By co-evaporation of cesium iodide and lead iodide thin layers of CsPbI3 can be produced even at moderate temperatures. An excess of cesium leads to stable perovskite phases. Image Credit: J. Marquez-Prieto. Helmholtz-Zentrum Berlin. Click image for the largest view.

Teams all over the world are working intensively on the development of perovskite solar cells. The focus is on what are known as metal-organic hybrid perovskites whose crystal structure is composed of inorganic elements such as lead and iodine as well as an organic molecule.

Completely inorganic perovskite semiconductors such as CsPbI3 have the same crystalline structure as hybrid perovskites, but contain an alkali metal such as caesium instead of an organic molecule. This makes them much more stable than hybrid perovskites, but usually requires an extra production step at very high temperature – several hundred degrees Celsius.

For this reason, inorganic perovskite semiconductors have thus far been difficult to integrate into thin-film solar cells that cannot withstand high temperatures. A team headed by Dr. Thomas Unold has now succeeded in producing inorganic perovskite semiconductors at moderate temperatures so that they might also be used in thin-film cells in the future.

The physicists designed an innovative experiment in which they synthesized and analyzed many combinations of material within a single sample. Using co-evaporation of caesium-iodide and lead-iodide, they produced thin layers of CsPbI3, systematically varying the amounts of these elements, while the substrate-temperature was less than 60° Celsius.

Unold explained, “A combinatorial research approach like this allows us to find optimal production parameters for new material systems much faster than with the conventional approach that typically requires 100 samples to be produced for 100 different compositions.” Through careful analysis during synthesis and the subsequent measurements of the optoelectronic properties, they were able to determine how the composition of the thin film affects the material properties.

Their measurements show that the structural as well as important optoelectronic properties of the material are sensitive to the ratio of caesium to lead. Thus, excess caesium promotes a stable perovskite phase with good mobility and lifetimes of the charge carriers.

In cooperation with the HZB Young Investigator Group of Prof. Steve Albrecht, these optimized CsPbI3 layers were used to demonstrate perovskite solar cells with an initial efficiency of more than 12 % and stable performance close to 11% for over 1200 hours.

Unold said, “We have shown that inorganic perovskite absorbers might also be suitable for use in thin-film solar cells if they can be manufactured adequately. We believe that there is great room for further improvements.”

One day the perovskite solar panels are going to go on sale in a big way. Good efficiency and a low price will vastly increase the applicability.