There is no suggestion of any wrongdoing by Liverpool, their players or officials and a club spokesman said: “Liverpool Football Club has not been contacted by anyone from Europol or Uefa in relation to this matter.”

The report in Ekstra Bladet said Europol sources had confirmed that the match between Debrecen and Liverpool was the one involved.

The newspaper claimed the game had already been highlighted in a Dutch book about match-fixing. It stressed Liverpool were not under suspicion.

German police have already established that another of Debrecen’s matches during that Champions League campaign – the 4-3 defeat to Italian side Fiorentina – was subject to attempted match-fixing by a Croatian-led criminal gang.

The goalkeeper who played for the Hungarian team that night, Vukasin Poleksic, was banned by Uefa for two years for failing to report an approach from match-fixers before the Fiorentina match.

He claimed to be innocent and took the case to the Court of Arbitration for Sport, where the ban was upheld.

“It has been proven to its comfortable satisfaction that there had been contacts between the player and the members of a criminal group involved in match-fixing and betting fraud,” the CAS panel ruled.

Liverpool won the match at Anfield 1-0, the goal coming from Dirk Kuyt after Poleksic had parried a shot from Fernando Torres.

The report in Ekstra Bladet claimed fixers wanted to rig the betting market for total goals in the match, but failed. The newspaper claimed that fixers wanted to ensure there were at least three goals in the match, and that according to court papers they texted each other to express frustration at Liverpool’s failure to score more.

It is understood evidence relating to the Liverpool-Debrecen game came to light when police in Bochum, Germany were investigating the Croatian match-fixer Ante Sapina, who was sentenced to five years in prison in 2011 for masterminding the fixing of at least 20 matches across Europe.

The Bochum police investigation was at the heart of the findings announced by Europol on Monday, with their work for around 150 of the games under suspicion in Europe.

Police had evidence of €8 million (£6.9 million) of profit generated from gambling on fixed matches, but said this was probably “the tip of the iceberg”.

Until yesterday, England has considered itself largely immune from the problem of match-fixing, which has tainted more than 40 countries across Europe in recent years.

Europol said yesterday 680 matches around the world were under suspicion following an 18-month investigation involving police forces and investigators in 13 countries.

They drew together evidence that criminal gangs based in Singapore had corrupted about 425 officials, players and other individuals in 15 countries, paying up to £120,000 in single bribes to rig the outcome of games.

Europol said that qualifying matches for the World Cup and European Championships were being investigated as well as matches in top European leagues. It declined to offer any detail, making it difficult to establish which of the many suspicious matches already in the public domain were being referred to.

In a statement the Football Association said it had not received any information regarding the suspicious game. “The FA are not aware of any credible reports into suspicious Champions League fixtures in England, nor has any information been shared with us,” it said.

Rob Wainwright, Europol’s director, indicated that the match had come to light because of overseas investigations, but said it was “naïve” to think England was immune from fixing.

“It is clear that the focus of this investigation has been on other countries, not the United Kingdom,” he said. “However we were surprised by the scale generally of the criminal enterprise and just how widespread it was.

“It would be naive and complacent of those in the UK to think such a criminal conspiracy does not involve the English game and all the football in Europe.”

Europol also drew on information provided by convicted match-fixer Wilson Raj Perumal, a Singaporean jailed in Finland and Hungary for serial corruption of matches.

A Telegraph Sport investigation in 2011 revealed that Perumal had operated for almost a year from the UK, living in a flat overlooking Wembley Stadium, and exposed his involvement in a number of fixed international friendly matches.

Uefa, the body responsible for overseeing the Champions League, said it would review Europol’s evidence once it had received it and Fifa’s director of security,

Ralph Mutschke, said football would require greater help to police match-fixing.