The purpose of this study is to evaluate a method for the measurement of N,N-Dimethylformamide (DMF) and to apply the method to the ambient air samples. For the determination of DMF together with other general VOCs (e.g., benzene, toluene, and xylenes), adsorption sampling and thermal desorption with GC/MS was used in this study. The sampling and analytical approaches tested in this study showed a good repeatability and linearity with lower detection limits of less than 0.35 ppb. Field measurements were carried out at three industrial sites (Daegu-Seongseo, Siwha and Banwall industrial complexes) and one residential site in Daegu city during a period from October 2006 to November 2008. DMF was detected in 71.8% of the total samples from the Seongseo industrial complex, well known for textile industry. In contrast, DMF was detected in only 20.4% and 12.9% of all the samples from the other two sites in Banwall and Siwha industrial complexes, respectively. This implies that sources of DMF should be strongly associated with textile industry. The mean concentration of DMF also appeared to be the highest in Seongseo site (5.95 ppb), followed by a residential site in Daegu (3.28 ppb), Banwall (0.88 ppb) and Siwha (0.55 ppb). In this study, we demonstrated the environmental significance of DMF in urban ambient air. To our knowledge, the DMF measurement introduced in this paper is the first case of an official report in Korea.

Future climate changes over the Seoul metropolitan area (SMA) were predicted by the Weather Research and Forecasting (WRF) model using future land-use data from the urban growth model (SLEUTH) and forecast fields from ECHAM5/MPI-OM1 GCM (IPCC scenario A1B). Simulations from the SLEUTH model with GIS information (slope, urban, hill-shade, etc.) derived from the water management information system (WAMIS) and the intelligent transportation systems-standard nodes link (ITS-SNL) showed that considerable increase by 17.1% in the fraction of urban areas (FUA) was found within the SMA in 2020. To identify the effects of the urban growth on the temperature and wind variations in the future, WRF simulations by considering urban growth were performed for two seasons (summer and winter) in 2020s (2018~2022) and they were compared with those in the present (2003~2007). Comparisons of model results showed that significant changes in surface temperature (2-meter) were found in an area with high urban growth. On average in model domain, positive increases of and were predicted during summer and winter, respectively. These were higher than contributions forced by climate changes. The changes in surface temperature, however, were very small expect for some areas. This results suggested that surface temperature in metropolitan areas like the SMA can be significantly increased only by the urban growth during several decades.

Airborne in-situ measurements of aerosol/cloud number concentrations were analyzed to investigate the effects of aerosols on warm cloud formation in the Pacific Dust Experiment (PACDEX) during April and May 2007. In the air masses originating from the Asian continent, high concentrations of fine particles including black carbon (BC) were observed when compared to other regions. A strong correlation (r

Black carbon (BC) concentrations were measured with an aethalometer (AE-16, 880 nm) at time interval of 5-min at an urban site of Gwangju over a year 2008. 24-hr filter-based integrated measurements of particles were also made at the same site during the winter and summer intensive periods to test any optical loading bias in the raw BC data measured by aethalometer. BC concentration was higher in winter than in summer, possibly due to increase in emissions from energy consumption and poor dispersion with reduction of boundary layer in winter. Also temporal cycles of BC indicate that short-term transient spikes were common, occurring primarily during the rush-hour periods. A similar feature was also observed in diurnal concentration cycle of CO, mainly emitted from motor vehicles. When both low wind speed and weather patterns such as mist, haze and etc were combined, high BC concentrations frequently occurred. The amount of optical loading effect described by the "k" factor showed the seasonal variation, ranging from 0.0003 to 0.0036. This implies that optical loading effect is not seen at all times. From the comparison between the filter-based elemental carbon (EC) and aethalometer BC data, it was found that the loading compensated BC values were more reasonable than the raw BC ones reported from the aethalometer.

Recently, emission tests for heavy-duty vehicles have been conducted by heavy-duty engine dynamometer. But, it contains weaknesses that present inconveniences to install and uninstall engines and limitations to reflect on practical characteristics for vehicle driving. On the other hand, chassis dynamometer test is able to differentiate characteristics of real driving patterns due to the reason that vehicles can be examined by utilizing chassis dynamometer. This study aimed at comparing the characteristic of emitting regulatory substances of urban buses on Heavy-duty chassis dynamometer. The characteristic was analyzed based on vehicle speed by using both domestic and overseas developed heavy-duty vehicle test modes. As a result, this work attempted to investigate possibilities to take advantage of Heavy-duty vehicle test modes as a method to manage emissions from heavy-duty vehicles.

Concurrent Multi Path-Differential Optical Absorption Spectroscopy (CMP-DOAS) is a novel active optical system to measure simultaneously ambient trace gases (such as , , , and HCHO) present on several light paths. The CMP-DOAS system consists of a 2D CCD camera, spectrometer, receiving telescopes, and artificial light sources. The system receives spectra, which have been transported through several paths. It also covers wavelength ranges of which trace gases of interest share at the same time. This study presents the instrumental setup of a CMP-DOAS in detail. A field campaign for a comparative measurement was carried out at an urban site in Gwangju for a month on January 2009. mixing ratios measured by the CMP-DOAS system and in-situ analyzers were in good agreement by 83%. It demonstrates the high capacities of the CMP-DOAS technique to cover atmospheric trace gases dispersed across wide light paths.

The water-soluble components have been analyzed from the total suspended particulate (TSP) collected at Gosan site of Jeju Island for ten years (1997~2006), and the long-term variations of ionic constituent concentrations have been investigated in order to understand the pollution characteristics of atmospheric aerosols. Their mean concentrations were in the order of nss- > > > > > nss- > > . The concentrations had increased somewhat smoothly compared to those of for the past 10 years, possibly indicating the recent energy consumption pattern changes in China. The concentrations of ionic aerosol components showed mostly higher values during the Asian Dust storm periods, and the concentration ratios of nss-, , and nss- between the Asian Dust and Non-Asian Dust periods were 6.9, 2.4, and 1.3, respectively. The anthropogenic nss-, , and the soil originated nss- components showed high concentrations as the air parcels were moved from the Asia continent, on the other hand, their concentrations were relatively low as moving from the Northern Pacific into the Gosan area.

Ammonia is a very important constituent of the atmospheric environment because it is the most dominant gaseous alkaline species present in the atmosphere. Ammonia is known to affect ecosystems at relatively low concentration. Ammonia flux from livestock facilities can be regulated by a number of environmental factors (pH, ammonium ion, temperature, wind speed, etc). The increases in wind speed above manure from 0.0 m/s to 1.0 7m/s resulted in 2.5 times increases in ammonia flux. Wind speed and ammonia flux showed 0.982. A linear relationship with a correlation coefficient (r

The objective of this study was to assess the catalytic activities of manganese oxide (MnO, , , and ) catalysts for odors (acetaldehyde and propionaldehyde) removal. We used a fixed bed reactor as the experimental apparatus and the catalytic performance were carried out over the temperature range of . The properties and performance of catalysts were characterized by the X-ray diffraction (XRD) and Brunauer Emmett Teller (BET). The catalytic activities of manganese oxide catalysts for acetaldehyde combustion were in the order of MnO < < < , and it is similar to that of propionaldehyde combustion. We also confirmed that the reactions have well followed the kinetic model of Power-Rate Law and the reaction order (n) is 1 for both of the acetaldehyde and propionaldehyde combustion. In addition, the reaction activation energy of acetaldehyde and propionaldehyde combustion over were found to be for 487~503 K and for 473~533 K, respectively.

In this article, the performance of the THC analyzer was inspected using two different span gases of methane () and propane (). To explore the effect of standard gas selection, MicroFID system was tested by the following procedures. Initially, the system is spanned by propane gas of 60 ppm (or 180 ppmC). The system is then run against methane standards prepared at 5 different concentrations of 200, 250, 300, 400, and 500 ppm. According to the suggestion of the KMOE`s test procedure to use multiplying a factor of 3 (for propane), the resulting THC values derived by methane standards were systematically biased with ~500% error relative to true value. This paper discusses the interpretation procedures to obtain the least biased THC values for a given span set-up.