Dr. Riolo earned a Bachelor of Science degree in mathematics from the University of Wisconsin, and received his Doctorate of Dental Surgery degree from the University of Michigan.
After graduating from dental school Dr. Riolo completed a specialty certificate and a Master of Science degree in orthodontics from the School of Dentistry, University of Detroit Mercy. Upon completion of his specialty training, Dr Riolo decided to pursue his interest in public health and returned to the University of Michigan and earned a Ph.D. in epidemiology from the University of Michigan's School of Public Health.

Dr. Riolo believes that the knowledge necessary to create a beautiful healthy smile is gained through a combination of education, practical experience, and dedication to life-long learning. Dr. Riolo is committed to increasing access to dental care for the underserved and continually strives for excellence in orthodontic care. Dr. Riolo is a diplomate of the American Board of Orthodontics.

When Dr Riolo is not practicing orthodontics, he enjoys spending time with his wife and two children, skiing, sailing and traveling.