Inspect the volume in Xsan admin. or check NamedStreams value in the volume.cfg file in /Library/Preferences/Xsan. The default for new volumes should be enabled.

I'm not suggesting you enable it if it isn't, because it might take a long time to enable without making a difference. But I wonder if it might make a difference. Maybe set up a test volume to check. (I would but I don't have Photoshop.)

Still haven't found anything - we've been using the save to desktop work around. Just saw that 10.8.2 was released - maybe something in there will solve this issue. Will try upgrading in the next week or two and let you know if it resolves the issue.

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