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Abstract:

A high efficient white emission light emitting element having peak
intensity in each wavelength region of red, green, and blue is provided.
Specifically, a white emission light emitting element having an emission
spectrum that is independent of current density is provided. A first
light emitting layer 312 exhibiting blue emission and a second light
emitting layer 313 containing a phosphorescent material that generates
simultaneously phosphorescent emission and excimer emission are combined.
In order to derive excimer emission from the phosphorescent material, it
is effective to disperse a phosphorescent material 323 having a high
planarity structure such as platinum complex at a high concentration of
at least 10 wt % to a host material 322. Further, the first light
emitting layer 312 is provided to be in contact with the second light
emitting layer 313 at the side of an anode. Ionization potential of the
second light emitting layer 313 is preferably larger by 0.4 eV than that
of the first light emitting layer 312.

Claims:

1. A light emitting device comprising: an anode and a cathode; a first
light emitting layer between the anode and the cathode; and a second
light emitting layer between the first light emitting layer and the
cathode, the second light emitting layer containing a host material and a
phosphorescent material, wherein the phosphorescent material is dispersed
to the host material at a concentration of at least 15 wt %.

3. The light emitting device according to claim 1, wherein the
phosphorescent material has a high planarity structure.

4. The light emitting device according to claim 1, wherein the
phosphorescent material comprises a metal.

5. The light emitting device according to claim 4, wherein the metal is
platinum.

6. The light emitting device according to claim 1, wherein the
phosphorescent material is an organic metal complex.

7. The light emitting device according to claim 6, wherein the organic
metal complex is an organic metal complex with platinum as a central
metal.

8. The light emitting device according to claim 7, wherein the organic
metal complex with platinum as the central metal is selected from
##STR00002##

9. The light emitting device according to claim 1, wherein the first
light emitting layer has an emission spectrum with maximum intensity in a
wavelength region of at least 400 nm and at most 500 nm.

10. The light emitting device according to claim 1, wherein the
phosphorescent material has an emission spectrum with at least two
intensity peaks at a wavelength region of at least 500 nm and at most 700
nm, and at least one of the intensity peaks corresponds to excimer
emission.

11. The light emitting device according to claim 1, wherein the first
light emitting layer has an emission spectrum with maximum intensity in a
wavelength region of at least 400 nm and at most 500 nm, the
phosphorescent material has an emission spectrum with at least two
intensity peaks at a wavelength region of at least 500 nm and at most 700
nm, and at least one of the intensity peaks in the emission spectrum of
the phosphorescent material corresponds to excimer emission.

12. The light emitting device according to claim 1, wherein the second
light emitting layer is capable of simultaneously generating
phosphorescent emission from the phosphorescent material and excimer
emission from the phosphorescent material.

16. An electric appliance comprising the light emitting device according
to claim 1.

17. A semiconductor device comprising the light emitting device according
to claim 1.

18. A light emitting device comprising: an anode and a cathode; a first
light emitting layer between the anode and the cathode, the first light
emitting layer comprising a first host material and a guest material; and
a second light emitting layer between the first light emitting layer and
the cathode, the second light emitting layer containing a second host
material and a phosphorescent material, wherein the phosphorescent
material is dispersed to the second host material at a concentration of
at least 15 wt %.

20. The light emitting device according to claim 18, wherein the
phosphorescent material has a high planarity structure.

21. The light emitting device according to claim 18, wherein the
phosphorescent material comprises a metal.

22. The light emitting device according to claim 21, wherein the metal is
platinum.

23. The light emitting element according to claim 18, wherein the
phosphorescent material is an organic metal complex.

24. The light emitting device according to claim 23, wherein the organic
metal complex is an organic metal complex with platinum as a central
metal.

25. The light emitting device according to claim 24, wherein the organic
metal complex with platinum as the central metal is selected from
##STR00003##

26. The light emitting device according to claim 18, wherein the first
light emitting layer has an emission spectrum with maximum intensity in a
wavelength region of at least 400 nm and at most 500 nm.

27. The light emitting device according to claim 18, wherein the
phosphorescent material has an emission spectrum with at least two
intensity peaks at a wavelength region of at least 500 nm and at most 700
nm, and at least one of the intensity peaks corresponds to excimer
emission.

28. The light emitting device according to claim 18, wherein the first
light emitting layer has an emission spectrum with maximum intensity in a
wavelength region of at least 400 nm and at most 500 nm, the
phosphorescent material has an emission spectrum with at last two
intensity peaks at a wavelength region of at last 500 nm and at most 700
nm, and at least one of the intensity peaks in the emission spectrum of
the phosphorescent material corresponds to excimer emission.

29. The light emitting device according to claim 18, wherein the second
light emitting layer is capable of simultaneously generating
phosphorescent emission from the phosphorescent material and excimer
emission from the phosphorescent material.

30. The light emitting device according to claim 18, wherein the guest
material is capable of exhibiting blue emission.

34. An electric appliance comprising the light emitting device according
to claim 18.

35. A semiconductor device comprising the light emitting device according
to claim 18.

36. A light emitting device comprising: a first electrode; a first light
emitting layer over the first electrode, a second light emitting layer
over the first light emitting layer, the second light emitting layer
containing a host material and a phosphorescent material, and a second
electrode over the second light emitting layer, wherein the
phosphorescent material is dispersed to the host material at a
concentration of at least 15 wt %.

38. The light emitting device according to claim 36, wherein the
phosphorescent material has a high planarity structure.

39. The light emitting device according to claim 36, wherein the
phosphorescent material comprises a metal.

40. The light emitting device according to claim 39, wherein the metal is
platinum.

41. The light emitting device according to claim 36, wherein the
phosphorescent material is an organic metal complex.

42. The light emitting device according to claim 41, wherein the organic
metal complex is an organic metal complex with platinum as a central
metal.

43. The light emitting device according to claim 42, wherein the organic
metal complex with platinum as the central metal is selected from
##STR00004##

44. The light emitting device according to claim 36, wherein the first
light emitting layer has an emission spectrum with maximum intensity in a
wavelength region of at least 400 nm and at most 500 nm.

45. The light emitting device according to claim 36, wherein the
phosphorescent material has an emission spectrum with at least two
intensity peaks at a wavelength region of at least 500 nm and at most 700
nm, and at least one of intensity peaks corresponds to excimer emission.

46. The light emitting device according to claim 36, wherein the first
light emitting layer has an emission spectrum with maximum intensity in a
wavelength region of at least 400 nm and at most 500 nm, the
phosphorescent material has an emission spectrum with at least two
intensity peaks at a wavelength region o at least 500 nm and at most 700
nm, and at least one of the intensity peaks in the emission spectrum of
the phosphorescent material corresponds to excimer emission.

47. The light emitting device according to claim 36, wherein the second
light emitting layer is capable of simultaneously generating
phosphorescent emission from the phosphorescent material and excimer
emission from the phosphorescent material.

51. An electric appliance comprising the light emitting device according
to claim 36.

52. A semiconductor device comprising the light emitting device according
to claim 36.

53. A light emitting device comprising: a first electrode; a first light
emitting layer over the first electrode, the first light emitting layer
containing a first host material and a guest material; a second light
emitting layer over the first light emitting layer, the second light
emitting layer containing a second host material and a phosphorescent
material, and a second electrode formed over the second light emitting
layer, wherein the phosphorescent material is dispersed to the second
host material at a concentration of at least 15 wt %.

55. The light emitting device according to claim 53, wherein the
phosphorescent material has a high planarity structure.

56. The light emitting device according to claim 53, wherein the
phosphorescent material comprises a metal.

57. The light emitting device according to claim 56, wherein the metal is
platinum.

58. The light emitting element according to claim 53, wherein the
phosphorescent material is an organic metal complex.

59. The light emitting device according to claim 58, wherein the organic
metal complex is an organic metal complex with platinum as a central
metal.

60. The light emitting device according to claim 59, wherein the organic
metal complex with platinum as the central metal is selected from
##STR00005##

61. The light emitting device according to claim 53, wherein the first
light emitting layer has an emission spectrum with maximum intensity in a
wavelength region of at least 400 nm and at most 500 nm.

62. The light emitting device according to claim 53, wherein the
phosphorescent material has an emission spectrum with at least two
intensity peaks at a wavelength region of at least 500 nm and at most 700
nm, and at least one of the intensity peaks corresponds to excimer
emission.

63. The light emitting device according to claim 53, wherein the first
light emitting layer has an emission spectrum with maximum intensity in a
wavelength region of at least 400 nm and at most 500 nm, the
phosphorescent material has an emission spectrum with at last two
intensity peaks at a wavelength region of at last 500 nm and at most 700
nm, and at least one of the intensity peaks in the emission spectrum of
the phosphorescent material corresponds to excimer emission.

64. The light emitting device according to claim 53, wherein the second
light emitting layer is capable of simultaneously generating
phosphorescent emission from the phosphorescent material and excimer
emission from the phosphorescent material.

65. The light emitting device according to claim 53, wherein the guest
material is capable of exhibiting blue emission.

69. An electric appliance comprising the light emitting device according
to claim 53.

70. A semiconductor device comprising the light emitting device according
to claim 53.

Description:

CROSS-REFERENCE TO RELATED APPLICATIONS

[0001] This application is a continuation of U.S. application Ser. No.
10/793,861, filed Mar. 8, 2004, now allowed, which claims the benefit of
a foreign priority application filed in Japan as Serial No. 2003-072275
on Mar. 17, 2003, both of which are incorporated by reference.

BACKGROUND OF THE INVENTION

[0002] 1. Field of the Invention

[0003] The present invention relates to a light emitting element that
comprises an anode, a cathode, and a layer containing an organic compound
(hereinafter, electroluminescent layer) that generates light by applying
electric field through the electrodes; and a light emitting device that
comprises the light emitting element. Specifically, the present invention
relates to a light emitting element that exhibits white emission and a
full color light emitting device comprising the light emitting element.

[0004] 2. Related Art

[0005] A light emitting element emits light when electric field is applied
thereto. The emission mechanism is a carrier injection type. That is, by
applying voltage through a pair of electrodes that interposes an
electroluminescent layer therebetween, electrons injected from a cathode
and holes injected from an anode are recombined within the
electroluminescent layer to form molecules in excited states
(hereinafter, excited molecule), and the excited molecules return to the
ground state while radiating energy to emit photon.

[0006] There are two excited states possible from organic compounds, the
singlet state and the triplet states. Light emission from the singlet
state is referred to as fluorescence and the same from the triplet state
is referred to as phosphorescence.

[0007] In such light emitting element, an electroluminescent layer is
generally formed to have a thickness of below 1 μm. Further, since a
light emitting element is a self-luminous element in which an
electroluminescent layer emits photon, a back light used for the
conventional liquid crystal display device is unnecessary. Therefore, a
light emitting element has a great advantage of being manufactured to
have a ultra thin film thickness and light weight.

[0008] In the case of an electroluminescent film with a thickness of
approximately 100 nm, the time between the injection of carriers and
their recombination is about several ten nanoseconds considering the
carrier mobility. Hence, the time required for the process of injecting
carriers and emitting light of the electroluminescent layer is on the
order of microsecond. Thus, an extremely high response speed is one of
the advantages thereof.

[0009] Further, since a light emitting element is carrier injection type,
it can be driven by a direct current voltage, thereby noise is hardly
generated. With respect to a drive voltage, an electroluminescent layer
is formed into a uniform ultra thin film having a thickness of
approximately 100 nm, and a material for an electrode is selected to
reduce a carrier injection barrier. Further, a hetero structure
(two-layers structure) is introduced. Accordingly, a sufficient luminance
of 100 cd/m2 can be obtained at an applied voltage of 5.5V
(reference 1: C. W. Tang and S. A. VanSlyke, Applied Physics Letters,
vol. 51, No. 12, pp. 913-915 (1987)).

[0010] A light emitting element has been attracted attention as a next
generation's device for a flat panel display in terms of the thin
thickness and light weight, the high response speed, the direct low
voltage operation, or the like. In addition, a light emitting element can
be used effectively as the device for the display screen of a portable
electric appliance in terms of the self luminous type, the wide viewing
angle, and the high level of visibility.

[0011] Wide variations of emission color is also one of the advantages of
a light emitting element. Richness of color is resulted from the
multiplicity of an organic compound itself. That is, an organic compound
is flexible enough to be developed to various materials by designing
molecules (such as introducing substituent). Accordingly, a light
emitting element is rich in color.

[0012] From these viewpoints, it would not be an overstatement to say that
the biggest application areas of a light emitting element is a full color
flat panel display device. Various means for full colorization have been
developed in view of characteristics of a light emitting element. At
present, there are three primary methods of forming the structure of a
full color light emitting device by using a light emitting element.

[0013] First, the method that light emitting elements having three primary
colors, that is, red (R), green (G), and blue (B) are patterned,
respectively, by shadow mask technique to serve them as pixels
(hereinafter, RGB method). Second, a blue light emitting element is used
as a light emission source, and the blue emission is converted into green
or red by color changing material (CCM) made from phosphorescent material
to obtain three primary colors (hereinafter, CCM method). Third, a white
light emitting element is used as a light emission source, and a color
filter (CF) used for a liquid crystal display device or the like is
provided to obtain three primary colors (hereinafter, CF method).

[0014] Of these methods, the CCM method and the CF method do not require
such elaborate patterning required in the RGB method since a light
emitting element used in the CCM method and the CF method exhibits single
color such as white (CCM method) or blue (CF method). The CCM materials
or color filter can be made by the conventional photolithography
technique without complicated processes. Further, in addition to these
advantages with respect to processes, the change in luminance with time
of each color is uniform since only one kind of device is used.

[0015] However, in case of adopting the CCM method, there has been a
problem in red color since color conversion efficiency of from blue to
red is poor in principle. In addition, there has been a problem that the
contrast becomes deteriorated since a color conversion material itself is
fluorescent so that light is generated in pixels due to outside light
such as sunlight. CF method has no such problems since a color filter is
used as well as the conventional liquid display device.

[0016] Accordingly, although the CF method has comparative few
disadvantages, the CF method has a problem that a high efficient white
light emitting element is indispensable to the CF method since a great
deal of light is absorbed into a color filter. A mainstream white light
emitting element is the device that combines complementary colors (such
as blue and yellow) (hereinafter, two wavelengths white light emitting
device) instead of white color having the peak intensity in each
wavelength of R, G, and B (reference 2: Kido et al., "46th Applied
Physics Relation Union Lecture Meeting" p1282, 28a-ZD-25 (1999)).

[0017] However, considering a light emitting device combined with a color
filter, a white light emitting element having an emission spectrum with
the peak intensity in each wavelength of R, G, and B (hereinafter, three
wavelengths white light emitting device) is desirable instead of the two
wavelengths white light emitting device, which was reported in the
reference 2.

[0018] Such three wavelengths white light emitting device has been
disclosed in some references (reference 3: J. Kido at al., Science, vol.
267, 1332-1334 (1995)). However, such three wavelengths white light
emitting device is inferior to the two wavelengths white light emitting
device in terms of luminous efficiency, consequently, significant
improvement is required. In addition, it is difficult for the three
wavelengths white light emitting device to obtain stable white emission
due to change in color with time or change in spectrum depending on the
current density.

SUMMARY OF THE INVENTION

[0019] In view of the foregoing, it is an object of the present invention
is to provide a high efficient white emission device having the emission
peak intensity in each wavelength region of red, green, and blue. A
further object of the invention is to provide a white emission device
having the emission spectrum, which does not depend on the current
density.

[0020] An even further object of the invention is to provide a light
emitting device, which operates at lower power and hardly has color shift
compared with the conventional light emitting device by manufacturing a
light emitting device using the light emitting element.

[0021] The inventor found out the means for solving the problems after
their earnest consideration by combining a first light emitting layer
exhibiting blue emission and a second light emitting layer exhibiting
simultaneously both phosphorescent emission and excimer emission.

[0022] A phosphorescent material can convert the triplet excited state to
light emission, that is, generate phosphorescent emission. In a light
emitting element, it is considered that singlet excited state and triplet
excited state are generated in the ratio of 1:3. Accordingly, it is known
that high light emission efficiency can be achieved by using a
phosphorescent material.

[0023] According to the invention, since a second light emitting layer is
formed by a phosphorescent material that can generate simultaneously both
phosphorescent emission and excimer emission, the second light emitting
layer can exhibit light emission having at least two peaks intensity.
Excimer emission is at the longer wavelength side compared with the
phosphorescent emission. Therefore, by designing the two peaks of
intensity to be in the wavelength region of from green to red, a high
efficient light emitting device having the peak intensity in each
wavelength region of red, green, blue can be obtained.

[0024] The constitution of the invention is a light emitting element that
comprises, between an anode and a cathode, a first light emitting layer
exhibiting blue emission; and a second light emitting layer containing a
phosphorescent material, and generating phosphorescent emission from the
phosphorescent material and excimer emission from the phosphorescent
material, simultaneously.

[0025] A first light emitting layer may contain a host material dispersed
with a guest material exhibiting blue emission. Therefore, the
constitution of the invention is a light emitting element that comprises,
between an anode and a cathode, a first light emitting layer containing a
host material dispersed with a guest material exhibiting blue emission;
and a second light emitting layer containing a phosphorescent material,
and generating phosphorescent emission from the phosphorescent material
and excimer emission from the phosphorescent material, simultaneously.

[0026] The inventor found out that it is effective to disperse a
phosphorescent material to a host material at a high concentration of at
least 10 wt % in order to derive excimer emission from the phosphorescent
material. Therefore, the constitution of the invention is a light
emitting element that comprises, between an anode and a cathode, a first
light emitting layer exhibiting blue emission; and a second light
emitting layer containing a host material dispersed with a phosphorescent
material at concentration of at least 10 wt %, and generating
phosphorescent emission from the phosphorescent material and excimer
emission from the phosphorescent material, simultaneously.

[0027] In addition, the first light emitting layer may contain a host
material dispersed with a guest material exhibiting blue emission.
Therefore, the constitution of the invention is a light emitting element
that comprises, between an anode and a cathode, a first light emitting
layer containing a first host material dispersed with a first guest
material exhibiting blue emission; and a second light emitting layer
containing a second host material dispersed with a phosphorescent
material at concentration of at least 10 wt %, and generating
phosphorescent emission from the phosphorescent material and excimer
emission from the phosphorescent material, simultaneously.

[0028] In a light emitting element according to above constitutions, the
first light emitting layer is provided to be in contact with the second
light emitting layer at a side of the anode, and ionization potential of
the second light emitting layer is larger by at least 0.4 eV than that of
the first light emitting layer.

[0029] In case that the first light emitting layer contains a host
material dispersed with a guest material exhibiting blue emission, the
first light emitting layer is preferably provided to be in contact with
the second light emitting layer at a side of the anode, and ionization
potential of the second light emitting layer is preferably larger by at
least 0.4 eV than that of the host material in a thin film shape.

[0030] In case that the second light emitting layer contains a host
material dispersed with a guest material exhibiting blue emission, the
first light emitting layer is preferably provided to be in contact with
the second light emitting layer at a side of the anode, and ionization
potential of the host material in a thin film shape is preferably larger
by at least 0.4 eV than that of the first light emitting layer.

[0031] In case that the first light emitting layer contains a host
material dispersed with a guest material exhibiting blue emission and in
case that the second light emitting layer contains a host material
dispersed with a guest material exhibiting blue emission, the first light
emitting layer is preferably provided to be in contact with the second
light emitting layer at a side of the anode, and ionization potential of
the second host material in a thin film shape is preferably larger by at
least 0.4 eV than that of the first host material in a thin film shape.

[0032] In the above constitution of the invention, an emission spectrum
with maximum intensity of the first light emitting device is preferably
in a wavelength region of at least 400 and at most 500 nm. In addition,
the phosphorescent material has an emission spectrum with at least two
peaks intensity at a region of at least 500 and at most 700 nm, and
either at least the two peaks is excimer emission, preferably. Further,
it is effective to combine the above emission for obtaining excellent
white emission.

[0033] In the invention, an organic metal complex with platinum as a
central metal is preferably used as the phosphorescent material.

[0034] By manufacturing a light emitting device using the light emitting
element according to the invention, a light emitting device, which
operates at low power and has hardly color shift, can be provided.
Therefore the invention includes a light emitting device using the light
emitting element according to the invention.

[0035] Especially, it is effective to apply the light emitting element
according to the invention to a full color light emitting device with a
color filter since the light emitting element can achieve high efficient
white emission having the peak in each red, green and blue wavelength.

[0036] As used herein, the term "light emitting device" refers to an image
display device, or the like. Further, a module having a light emitting
element attached with a connector such as FPC (Flexible Printed Circuit),
TAB (Tape Automated Bonding), or TCP (Tape Carrier Package); a module
having TAB or TCP provided with a printed wiring board; and a module
having a light emitting element installed directly with IC (Integrated
Circuit) by COG (Chip On Glass) are all included in the light emitting
device.

BRIEF DESCRIPTION OF THE DRAWINGS

[0037] FIGS. 1A and 1B are band diagrams of a light emitting element
according to the present invention;

[0038] FIGS. 2A and 2B are band diagrams of a light emitting element
according to the invention;

[0039]FIG. 3 shows a device configuration of a light emitting element
according to the invention;

[0040]FIG. 4 shows a device configuration of a light emitting element
according to the invention;

[0041]FIG. 5 shows specifically a device configuration of a light
emitting element according to the invention;

[0042] FIGS. 6A and 6B are schematic views of a light emitting device
according to the invention;

[0043] FIGS. 7A to 7G show examples of electric appliances using a light
emitting device according to the invention;

[0050] Hereinafter, embodiments of the present invention will be described
in detail with reference to the principal of operation and the specific
examples of the device configuration. Although the present invention will
be fully described by way of examples with reference to the accompanying
drawings, it is to be understood that various changes and modifications
will be apparent to those skilled in the art. Therefore, unless otherwise
such changes and modifications depart from the scope of the present
invention hereinafter described, they should be construed as being
included therein. Either electrode of a light emitting element may be
transparent since light is extracted from the either electrode.
Therefore, not only the conventional configuration that light is
extracted from a substrate provided with a transparent electrode, but
also the configuration that light is extracted from the side opposing to
the substrate or the configuration that light is extracted from both side
of the electrode can be applied actually to the light emitting device.

[0051] The basic concept of the invention is to apply a first light
emitting layer exhibiting blue emission and a second light emitting layer
comprising a phosphorescent material, which generates simultaneously both
phosphorescent emission and excimer emission.

[0052] Excimer emission is always at the longer wavelength side
(specifically, at least several ten nm distant from normal emission)
compared with the normal emission (phosphorescent emission in case of a
phosphorescent material). Consequently, excimer emission of a
phosphorescent material generating phosphorescent emission in green
wavelength region is at red wavelength region. Therefore, a high
efficient light emitting element having peak intensity in each wavelength
region of red, green, and blue can be achieved by adopting the underlying
concept of the invention.

[0053] As a first light emitting layer exhibiting the blue emission, a
layer formed by a single substance (blue luminous body), or a layer
formed by dispersing a guest material serving a blue luminous body to a
host material.

[0054] Further, it is necessary that both phosphorescent emission and
excimer emission are generated from a phosphorescent material in order to
complete the invention. Specifically, there is a technique that a.
phosphorescent material having a high planarity structure such as
platinum complex is used as a guest material, and the phosphorescent
material is doped at high concentration (more specifically, at least 10
wt %). By doping the phosphorescent material at least 10 wt % in
concentration, mutual action of the phosphorescent material each other is
increased, and excimer emission is derived. Alternatively, the technique
that a phosphorescent material is not used as a guest material but as a
thin film light emitting layer or a dotted light emission region is
acceptable. However, the way of deriving excimer emission from a
phosphorescent material is not limited thereto.

[0055] From a device configuration perspective, the device configuration
is necessary to be designed to generate light in both the first light
emitting layer and the second light emitting layer. As a means of
designing the configuration, the first light emitting layer having hole
transportation properties is provided to come in contact with the second
light emitting layer and to be interposed between the second light
emitting layer and an anode via other layers; and ionization potential of
the second light emitting layer is sufficiently increased compared with
that of the first light emitting layer.

[0056] The band diagram for explaining the principle is shown in FIG. 1A.
FIG. 1A shows the HOMO level (ionization potential) 110 and the LUMO
level 111 of a first light emitting layer 101, the HOMO level (ionization
potential) 112 and the LUMO level 113 of the second light emitting layer
102, respectively.

[0057] In this instance, in case that energy gap 120 between the
ionization potential 110 of the first light emitting layer 101 and the
ionization potential 112 of the second light emitting layer 102 is small,
holes are penetrating from the first light emitting layer 101 into the
second light emitting layer 102. Then, almost carriers are eventually
recombined within the second light emitting layer 102 since the first
light emitting layer 101 has hole transportation properties. Accordingly,
the second light emitting layer 102 exhibits light emission in green
wavelength region and red wavelength region. Consequently, the second
light emitting layer 102 cannot transfer energy to the first light
emitting layer 101, which exhibits blue emission at short wavelength
side, and only the second light emitting layer 102 generates light.

[0058] For preventing the phenomenon, the energy gap 120 may be
sufficiently increased. Accordingly, almost carriers are recombined at
the vicinity of the boundary face of the first light emitting layer 101
and the second light emitting layer 102. Then, both the first light
emitting layer 101 and the second light emitting layer 102 can exhibit
light by the recombination of the small numbers of carriers within the
second light emitting layer 102, or the partly energy transfer, the
energy is generated by the recombination in the first light emitting
layer 101, from the first light emitting layer 101 to the second light
emitting layer 102. In addition, the energy gap 120 may be, specifically,
at least 0.4 eV. From some results of experiment, there are many cases
where both the first light emitting layer and the second light emitting
layer generate light at energy gap 120 of 0.4 eV.

[0059] The same is equally true of the case where the configuration that a
guest material generating blue emission is dispersed in a host material.
That is, the ionization potential of the second light emitting layer 102
is preferably larger by at least 0.4 eV than that of the whole first
light emitting layer 101 (in the state that a guest material generating
blue emission is dispersed in a host material of the first light emitting
layer).

[0060] More preferably, the ionization potential of the second light
emitting layer 102 is larger by 0.4 eV than that of the host material of
the first light emitting layer in a thin film shape. The principle is
explained with reference to band diagram shown in FIG. 1B. FIG. 1B shows
the HOMO level (ionization potential) 114 and the LUMO level 115 of the
host material of the first light emitting layer in a thin film shape, and
the HOMO level (ionization potential) 116 and the LUMO level 117 of a
guest material generating blue emission, respectively. Another components
are denoted by like numerals as of FIG. 1A.

[0061] In FIG. 1B, holes are transported into the HOMO level (ionization
potential) 114 of the host material of the first light emitting layer in
a thin film shape. Therefore, the energy gap 121 between the ionization
potential 112 of the second light emitting layer 102 and the ionization
potential 114 of the host material of the first light emitting layer in a
thin film shape is preferably at least 0.4 eV.

[0062] The principle with respect to the case of using a phosphorescent
material as a guest material will be explained. FIG. 2A is the band
diagram. FIG. 2A shows the HOMO level (ionization potential) 210 and the
LUMO level 211 of a first light emitting layer 201, the HOMO level
(ionization potential) 212 and the LUMO level 213 of the host material of
a second light emitting layer 202 in a thin film shape, and the HOMO
level (ionization potential) 214 and the LUMO level 215 of the guest
material (phosphorescent material) of a second light emitting layer 202,
respectively.

[0063] In this instance, as well as the case explained with reference to
FIGS. 1A and 1B, the ionization potential of the whole second light
emitting layer 202 (in the state that a phosphorescent material is
dispersed in the host material of the second light emitting layer) is
preferably larger by at least 0.4 eV than that of the first light
emitting layer 201.

[0064] More preferably, the ionization potential 212 of the host material
of the second light emitting layer in a thin film shape is larger by at
least 0.4 eV than the ionization potential 210 of the first light
emitting layer 201.

[0065] In such state, almost holes are accumulated at the vicinity of
boundary face of the first light emitting layer 201 and the second light
emitting layer 202 since the energy gap 220 is large. However, a part of
the holes are trapped into HOMO level 214 of a phosphorescent material.
Therefore both the first light emitting layer 201 and the second light
emitting layer 202 can exhibit light emission.

[0066] In case of adopting the configuration that a guest material
generating blue emission is dispersed in a host material to the first
light emitting layer 201, as well as the case described with reference to
FIGS. 1A and 1B, the ionization potential of the whole second light
emitting layer 202 (in the state that a phosphorescent material is
dispersed in the host material of the second light emitting layer) is
preferably larger by at least 0.4 eV than that of the whole first light
emitting layer 201 (in the state that a guest material generating blue
emission is dispersed in the host material of the first light emitting
layer).

[0067] More preferably, the ionization potential of the host material of
the second light emitting layer in a thin film shape is larger by at
least 0.4 eV than that of the host material of the first light emitting
layer in a thin film shape. The principle is explained with reference to
a band diagram in FIG. 2B. FIG. 2B shows the HOMO level (ionization
potential) 216 and the LUMO level 217 of the host material of the first
light emitting layer in a thin film shape and the HOMO level (ionization
potential) 218 and the LUMO level 219 of the guest material generating
blue emission. Another components are denoted by like numerals as of FIG.
2A.

[0068] In FIG. 2B, holes are transported into the HOMO level 216 of the
host material of the first light emitting layer in a thin film shape.
Therefore, in case that the energy gap between the ionization potential
212 of the host material of the second light emitting layer 202 in a thin
film shape and the ionization potential 216 of the host material of the
first light emitting layer 201 is at least 0.4 eV, the phenomenon
described with reference to FIG. 2A is resulted, consequently, both the
first light emitting layer and the second light emitting layer exhibit
light emission.

[0069] Hereinafter, the device configuration of a light emitting element
according to the invention will be explained. An electroluminescent layer
of the light emitting element according to the invention comprises at
least the above described first light emitting layer and second light
emitting layer. Further, layers having other properties than light
emission, which are known as the components of the conventional light
emitting element, such as a hole injecting layer, a hole transporting
layer, an electron transporting layer, and an electron transporting layer
can be appropriately included.

[0070] Materials that can be used for each the layers will be illustrated
in specific. However, the materials that can be applied to the invention
are not limited thereto.

[0071] As a hole injection material for forming a hole transporting layer,
porphyrin compounds are useful among other organic compounds such as
phthalocyanine (abbreviated H2-Pc), copper phthalocyanine
(abbreviated Cu-Pc), or the like. Further, chemical-doped conductive
polymer compounds can be used, such as polyethylene dioxythipophene
(abbreviated PEDOT) doped with polystyrene sulfonate (abbreviated PSS),
polyaniline (abbreviated PAni), polyvinyl carbazole (abbreviated PVK), or
the like. A thin film of an inorganic semiconductor such as vanadium
pentoxide or a ultra thin film of an inorganic insulator such as aluminum
oxide can also be used.

[0072] As a hole transportation material for using a hole transporting
layer, aromatic amine (that is, the one having a benzene ring-nitrogen
bond) compounds are preferably used. For example,
N,N'-bis(3-methylphenyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine
(abbreviated TPD) or derivatives thereof such as
4,4'-bis[N-(1-naphthyl)-N-phenyl-amino]-biphenyl (hereafter, referred to
as α-NPD) is widely used. Also used are star burst aromatic amine
compounds, including: 4,4',4''-tris(N,N-diphenyl-amino)-triphenyl amine
(hereafter, referred to as TDATA); and
4,4',4''-tris[N-(3-methylphenyl)-N-phenyl-amino]-triphenyl amine
(hereafter, referred to as "MTDATA").

[0074] As electron injection material for forming an electron injecting
layer, above described electron transportation materials can be used.
Besides, a ultra thin film of insulator, for example, alkaline metal
halogenated compounds such as LiF, CsF, or the like; alkaline earth
halogenated compounds such as CaF2 or the like; or alkaline metal
oxides such as Li2O is often used. In addition, alkaline metal
complexes such as lithium acetylacetonate (abbreviated Li(acac)),
8-quinolinolato-lithium (abbreviated Liq), or the like can also be used.

[0075] As a luminous body in the first light emitting layer, blue
fluorescent materials having hole transportation properties such as above
described TPD, α-NPD, or the like; or blue fluorescent materials
having electron transportation properties such as Balq, Zn(BOX)2, or
the like. Various blue fluorescent dyes, for example, perylene,
9,10-diphenyl anthracene, coumarin based fluorescent dyes (coumarin 30 or
the like) can be used as a guest material. Further, phosphorescent
materials such as bis(4,6-difluorophenyl)pyridinato-N,C2')
(acetylacetonato)iridium (abbreviated Ir(Fppy)2(acac)) can be used.
All of these materials have emission peak intensity in the wavelength of
from 400 to 500 nm, so that they are suitable for materials for the
luminous body of the first light emitting layer according to the
invention.

[0076] As the luminous body of the second light emitting layer, an organic
metal complex, with platinum as the central metal, is effectively used.
Specifically, if materials represented by the following structural
formulas 1 to 4 dispersed in a host material in high concentration, both
phosphorescent emission and excimer emission can be derived. However, the
invention is not limited thereto, any phosphorescent material can be
used, as long as it can generate phosphorescent emission and excimer
emission.

##STR00001##

[0077] In case of using guest materials for the first light emitting layer
and the second light emitting layer, the hole transportation materials or
electron transportation materials typified by the above described
examples can be used as the host material. In addition, a bipolar
material such as 4,4'-N,N'-di carbazolyl-biphenyl (abbreviated CBP) can
be used.

[0078] As a material for an anode of the light emitting element according
to the invention, a conductive material having large work function is
preferably used. In case of extracting light through an anode, a
transparent conductive material such as indium-tin oxide (ITO),
indium-zinc oxide (IZO), or the like may be used for forming the anode.
In case of forming an anode to have a light blocking effect, a single
layered film such as TiN, ZrN, Ti, W, Ni, Pt, Cr, or the like; a
lamination layered film of a titanium nitride film and a film containing
aluminum as its main components; a three layered film of a titanium
nitride film, a film containing aluminum as its main components, and a
titanium nitride film can be used for forming the anode. Alternatively,
an anode having a light blocking effect can be formed by stacking the
above described conductive material over a reflective electrode such as
Ti, Al, or the like.

[0079] As a material for a cathode, conductive materials having small work
function is preferably used. Specifically, alkaline metals such as Li,
Cs, or the like; alkaline earth metals such as Mg, Ca, Sr, or the like;
alloys of theses metals (Mg: Ag, Al: Li, or the like); or rare earth
metals such as Yb, Er, or the like. In addition, in case of using an
electron injecting layer such as LiF, CsF, CaF2, Li2O, or the
like, the conventional conductive thin film such as aluminum can be used.
In case of extracting light through cathode, alkaline metals such as Li,
Cs, or the like, or a lamination structure comprising a ultra thin film
containing alkaline earth metals such as Mg, Ca, Sr, or the like and a
transparent conductive film (ITO, IZO, ZnO, or the like). Alternatively,
the cathode having a light blocking effect is formed by forming an
electron injecting layer by alkaline metals or alkaline earth metals, and
electron transportation materials by co-evaporation and stacking a
transparent conductive film (ITO, IZO, ZnO, or the like) thereon.

[0080] FIGS. 3 and 4 show examples of the light emitting element according
to the invention. However, the invention is not limited thereto.

[0081]FIG. 3 shows the device configuration having an electroluminescent
layer 302 interposed between an anode 301 and a cathode 303. The device
comprises an anode 301, a hole injecting layer 311, a first light
emitting layer 312, a second light emitting layer 313, an electron
transporting layer 314, and a hole injecting layer 315, sequentially.
Here, the first light emitting layer 312 is composed of a luminous body
having hole transporting properties such as α-NPD. In the second
light emitting layer 313, a phosphorescent material 323 such as platinum
complexes (represented by above structural formulas 1 to 4) is dispersed
in a host material 322 in high concentration (specifically, at least 10
wt %). Consequently, both phosphorescent emission and excimer emission is
derived.

[0082] By practicing the present invention, a white light emitting element
having such simple configuration can be provided having emission peak
intensity in each wavelength of red, green, and blue. Further, the device
shown in FIG. 3 can exhibit stable white emission without changing the
shape of emission spectrum even when current density is changed or the
element is continuously operated since only one kind of doping material
(a phosphorescent material 323) is used to the device.

[0083]FIG. 4 shows the configuration having an electroluminescent layer
402 interposed between an anode 401 and a cathode 403. The device
comprises an anode 401, a hole injecting layer 411, a hole transporting
layer 412, a first light emitting layer 413, a second light emitting
layer 414, an electron transporting layer 415, and a hole injecting layer
416, sequentially. In the first light emitting layer 413, a hole
transportation material 421 used for the hole transporting layer 412 is
used as host and a blue luminous body 422 such as perylene is used as
guest. In the second light emitting layer 414, a phosphorescent material
424 such as platinum complexes (represented by above structural formulas
1 to 4) is dispersed in a host material 423 in high concentration
(specifically, at least 10 wt %). Consequently, both phosphorescent
emission and excimer emission is derived.

[0084] A method for stacking each layer of the light emitting element
according to the invention is not limited. Any method for stacking such
as vacuum vapor deposition, spin coating, ink jetting, dip coating, or
the like can be used, as long as layers can be stacked by these methods.

EXAMPLES

[0085] Hereinafter, examples of the present invention will be explained.

Example 1

[0086] In this example, a device configuration of a light emitting element
and a method for manufacturing thereof according to the present invention
will be explained with reference to FIG. 5.

[0087] An anode 501 of the light emitting element is formed over a glass
substrate 500 having an insulating surface. As a material for the anode
501, ITO, a transparent conductive film, is used. The anode 501 is formed
by sputtering to have a thickness of 110 nm. The anode 501 is square in
shape and 2 mm in height and width.

[0088] Then, an electroluminescent layer 502 is formed over the anode 501.
In this example, the electroluminescent layer 502 has a lamination
structure comprising a hole injecting layer 511; a first light emitting
layer 512, which has hole injection properties; a second light emitting
layer 513; an electron transporting layer 514; and an electron injecting
layer 515. The first light emitting layer 512 is formed by a material,
which can achieve blue emission, specifically, a material, which has the
emission spectrum with maximum intensity in the wavelength of from 400 to
500 nm. In addition, the second light emitting layer 513 is formed by a
host material or a guest material that generates phosphorescent light
emission.

[0089] First, a substrate provided with the anode 501 is secured with a
substrate holder of a vacuum deposition system in such a way that the
surface provided with the anode 501 is down. Then, Cu-Pc is put into an
evaporation source installed in the internal of the vacuum deposition
system. And then, the hole injection layer 511 is formed to have a
thickness of 20 nm by vacuum vapor deposition with a resistive heating
method.

[0090] Then, the first light emitting layer 512 is formed by a material,
which has excellent hole transportation properties and light-emission
properties. In this example, α-NPD is deposited in accordance with
the same procedures as those conducted for forming the hole injection
layer 511 to have a thickness of 30 nm.

[0091] And then, the second light emitting layer 513 is formed. In this
example, the second light emitting layer 513 is formed by CBP as a host
material and Pt(ppy)acac represented by the structural formula 1 as a
guest material, which is controlled to be 15 wt % in concentration, to
have a thickness of 20 nm by co-evaporation.

[0092] Further, the electron transporting layer 514 is formed over the
second light emitting layer 513. The electron transporting layer 514 is
formed by BCP (bathocuproin) to have a thickness of 20 nm by vapor
deposition. CaF2 is deposited to have a thickness of 2 nm as the
electron injection layer 515 thereon to complete the electroluminescent
layer 502 having a lamination structure.

[0093] Lastly, a cathode 503 is formed. In this example, the cathode 503
is formed by aluminum (Al) by vapor deposition with a resistive heating
method to have a thickness of 100 nm.

[0094] Therefore, a light emitting element according to the invention is
formed. In addition, in the device configuration described in Example 1,
the first light emitting layer 512 and the second light emitting layer
513 can exhibit light emission, respectively, so that a device that
exhibits white emission as a whole can be formed.

[0095] In this example, an anode was formed over a substrate; however, the
invention is not limited thereto. A cathode can be formed over a
substrate. In this case, that is, in case of exchanging an anode to
cathode, lamination sequence of the electroluminescent layer described in
this example is reversed.

[0096] In this example, the anode 501 is a transparent electrode in order
to extract light generated in the electroluminescent layer 502 from the
anode 501; however, the invention is not limited thereto. If the cathode
503 is formed by a selected material that is suitable for securing
transmittance, light can be extracted from the cathode.

Example 2

[0097] In this example, device characteristics of the light emitting
element described in Example 1 having the configuration: ITO/Cu-Pc (20
nm)/α-NPD (30 nm)/CBP+Pt(ppy)acac: 15 wt % (20 nm)/BCP (30 nm)/CaF
(2 nm)/Al (100 nm) will be explained. Emission spectrum of the light
emitting element having the above described configuration is shown by
each spectrum 1 in FIG. 8 and FIG. 9. Each plot 1 in FIGS. 10 to 13 shows
for electric characteristics.

[0098] Spectrum 1 in FIG. 8 shows the emission spectrum of the light
emitting element having the above described configuration at an applied
current of 1 mA (approximately 960 cd/m2). From the result shown by
spectrum 1, white emission can be obtained having three components: blue
emission from α-NPD composing the first light emitting layer
(˜450 nm); green emission of phosphorescent light emission from
Pt(ppy)acac contained in a second light emitting layer (˜490 nm,
˜530 nm); and orange emission from excimer light emission of
Pt(ppy)acac contained in the second light emitting layer. CIE
chromaticity coordinate is (x, y)=(0.346, 0.397). The light emission was
almost white in appearance.

[0099] Ionization potential of the α-NPD used for the first light
emitting layer and the CBP used for the second light emitting layer was
measured. The α-NPD had ionization potential of approximately 5.3
eV, and the CBP had that of approximately 5.9 eV. The difference in the
ionization potential between the α-NPD and the CBP was
approximately 0.6 eV. Therefore, preferable condition of the invention,
that is, ionization potential of at least 0.4 eV is satisfied.
Consequently, it can be considered that the fact resulted in good white
emission. In addition, the measurement of ionization potential was
carried out with photoelectron spectrometer (AC-2) (RIKEN KEIKI Co.,
Ltd.).

[0100]FIG. 9 shows measurement results of each spectrum at different
amount of current flow in the light emitting element having the above
described configuration. FIG. 9 shows measurement results at different
amount of current flow denoted by spectrum a (0.1 mA), spectrum b (1 mA),
and spectrum c (5 mA). Clearly from the measurement results, a spectral
shape was hardly changed even when the amount of current flow was
increased (luminance wasa increased). It can be considered that the light
emitting element according to the invention exhibits stable white
emission, which is hardly affected by the change of the amount of current
flow.

[0101] As electric characteristics of the light emitting element having
the above described configuration, the luminance-current plot 1 in FIG.
10 shows that a luminance of approximately 460 cd/m2 was obtained at
a current density of 10 mA/cm2.

[0102] The luminance-voltage plot 1 in FIG. 11 shows that a luminance of
approximately 120 cd/m2 was obtained at an applied voltage of 9 V.

[0103] The current efficiency-luminance plot 1 in FIG. 12 shows that
current efficiency of approximately 4.6 cd/A was obtained at a luminance
of 100 cd/m2.

[0104] The current-voltage plot 1 in FIG. 13 shows that a current flow was
approximately 0.12 mA at applied voltage of 9 V.

Comparative Example 1

[0105] Correspondingly, each spectrum 2 and spectrum 3 in FIG. 8 shows
emission spectrum measured from a light emitting element formed by
different concentration of Pt(ppy)acac contained in a light emitting
layer from that in Example 1. The spectrum 2 shows a measurement result
in the case that concentration of Pt(ppy)acac is 7.9 wt %. The spectrum 3
shows a measurement result in the case that concentration of Pt(ppy)acac
is 2.5 wt %. In each case, the spectrum was obtained at the current flow
of 1 mA.

[0106] As shown by spectrum 3 of FIG. 8, in case that Pt(ppy)acac is
contained at concentration of 2.5 wt %, blue emission from α-NPD
composing a first light emitting layer (approximately 450 nm) and green
emission from Pt(ppy)acac contained in a second light emitting layer
(approximately 490 nm, approximately 530 nm) were only observed,
consequently, white emission could not be obtained. As shown in spectrum
2, in case that Pt(ppy)acac is contained at concentration of 7.9 wt %, a
slight of excimer emission was in the spectrum as a shoulder at the
vicinity of 560 nm; however the peak was insufficient, consequently,
excellent white emission could not be obtained.

[0107] Further, current characteristics were measured from the devices.
Each plot 2 in FIGS. 10 to 13 shows measurement results from the device
containing Pt(ppy)acac at concentration of 7.9 wt %. Each plot 3 in FIGS.
10 to 13 shows measurement results from the device containing Pt(ppy)acac
at concentration of 2.5 wt %.

[0108] The luminance-voltage characteristics in FIG. 10 shows that a
luminance of approximately 180 cd/m2 was obtained from the device
containing Pt(ppy)acac at concentration of 7.9 wt % and a luminance of
approximately 115 cd/m2 was obtained from the device containing
Pt(ppy)acac at concentration of 2.5 wt % at a current density of 10
mA/cm2, respectively.

[0109] The luminance-voltage characteristics in FIG. 11 shows that a
luminance of approximately 93 cd/m2 was obtained form the device
containing Pt(ppy)acac at concentration of 7.9 wt % and a luminance of
approximately 73 cd/m2 was obtained from the device containing
Pt(ppy)acac at concentration of 2.5 wt % at an applied voltage of 9 V,
respectively.

[0110] The current efficiency-luminance characteristics in FIG. 12 shows
that a current efficiency of approximately 1.8 cd/A was obtained from the
device containing Pt(ppy)acac at concentration of 7.9 wt % and a current
efficiency of approximately 1.1 cd/A was obtained from the device
containing Pt(ppy)acac at concentration of 2.5 wt % at the luminance of
100 cd/m2, respectively.

[0111] The current-voltage characteristics in FIG. 13 show that a current
flow was approximately 0.21 mA in the device containing Pt(ppy)acac at
concentration of 7.9 wt % and a current flow was approximately 0.27 mA in
the device containing Pt(ppy)acac at concentration of 2.5 wt % at an
applied voltage of 9 V, respectively.

[0112] The above measurement results (especially, the result of the
current-voltage characteristics) provide the fact that the light emitting
element according to the invention containing Pt(ppy)acac as a guest
material in high concentration (15 wt %) has the same level of electric
characteristics as those of the light emitting element containing
Pt(ppy)acac as a guest material in such low concentration (7.9 wt %, 2.5
wt %).

Example 3

[0113] In this example, a method for manufacturing a light emitting device
(top emission structure) having a light emitting element according to the
present invention, which exhibits white emission, over a substrate having
an insulating surface will be explained with reference to FIG. 6. As used
herein, the term "top emission structure" refers to a structure in which
light is extracted from the opposite side of the substrate having an
insulating surface.

[0114] FIG. 6A is a top view of a light emitting device. FIG. 6B is a
cross-sectional view of FIG. 6A taken along the line A-A'. Reference
numeral 601 indicated by a dotted line denotes a source signal line
driver circuit; 602, a pixel portion; 603, a gate signal line driver
circuit; 604, a transparent sealing substrate; 605, a first sealing
agent; and 607, a second sealing agent. The inside surrounded by the
first sealing agent 605 is filled with the transparent second sealing
agent 607. In addition, the first sealing agent 605 contains a gap agent
for spacing between substrates.

[0115] Reference 608 denotes a wiring for transmitting signals inputted to
the source signal line driver circuit 601 and the gate signal line driver
circuit 603. The wiring receives video signals or clock signals from an
FPC (flexible printed circuit) 609 serving as an external input terminal.
Although only FPC is illustrated in the drawing, a PWB (printed wirings
board) may be attached to the FPC.

[0116] Then, a cross-sectional structure will be explained with reference
to FIG. 6B. A driver circuit and a pixel portion are formed over a
substrate 610. In FIG. 6B, the source signal line driver circuit 601 and
the pixel portion 602 are illustrated as a driver circuit.

[0117] The source signal line driver circuit 601 is provided with a CMOS
circuit formed by combining an n-channel TFT 623 and a p-channel TFT 624.
A TFT for forming a driver circuit may be formed by a known CMOS, PMOS,
or NMOS circuit. In this example, a driver integrated type in which a
driver circuit is formed over a substrate is described, but not
exclusively, the driver circuit can be formed outside instead of over a
substrate. In addition, the structure of a using a polysilicon film as an
active layer is not especially limited. A top gate TFT or a bottom gate
TFT can be adopted.

[0118] The pixel portion 602 is composed of a plurality of pixels
including a switching TFT 611, a current control TFT 612, and a first
electrode (anode) 613 connected to the drain of the current control TFT
612. The current control TFT 612 may be either an n-channel TFT or a
p-channel TFT. In case that the current control TFT 612 is connected to
an anode, the TFT is preferably a p-channel TFT. In FIG. 6B, a
cross-sectional structure of only one of thousands of pixels is
illustrated to show an example that two TFTs are used for the pixel.
However, three or more numbers of pixels can be appropriately used.

[0119] Since the first electrode (anode) 613 is directly in contact with
the drain of a TFT, a bottom layer of the first electrode (anode) 613 is
preferably formed by a material capable of making an ohmic contact with
the drain formed by silicon, and a top layer, which is in contact with a
layer containing an organic compound, is preferably formed by a material
having a large work function. In case of forming the first electrode
(anode) by three layers structure comprising a titanium nitride film, a
film containing aluminum as its main component, and a titanium nitride
film, the first electrode (anode) can reduce resistance as a wiring, make
a favorable ohmic contact, and function as an anode. Further, the first
electrode (anode) 613 can be formed by a single layer such as a titanium
nitride film, a chromium film, a tungsten film, a zinc film, or a
platinum film; or a lamination layer composed of three or more layers.

[0120] Insulator (also referred to as a bank) 614 is formed at the edge of
the first electrode (anode) 613. The insulator 614 may be formed by an
organic resin film or an insulating film containing silicon. In this
example, an insulator is formed by a positive type photosensitive acrylic
film as the insulator 614 in the shape as illustrated in FIG. 6B.

[0121] In order to make favorable coverage, an upper edge portion and a
lower edge portion of the insulator 614 are formed to have a curved face
having a radius of curvature. For example, positive type photosensitive
acrylic is used as a material for the insulator 614, only upper edge
portion of the insulator 614 is preferably have a radius of curvature
(from 0.2 to 3 μm). As the insulator 614, either a negative type
photosensitive resin that becomes insoluble to etchant by light or a
positive type photosensitive resin that becomes dissoluble to etchant by
light can be used.

[0122] Further, the insulator 614 may be covered by a protective film
formed by an aluminum nitride film, an aluminum nitride oxide film, a
thin film containing carbon as its main component, or a silicon nitride
film.

[0123] An electroluminescent layer 615 is selectively formed over the
first electrode (anode) 613 by vapor deposition. Moreover, a second
electrode (cathode) 616 is formed over the electroluminescent layer 615.
As the cathode, a material having a mall work function (Al, Ag, Li, Ca;
or alloys of these elements such as Mg: Ag, Mg: In, or Al: Li; or CaN)
can be used.

[0124] In order to pass light, the second electrode (cathode) 616 is
formed by a lamination layer of a thin metal film having a small work
function and a transparent conductive film (ITO, IZO, ZnO, or the like).
A light emitting element 618 is thus formed comprising the first
electrode (anode) 613, the electroluminescent layer 615, and the second
electrode (cathode) 616.

[0125] In this example, the electroluminescent layer 615 is formed by a
lamination structure explained in Example 1. That is, the
electroluminescent layer 615 is formed by stacking sequentially Cu-Pc as
a hole injecting layer (20 nm), α-NPD as a first light emitting
layer having hole transporting properties (30 nm), CBP+Pt(ppy)acac:15 wt
% (20 nm) as a second light emitting layer, and BCP as an electron
transporting layer (30 nm). In addition, an electron injecting layer
(CaF2) is unnecessary in the device since a thin film metal film
having a small work function is stacked as the second electrode
(cathode).

[0126] Thus formed light emitting element 618 exhibits white emission. In
addition, a color filter comprising a coloring layer 631 and a light
shielding layer (BM) 632 is provided to realize full color (for
simplification, an over coat layer is not illustrated).

[0127] In order to seal the light emitting element 618, a transparent
protective lamination layer 617 is formed. The transparent protective
lamination layer 617 comprises a first inorganic insulating film, a
stress relaxation film, and a second inorganic insulating film. As the
first inorganic insulating film and the second inorganic insulating film,
a silicon nitride film, a silicon oxide film, a silicon oxynitride film
(composition ratio: N<O), a silicon nitride oxide film (composition
ratio: N>O), or a thin film containing carbon as its main component
(for example, a DLC film or a CN film) can be used. These inorganic
insulating films have high blocking properties against moisture. However,
when the film thickness is increased, film stress is also increased,
consequently, film peeling is easily occurred.

[0128] By interposing a stress relaxation film between the first inorganic
insulating film and the second inorganic insulating film, moisture can be
absorbed and stress can be relaxed. Even when fine holes (such as pin
holes) are existed on the first inorganic insulating film at film
formation for any reason, the stress relaxation film can fill in the fine
holes. The second inorganic insulating film formed over the stress
relaxation film gives the transparent protective lamination film
excellent blocking properties against moisture or oxygen.

[0129] A stress relaxation film is preferably formed by a material having
smaller stress than that of an inorganic insulating film and hygroscopic
properties. In addition, a material that is transparent to light is
preferable. As the stress relaxation film, a film containing an organic
compound such as α-NPD, BCP, MTDATA, or Alq3 can be used.
These films have hygroscopic properties and are almost transparent in
case of having thin film thickness. Further, MgO, SrO2, or SrO can
be used as the stress relaxation film since they have hygroscopic
properties and translucency, and can be formed into a thin film by vapor
deposition.

[0130] In this example, a silicon nitride film having high blocking
properties against impurities such as moisture or alkaline metals is
formed by vapor deposition using a silicon target in the atmosphere
containing nitrogen and argon as the first inorganic insulating film or
the second inorganic insulating film. A thin film formed by Alp3 by
vapor deposition as the stress relaxation film. In order to pass light
through the transparent protective lamination layer, the total film
thickness of the transparent protective lamination layer is preferably
formed to be thin as possible.

[0131] In order to seal the light emitting element 618, the sealing
substrate 604 is pasted with the first sealing agent 605 and the second
sealing agent 607 in an inert gas atmosphere. Epoxy resin is preferably
used for the first sealing agent 605 and the second sealing agent 607. It
is desirable that the first sealing agent 605 and the second sealing
agent 607 inhibit moisture or oxygen as possible.

[0132] In this example, as a material for the sealing substrate 604, a
plastic substrate formed by FRP (Fiberglass-Reinforced Plastics), PVF
(polyvinyl fluoride), Myler, polyester, acrylic, or the like can be used
besides a glass substrate or a quartz substrate. After pasting the
sealing substrate 604 with the first sealing agent 605 and the second
sealing agent 607, a third sealing agent can be provided to seal the side
face (exposed face).

[0133] By encapsulating the light emitting element 618 in the first
sealing agent 605 and the second sealing agent 607, the light emitting
element 618 can be shielded completely from outside to prevent moisture
or oxygen that brings deterioration of the electroluminescent layer 615
from penetrating into the light emitting element 618. Therefore a high
reliable light emitting device can be obtained.

[0134] If the first electrode (anode) 613 is formed by a transparent
conductive film, a dual light emission device can be manufactured.

[0135] The light emitting device according to this example can be
practiced by utilizing not only the device configuration of the
electroluminescent device explained in Example 1 but also the
configuration of the electroluminescent device according to the
invention.

Example 4

[0136] Various electric appliances completed by using a light emitting
device having a light emitting element according to the present invention
will be explained in this example.

[0137] Given as examples of such electric appliances manufactured by using
the light emitting device having the light emitting element according to
the invention: a video camera, a digital camera, a goggles-type display
(head mount display), a navigation system, a sound reproduction device (a
car audio equipment, an audio set and the like), a laptop personal
computer, a game machine, a portable information terminal (a mobile
computer, a cellular phone, a portable game machine, an electronic book,
or the like), an image reproduction device including a recording medium
(more specifically, a device which can reproduce a recording medium such
as a digital versatile disc (DVD) and so forth, and includes a display
for displaying the reproduced image), or the like. FIGS. 7A to 7G show
various specific examples of such electric appliances.

[0138] FIG. 7A illustrates a display device which includes a frame 7101, a
support table 7102, a display portion 7103, a speaker portion 7104, a
video input terminal 7105, or the like. The light emitting device using
the light emitting element according to the invention can be used for the
display portion 7103. The display device is including all of the display
devices for displaying information, such as a personal computer, a
receiver of TV broadcasting, and an advertising display.

[0139]FIG. 7B illustrates a laptop computer which includes a main body
7201, a casing 7202, a display portion 7203, a keyboard 7204, an external
connection port 7205, a pointing mouse 7206, or the like. The light
emitting device using the light emitting element according to the
invention can be used to the display portion 7203.

[0140] FIG. 7C illustrates a mobile computer which includes a main body
7301, a display portion 7302, a switch 7303, an operation key 7304, an
infrared port 7305, or the like. The light emitting device using the
light emitting element according to the invention can be used to the
display portion 7302.

[0141] FIG. 7D illustrates an image reproduction device including a
recording medium (more specifically, a DVD reproduction device), which
includes a main body 7401, a casing 7402, a display portion A 7403,
another display portion B 7404, a recording medium (DVD or the like)
reading portion 7405, an operation key 7406, a speaker portion 7407 or
the like. The display portion A 7403 is used mainly for displaying image
information, while the display portion B 7404 is used mainly for
displaying character information. The light emitting device using the
light emitting element according to the invention can be used to the
display potion A 7403 and the display portion B 7404. Note that the image
reproduction device including a recording medium further includes a
domestic game machine or the like.

[0142] FIG. 7E illustrates a goggle type display (head mounted display),
which includes a main body 7501, a display portion 7502, and an arm
portion 7503. The light emitting device using the light emitting element
according to the invention can be used to the display portion 7502.

[0143] FIG. 7F illustrates a video camera which includes a main body 7601,
a display portion 7602, an casing 7603, an external connecting port 7604,
a remote control receiving portion 7605, an image receiving portion 7606,
a battery 7607, a sound input portion 7608, an operation key 7609, an
eyepiece potion 7610 or the like. The light emitting device using the
light emitting element according to the invention can be used to the
display portion 7602.

[0144] FIG. 7G illustrates a cellular phone which includes a main body
7701, a casing 7702, a display portion 7703, a sound input portion 7704,
a sound output portion 7705, an operation key 7706, an external
connecting port 7707, an antenna 7708, or the like. The light emitting
device using the light emitting element according to the invention can be
used to the display portion 7703. Note that the display portion 7703 can
reduce power consumption of the cellular phone by displaying
white-colored characters on a black-colored background.

[0145] As set forth above, the light emitting device using the light
emitting element according to the invention can be applied variously to a
wide range of electric appliances in all fields. The light emitting
device can be applied to various fields' electric appliances.

[0146] By practicing the present invention, a white light emitting element
having high light emission efficiency can be provided. Especially, a high
efficient white light emitting device, which has the peak intensity in
each wavelength region of red, green, and blue, can be provided.
Moreover, by manufacturing a light emitting device using the light
emitting element, a light emitting device, which operates at lower power
than that of the conventional light emitting device, can be provided.