LONDON — The so-called “Big 4” who have won 35 of the past 37 Grand Slam singles titles — Novak Djokovic, Rafael Nadal, Andy Murray and Roger Federer — are all around for the second week at Wimbledon, joined by the new major winner on the block, Australian Open champion Stan Wawrinka.

The same can’t be said on the women’s side, where top-seeded and five-time champion Serena Williams won’t see any action at the All England Club in Week 2 except in doubles with her sister Venus, another five-time Wimbledon winner who is also out of singles.

With Serena out and second-seeded Li Na also a third-round loser, it marks the first time in the Open era that the top two women’s seeds haven’t advanced to the fourth round.

Williams hadn’t been knocked out of Wimbledon so soon since 2005 but has departed before the quarterfinals at four of the past five majors.

On a sunny but blustery middle Sunday — traditionally an off-day at Wimbledon — many players remaining in the singles draw held sessions at the nearby Aorangi Park courts.

Federer and Murray were there at the same time, although because of rain delays on Friday, Federer, like Nadal, won’t play his fourth-round match until Tuesday.

Federer says he’s amazed as anyone about the Big 4’s ability to maintain such a stellar record in Grand Slam tournaments.

“I came through the ranks where it was normal for top guys to have a bad Slam, have maybe two bad Slams from time to time, but it barely happens anymore,” Federer said.

Djokovic’s chances of advancing might rest with his sore arm. He had an afternoon training session Sunday to test his left arm and shoulder he injured in a nasty fall Friday.

“Luckily there is nothing damaged,” he said. “I’m quite confident that it will not affect my physical state or regimen or daily routine.”

Alize Cornet, who scored the biggest upset of the tournament when she beat Serena Williams, opens Monday’s play on Centre Court against Canadian Eugenie Bouchard, the only woman to advance to the semifinals of both Grand Slam tournaments this year.

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