A complete assignment of the microwave spectrum of the ground vibrational state of t-butyl alcohol has now been obtained. This assignment was made and checked using double resonance techniques. The barrier to internal rotation is determined to be 1268 cal/mole. By adding simple centrifugal distortion corrections to the rigid top-rigid frame (six parameter) theory we obtain a fit to the large number of transitions measured with a standard deviation of only a few MHz up to $J = 20$.

Description:

Author Institution: Department of Chemistry, University of Wisconsin

URI:

http://hdl.handle.net/1811/9384

Other Identifiers:

1975-RG-15

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