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2014 ACM Awards: See the Full List of Winners!

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It was all about the duets at the 2014 Academy of Country Music Awards.

While awards show co-host Blake Shelton and Shakira performed their single, "Medicine," Sunday night for the first time, husband and wife duo Faith Hill and Tim McGraw got nostalgic with "Meanwhile Back at Mama's."

Dierks Bentley and Sheryl Crow also hit the stage at the MGM Grand Garden Arena in Las Vegas to perform "I Hold on."

Tim McGraw and Miranda Lambert were the top nominated artists going into the show, with both up for seven awards, but only one walked away the big winner of the night.

The "Mama's Broken Heart" songstress took home three awards, including Female Vocalist of the Year and Vocal Event of the Year for "We Were Us" with Keith Urban, while McGraw took home Video of the Year for "Highway Don't Care" with Taylor Swift and Urban.

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