I have libdvdread installed, version 4.1.3-i486-1, along with k3b version 2.0.2-i586-1vl70 installed. I still get the issue that Locater described (that being that the "Start Ripping" link is greyed out).

[export_ffmpeg.so] Error opening configuration file ./ffmpeg.cfg: No such file or directoryThe above feedback was from the "Show Debugging Output" after the rip of both titles on the dvd failed. Also, the original feedback that Locater noted in his/her screenshot after pressing the "show files" link is still present. I did a search on my system for ffmpeg.cfg, and it's not present:

transcode is a text-console utility for video stream processing. Decoding and encoding is done by loading modules that are responsible for feeding transcode with raw video/audio streams (import modules) and encoding the frames (export modules). It supports elementary video and audio frame transformations, including de-interlacing or fast resizing of video frames and loading of external filters.