A record photovoltaic effect observed in antiferroelectrics

(Nanowerk News) The photovoltaic effect is the main physical and chemical principle behind every photovoltaic device, more popular known as a Solar Cell. It is characterized by the conversion of photons (from any artificial or natural light source like sunlight) into usable electrical energy. Modern photovoltaic devices have been intensively researched since the early days of the semiconductor transistor revolution (1940s) and nowadays they provide around 13% of the global renewable electric energy, a figure that will steadily increase to meet the COP21 directives.

A fundamental limit of current photovoltaic devices –all of which are based on semiconductor junctions- is its output voltage, which typically is limited to ~ 1.5 volts (like AA battery) per junction. This limit is due to intrinsic material properties –basically, the semiconductor bandgap- and is therefore independent of the solar cell area, regardless whether it is a microscopic dot or a large area solar panel. .

By contrast, there is another family of materials where photovoltages much larger than the bandgap can be achieved; they are the so-called ferroelectrics, intrinsically polar materials where the photovoltage is originated by the asymmetry of the crystal lattice instead of by a semiconductor interfacial effect. Until now, ferroelectric materials held the record for the highest photoelectric fields ever produced (the photovoltaic field is, in first approximation, the photovoltage divided by the thickness of the device).

A timeline review of the reported photovoltaic fields for different above bangap and/or ferroelectric photovoltaic materials from the literature. (click on image to enlarge)

Now, a multidisciplinary research team from the Institut Catalŕ de Nanocičncia i Nanotecnologia (ICN2), funded by Severo Ochoa Excellence Program, has reported in Advanced Materials ("Above-Bandgap Photovoltages in Antiferroelectrics") the largest ever photovoltaic field, reaching values in excess of a million volt per centimetre and beating by a factor of x20 the previous state of the art. Furthermore they have discovered the effect in a class of materials (known as antiferroelectrics) where the photovoltaic effect had not been explored before. The ICN2 research team behind the discovery is formed by Dr Amador Pérez-Tomás from ICN2, Prof Mónica Lira-Cantú from CSIC and ICREA research professor Gustau Catalán.

It was in many ways a real surprise as these materials are antipolar and not polar (hence the name antiferroelectrics) and thus it was not expected to present stable photovoltaic action, but the authors have proposed an explanation for the observed results. There is, however, still some way for this discovery to be of practical use in photovoltaic cells, because even though their photovoltage is very large, their electrical current still remains too low, meaning that the electrical power is still below that of standard semiconductor devices. The researchers have nevertheless filled a patent to protect the technology, and are working on the optimization of the device to rapidly advance into practical applications as they believe it can find uses in practical applications such as photovoltaic sensors and photocatalysts.