Todays, due to increase of population, growing of food, pharmaceutical, and oil industries the level of soil, water, and air pollution is at critical condition. Therefore, researchers are looking for new, simple, low cost, and rapid methods for determination and removal of pollutants from different environmental samples. Different analytical methods were suggested for this purpose. But due to trace amounts of pollutants in environment, their detection and determination are difficult. To solve this problem, solid phase extraction can be used for preconcentration of samples. In this article, application and influence of nanostructure sorbents like, nanofibers, carbon based and magnetic nanostructures on solid phase extraction are investigated.