Picric acid, also called 2,4,6-trinitrophenol, pale yellow, odourless crystalline solid that has been used as a military explosive, as a yellow dye, and as an antiseptic. Picric acid (from Greek pikros, “bitter”) was so named by the 19th-century French chemist Jean-Baptiste-André Dumas because of the extremely bitter taste of its yellow aqueous solution. Percussion or rapid heating can cause it (or its salts with heavy metals, such as copper, silver, or lead) to explode.

Picric acid was first obtained in 1771 by Peter Woulfe, a British chemist, by treating indigo with nitric acid. It was used as a yellow dye, initially for silk, beginning in 1849.

As an explosive, picric acid was formerly of great importance. The French began using it in 1886 as a bursting charge for shells under the name of melinite. By the time of the Russo-Japanese War, picric acid was the most widely used military explosive. Its highly corrosive action on the metal surfaces of shells was a disadvantage, however, and after World War I its use declined. Ammonium picrate, one of the salts of picric acid, is used in modern armour-piercing shells because it is insensitive enough to withstand the severe shock of penetration before detonating.

Picric acid has antiseptic and astringent properties. For medical use it is incorporated in a surface anesthetic ointment or solution and in burn ointments.

Picric acid is a much stronger acid than phenol; it decomposes carbonates and may be titrated with bases. In a basic medium, lead acetate produces a bright yellow precipitate, lead picrate.

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Picric acid was used as a shell explosive in Europe during the 1880s and carried through World War I on a large scale. Quantities of it were made in the United States, but the army and navy used mainly TNT.

...the development of propellants and explosives. Smokeless powders based on nitrocellulose (called ballistite in France and cordite in Britain) became the standard propellant, and compounds based on picric acid (under various names such as lyddite in Britain, melinite in France, and shimose in Japan) introduced modern high-explosive filling for shells. These more stable compounds demanded the...