It shouldn't come as much of a surprise, especially since the designer opened his estate to Kimye (and the clan) when he hosted a lunch in their honor the day before their wedding. And with a sartorial history that boasts a series of skin-skimming silhouettes, her choice in clothing came as no surprise, either. Kardashian showed off her best assets with a plunging teal blue Valentino gown with Hermes sandals.

Later that night, she traded in her gown in favor of a party-ready ensemble and graced a Couture Fashion Week event in Balmain separates—a sexy corded top and a leopard-print pencil skirt—with her go-to Hermes sandals. Fierce! Jenner also made quite a fierce impression in Balmain. She went for an olive-green gladiator-like frock complete with mesh Balmain booties.

Around The Web

1. The Kardashians at Couture Fashion Week

On the heels of Kendall Jenner's couture runway debut at Chanel, Kim Kardashian joined her younger half-sister and hit the Couture Fashion Week circuit starting with a front row seat at Valentino where she wore a plunging teal Valentino gown. That night, the duo made a fierce statement at a Couture Fashion Week party, both in Balmain-Kim in a sexy corded top and leopard-print pencil, Kendall in a gladiator-style frock.

Imaxtree

2. A Literal Take On Red Carpet Fashion

For their Viktor & Rolf Couture fall/winter 2014 collection, designers Viktor Horsting and Rolf Snoeren took inspiration from the red carpet-literally. They fashioned styles made from the heavy material, which resulted in cocoon-like silhouettes and dramatic bows.

4. Togas for Grown-Ups at Valentino Couture

Designers Maria Grazia Chiuri and Pierpaolo Piccioli traveled back in time (the Pre-Raphaelites movement, to be exact) and modernized Roman togas with languid shapes and rustic prints, complete with gladiator sandals and corset-like belts.

Catwalking/Getty Images

5. Conchita Wurst Makes Her Runway Debut

Conchita Wurst (Austrian singer Tom Neuwirth's stage name) made her runway debut at the Jean Paul Gaultier Couture fall/winter 2014 show when she closed as a Gothic bride to a tremendous round of applause.

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6. Pocket Transparency at Elie Saab Couture

It's common knowledge that an evening dress with pockets is infinitely superior to an evening dress without pockets. Designer Elie Saab knows this too-he didn't let sheer fabrics deter him from fashioning his confectionery confections with handy pockets.

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7. Making Statement at MMM Couture

An embellished lobster throw, a Japanese bomber-turned-gown, and an "I love you" heart-shaped bodice printed from a helium balloon, were just a few of the statement-making looks that made up the magnificent Maison Martin Margiela Couture fall/winter 2014 collection.

Dominique Charriau/WireImage

8. Kate Hudson Does Glitz & Glam At Armani Prive

Hudson took her front row seat at the Armani Prive fall/winter 2014 show in a blinding sparkle-studded top and matching plisse pants from the Armani Prive spring 2014 collection. Couture perfection!

11. Next Big Trend: Dresses Over Shorts

Thanks to Lagerfeld's say-so, dress-and-pant combos (or in this case, shorts) are officially in. A parade of zippy A-line dresses and coatdresses were layered over coordinating shorts (that had us reminiscing of biker shorts in their heyday) at the Chanel Couture fall/winter 2014 show.

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12. Kendall Jenner's Couture Debut

The younger half-sister to the Kardashian clan has booked the ultimate gig! The reality star-turned-model walked the Chanel Haute Couture show outfitted in a feathery plaid number, topped with a punky spiked 'do.

Pascal Le Segretain/Getty Images

13. Kristen Stewart's Impromptu Makeover

The actress surprised everyone at the Chanel Haute Couture show by pairing her daring ensemble with an even more daring pixie cut, which was set off by long, side-swept fringe.

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14. Pajama-Style Tops, Reimagined

Giambattista Valli brought the relaxed shirt to new, red carpet-ready heights when he paired them with full tea-length and ground-grazing ball skirts for the fall/winter 2014 couture line. Gorgeous!

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15. A Study In Contrasts at Dior Haute Couture

What started as a romantic line-up with pretty floral prints and centuries-old pannier-style silhouettes quickly transitioned into futuristic one-pieces and slick menswear-inspired tailoring.

19. Gowns, Pants & Gown-Pants At Atelier Versace

Donnatella Versace playfully mixed silhouettes for fall/winter 2014 couture, layering sweeping gowns over one-leg pants, and even going as far as fusing the two together to create dramatic gown-pant hybrids.

AKM-GSI

20. Jennifer Lopez Gives Us a Preview of Atelier Versace

The Atelier Versace fall/winter 2014 show kicked off Paris Haute Couture Fashion Week, but it was Jennifer Lopez who stole the spotlight. She wore a gown-pant hybrid from the collection (before it walked the runway), which featured a white strapless column with a thigh-high slit that revealed one beaded pant leg. Atelier Versace jewelry and silver Versace platform sandals served as the finishing touches.

Up Next:

The Kardashians at Couture Fashion Week

On the heels of Kendall Jenner's couture runway debut at Chanel, Kim Kardashian joined her younger half-sister and hit the Couture Fashion Week circuit starting with a front row seat at Valentino where she wore a plunging teal Valentino gown. That night, the duo made a fierce statement at a Couture Fashion Week party, both in Balmain-Kim in a sexy corded top and leopard-print pencil, Kendall in a gladiator-style frock.