Anne Hathaway couldn’t hold back the tears as she received the dual honor of Best Actress at Thursday night’s VH1 Critics Choice Awards. But one lady who looked less-than-impressed was fellow nominee Angelina Jolie.

The “Ugly Betty” star is the latest closet celebrity smoker to be exposed after she was spotted puffing away on American Spirits this weekend in Beverly Hills alongside her 1-year-old daughter, Valentina.