Three novel self-catenated 4-connected uninodal (65·8)-mok metal–organic rotaxane frameworks (MORFs) containing cucurbit[6]uril were constructed from the in situ trans/cis-configuration (1:1) of rotaxanes by taking advantage of a d10 metal ion directed synthesis. It was revealed that the effect of hydrogen bonds and π–π stacking interactions play significant roles in the self-assembly process.