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Kane was born in Claremont, Western Australia. Kane has been performing since the age of 3, starting in dance, then progressing to singing and acting. At the age of 6, she began to work professionally in print ads and moved on to television commercials and work on various children’s television shows.

At the age of 16, Kane was chosen from 7,000 actresses who auditioned for a role in the iconic Australian television soap opera “Neighbours,” where she was a series regular.

From March to December 2009, Kane portrayed the character of Tenaya on Power Rangers RPM, part of the long-running Power Rangers franchise. The series was shot over a six-month period in Auckland, New Zealand. In 2010, Kane has a starring role in the Vuguru production Pretty Tough, a 20-episode web series based on the novel of the same name by Liz Tigelaar. On 28 November 2012, it was announced that Kane had joined the cast of Teen Wolf in the recurring role of Cora Hale , "a mysterious and beautiful young woman toughened by a life on her own".

In February 2013, Kane was cast as Mary, Queen of Scots, the young woman the world would come to know as Mary, Queen of Scots. The teenage Mary is a headstrong monarch – beautiful, passionate, and poised at the beginning of her tumultuous rise to power in The CW's drama series Reign.

Season One
Pilot
Snakes in the Garden
Kissed
Hearts and Minds
A Chill in the Air
Chosen
Left Behind
Fated
For King and Country
Sacrifice
Inquisition
Royal Blood
Consummation
Dirty Laundry
The Darkness
Monsters
Liege Lord
No Exit
Toy Soldiers
Higher Ground
Long Live The King
Slaughter Of Innocence

Season Two
The Plague
Drawn and Quartered
Coronation
The Lamb and the Slaughter
Blood for Blood
Three Queens
The Prince of the Blood
Terror of the Faithful
Acts of War
Mercy
Getaway
Banished
Sins of the Past
The End of Mourning
Forbidden
Tasting Revenge
Tempting Fate
Reversal of Fortune
Abandoned
Fugitive
The Siege
Burn