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Not to worry, the CDG Terminal 2 train station will be open already for your 6am arrival.

First, follow the instructions for taking a train from CDG to Paris. You'll be taking the RER B train, which cuts north to south through Paris. Get off this train at Cité Universitaire station. Here, transfer to the Tram 3, in direction Pont de Garigliano. You'll need a new ticket, a regular Metro ticket t+ to ride the tram. You can purchase it from the tram stop outside of Cité Universitaire. You could save yourself this step by buying the ticket when you buy your RER B train ticket at CDG Airport train station. This Tram 3 will stop right at Porte de Versailles, which should be close to your hotel.