The Originals will return on its new night, Monday, Oct. 6 at 8/7c, followed by a special Supernatural at 9/8c. The next day, Supernatural will kick off its 10th season at 9/8c, airing after the series premiere of The Flashat 8/7c.

Arrow will return for its third season on Wednesday, Oct. 8 at 8/7c, with The 100 debuting in the 9/8c timeslot starting Oct. 22.

The CW's heartwarming family comedy Jane the Virgin will premiere Monday, Oct. 13 at 9/8c.

(Full Disclosure: TVGuide.com is owned by CBS, one of The CW's parent companies.)