Wearables may get boost from boron-infused graphene

Rice U. researchers flex muscle of laser-written microsupercapacitors

HOUSTON – (May 18, 2015) – A microsupercapacitor designed by scientists at Rice University that may find its way into personal and even wearable electronics is getting an upgrade. The laser-induced graphene device benefits greatly when boron becomes part of the mix.

The Rice lab of chemist James Tour uses commercial lasers to create thin, flexible supercapacitors by burning patterns into common polymers. The laser burns away everything but the carbon to a depth of 20 microns on the top layer, which becomes a foam-like matrix of interconnected graphene flakes.

By first infusing the polymer with boric acid, the researchers quadrupled the supercapacitor’s ability to store an electrical charge while greatly boosting its energy density.

The simple manufacturing process may also be suitable for making catalysts, field emission transistors and components for solar cells and lithium-ion batteries, they said.

The research is detailed in the American Chemical Society journal ACS Nano.

Capacitors charge quickly and release their energy in a burst when needed, as in a camera flash. Supercapacitors add the high-energy capacity of batteries to the package and have potential for electric vehicles and other heavy-duty applications. The potential to shrink them into a small, flexible, easily produced package could make them suitable for many more applications, according to the researchers.

In the earlier work, the team led by Rice graduate student Zhiwei Peng tried many polymers and discovered a commercial polyimide was the best for the process. For the new work, the lab dissolved boric acid into polyamic acid and condensed it into a boron-infused polyimide sheet, which was then exposed to the laser.

The two-step process produces microsupercapacitors with four times the ability to store an electrical charge and five to 10 times the energy density of the earlier, boron-free version. The new devices proved highly stable over 12,000 charge-discharge cycles, retaining 90 percent of their capacitance. In stress tests, they handled 8,000 bending cycles with no loss of performance, the researchers reported.

Tour said the technique lends itself to industrial-scale, roll-to-roll production of microsupercapacitors. “What we’ve done shows that huge modulations and enhancements can be made by adding other elements and performing other chemistries within the polymer film prior to exposure to the laser,” he said.

“Once the laser exposes it, those other elements perform new chemistries that really increase the supercapacitor’s performance. This is a step in making these even more amenable for industrial applications.”

Co-authors of the paper are Rice graduate students Ruquan Ye, Dante Zakhidov and Yilun Li; alumni Jason Mann, a research chemist at Exxon Chemical, and Jian Lin, an assistant professor at the University of Missouri; and Preston Smalley, a student at Second Baptist School, Houston.

Rice University scientists made this supercapacitor with interlocked “fingers” using a laser and writing the pattern into a boron-infused sheet of polyimide. The device may be suitable for flexible, wearable electronics. (Credit: Tour Group/Rice University)

Rice University scientists made this supercapacitor with interlocked “fingers” using a laser and writing the pattern into a boron-infused sheet of polyimide. The device may be suitable for flexible, wearable electronics. (Credit: Tour Group/Rice University)

An electron microscope image shows the foamy surface of a polyimide treated with boron and burned with a laser to create a lattice of graphene flakes. The material shows promise as a highly efficient, flexible energy storage device for electronics. (Credit: Tour Group/Rice University)

An electron microscope image shows the edges of graphene flakes burned into a polymer sheet with a laser by scientists at Rice University. The electronically active edges make the material suitable for use as a microsupercapacitor. (Credit: Tour Group/Rice University)

A microsupercapacitor designed by scientists at Rice University may find its way into personal and even wearable electronics. The lab upgraded its laser-induced graphene device by treating the raw polymer material in advance with boron. (Credit: Tour Group/Rice University)

Located on a 300-acre forested campus in Houston, Rice University is consistently ranked among the nation’s top 20 universities by U.S. News & World Report. Rice has highly respected schools of Architecture, Business, Continuing Studies, Engineering, Humanities, Music, Natural Sciences and Social Sciences and is home to the Baker Institute for Public Policy. With 3,888 undergraduates and 2,610 graduate students, Rice’s undergraduate student-to-faculty ratio is 6-to-1. Its residential college system builds close-knit communities and lifelong friendships, just one reason why Rice is ranked among some of the top schools for best quality of life by the Princeton Review and for best value among private universities by Kiplinger’s Personal Finance. To read “What they’re saying about Rice,” go to http://tinyurl.com/AboutRiceU.