On 21 July 2009 he signed with Romania's FC Dinamo București, leaving Spain for the first time in his career. He spent only one year in Liga I, however, cancelling his contract in the summer and returning to his country, joining division two club SD Huesca.

On 6 July 2011, Molinero signed with Real Murcia for three years. On 26 June 2014, after being an undisputed starter for the latter, he moved to Real Betis also in the second level.