And, this just in, Brad told People.com that he and Angelina want more kids!

Speaking of family, Brad was in for a surprise when Jerry introduced his biggest fan, who happens to be Jerry’s mom.

“You came all the way to meet me?” Brad asked the Florida native. “I did customs in Florida; I just landed in Florida this morning.”

But Mama Penacoli wasn’t the only woman Mr. Pitt made blush; Sienna Miller was a little flustered herself after Brad kissed her cheek.

“I can think of worse things, I have to say,” she said of the peck.

Inside the annual film fest, Brad and Cate picked up an Ensemble Performance award for “Babel,” while Cate also nabbed the Career Achievement Award for her amazing body of work, including “Notes on a Scandal.”

“I’m too young for this,” she joked of the honor.

Meanwhile, we asked Brad what he thought about his good friend George Clooney lobbying for Cate to pick up a golden statue at this year’s Academy Awards.

“He’s always lobbying for something,” Brad said.

Also at the festival, Kate Winslet, who stunned the crowd in Valentino, picked up acting nods for “Little Children.”

On Sunday, the stars winded down from the red carpet event by attending a Screen Actors Guild Foundation brunch, hosted by Jerry Penacoli himself.