Crystal size is the most striking feature of pegmatites, with crystals usually over 5 cm in size. Individual crystals over 10 metres across have been found, and the world's largest crystal was found within a pegmatite.Template:Citation needed

Similarly, crystal texture and form within pegmatitic rock may be taken to extreme size and perfection. Feldspar within a pegmatite may display exaggerated and perfect twinning, exsolution lamellae, and when affected by hydrous crystallization, macroscale graphic texture is known, with feldspar and quartz intergrown. Perthite feldspar within a pegmatite often shows gigantic perthitic texture visible to the naked eye.

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There is no single feature that is diagnostic to all pegmatites. Therefore, a list of criteria is used to distinguish them from other rocks. A very diagnostic feature are crystals that are larger than in normal igneous rocks. Pegmatites are usually small compared to typical intrusions. Their size is in the order of magnitude of 1 m to a few 100 m. Compared to typical igneous rocks they are rather inhomogeneous and usually show zones with different mineral assemblages. Crystal size and mineral assemblages are usually oriented parallel to the wall rock or even concentric for pegmatite lenses.[2]

Crystal growth rates in pegmatite must be incredibly fast to allow gigantic crystals to grow within the confines and pressures of the Earth's crust. For this reason, the consensus on pegmatitic growth mechanisms involves a combination of the following processes;

Low rates of nucleation of crystals coupled with high diffusivity to force growth of a few large crystals instead of many smaller crystals

High vapor and water pressure, to assist in the enhancement of conditions of diffusivity

High concentrations of fluxing elements such as boron and lithium which lower the temperature of solidification within the magma or vapor

Low thermal gradients coupled with a high wall rock temperature, explaining the preponderance for pegmatite to occur only within greenschist metamorphic terranes

Despite this consensus on likely chemical, thermal and compositional conditions required to promote pegmatite growth there are three main theories behind pegmatite formation;

pegmatites tend to occur in the aureoles of granites in most cases, and are usually granitic in character, often closely matching the compositions of nearby granites. Pegmatites thus represent exsolved granitic material which crystallises in the country rocks

pegmatite, in a few cases, could be explained by the action of hot alteration fluids upon a rock mass, with bulk chemical and textural change.

Metasomatism is currently not well favored as a mechanism for pegmatite formation and it is likely that metamorphism and magmatism are both contributors toward the conditions necessary for pegmatite genesis.

The mineralogy of a pegmatite is in all cases dominated by some form of feldspar, often with mica and usually with quartz, being altogether "granitic" in character. Beyond that, pegmatite may include most minerals associated with granite and granite-associated hydrothermal systems, granite-associated mineralisation styles, for example greisens, and somewhat with skarn associated mineralisation.

It is however impossible to quantify the mineralogy of pegmatite in simple terms because of their varied mineralogy and difficulty in estimating the modal abundance of mineral species which are of only a trace amount. This is because of the difficulty in counting and sampling mineral grains in a rock which may have crystals from centimeters to meters across.

Pegmatite is difficult to sample representatively due to the large size of the constituent mineral crystals. Often, bulk samples of some 50–60 kg of rock must be crushed to obtain a meaningful and repeatable result. Hence, pegmatite is often characterised by sampling the individual minerals which comprise the pegmatite, and comparisons are made according to mineral chemistry.

Geochemically, pegmatites typically have major element compositions approximating "granite", however, when found in association with granitic plutons it is likely that a pegmatite dike will have a different trace element composition with greater enrichment in large-ion lithophile (incompatible) elements, boron, beryllium, aluminium, potassium and lithium, uranium, thorium, cesium, et cetera.

Occasionally, enrichment in the unusual trace elements will result in crystallisation of equally unusual and rare minerals such as beryl, tourmaline, columbite, tantalite, zinnwaldite and so forth. In most cases, there is no particular genetic significance to the presence of rare mineralogy within a pegmatite, however it is possible to see some causative and genetic links between, say, tourmaline-bearing granite dikes and tourmaline-bearing pegmatites within the area of influence of a composite granite intrusion (Mount Isa Inlier, Queensland, Australia).

Pegmatites are the primary source of lithium either as spodumene, lithiophyllite or usually from lepidolite. The primary source for caesium is pollucite, a mineral from a zoned pegmatite. The majority of the world's beryllium is sourced from non-gem quality beryl within pegmatite. Tantalum, niobium, rare-earth elements are sourced from a few pegmatites worldwide, notably the Greenbushes Pegmatite. Bismuth, molybdenum and tin have been won from pegmatite, but this is not yet an important source of these metals.

Pegmatites can be classified according to the elements or mineral of interest, for instance "lithian pegmatite" to describe a Li-bearing or Li-mineral bearing pegmatite, or "boron pegmatite" for those containing tourmaline.

There is often no meaningful way to distinguish pegmatites according to chemistry due to the difficulty of obtaining a representative sample, but often groups of pegmatites can be distinguished on contact textures, orientation, accessory minerals and timing. These may be named formally or informally as a class of intrusive rock or within a larger igneous association.

While difficult to be certain of derivation of pegmatite in the strictest sense, often pegmatites are referred to as "metamorphic", "granitic" or "metasomatic", based on the interpretations of the investigating geologist.

Worldwide, notable pegmatite occurrences are within the major cratons, and within greenschist-facies metamorphic belts. However, pegmatite localities are only well recorded when economic mineralisation is found.

Within the metamorphic belts, pegmatite tends to concentrate around granitic bodies within zones of low mean strain and within zones of extension, for example within the strain shadow of a large rigid granite body. Similarly, pegmatite is often found within the contact zone of granite, transitional with some greisens, as a late-stage magmatic-hydrothermal effect of syn-metamorphic granitic magmatism. Some skarns associated with granites also tend to host pegmatites.

Aplite and porphyrydikes and veins may intrude pegmatites and wall rocks adjacent to intrusions, creating a confused sequence of felsic intrusive apophyses (thin branches or offshoots of igneous bodies) within the aureole of some granites.