Guangdong Baiyun City HotelThe Guangdong Baiyun City Hotel (Baiyun Chengshi Jiudian) is handy to Guangzhou Railway Station Square, Pazhou Complex and Jinhan Exhibition Center. This Guangzhou hotel enjoys convenient transportation access such as metro trains and public buses.
Guests can surf the internet for free.Guangzhou Location & Guangzhou Transportation:Airport Guangzhou New Baiyun International Airport 35 km
Downtown Beijing Lu Pedestrian Street 5 km
Railway Station Guangzhou Railway Station 0.05 km
Railway Station Guangzhou East Railway Station 5 km
The place is quite nice with english speaking staff both on front desk and the floor attendents. The rooms are clean. Just in front of the metro station, bus station, long route bus station and the railway station so suited me perfectly for travelling. Has airport shuttle service operating from just beside the hotel. The only negative is that it does not have any restaurant

Maoming Shihua HotelFixed-line phone: 86-020-86220388
Fax: 86-020-86220522
The Maoming Shihua Hotel (Guangzhou Maoming Shihua Binguan) is within walking distance of Guangzhou Railway Station and Liuhua Bus Terminus, near a metro station.
Various rooms are air-conditioned with broadband internet access and sound-proof doors and windows.
For those with more serious pursuits on their agendas, the hotel hosts small and medium-sized conference rooms.Guangzhou Location & Transportation:Airport Guangzhou New Baiyun International Airport 30 km
Railway Station Guangzhou Railway Station 0.4 km

Q-City Hotel
广州倾城酒店(广州市越秀区盘福路79号 )
Q-City Hotel is located in the Yuexiu – Main Railway Station neighborhood of Guangzhou, close to National Dr. Sun Yat Sen Memorial Hall, Zhenhai Tower, and The Western Han Museum of the Nanyue King Mausoleum. Nearby points of interest also include Six Banyon Tree Temple and Flower Pagoda and Yuexiu Park.
Address: No.79 Panfu Road,Yuexiu District Guangzhou, 510182 China

Hello there
It was seem that not much4 star hotels near the Guangzhou Railway station,but I still find one 4 star hotel close the Guangzhou Railway Station , it is XingHe International Hotel Guangzhou Railway Station Branch (Click here) , it is about 10-15 minutes walking to the Zhanxi lu, you will see the park in front of the hotel when you see the map . The hotel is close the metro station Exit A, it is convenient as well.

Another hotel is Landsman Hotel (Click here) , it is close the Guangzhou railway station ,if you take a taxi to railway station from hotel , would be about 10 minutes, but not close metro station .

but what do you think about the Hotel Landmark Canton? （click here) it was at the Haizhu square, it is about 3 minutes walking to the metro station and about 8 minutes if you take a metro at Haizhu Square to Guangzhou Railway station , if you take a taxi from the hotel to guangzhou railway station , about 10-15 minutes.
If you want to find some 3 stars hotels, you can search “Xiaobei or Taojing lu” there are some good 5 start and 3 start hotels there. like Crowne Plaza Guangzhou City Centre Hotel, Asia International Hotel