Cyanobacteria frequently dominate the freshwater phytoplankton community in eutrophic waters. Cyanotoxins can be classified according to toxicity as neurotoxin (Anatoxin-a, Anatoxin-a(s), Saxitoxins) or hepatotoxin (microcystins, nodularin, cylindrospermopsin). Microcystins are present within cyanobacterial cells generally, and they are extracted by the damage of cell membrane. It has been reported that cyanotoxins caused adverse effects and they are acculmulated in aquatic oganisms of lake, river and ocean. In natural, microcystins are removed by biodegradation of microorganisms and/or feeding of predators. However, in process of water treatment, the use of copper sulfate to remove algal cells caused extraction of a mess of microcystins. Microcysitns are removed by physical, chemical and biological methods according to reports. The reduction of nutrients (N and P) inflow is basic method of prevention of cyanobacteria bloom formation. However, it is less effective than investigation because nutrients already present in the eutrophic lake. In natural lake, cyanobacteria bloom are not formed because macrophytes invade from coastal lake by eutrophication. Therefore, a coastal lake has to recover to prevent of cyanobacteria bloom formation.

Alumina-based catalysts with different Ce loadings were studied in the decomposition of using microwave heating system. Heating material of microwave system used Silicon Carbide. The crystallographic phases of catalysts were investigated by XRD and decomposition rates of were examined by GC-TCD. The catalysts of 10 wt% Ce modified showed higher decomposition rate than un-modified for reaction temperature. The k value of catalysts shows the order of <<. XRD patterns of were no difference before and after the reaction and showed phases. With the increase in Ce loadings, , of XRD peaks was observed. The results was indicated that Ce modifed than un-modifed was decreased reaction temperature to with same decomposition rate. Also the appropriated cerium sulfate loadings on were 5~10 wt%.

This research conducts both experimental evaluation and resident's assessment of zero food waste system (ZFWS) in multifamily housing estates in order to explore the feasibility of ZFWS embedded in fermentation and extinction technology utilizing wood chips turned into fertilizer. Having been established in a multifamily housing estate, ZEFWS was proved to be functional and effective. During the 3-month experimental period, the weight between infused food waste and its reactor was reduced significantly enough, and the chemical analysis showed that the concentration of organic compounds went from 87.9% to 75.8%, decreased from 69.7% to 45.5%, NaCl rose from 0.2% to 0.5%, pH increased from 4.6 to 7.8, and ATP escalated from 505.3 nmol/L to 723.5 nmol/L. Also, the chemical analysis of the output in the experimentation indicated adequacy of the organic fertilizer. In the self-administered questionnaire survey for residents participating in the field project, almost all the respondents viewed that ZFWS can compete with conventional food waste disposal methods and an idealistic way to upcycling food waste into fertilizer.

Effect of electrode spacing on the performance of microbial electrolysis cells(MECs) for treating sewage sludge was investigated through lab scale experiment. The reactors were equipped with two pairs of electrodes that have a different electrode spacing (16, 32 mm). Shorter electrode distance improved the overall performance of MEC system. With the 16 mm of electrode distance, the current density was and methane production was , which were higher than those obtained with 32 mm of electrode spacing (, ). The COD removal was in the range of 34~40%, and the VSS reduction ranged 32~38%. As the current production increased, VSS reduction and methane production were increased possibly due to the improved bioelectrochemical performance of the system. Methane production was more affected by current density than VSS reduction. These results imply that the reducing the electrode spacing can enhance the methane production and recovery from sewage sludge with the decreased internal resistance, however, it was not able to improve VSS reduction of sewage sludge.

A biofilm filtration for the removal of gaseous pollutants has been recognized as a process with a complex interaction between the gas flow characteristics and the process operating variables. This study aims to develop an one dimensional dynamic numerical model which can be utilized as a tool for the analysis of biofilm filtration process operated in plug flow mode. Since, in a plug flow system, minor environmental changes in a gaseous unit process cause a drastic change in reaction and the interaction between the pollutants is an influencing factor, plug flow system was generalized in developing the model. For facilitation of the model development, dispersion was simplified based on the principles of material balance. Several reactions such as competition, escalation, and control between the pollutants were included in the model. The applicability of the developed model was evaluated by taking the calibration and verification steps on the experimental data performed for the removal of BTX at both low and high flow concentration. The model demonstrated a correlation coefficient () greater than 0.79 under all the experimental conditions except for the case of toluene at high flow condition, which suggested that this model could be used for the generalized gaseous biofilm plug flow filtration system. In addition, this model could be a useful tool in analyzing the design parameters and evaluating process efficiency of the experiments with substantial amount of complexity and diversity.

This study was carried out to evaluate the optimum operational condition of Semi-continuously Fed and Mixed Reactor (SCFMR) to treat the dairy cow manure and saw dust mixture. Step-wise increase in organic loading rates (OLRs) or decrease in hydraulic retention times (HRTs) were utilized until the biogas volume became significantly decreased at mesophilic temperature (). The optimum operating condition of the SCFMR fed with TS 13% dairy cow manure and saw dust mixture was found to be an HRTs of 25 days and its corresponding OLRs of . At this condition the biogas and methane production rates were 1.44 v/v-d and 1.12 v/v-d (volume of biogas per volume of reactor per day), respectively and the TVS removal efficiency of 37% was achieved. The successful operation with such a high OLR was due to the high reactor alkalinity concentration of 14,500~15,600 mg/L as as a result of the characteristic of the original substrate, dairy cow manure and saw dust mixture whose alkalinity was more than 8,000 mg/L as . The parameters for the reactor stability, the ratios of volatile acids and alkalinity concentrations (V/A) and the ratio of propionic acid and acetic acid concentrations (P/A) appeared to be 0.11 and 0.43, respectively, that were greatly stable in operation. Free ammonia toxicity was not experienced due to the long term acclimation by the reactor TS content ranged 7.2~10.4% during the entire operational period.

Degradation of 2,6-Dichlorophenol (DCP) using liquid ferrate(VI) synthesized by wet oxidation method has been studied. Several parameters such as pH (acid, base and neutral), DCP initial concentration, ferrate dosage, and temperature have been examined to determine the optimal experimental conditions. The ferrate(VI) has useful properties such as strong oxidizing power and selectivity and generates a non-toxic end product, Fe(III). Ferrate ion reduced rapidly to Fe(III) and oxygen in acidic and neutral conditions. The experimental results showed the higher DCP degradation efficiency in the neutral condition than in the acidic and basic conditions. The oxidation of DCP strongly depended on the dosage of ferrate added to the reactor and DCP initial concentration. With increasing of ferrate dosage the degradation efficiency of DCP increased, while the degradation efficiency of DCP decreased with increasing of DCP initial concentration. The effect of temperature has been tested at 4 different levels (10, 25, 35, and ). The optimal temperature was obtained in and degradation efficiency decreased as the temperature increased in the range from to . The DCP degradation pathways were studied and proposed based on the intermediate products identified by GC/MS analysis.