Chuck still wants to retrieve the Intersect out of his head and looking for a person under the pseudonym of Orion, the inventor of the Intersect. Sarah away from the temptation to escape from the British intelligence agent Cole Barker, who feels warm feelings to her. Chuck also learns the true motives Jill, his former classmate: causes of their quarrel and her true identity. Chuck and Sarah are gradually converging. Meanwhile, in the native Chuckâ€™s store: Big Mike falls in love with the mother of Morgan, in Morganâ€™s fault Big Mike demoted and Emmett grabs a chair control. Morgan could no longer endure the situation and he resigned, carries his dream. After all the events Chuck decides to follow his example. Chuckâ€™s sister, Ellie, marries her dream also come true â€“ father leads her to the altar.

Chuck season 2 episodes list:

Episode #1:
Chuck Versus the First Date (air date: 2008-09-29)

Chuck must prevent a menacing operative from obtaining a device that would ultimately lead to a new intersect. Meanwhile Chuck asks Sarah out on a real first date as Casey deals with a difficult assignment.

Chuck needs to go undercover to seduce a woman named Sasha Banachek, so an old school spy named Roan Montgomery is assigned as his mentor. Meanwhile, Captain Awesome finds himself in need of some relationship advice, and and turns to Morgan, and Lester faces his first problems as assistant manager.

Bryce Larkin returns to town with news about Fulcrum. They have hired a wealthy software magnate named Von Hayes to decrypt information on a stolen chip containing a refresh to the Intersect with highly classified information. Bryce and Sarah have to pose as a married couple at Von Hayes' dining party to steal back the chip, while Chuck has to pose as a waiter.
Meanwhile, Morgan has an encounter with the Mighty Jocks at the Buy More.

Efficiency expert Emmett Milbarge pays the Buy More a visit to inspect the branch, while a global terrorist looks for Jeff. Chuck needs to socialize with Jeff to find out about his connection to the terrorist. Finally, it all comes down to video games and the prevention of World War III.

At a BioScience conference, Chuck runs into Jill, his ex-girlfriend who broke up with him and later dated Bryce Larkin. He flashes on her boss, Guy Lafleur, who is suspected to be working on biochemical weapons. Chuck is ordered to reconnect with Jill in order to gain more information on Lafleur. Meanwhile, Emmett wants the staff to take CPR lessons including a test.

The team needs to acquire a Fulcrum agent list by solving several riddles left behind by Guy Lafleur.
Meanwhile, Emmett tries to find out why Chuck is absent so often and goes after his colleagues to get the information.

After finding out that Jill is a Fulcrum agent, Chuck is ordered to use her to infiltrate Fulcrum. Meanwhile, Ellie is preparing the apartment for Thanksgiving and the arrival of Captain Awesome's parents. Morgan, Jeff and Lester are assigned to guard the store over Thanksgiving.

The team is assigned to survey the Global Launch Agency, when intel shows that someone might penetrate their security. During the surveillance someone intrudes the lab who turns out to be Casey's former sensei Ty Bennett. Meanwhile, Captain Awesome's perfect parents decide to pay Devon and Ellie a surprise visit to help them plan the wedding, and Emmett Milbarge introduces an "Employee of the Month" contest to the Buy More, but the employees start their own contest instead.

Sarah's father, a con artist, comes to meet her, revealing that he conned a Saudi Arabian sheik, Rajiv Amad, out of nearly a million dollars. The sheik turns out to be connected to terrorist fundings, so the General wants Sarah and Chuck to gain intel from Sarah's father, but things get complicated when Amad shows up.
Anna wants to take her relationship with Morgan a step further and asks him to move in an apartment with her. Devon lends him some money to buy one, but instead, he buys a car.

Christmas Eve does not go as planned when an amateur criminal on the run from the police crashes into the Buy More and takes Chuck, Ellie, Awesome and the rest of the Buy More gang hostage. In order to protect Chuck’s cover and the safety of the other hostages, Sarah and Casey secretly go in to the store to remove Chuck, but the mission quickly falls apart when Chuck refuses to leave his friends and family behind.

Chuck and Sarah must pose as a happily married couple living in the suburbs, where they meet some interesting characters. Meanwhile, after his wife files for divorce, Big Mike goes on a rampage at work.

Chuck uses his burgeoning spy skills to help keep an eye on Anna for a heart sick Morgan. But their discovery leads to a chance that Anna's new boyfriend may be part of a dangerous gang. Meanwhile, Jeff and Lester nag Ellie into hiring their band, Jeffster!, to play at her wedding.

Chuck, Sarah and Casey learn about a man called “Perseus” who is behind Fulcrum’s plans to build their own Intersect. While Sarah and Casey are sent to find Perseus, Chuck and Agent Cole Barker are forced to stay in a safety bunker. When the mission takes a dangerous turn, their orders to stay out of harm’s way go out the window. Meanwhile, Morgan tries to convince Anna that moving in with him would be a bad idea

Chuck is contacted by the one person that can erase the Intersect from his mind. He starts having trust issues and doesn't know who to lean for help. Meanwhile, Buy More is having problems with the Buy More from Beverly Hills.

After Chuck's father Steve is kidnapped by Fulcrum, Chuck learns the only chance he has to find him is by putting his trust and life into the hands of the person he trusts the least—his ex-girlfriend Jill Roberts. Meanwhile, the Buy More team tries to sabotage Emmett’s corporate evaluation.