Very early in the season Takumi Usui was walking by the back of this shop and he spots Misaki. She is very worried but after hearing Misaki's reasons for working, Takumi keeps her secret and chooses to annoy her by regularly visiting Misaki at work as a customer. Every day from then on Usui visits Maid Latte which annoys Misaki very much. The Moron Trio also try to attend every day that they have money.

One night, when Misaki is closing the café all by herself, she is caught by two stalkers, who are none other than two of her regular customers. Usui hears the commotion at Maid Latte and heads there to rescue Misaki. The stalkers, having restrained Misaki with handcuffs, think that the "real Misaki" is a submissive woman, but they get a rude surprise when she breaks out of her handcuffs and reveals the "real Misaki": a very angry woman who proceeds to pound both of them using her Aikido. When Usui finally arrives, he can only do nothing but laugh at what he sees.

The Miyabigaoka Student Council returns as they, through the powerful dining company owned by Maki's family, aim to buy Maid Latte in a hostile takeover, and plan to replace it with a butler café. The only way for Misaki to stop this is to join the male-only footman auditions that Maki, through his "boss" Tora, set up, in disguise. However, Maki, moved by Misaki's speech, decides to call off buying Maid Latte and move his butler café elsewhere.

In Episode 24 (Latte Magic Mellow Mellowing), Maid Latte maids are cosplaying as characters from the anime “Maid Witches”, so Satsuki gives Misaki the anime’s DVDs to do research and get into character.

In episode 25, Hinata, Misaki, and Usui, the café hosts a Fortune Telling Day, with Erika as the fortune teller. Erika reads Hinata’s and Usui's relationship with Misaki with the former “flat as a paper balloon” and the latter “incompatible like fire and water unless he tries harder”.

In chapter 70, before the party, Satsuki announces a match between Takumi and Sakuya. If Sakuya manages to beat Takumi, then he will be recruited as a full-time employee and the customers will vote for the food.