colloquially referred to asphenethylamine psychedelic It was discovered in 2003 by chemist Ralf Heim at the Free University of Berlin, who published his findings in his PhD dissertation.The compound was subsequently investigated by a team at Purdue University led by David Nichols.

The , was synthesized and validated as a radiotracer for positron emission tomography in Copenhagen.[7][8] Being the first 5-HT2A receptor full agonist PET radioligand, [11C]-CIMBI-5 shows promise as a more functional marker of these receptors, particularly in their high affinity states.

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