Charlize Theron

Charlize Theron

"Placing a chignon off-center adds softness," says celebrity hairstylist Mara Roszak. Add a statement hair accessory to the mix, and you've got a winning look: "Her Cartier headband was one of a kind—with such an important piece of jewelry, we wanted to keep the hair understated yet modern and romantic," says Moroccanoil coiffeur Enzo Angileri, who created Theron's stunning hairstyle for this year's Golden Globe awards. After spraying Moroccanoil Frizz Control on Theron's damp hair, he blowdried it and used a curling iron to enhance her natural waves. With the headband in place, he then pinned her tresses into a textured side-roll.