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Considering the known popularity of the Railgun team and the unknown qualities of anyone yet to appear (remember no spoilers!), it's easy to say "we'll promote the series using the characters everyone (non/manga readers) know and save anyone new for future magazine promotions. Who was on the first key visual for the Index movie? Touma, Index, and Mikoto. Were there new characters? Yes, but they waited and used the ones people knew to promote it at first. Wait and you'll get to see anyone you want as we progress through the season.

Dengeki does confirm that the series will be aired on:
Tokyo MX
MBS
CBC
BS11
ATX
and other online/streaming methods.

The important point to take away from that post is that AT-X will have the first viewing each week at 23:30 on Fridays. Otherwise it makes little difference to us that it's on AT-X as the station tends to broadcast nearly every late night show in a season (sometimes later) due to its necessity to provide anime 24/7.

Likely the music producer at Warner is doing so. They were partially in charge of music for the Index movie, which had her first single as the theme, and they're on the production committee for Railgun S too. This is under the Warner Home Video label, while fripSide is under the Geneon label.

No idea which one will be releasing the BD/DVDs, though Geneon has re-released the previous seasons in DVD-box form and was top on the production committee for the Index movie, which likely indicates they'll physically release it on disc form. Warner would have a much higher chance of including English subtitles though, so I'm not sure which one I'd rather want.