We report the synthesis of the first stable, solution-processable and photocrosslinkable hybrid organic/inorganic titanium dioxide nanorods as ‘hairy rods’ coated with phosphonate ligands with photoreactive coumarin groups located in a terminal posit...
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We report for the first time the one-step synthesis of solution-processable, highly crystalline, niobiumdoped titanium dioxide (Nb-TiO2) nanorods in the anatase phase by the hydrolytic condensation of Ti(OiPr)4 and niobium(V) ethoxide using oleic aci...
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Lipase immobilised on silica monoliths has been prepared and applied as biocatalytic continuous-flow microreactors for the transesterification of tributyrin as a model bio-oil component. Candida antarctica lipase was trapped within the pores of silic...
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We report the use of mesoporous silicon diimide gel as a basic stationary phase in thin layer chromatography for the characterisation and purification of acid-sensitive compounds. The gel is prepared by a simple sol-gel process and exhibits a large s...
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The synthesis and liquid crystalline behaviour of new comb-shaped methacrylate oligomers, derived from a new key intermediate in the synthesis of heterocyclic liquid crystals, i.e., 3-(4-bromophenyl)-5-(4-hydroxyphenyl)isoxazole, are reported. These...
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In order to inhibit the photocatalytic degradation of organic material supports induced by small titania (TiO₂) nanoparticles, highly photocatalytically active, commercially available P25-TiO₂ nanoparticles were first modified with a thin layer of (3...
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Small, carboxymethyl-starch-stabilised zinc oxide nanoparticles with a defined shape, size and morphology were prepared in situ in water at relatively low reaction temperatures using soluble carboxymethyl starch (CMS) as a combined crystallising, sta...
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The cross-linking of polymerisable liquid crystalline semiconductors is a promising approach to solution-processable, multilayer, organic photovoltaics. Here we demonstrate an organic bilayer photovoltaic with an insoluble electron-donating layer for...
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Differential scanning calorimetry in combination with atomic force microscopy is used to examine the phase separation of a blended nematic liquid crystalline electron-donor and crystalline perylene electron-acceptor mixture. Separate domains of donor...
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A simple, environmentally friendly and cost-effective synthetic method has been developed to prepare highly stable aqueous colloidal solutions of small (2-14 nm) silver nanoparticles using aminocellulose (AMC) as a combined reducing and capping reage...
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