Yes there is a way using the virtual button layout. If you are familiar with the sixaxis application you will know about the mouse emulation. Very handy for navigating menus instead of touching. But for some unknown reason fifa 14 doesn't support this. No idea why. But fifa 14 for Android and iPhone will be getting full gamepad support at some point like it's console brothers. Is just a matter of when. But it will be in the next update that's for sure.

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