Abstract

Corrole complexes with gold(I) and gold(III) were synthesized and their structural, photophysical, and electrochemical properties investigated. This work includes the X-ray crystallography characterization of gold(I) and gold(III) complexes, both chelated by a corrole with fully brominated β-pyrrole carbon atoms. The mononuclear and chiral gold(I) corrole appears to be the first of its kind within the porphyrinoid family, while the most unique property of the gold(III) corrole is that it displays phosphorescence at ambient temperatures.

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Publication History

Issue online: 17 October 2011

Version of record online: 4 October 2011

Manuscript Revised: 3 August 2011

Manuscript Received: 28 July 2011

Funded by

DFG

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