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Career: Anne became famous for her role in The Princess Diaries and its sequels. She won acclaim for her roles in Brokeback Mountain, The Devil Wears Prada and Rachel Getting Married, for which she was nominated for a Best Actress Oscar. Other films include box office hits Valentine’s Day and Alice in Wonderland.

Relationships: In 2004, Anne started dating Italian real estate developer Raffaello Follieri. He was arrested in June 2008 on fraud charges, and Anne ended her relationship with him soon after. She then began dating Adam Shulman and got engaged to him in 2012. The couple married in September 2012.

FYI: Anne was a raised a Catholic and wanted to be a nun when she grew up. She changed her mind when she was 15.