Related Articles

To explain the impossible, the researchers propose that a quantum mechanical phenomenon, known as 'quantum tunnelling', is revving up the chemical reaction. They found that the rate at which the reaction occurs is 50 times greater at minus 210 degrees Celsius than at room temperature.

It's the harsh environment that makes space-based chemistry so difficult to understand; the extremely cold conditions should put a stop to chemical reactions, as there isn't sufficient energy to rearrange chemical bonds. It has previously been suggested that dust grains -- found in interstellar clouds, for example -- could lend a hand in bringing chemical reactions about.

The idea is that the dust grains act as a staging post for the reactions to occur, with the ingredients of complex molecules clinging to the solid surface. However, last year, a highly reactive molecule called the 'methoxy radical' was detected in space and its formation couldn't be explained in this way.

Laboratory experiments showed that when an icy mixture containing methanol was blasted with radiation -- like would occur in space, with intense radiation from nearby stars, for example -methoxy radicals weren't released in the emitted gases. The findings suggested that methanol gas was involved in the production of the methoxy radicals found in space, rather than any process on the surface of dust grains. But this brings us back to the problem of how the gases can react under extremely cold conditions.

"The answer lies in quantum mechanics," says Professor Dwayne Heard, Head of the School of Chemistry at the University of Leeds, who led the research.

"Chemical reactions get slower as temperatures decrease, as there is less energy to get over the 'reaction barrier'. But quantum mechanics tells us that it is possible to cheat and dig through this barrier instead of going over it. This is called 'quantum tunnelling'."

To succeed in digging through the reaction barrier, incredibly cold temperatures -- like those that exist in interstellar space and in the atmosphere of some planetary bodies, such as Titan -- are needed. "We suggest that an 'intermediary product' forms in the first stage of the reaction, which can only survive long enough for quantum tunnelling to occur at extremely cold temperatures," says Heard.

The researchers were able to recreate the cold environment of space in the laboratory and observe a reaction of the alcohol methanol and an oxidising chemical called the 'hydroxyl radical' at minus 210 degrees Celsius. They found that not only do these gases react to create methoxy radicals at this incredibly cold temperature, but that the rate of reaction is 50 times faster than at room temperature.

To achieve this, the researchers had to create a new experimental setup. "The problem is that the gases condense as soon as they hit a cold surface," says Robin Shannon from the University of Leeds, who performed the experiments. "So we took inspiration from the boosters used for the Apollo Saturn V rockets to create collimated jets of gas that could react without ever touching a surface."

The researchers are now investigating the reactions of other alcohols at very cold temperatures. "If our results continue to show a similar increase in the reaction rate at very cold temperatures, then scientists have been severely underestimating the rates of formation and destruction of complex molecules, such as alcohols, in space," concludes Heard.

More From ScienceDaily

More Space & Time News

Featured Research

Mar. 3, 2015 — Meteorologists sometimes struggle to accurately predict the weather here on Earth, but now we can find out how cloudy it is on planets outside our solar system, thanks to new ... full story

Mar. 3, 2015 — Recent research contributes to the effort to determine the nature of dark matter, one of the most important mysteries in physics. As indirect evidence provided by its gravitational effects, dark ... full story

Mar. 2, 2015 — Dust plays an extremely important role in the universe -- both in the formation of planets and new stars. But the earliest galaxies had no dust, only gas. Now an international team of astronomers has ... full story

Mar. 2, 2015 — NASA's Dawn spacecraft has returned new images captured on approach to its historic orbit insertion at the dwarf planet Ceres. Dawn will be the first mission to successfully visit a dwarf planet when ... full story

Mar. 2, 2015 — An international team of researchers has demonstrated a way to assess the quality of water on Earth from space by using satellite technology that can visualize pollution levels otherwise invisible to ... full story

Feb. 27, 2015 — A new type of methane-based, oxygen-free life form that can metabolize and reproduce similar to life on Earth has been modeled. It is theorized to have a cell membrane, composed of small organic ... full story

Feb. 27, 2015 — Astronomers using data from NASA's Wide-field Infrared Survey Explorer, or WISE, have found a cluster of stars forming at the very edge of our Milky Way galaxy. This is the first time astronomers ... full story

Feb. 26, 2015 — If you put a camera in the ice machine and watched water turn into ice, the process would look simple. But the mechanism behind liquids turning to solids is actually quite complex, and understanding ... full story

Feb. 26, 2015 — Like a cowboy at a rodeo, NASA's newest Earth-observing satellite, the Soil Moisture Active Passive (SMAP), has triumphantly raised its "arm" and unfurled a huge golden "lasso" (antenna) that it will ... full story

NASA EDGE: SMAP Launch

NASA (Mar. 2, 2015) — Join NASA EDGE as they cover the launch of the Soil Moisture Active Passive (SMAP) spacecraft live from Vandenberg Air Force Base. Special guests include NASA Administrator Charlie Bolden, SMAP Project System Engineer Shawn Goodman and Lt Col Brande Walton and Joseph Sims from the Air Force. No word on the Co-Host&apos;s whereabouts.
Video provided by NASA

Related Stories

Oct. 16, 2013 — Chemists have developed a new “click” chemistry process for specific assembly of two components without modifying their properties or the medium in which the reaction takes place. The process can ... full story

Sep. 11, 2013 — Chemists have found a way to apply a "foundational reaction" of organic chemistry to a stubborn class of chemicals, in a transformation that has been thought impossible for a ... full story

Mar. 14, 2013 — How you get the chameleon of the molecules to settle on a particular "look" has been discovered by chemists in Germany. The molecule CH5+ is normally not to be described by a single rigid ... full story

Dec. 26, 2012 — Physicists have found that a new powerful tool they call 'Wigner flow' is the quantum analog of phase space flow. Wigner flow provides information for quantum dynamics similar to that ... full story

ScienceDaily features breaking news and videos about the latest discoveries in health, technology, the environment, and more -- from major news services and leading universities, scientific journals, and research organizations.