A reception was being held at the Stoke Park hotel in the U.K., which is near Pinewood Studios, where Pitt is currently shooting his new WWII film Fury. The groom, Daniel, happened to see Pitt drinking at the bar and pulled his bride, Abi, in to meet the actor, who posed for pictures with the newlyweds.

"He said sure, no problem, and said congratulations and I hope you have had a great day," the bride told the paper. "And he said I looked nice. He was really nice."

Pitt will next appear in the dramas 12 Years a Slave, which hits theaters on Oct. 18.