.

Since metals form positive ions readily, i.e., they donate their orbital electrons, they are used in chemistry as reducing agents (see oxidation and reduction). Finely divided metals or their oxides are often used as surface catalysts. Iron and iron oxides catalyze the conversion of hydrogen and nitrogen to ammonia in the Haber process. Finely divided catalytic platinum or nickel is used in the hydrogenation of unsaturated oils. Metal ions orient electron-rich groups called ligands around themselves, forming complex ions. Metal ions are important in many biological functions, including enzyme and coenzyme action, nucleic acid synthesis, and transport across membranes.

Any chemical element with valence electrons in two shells instead of only one. This structure gives them their outstanding ability to form ions containing more than one atom (complex ions, or coordination compounds), with a central atom or ion (often of a transition metal) surrounded by ligands in a regular arrangement. Theories on the bonding in these ions are still being refined. The elements in the periodic table from scandium to copper (atomic numbers 21–29), yttrium to silver (39–47), and lanthanum to gold (57–79, including the lanthanide series) are frequently designated the three main transition series. (Those in the actinide series and beyond, 89–111, also qualify.) All are metals, many of major economic or industrial importance (e.g., iron, gold, nickel, titanium). Most are dense, hard, and brittle, conduct heat and electricity well, have high melting points, and form alloys with each other and other metals. Their electronic structure lets them form compounds at various valences. Many of these compounds are coloured and paramagnetic (seeparamagnetism) and (as do the metals themselves) often act as catalysts. Seealsorare earth metal.

Used metals that are an important source of industrial metals and alloys, particularly in the production of steel, copper, lead, aluminum, and zinc. Smaller amounts of tin, nickel, magnesium, and precious metals are also recovered from scrap. Impurities consisting of such organic materials as wood, plastic, paint, and fabric can be burned off. Scrap is usually blended and remelted to produce alloys similar to or more complex than those from which the scrap was derived. Seealsorecycling.

Any of a large class of chemical elements including scandium (atomic number 21), yttrium (39), and the 15 elements from 57 (lanthanum) to 71 (seelanthanides). The rare earths themselves are pure or mixed oxides of these metals, originally thought to be quite scarce; however, cerium, the most plentiful, is three times as abundant as lead in the Earth's crust. The metals never occur free, and the pure oxides never occur in minerals. These metals are similar chemically because their atomic structures are generally similar; all form compounds in which they have valence 3, including stable oxides, carbides, and borides.

Method of drawing with a small sharpened metal rod—of lead, copper, gold, or most commonly silver—on specially prepared paper or parchment. Silverpoint produces a fine gray line that oxidizes to a light brown; the technique is best suited for small-scale work. It first appeared in medieval Italy and achieved great popularity in the 15th century. Albrecht Dürer and Leonardo da Vinci were its greatest exponents. It went out of fashion in the 17th century with the rise of the graphite pencil but was revived in the 18th century by the miniaturists and in the 20th century by Joseph Stella.

Weakened condition of metal parts of machines, vehicles, or structures caused by repeated stresses or loadings, ultimately resulting in fracture under a stress much weaker than that necessary to cause fracture in a single application. Fatigue-resistant metals have been developed and their performance improved by surface treatments, and fatigue stresses have been significantly reduced in aircraft and other applications by designing to avoid stress concentrations.

Any of a class of substances with, to some degree, the following properties: good heat and electricity conduction, malleability, ductility, high light reflectivity, and capacity to form positive ions in solution and hydroxides rather than acids when their oxides meet water. About three-quarters of the elements are metals; these are usually fairly hard and strong crystalline (seecrystal) solids with high chemical reactivity that readily form alloys with each other. Metallic properties increase from lighter to heavier elements in each vertical group of the periodic table and from right to left in each row. The most abundant metals are aluminum, iron, calcium, sodium, potassium, and magnesium. The vast majority are found as ores rather than free. The cohesiveness of metals in a crystalline structure is attributed to metallic bonding: The atoms are packed close together, with their very mobile outermost electrons all shared throughout the structure. Metals fall into the following classifications (not mutually exclusive and most not rigidly defined): alkali metals, alkaline earth metals, transition elements, noble (precious) metals, platinum metals, lanthanide (rare earth) metals, actinide metals, light metals, and heavy metals. Many have essential roles in nutrition or other biochemical functions, often in trace amounts, and many are toxic as both elements and compounds (seemercury poisoning, lead poisoning).

Type of rock music marked by highly amplified, distorted “power chords” on electric guitar, a hard beat, thumping bass, and often dark lyrics. It evolved in Britain and the U.S. in the late 1960s from the heavy, blues-oriented music of Steppenwolf, Jimi Hendrix, and others. In the 1970s the genre was defined by the music of bands such as Led Zeppelin, Black Sabbath, Kiss, AC/DC, and Aerosmith. After a period of decline, a new generation of bands such as Def Leppard, Iron Maiden, Mötley Crüe, and Van Halen revived heavy metal in the 1980s, along with the careers of many of its pioneers, including Ozzy Osbourne of Black Sabbath.

Any of the six chemical elements in the leftmost group of the periodic table (lithium, sodium, potassium, rubidium, cesium, and francium). They form alkalies when they combine with other elements. Because their atoms have only one electron in the outermost shell, they are very reactive chemically (they react rapidly, even violently, with water), form numerous compounds, and are never found free in nature.

Definition

Metals are sometimes described as a lattice of positive ions surrounded by a cloud of delocalized electrons. They are one of the three groups of elements as distinguished by their ionization and bonding properties, along with the metalloids and nonmetals. On the periodic table, a diagonal line drawn from boron (B) to polonium (Po) separates the metals from the nonmetals. Most elements on this line are metalloids, sometimes called semi-metals; elements to the lower left are metals; elements to the upper right are nonmetals (see the periodic table showing the metals).

An alternative definition of metals is that they have overlapping conduction bands and valence bands in their electronic structure. This definition opens up the category for metallic polymers and other organic metals, which have been made by researchers and employed in high-tech devices. These synthetic materials often have the characteristic silvery-grey reflectiveness (luster) of elemental metals.

Chemical properties

Metals are usually inclined to form cations through electron loss, reacting with oxygen in the air to form oxides over changing timescales (iron rusts over years, while potassium burns in seconds).
Examples:

4Na + O2 → 2Na2O (sodium oxide)

2Ca + O2 → 2CaO (calcium oxide)

4Al + 3O2 → 2Al2O3 (aluminium oxide)

The transition metals (such as iron, copper, zinc, and nickel) take much longer to oxidize. Others, like palladium, platinum and gold, do not react with the atmosphere at all. Some metals form a barrier layer of oxide on their surface which cannot be penetrated by further oxygen molecules and thus retain their shiny appearance and good conductivity for many decades (like aluminium, some steels, and titanium). The oxides of metals are basic (as opposed to those of nonmetals, which are acidic), although this may be considered a rule of thumb, rather than a fact.

Physical properties

Metals in general have superior electric and thermal conductivity, high luster and density, and the ability to be deformed under stress without cleaving. While there are several metals that have low density, hardness, and melting points, these (the alkali and alkaline earth metals) are extremely reactive, and are rarely encountered in their elemental, metallic form.

The majority of metals have higher densities than the majority of nonmetals. Nonetheless, there is wide variation in the densities of metals; lithium is the least dense solid element and osmium is the densest. The metals of groups I A and II A are referred to as the light metals because they are exceptions to this generalization. The high density of most metals is due to the tightly-packed crystal lattice of the metallic structure. The strength of metallic bonds for different metals reaches a maximum around the center of the transition series, as those elements have large amounts of delocalized electrons in a metallic bond. However, other factors (such as atomic radius, nuclear charge, number of bonding orbitals, overlap of orbital energies, and crystal form) are involved as well.

The nondirectional nature of metallic bonding is thought to be the primary reason for the malleability of metal. Planes of atoms in a metal are able to slide across one another under stress, accounting for the ability of a crystal to deform without shattering.

When the planes of an ionic bond are slid past one another, the resultant change in location shifts ions of the same charge into close proximity, resulting in the cleavage of the crystal. Covalently bonded crystals can only be deformed by breaking the bonds between atoms, thereby resulting in fragmentation of the crystal.

The electrical and thermal conductivity of metals originate from the fact that in the metallic bond, the outer electrons of the metal atoms form a gas of nearly free electrons, moving as an electron gas in a background of positive charge formed by the ion cores. Good mathematical predictions for electrical conductivity, as well as the electrons' contribution to the heat capacity and heat conductivity of metals can be calculated from the free electron model, which does not take the detailed structure of the ion lattice into account.

When considering the exact band structure and binding energy of a metal, it is necessary to take into account the positive potential caused by the specific arrangement of the ion cores - which is periodic in crystals. The most important consequence of the periodic potential is the formation of a small band gap at the boundary of the brillouin zone. Mathematically, the potential of the ion cores is treated in the nearly-free electron model.

Alloys

An alloy is a mixture of two or more elements in solid solution in which the major component is a metal. Most pure metals are either too soft, brittle or chemically reactive for practical use. Combining different ratios of metals as alloys modifies the properties of pure metals to produce desirable characteristics. The aim of making alloys is generally to make them less brittle, harder, resistant to corrosion, or have a more desirable color and luster. Examples of alloys are steel (iron and carbon), brass (copper and zinc), bronze (copper and tin), and duralumin (aluminium and copper). Alloys specially designed for highly demanding applications, such as jet engines, may contain more than ten elements.

In alchemy, a base metal was a common and inexpensive metal, as opposed to precious metals, mainly gold and silver. A longtime goal of the alchemists was the transmutation of base metals into precious metals.

Ferrous metal

The term "ferrous" is derived from the latin word meaning "containing iron". This can include pure iron, such as wrought iron, or an alloy such as steel. Ferrous metals are often magnetic, but not exclusively.

The demand for precious metals is driven not only by their practical use, but also by their role as investments and a store of value. Palladium was, as of summer 2006, valued at a little under half the price of gold, and platinum at around twice that of gold. Silver is substantially less expensive than these metals, but is often traditionally considered a precious metal for its role in coinage and jewelry.

Extraction

Metals are often extracted from the Earth by means of mining, resulting in ores that are relatively rich sources of the requisite elements. Ore is located by prospecting techniques, followed by the exploration and examination of deposits. Mineral sources are generally divided into surface mines, which are mined by excavation using heavy equipment, and subsurface mines.

Once the ore is mined, the metals must be extracted, usually by chemical or electrolytic reduction. Pyrometallurgy uses high temperatures to convert ore into raw metals, while hydrometallurgy employs aqueous chemistry for the same purpose. The methods used depend on the metal and their contaminants.

Metallurgy

Metallurgy is a domain of materials science that studies the physical and chemical behavior of metallic elements, their intermetallic compounds, and their mixtures, which are called alloys.

Applications

Some metals and metal alloys possess high structural strength per unit mass, making them useful materials for carrying large loads or resisting impact damage. Metal alloys can be engineered to have high resistance to shear, torque and deformation. However the same metal can also be vulnerable to fatigue damage through repeated use, or from sudden stress failure when a load capacity is exceeded. The strength and resilience of metals has led to their frequent use in high-rise building and bridge construction, as well as most vehicles, many appliances, tools, pipes, non-illuminated signs and railroad tracks.

Metals are good conductors, making them valuable in electrical appliances and for carrying an electric current over a distance with little energy lost. Electrical power grids rely on metal cables to distribute electricity. Home electrical systems, for the most part, are wired with copper wire for its good conducting properties.

The thermal conductivity of metal is useful for containers to heat materials over a flame. Metal is also used for heat sinks to protect sensitive equipment from overheating.

The high reflectivity of some metals is important in the construction of mirrors, including precision astronomical instruments. This last property can also make metallic jewelry aesthetically appealing.