Single UPS Configuration information with PowerChute and vCenter Server running on Windows system can be found on page 91 of the User's Guide.

Shutdown of HA cluster with PowerChute on standalone Windows system and vCenter server running on VM can be found on page 92 of the User's Guide.
Shutdown of HA cluster with PowerChute and vCenter server VM can be found on page 94 of the User's Guide.
Configuration information with PowerChute and vCenter Server running on Windows system advanced configuration can be found on page 96 of the User's Guide.