Revision number: 5 Section 2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDS Not classified HEALTH HAZARDS Acute toxicity (Oral) Category 4
Category 1 Skin sensitization Reproductive toxicity Category 2
Not classified ENVIRONMENTAL HAZARDS GHS label elements, including precautionary statements Pictograms or hazard symbols Signal word Warning Hazard statements Harmful if swallowed
May cause an allergic skin reaction
Suspected of damaging fertility or the unborn child Precautionary statements:
Obtain special instructions before use. [Prevention]
Do not handle until all safety precautions have been read and understood.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Do not eat, drink or smoke when using this product.
Contaminated work clothing should not be allowed out of the workplace.
Wash hands thoroughly after handling.
Wear protective gloves/eye protection/face protection. [Response] IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Rinse mouth.
IF ON SKIN: Gently wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention. [Storage] Store locked up. [Disposal] Dispose of contents/container through a waste management company authorized by
the local government. Sulindac SulfideSection 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture: Substance Components: Sulindac Sulfide Percent: >98.0%(LC) CAS Number: 32004-67-4 Synonyms: 5-Fluoro-2-methyl-1-[p-(methylthio)benzylidene]indene-3-acetic Acid Chemical Formula: C20H17FO2S Section 4. FIRST AID MEASURES
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Inhalation:
Get medical advice/attention. Skin contact: Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. Get medical advice/attention. Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Get medical advice/attention. Ingestion: Get medical advice/attention.Rinse mouth.
A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders:
tight goggles.Section 5. FIRE-FIGHTING MEASURES Suitable extinguishing Dry chemical, foam, water spray, carbon dioxide. media: Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so. Special protective When extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters:Section 6. ACCIDENTAL RELEASE MEASURES Personal precautions, Use extra personal protective equipment (P3 filter respirator for toxic particles). Keep protective equipment and people away from and upwind of spill/leak. Entry to non-involved personnel should emergency procedures: be controlled around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations.Section 7. HANDLING AND STORAGE Precautions for safe handling Technical measures: Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent dispersion of dust. Wash hands and face thoroughly after handling.
Use a closed system if possible. Use a local exhaust if dust or aerosol will be
generated. Advice on safe handling: Avoid all contact! Conditions for safe storage, including any incompatibilities Storage conditions: Keep container tightly closed. Store in a freezer.
Store locked up.
Store away from incompatible materials such as oxidizing agents.
Heat-sensitive Packaging material: Comply with laws. Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Install a closed system or local exhaust. Also install safety shower and eye bath. Engineering controls: Personal protective equipment Sulindac SulfideSection 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator,
etc. Use respirators approved under appropriate government standards and follow
local and national regulations. Hand protection: Impervious gloves. Eye protection: Safety goggles. A face-shield, if the situation requires. Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Solid Physical state (20°C): Form: Crystal- Powder Colour: Pale yellow - Reddish yellow Odour: No data available pH: No data available Melting point/freezing point:186°C Boiling point/range: No data available Flash point: No data available Flammability or explosive limits: Lower: No data available Upper: No data available Relative density: No data available Solubility(ies): [Water] No data available [Other solvents] No data available Section 10. STABILITY AND REACTIVITY Chemical stability: Stable under proper conditions. Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen fluoride, Sulfur oxides products:Section 11. TOXICOLOGICAL INFORMATION Acute Toxicity: No data available Skin corrosion/irritation: No data available Serious eye No data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC = No data available NTP = No data available Reproductive toxicity: No data available RTECS Number: NK8236000 Section 12. ECOLOGICAL INFORMATION Ecotoxicity: Fish: No data available
No data available Crustacea: Algae: No data available Persistence / degradability: No data available Bioaccumulative No data available potential(BCF): Mobility in soil
No data available Log Pow: Soil adsorption (Koc): No data available Sulindac SulfideSection 12. ECOLOGICAL INFORMATION Henry's Law No data available constant(PaM3/mol):Section 13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
Observe all federal, state and local regulations when disposing of the substance.Section 14. TRANSPORT INFORMATION Hazards Class: Does not correspond to the classification standard of the United Nations
Not listed UN-No:Section 15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.