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Angelina Jolie: world-famous actress, UN ambassador, and now, the face of Louis Vuitton. Jolie snagged a huge deal with the French fashion giant—a source tells E! she'll make "close to $10 million," which is believed to be the most profitable endorsement deal of her career. Annie Leibovitz will shoot the print-only campaign, scheduled to launch globally this summer. Click here for more.