The only thought I have is that this may be happening due to the first show in your queue, which has to load when the app starts. There are a few shows that will automatically crash the app for me. I also avoid extremely long running shows like Bleach because I've read that will crash it. Try moving the first show in your queue to elsewhere via your PC and see if your PS3 app will now load.

Same here! I've tried changing my DNS and actually got through to the interface. But then it refused to play anything, resulting in a crash. The longest shows in my queue are Kenshin, Naruto Shippuuden and Hunter X Hunter. I'll try clearing my queue later today to see if that works, but I doubt that.