σd - diagonal reflection plane (contains the principal axis and bisect the angle between two C2 axes perpendicular to the principal axis)

* - n is an integer** - principal axis is a Cn axis with the biggest n.

Molecule belongs to a symmetry point group if it is unchanged under all the symmetry operations of this group.

Certain properties of the molecule (vibrational, electronic and vibronic states, normal vibrational modes, orbitals) may behave the same way or differently under the symmetry operations of the molecule point group. This behavior is described by the irreducible representation(irrep, character). All irreducible representations of the symmetry point group may be found in the corresponding character table. Molecular property belongs to the certain irreducible representation if it changes undersymmetry operations exactly as it is specified for this irreducible representation in the character table.

If some molecular property A is a product of other properties B and C, the character of A is a product of B and C characters and may be determined from the character product table.

In general assignment of a character (irriducible representation) to a given molecular property depends on the molecular orientation. To make this assignment unambiguous Mulliken developed conventions for symmetry notations which became widely accepted.