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Ian Somerhalder (Damon) and Nina Dobrev (Elena) walked away with the award for “Favorite On-Screen Chemistry,” while Ian also nabbed “Favorite Sci-Fi/Fantasy Actor” for the second consecutive year. Beauty and the Beast’s Kristin Kreuk beat out Nina for “Favorite Sci-Fi/Fantasy Actress,” but Nina is totally the winner in our hearts. (Sorry, Kristen.)

Ian and Nina were all smiles at the ceremony, and their joint acceptance speech for “Favorite On-Screen Chemistry” is probably the sweetest thing you’ll see all week. (Unless, of course, you happen to be following Nina’s birthday celebrations.) The former couple accepted the award with reference to the potential awkwardness considering their real-life breakup — but it was anything but awkward, both cheekily delivering the line “At least we have great chemistry!” before Ian kissed Nina's cheek. Aww!

And did you catch the mention that their “characters are still dating on the show”? Perhaps we’re reading too much into an award show reference, but does this mean Delena will soon be getting back together? Because, last time we checked, Damon broke up with Elena to save her from his serial killer baggage. Don’t toy with our emotions, PCAs!

Check out a full list of the PCA winners. Are you happy with who took home the awards? Sound off in the comments below!

Catch the next episode of The Vampire Diaries on Thursday, January 23, 2014 at 8 p.m. ET on the CW, followed by an all-new episode of Reign.

Kayti Burt is a contributing writer for Wetpaint Entertainment with a penchant for all things pop culture. Follow her on Twitter and Google+!