It is an object of the present invention to provide spherical metal particles having excellent monodispersity. The present invention relates to a method of manufacturing monodisperse spherical metal particles characterized by passing liquid metal through a porous membrane so as to disperse the resulting liquid metal particles in a continuous liquid phase.

2. The method according to claim 1, wherein the porous membrane is a porous glass membrane.

3. The method of claim 2, wherein the monodisperse spherical metal particles have a mean particle diameter in the range of 0.1-160 .mu.m.

4. The method according to claim 1, wherein the liquid metal is a metal having a melting point of at most 250.degree. C. which has been melted.

5. The method according to claim 1, wherein the continuous liquid phase further contains a dispersant.

6. The method according to claim 5, wherein the dispersant is a metallic soap.

7. The method of claim 1, wherein the monodisperse spherical metal particles have a mean particle diameter (particle diameter corresponding to 50 vol % in the cumulative volume distribution) in the range of 0.1-1000 .mu.m.

8. The method of claim 1, wherein the monodisperse spherical metal particles have a cumulative volume distribution in which: (a) a particle diameter corresponding to 10 vol % in the distribution is at least 60% of the particle diametercorresponding to 50 vol % in the distribution; and (b) a particle diameter corresponding to 90 vol % in the distribution is at most 125% of the particle diameter corresponding to 50 vol % in the distribution.

9. The method of claim 8, wherein a particle diameter corresponding to 50 vol % in the distribution is 10 .mu.m or smaller.

In so-called surface mount technology which is technology for mounting electronic devices with a high density on a printed wiring board or the like, a solder paste obtained by admixing solder particles and a paste-like flux is generally used. The solder paste is printed onto a printed wiring board using a screen printing machine, for example, lead terminals of electronic devices are then brought into contact with the top of the applied solder paste, joining is carried out by reflow (heating),and finally precision wiring is formed on the board.

Spherical particles having a diameter of about 20 to 100 .mu.m are predominantly used as the solder particles in the solder paste. In special cases, particles having a diameter of about 10 .mu.m are used. The solder particles are required tohave as uniform a particle diameter as possible and as high a sphericity as possible in order to improve and stabilize the printing characteristics. At the same time, it is necessary for the solder particles to prevent as much as possible surfaceoxidation of the particles, which has a significant influence on solderability.

In addition to solder particles, another spherical solder material called a solder ball which has a diameter of 100 .mu.m to 1 mm is also used as a terminal material for BGA/CSP type packages, which are becoming the most common type ofhigh-density semiconductor packages. As with solder particles, solder balls are required in terms of product quality to have an extremely narrow particle diameter distribution and a high sphericity.

In recent years, there has been an increasingly accelerated demand for electronic equipment typified by mobile phones, digital video cameras, notebook-sized personal computers and the like to be made smaller, lighter, and of higher performance. This is accompanied by advances in reduction in size of electronic devices. There are thus strong demands for surface mount technology to cope with higher density mounting than hitherto. Taking semiconductor integrated circuit packages as an example,the number of terminal pins increases year by year as the degree of integration of the packages increases, and now it has reached several hundred pins, with the pitch between terminal pins being 0.5 to 0.4 mm. In some cases, a pitch of 0.3 mm has beenrealized in practical use. This is considered to be the practical limit in surface mount technology at present. Various technical developments and improvements are required to further increase the density of surface mounting.

One of these requirements is to make solder particles smaller, make their particle diameter distribution more uniform, and improve their sphericity. Regarding solder balls, it will be necessary for ultrahigh density, ultra-small packages of thenext generation to mount several thousand solder balls per square centimeter. That is, for solder balls, technology for making the particle diameter yet smaller while maintaining an extremely narrow particle diameter distribution and a high sphericityis necessary.

At present, for the manufacture of solder particles, minute particle manufacturing techniques such as (1) a centrifugal atomization method (rotating disc method) and (2) a gas atomization method are used. On the other hand, for the manufactureof solder balls, examples of known methods include (1) a method in which relatively large solder particles obtained through the centrifugal atomization method or the gas atomization method are remelted in alumina powder to make the particles perfectlyspherical, (2) a method in which a thin solder wire is accurately cut into small sections and the small sections are then made spherical by remelting in an oil bath, and (3) a method involving dripping drops from a narrow nozzle.

However, the solder particles or solder balls obtained through these methods are polydisperse, and hence a classification process is essential. When trying to manufacture minute spherical solder particles having a high sphericity, the yield isthus extremely low, leading to a loss in productivity. Moreover, even if one tries to obtain minute spherical particles through a classification process while ignoring the low yield, the particles have an increased surface area per unit volume, therebymaking surface oxidation of the particles marked. It is thus difficult to manufacture minute spherical solder particles suitable for mounting with an increased density as will be demanded in the future.

Accordingly, it will inevitably become the case that prior art solder particles and balls will no longer be able to cope with surface mounting technology in which the mounting density is becoming increasingly higher, and hence development of newalternative materials is considered to be an urgent task.

SUMMARY OF THE INVENTION

It is thus a principal object of the present invention to provide spherical metal particles having excellent monodispersity.

In view of the above problems of the prior art, the present inventors carried out assiduous studies, and as a result found that metal particles manufactured using a certain specific method enable the above-mentioned object to be achieved, thuseventually accomplishing the present invention.

Thus, the present invention relates to the following monodisperse spherical metal particles and manufacturing method thereof.

1. Monodisperse spherical metal particles, which are metal particles having a cumulative volume distribution satisfying the following conditions as prepared: 1) a particle diameter corresponding to 50 vol % in the distribution is 10 .mu.m orsmaller; 2) a particle diameter corresponding to 10 vol % in the distribution is at least 60% of the particle diameter corresponding to 50 vol % in the distribution; and 3) a particle diameter corresponding to 90 vol % in the distribution is at most 125%of the particle diameter corresponding to 50 vol % in the distribution.

2. The monodisperse spherical metal particles as set forth in 1 above, wherein a mean aspect ratio (long/short ratio) of the metal particles is 1.1 or less.

3. The monodisperse spherical metal particles as set forth in 1 above, wherein the metal particles is made of a metal having a melting point of 250.degree. C. or less.

5. The manufacturing method as set forth in 4 above, wherein the porous membrane is a porous glass membrane.

6. The manufacturing method as set forth in 4 above, wherein the liquid metal is a metal having a melting point of 250.degree. C. or less that has been melted.

7. The manufacturing method as set forth in 4 above, wherein the continuous liquid phase further contains a dispersant.

8. The manufacturing method as set forth in 7 above, wherein the dispersant is a metallic soap.

9. The method as set forth in 4 above, wherein the monodisperse spherical metal particles has a mean particle diameter (particle diameter corresponding to 50 vol % in the cumulative volume distribution) in the range of 0.1-1000 .mu.m.

10. The method as set forth in 5 above, wherein the monodisperse spherical metal particles has a mean particle diameter in the range of 0.1-160 .mu.m.

11. The method as set forth in 4 above, wherein the monodisperse spherical metal particles have a cumulative volume distribution in which

a article diameter corresponding to 10 vol % in the distribution is at least 60% of the particle diameter corresponding to 50 vol % in the distribution; and

a particle diameter corresponding to 90 vol % in the distribution is at most 125% of the particle diameter corresponding to 50 vol % in the distribution.

12. The method as set forth in 11 above wherein a particle diameter corresponding to 50 vol % in the distribution is 10 .mu.m or smaller.

13. An apparatus for manufacturing monodisperse spherical metal particles, comprising a porous membrane which is in contact with liquid metal on one surface and with a continuous liquid phase on the other surface, and a means for pressurizingthe liquid metal.

14. The apparatus as set forth in 13 above, wherein the porous membrane is a porous glass membrane.

15. The use of the monodisperse spherical metal particles as set forth in 3 above as solder balls for BGA/CSP type packages.

16. A solder paste comprising the monodisperse spherical metal particles as set forth in 3 above.

The monodisperse spherical metal particles and manufacturing method thereof according to the present invention will be described below in detail.

1. Monodisperse Spherical Metal Particles

The monodisperse spherical metal particles of the present invention are metal particles which have a cumulative volume (size) distribution characterized in that:

1) the particle diameter corresponding to 50 vol % in the distribution (hereinafter referred to as the "50% diameter") is 10 .mu.m or smaller;

2) the particle diameter corresponding to 10 vol % in the distribution (hereinafter referred to as the "10% diameter") is at least 60% of the 50% diameter; and

3) the particle diameter corresponding to 90 vol % in the distribution (hereinafter referred to as the "90% diameter") is at most 125% of the 50% diameter.

The 50% diameter in (1) above is the particle diameter corresponding to a cumulative volume of 50 vol %. In the present invention, the 50% diameter should be 10 .mu.m or smaller and preferably in the range of 0.1 to 10 .mu.m. For example, inFIG. 7, which shows an example of the cumulative volume distribution, the 50% diameter is the particle diameter at the point shown as 23 (about 6.7 .mu.m on the abscissa). The 50% diameter may be determined as appropriate from within the above-mentionedrange depending on the application, the purpose of use, and so on.

The 10% diameter in (2) above is the particle diameter corresponding to a cumulative volume of 10 vol %. For example, in FIG. 7, which shows an example of the cumulative volume distribution, the 10% diameter is the particle diameter at the pointshown as 22 (about 5.7 .mu.m on the abscissa). In the present invention, the 10% diameter is at least 60% and preferably at least 80% of the 50% diameter.

The 90% diameter in (3) above is the particle diameter corresponding to a cumulative volume of 90 vol %. For example, in FIG. 7, which shows an example of the cumulative volume distribution, the 90% diameter is the particle diameter at the pointshown as 24 (about 7.7 .mu.m on the abscissa). In the present invention, the 90% diameter is not greater than 125% and preferably not greater than 110% of the 50% diameter.

The shape of the particles of the present invention may be a sphere or a shape close thereto. Insofar as the effects of the present invention are not impeded, particles having a non-spherical shape (an irregular shape, an ellipsoidal shape,etc.) may be present. In the present invention, the closer the shape is to a perfect sphere, the better. The mean aspect ratio of the particles is thus preferably not more than 1.1 and more preferably not more than 1.05. In the present invention, themean aspect ratio indicates the value determined by observing spherical metal particles under a scanning electron microscope, an optical microscope, or a metallurgical microscope, measuring the maximum diameter and the minimum diameter for each of 200particles chosen at random, calculating the aspect ratio (maximum diameter divided by minimum diameter) for each of the chosen particles, and taking the arithmetic mean of the calculated values. In the present invention, the mean aspect ratio is takenas a measure of the sphericity; the closer the value of the mean aspect ratio is to 1, the higher the sphericity.

The material of the monodisperse spherical metal particles of the present invention is not limited, but it is particularly preferable for this material to be a metal having a melting point of 250.degree. C. or below. Note that in the presentinvention the term "metal" includes alloys, intermetallic compounds, and the like.

The method of manufacturing the particles of the present invention is characterized by passing liquid metal through a porous membrane so as to disperse the resulting liquid metal particles in a continuous liquid phase.

There are no limitations on the above-mentioned porous membrane, provided that it allows the liquid metal to pass therethrough. Thus, it can be any porous membrane having at least two through holes.

The shape of the porous membrane is not limited; the shape may be determined as appropriate depending on the manufacturing conditions of the particles of the present invention and other factors. Examples of the shape include a plate shape (flatmembrane shape) and a cylindrical shape (pipe shape). Structurally, the membrane may be either symmetrical or asymmetrical, and may be either homogenous or non-homogenous. Furthermore, the membrane may be one in which substrates each having uniformgrooves formed in the surfaces thereof are placed on top of one another, or one or more substrates having uniform grooves formed in the surfaces thereof and those having no grooves are placed on top of one another, in such a manner that a porous membraneis finished.

The pore diameter of the porous membrane is not limited, but the mean pore diameter is generally selected as appropriate from the range of 0.05 to 100 .mu.m in accordance with the desired particle diameter and so on. In the present invention,the porous membrane is preferably a microporous membrane having a relative cumulative pore distribution curve in which the value obtained by dividing the pore diameter at which the pore volume accounts for 90% of the total pore volume (90% pore diameter)by the pore diameter at which the pore volume accounts for 10% of the total pore volume (10% pore diameter) (or the ratio of 90% pore diameter to 10% pore diameter) is substantially in the range from 1 to 1.5. Such a membrane itself can be manufacturedby a known method. Alternatively, a commercially available membrane can be used.

The cross-sectional shape of the through holes (pores) may be any of circular, elliptical, rectangular (slit-shaped), square, and so on. The through holes may pass through the membrane perpendicular to the membrane surfaces, or obliquely. Thethrough holes may be interconnected with one another.

The material of the porous membrane is not limited, and it includes, for example, glass, ceramics, silicon, resins (especially heat-resistant resins), and metals. A porous membrane having a contact angle in excess of 90.degree. with the liquidmetal used is particularly preferable. Even in the case of a porous membrane having a contact angle of 90.degree. or less with the liquid metal, the contact angle can be made to exceed 90.degree. by surface treatment of the porous membrane. Forexample, it is possible to make the porous membrane hydrophilic or water-repellent by coating with a commercially available surface treating agent, thereby modifying the membrane surface such that the contact angle exceeds 90.degree..

In the present invention, it is particularly preferable to use a porous glass membrane, which has been used in membrane emulsification for an oil-aqueous phase system as disclosed in Japanese Patent Publication No. 8-2416 and U.S. Pat. No.5,278,106. A preferred porous glass membrane is made, for example, from porous glass manufactured using micro glass phase separation. Specifically, the porous glass membrane includes the CaO--B.sub.2O.sub.3--SiO.sub.2--Al.sub.2O.sub.3 porous glassdisclosed in Japanese Patent Publication No. 63-66777, and the CaO--B.sub.2O.sub.3--SiO.sub.2--Al.sub.2O.sub.3--Na.sub.2O porous glass and CaO--B.sub.2O.sub.3--SiO.sub.2--Al.sub.2O.sub.3--Na.sub.2O--MgO porous glass disclosed in U.S. Pat. No.4,657,875. Regarding these porous glass membranes, again it is preferably a microporous glass membrane having a relative cumulative pore distribution curve in which the ratio of 90% pore diameter to 10% pore diameter is substantially in the range from 1to 1.5. The mean pore diameter can be selected as appropriate from within the range mentioned above.

There are no limitations on the continuous liquid phase, as long as it is capable of well dispersing liquid metal particles therein, and it can be selected as appropriate depending on the particular liquid metal used and other factors.

For example, water or a water-based liquid phase (such as one selected from various aqueous solutions) can be used. Alternatively, an oil, an organic solvent, or the like can be used.

The oil may be a fat or fatty oil or a mineral oil. The fat or fatty oil includes vegetable oils and fats as well as animal oils and fats. Examples of vegetable oils and fats include soybean oil, rapeseed oil, linseed oil, palm oil, olive oil,coconut oil, and corn oil. Examples of animal oils and fats include beef tallow, lard, whale oil, and sardine oil. As a mineral oil, either a petroleum oil or a synthetic oil can be used. Examples of a petroleum oil include fuel oils such as kerosene,light oil, and heavy oil; lubricating oils such as spindle oil, compressor oil, turbine oil, machine oil, engine oil, and gear oil; paraffin oils such as liquid paraffin and petroleum wax; and other oils such as rust-preventing agents, metal workingfluids and insulating oils. Examples of a synthetic oil include silicone oils, olefin polymer oils, diester oils, and polyalkylglycol oils.

The organic solvent may be either hydrophilic or hydrophobic. Thus, a water-soluble organic solvent such as a polyethylene glycol may be used.

In the present invention, it is desirable to select a continuous liquid phase which has a boiling point higher than the melting point of the metal to be used and which is not susceptible to decomposition.

In the present invention, it is preferable that the continuous liquid phase further contain a dispersant. The dispersant is not limited, as long as it can be dissolved or dispersed in the continuous liquid phase and it is capable of suppressingor preventing coalescence of the liquid metal particles even at a temperature in the vicinity of the melting point of the metal which is used.

The dispersant can be selected as appropriate depending on the particular continuous liquid phase used and other factors. Examples of the dispersant include anionic surfactants, cationic surfactants, nonionic surfactants, polymeric surfactants,fluorinated surfactants, and organometallic surfactants.

One or more of these dispersants can be used depending on the particular continuous liquid phase used and other factors. For example, in the case where the continuous liquid phase is (1) a water phase, (2) a water-based phase, or (3) a phasecomprising a component or components that dissolve in water, it is preferable to use an anionic surfactant, a cationic surfactant, a nonionic surfactant, a polymeric surfactant, a fluorinated surfactant, an organometallic surfactant, or the like. On theother hand, in the case where the continuous liquid phase is, for example, an oil phase or other than (1) to (3) above (e.g., an oil phase comprising a fat or fatty oil, a mineral oil, or the like), it is preferable to use a flux, an oleophilicsurfactant (oil-soluble surfactant), a metallic soap, a saturated fatty acid, an unsaturated fatty acid, or the like.

The amount of the dispersant(s) added may be determined as appropriate depending on the particular dispersant(s), metal, and continuous liquid phase used, and similar factors, but it is generally about 0.1 to 20 wt % and preferably 0.5 to 5 wt %.

When passing the liquid metal through the porous membrane to disperse the resulting liquid metal particles in the continuous liquid phase, there are no limitations on the manner of arrangement of the liquid metal, the continuous liquid phase, andthe porous membrane. For example, it is possible to prepare a vessel for the liquid metal and a vessel for the continuous liquid phase, fill these vessels with the liquid metal and the continuous liquid phase, respectively, apply a predeterminedpressure to the liquid metal so as to force it into the porous membrane, whereby the liquid metal that has passed through the porous membrane becomes particles and disperse in the form of liquid metal particles in the continuous liquid phase. Subsequently, the resulting liquid metal particles are cooled and the particles of the present invention can be obtained. The manufacturing method according to the present invention will be described below more fully with reference to the drawings.

FIG. 1 is a schematic drawing showing conceptually the state in which monodisperse liquid metal particles are produced according to the present invention. First, a liquid metal 2 and a continuous liquid phase 3 are disposed with a porousmembrane 1 having uniform through holes therebetween. In this state, the membrane surface and the pores 4 of the porous membrane are preferentially wetted by the continuous liquid phase. When the pressure applied to the liquid metal exceeds a criticalpressure Pc (Pc=4.gamma.cos .theta./Dm (where .gamma. represents the interface tension, .theta. represents the contact angle, and Dm represents the mean pore diameter)), the liquid metal penetrates through the pores to form liquid particles, which aredispersed in the continuous liquid phase, thus producing monodisperse liquid metal particles 5. In the case where a dispersant has been added to the continuous liquid phase, the dispersant is present at the interfaces between the liquid metal and thecontinuous liquid phase, thus serving to increase the stability of the liquid metal particles and suppress coalescence of the particles more effectively. The particle diameter of the liquid metal particles produced is basically determined by the meanpore diameter of the porous membrane. The ratio (Dp/Dm) of the particle diameter Dp to the mean pore diameter Dm generally varies depending on the shape of the pores. For example, when a porous glass membrane is used, this ratio can be controlled to bea fixed value within the range of 2.5 to 8, and hence in general the particle diameter of the liquid metal particles can be controlled within the range of 0.1 to 160 .mu.m. When a porous membrane other than a porous glass membrane is used, in generalthe particle diameter of the liquid metal particles can be controlled to be within the range of 1 to 1000 .mu.m. The particle diameter may be selected as appropriate depending on the usage of the final product and so on. For example, in the case wherethe monodisperse spherical metal particles of the present invention are used as solder particles for high-density mounting, it is preferable to make the mean particle diameter (50% diameter) 0.1 to 160 .mu.m and especially 0.1 to 100 .mu.m.

FIG. 2 shows an example of an apparatus for implementing the manufacturing method of the present invention. A liquid metal vessel 6 for containing a liquid metal and a membrane module 7 having an integrated porous membrane 1 are immersed in acontinuous liquid phase 3 in an upper vessel 8. The continuous liquid phase 3 is heated to a temperature above the melting point of the metal by a heater 9. The continuous liquid phase 3 is also agitated by a circulating pump 10.

The membrane module shown here is of a type in which the liquid metal 2 is forced in from the outside of a pipe-shaped membrane. The material of the vessels may be a corrosion-resistant metal such as stainless steel, a corrosion-resistant resinsuch as a fluororesin, glass, or the like. The circulating pump causes the continuous liquid phase to flow so that liquid metal particles produced on the membrane surface will not interfere with the production of new liquid metal particles. Theapplication of pressure to the liquid metal may be performed using a gas or hydraulic pressure.

Since the monodisperse liquid metal particles 5 produced have a high density, they move downwards and enter a lower vessel 11 filled with the continuous liquid phase. Here, the temperature in the lower vessel is set using a heater 12 to be lowerthan the melting point of the metal so that the metal particles solidify in the lower vessel, thus producing a suspension in which solid spherical metal particles 13 are dispersed. The apparatus and technique (for example, the method of causing thecontinuous phase to flow or circulate, the heating method or means, the vessel shapes, the method of applying pressure, etc.) are not limited to the above-described ones, but a combination of various other methods can be employed.

FIG. 3 shows an example in which the present invention is implemented using a membrane module 15 having a fixed porous membrane 14 of a flat plate shape. A liquid metal in the membrane module is pressurized so as to pass through the porousmembrane and disperse in a continuous liquid phase 3 in the form of monodisperse liquid metal particles 5. Here, a magnetic stirrer 16 and a spin bar 17 are used for agitating the continuous liquid phase to produce a flow. The liquid metal particles 5produced move downwards to pass through a mesh 18 and are accumulated in a lower part of a vessel 19. The mesh can be installed in order to prevent destruction or deformation of the metal particles by the spin bar. With this apparatus, the liquid metalparticles are solidified by stopping heating by a heater 9 to allow the system to cool.

The metal particles (solid spherical metal particles) produced by the method of the present invention can be recovered in accordance with a known separation and recovery method. For example, when the solid spherical metal particles are recoveredfrom the above-mentioned suspension, it is possible to replace the continuous liquid phase in the suspension by an organic solvent such as an alcohol, toluene, or acetone, and recover and store the solid spherical metal particles in the organic solventas is. The continuous liquid phase may be replaced by a paste-like flux. In the case of recovering the solid spherical metal particles as dry particles, the organic solvent may be evaporated in vacuo or in an inert gas (nitrogen gas, argon gas, heliumgas, etc.) such that the particles can be recovered without exposure to oxygen.

The manufacturing method of the present invention is generally capable of producing spherical metal particles having a desired particle diameter which is controlled to have a mean particle diameter (50% diameter) in the range of 0.1 to 1000.mu.m. For example, when the spherical metal particles are to be used as solder particles for high-density mounting, it is possible to produce spherical metal particles having a mean particle diameter of 0.1 to 160 .mu.m and preferably of 0.1 to 100.mu.m.

In particular, with the manufacturing method of the present invention, it is possible to obtain monodisperse spherical metal particles, which are metal particles having a cumulative volume distribution characterized in that:

1) the particle diameter corresponding to 50 vol % in the distribution is 10 .mu.m or smaller;

2) the particle diameter corresponding to 10 vol % in the distribution is at least 60% of the particle diameter corresponding to 50 vol % in the distribution; and

3) the particle diameter corresponding to 90 vol % in the distribution is at most 125% of the particle diameter corresponding to 50 vol % in the distribution.

The above conditions 2) and 3) are preferably satisfied for monodisperse metal spherical particles having a mean particle diameter larger than 10 .mu.m which are manufactured by the method of the present invention.

According to the present invention, the following excellent effects can be obtained.

(1) Spherical metal particles having excellent monodispersity, which were considered to be difficult to manufacture in the prior art, can be manufactured relatively easily. In particular, the particles of the present invention are advantageousas minute spherical solder particles required for high-density mounting technology or as high-quality solder balls used in BGA/CSP packages and the like. The particles have a high sphericity which results from the high surface tension of the liquidmetal particles. The liquid metal particles in the continuous liquid phase have a shape close to that of perfect spheres, and the method of the present invention allows these particles to cool and solidify while preventing them from deforming as far aspossible. Thus, the method of the present invention can realize an increased sphericity.

(2) With the method of the present invention, which is implemented in a liquid phase, it is possible to obtain metal particles in which surface oxidation is suppressed compared to the prior art. The manufacturing method of the present inventionis capable of producing solid spherical metal particles having a shape close to that of perfect spheres while suppressing surface oxidation, which is a problem with conventional spherical solder particles and solder balls. The reason why surfaceoxidation can be suppressed is that liquid metal particles are produced in a continuous liquid phase which is isolated from a gaseous phase and can be solidified in that phase. That is, there is absolutely no opportunity for the metal particles to comeinto contact with oxygen. As a result, solder particles or solder balls for which surface oxidation is suppressed or prevented can be manufactured to advantage by the method of the present invention.

(3) The metal particles of the present invention are also improved in monodispersity, and due to this combined with a spherical shape, they are suitable for use in solder paste or the like. In particular, when a dispersant is used in thecontinuous liquid phase to produce solid spherical metal particles having hydrophobic groups remaining on the surfaces of the particles, the metal particles have an improved affinity for organic matrices and hence become yet more suitable for use insolder paste. The metal particles are also suitable for use in ink-jet printing or for use as solder particles for fine dispenser application and three-dimensional mounting.

(4) The present invention can greatly contribute to the electronics industry, especially with respect to reduction in size and weight and enhancement in performance of electronic products typified by information and communications equipment.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic drawing showing a state in which monodisperse liquid metal particles are produced;

FIG. 2 is a drawing showing an example of an apparatus for implementing the present invention using a pipe-shaped (cylindrical) porous membrane;

FIG. 3 is a drawing showing an example of an apparatus for implementing the present invention using a flat plate-shaped porous membrane;

The following examples and comparative examples are given to make the characteristic features of the present invention yet clearer. It should be understood that the present invention is not limited to these examples.

The materials used were a commercially available lead-free solder (sold under the tradename "M705" by Senju Metal Industry Co., Ltd., composition: 96.5 Sn/3 Ag/0.5 Cu, melting point: 217-220.degree. C.) as a metal, a hydrophilic porous glassmembrane having a mean pore diameter of 2.52 .mu.m (of the CaO--B.sub.2O.sub.3--SiO.sub.2--Al.sub.2O.sub.3--Na.sub.2O--MgO type, tradename "SPG" manufactured by Miyazaki Prefecture Industrial Technology Center) as a porous membrane, a commerciallyavailable lubricating oil as a continuous liquid phase, and zinc stearate (2.0 wt % relative to the oil) as a dispersant. An apparatus as shown in FIG. 2 was used as a manufacturing apparatus.

First, the lead-free solder was heated to melt it in a separate vessel, and the molten solder was put into the liquid metal vessel 6 of the apparatus shown in FIG. 2 after removal of an oxidized layer floating on the surface while the temperaturein the upper vessel 8 was kept at about 230.degree. C., which is higher than the melting point of the solder. The inside of the lower vessel 11 was kept at a temperature (about 180.degree. C.) which is lower than the melting point of the solder and atwhich zinc stearate does not precipitate out. Next, the liquid metal 2 was pressurized using a nitrogen gas cylinder as a pressure source, while the continuous liquid phase 3 consisting of the lubricating oil and the dispersant was allowed to circulateusing the circulating pump 10. As a result, the liquid metal passed through the membrane at a pressure of 0.56 MPa, thereby forming liquid metal particles of uniform size dispersed in the continuous liquid phase, and a monodisperse emulsion (hereinafteralso referred to as the "M/O (metal in oil) emulsion") was obtained. The liquid metal particles sank down into the lower vessel 11 and solidified therein. After the test had been completed, the solid metal particles were recovered along with thecontinuous liquid phase from the lower vessel 11, and the continuous liquid phase was removed by decantation with toluene. The monodisperse solid spherical metal particles which were obtained were observed under an optical microscope and a scanningelectron microscope. The results are shown in FIGS. 4 to 6. FIG. 7 shows the results of measuring the particle diameter distribution of the spherical metal particles. According to the particle diameter distribution of FIG. 7, the distribution isextremely narrow, with the 10% diameter 22 in the cumulative volume distribution 21 being 0.85 times the 50% diameter, and the 90% diameter 24 being 1.15 times the 50% diameter, which indicates that the spherical metal particles are monodisperse. Themean aspect ratio of the particles was 1.03 indicating that the particles had a high sphericity.

EXAMPLE 2

To investigate the control of the particle diameter, which is a characteristic feature of the present invention, the relationship between the mean particle diameter of the solid spherical metal particles and the mean pore diameter of the porousglass membrane which was used was investigated.

Six different hydrophilic porous glass membranes having mean pore diameters of 0.52 .mu.m, 1.36 .mu.m, 2.52 .mu.m, 5.16 .mu.m, 10.61 .mu.m, and 19.9 .mu.m, respectively, were used (all being of theCaO--B.sub.2O.sub.3--SiO.sub.2--Al.sub.2O.sub.3--Na.sub.2O---MgO type, tradename "SPG" manufactured by Miyazaki Prefecture Industrial Technology Center and having ratios of 90% pore diameter to 10% pore diameter of 1.34, 1.42, 1.28, 1.48, 1.38, and 1.22,respectively). A lead-containing solder having a melting point of 183.degree. C. (sold under the tradename "SN63" by Senju Metal Industry Co., Ltd., composition: 63 Sn/37 Pb) was used as a metal, purified soybean oil was used as an oil, and leadstearate was used as a dispersant (2.0 wt % relative to the oil). Other conditions were the same as in Example 1.

The particle diameter distribution of the solid spherical metal particles obtained using each of the above-mentioned six porous glass membranes is shown in FIG. 8. A distribution diagram 25 shows the particle diameter distribution for the solidspherical metal particles prepared using the porous glass membrane having a mean pore diameter of 0.52 .mu.m. Similarly, distribution diagrams 26, 27,28, 29, and show the particle diameter distributions for those particles in which the mean porediameters were 1.36 .mu.m, 2.52 .mu.m, 5.16 .mu.m, 10.61 .mu.m, and 19.9 .mu.m, respectively.

As shown in FIG. 9, the mean particle diameter Dp and the mean pore diameter Dm were proportional to one another, with the ratio Dp/Dm (slope of line 31) being about 2.8. These results indicate that monodisperse solid spherical metal particlesof a desired size can be manufactured by varying the mean pore diameter of the porous membrane. FIG. 10 shows the results of measuring the minimum pressure Pc at which the liquid metal started to permeate through the porous membrane for each of theporous membranes. Pc and 1/Dm were proportional to one another, with the slope 4.gamma.cos .theta. (slope of line 32) being 1.41 N/m. Assuming that .theta. is 180.degree., then the interfacial tension, .gamma., between the liquid metal and thecontinuous phase is calculated as .gamma.=350 mN/m.

EXAMPLE 3

Solid spherical metal particles were prepared using two different systems. The preparation method was the same as in Example 1 except for the following conditions.

The systems which were prepared were system A in which a continuous phase consisted of a silicone oil as an oil and 2 wt % of lead stearate as a dispersant, and system B in which a continuous phase consisted of castor oil as an oil and 2 wt % ofzinc stearate as a dispersant. The porous glass membrane used was of the CaO--B.sub.2O.sub.3--SiO.sub.2--Al.sub.2O.sub.3--Na.sub.2O--MgO type having a mean pore diameter of 2.52 .mu.m (tradename "SPG" manufactured by Miyazaki Prefecture IndustrialTechnology Center). A lead-containing solder of 43 Sn/14 Bi/43 Pb having a melting point of 135-165.degree. C. (solidus temperature: 135.degree. C., liquidus temperature: 165.degree. C.) (sold as "#165" by Senju Metal Industry Co., Ltd.) was used asa metal: The temperature of the upper vessel 8 was kept at about 180.degree. C., and that of the lower vessel 11 at about 130.degree. C.

The results indicated that the solid spherical metal particles prepared using the systems A and B had approximately the same particle diameter distributions as in Example 1. The mean particle diameter was 7.0 .mu.m for system A and 7.1 .mu.m forsystem B, compared with 7.1 .mu.m for Example 1. The mean aspect ratio was 1.04 for system A and 1.03 for system B, compared with 1.03 for Example 1.

EXAMPLE 4

In order to compare with solder particles contained in commercially available solder pastes with respect to the extent of surface oxidation, two classes of solid spherical metal particles were prepared.

The solid spherical metal particles manufactured in Example 2 having a mean particle diameter of 30 .mu.m and the particle diameter distribution diagram 24 (sample E) were used for comparison with the solder particles in commercial product C.

For comparison with the solder particles in commercial product D, solid spherical metal particles (mean particle diameter: 30 .mu.m) (sample F) were used, the particles being obtained in accordance with Example 1 using as a metal a 96.5 Sn/3Ag/0.5 Cu lead free-solder ("#M705" manufactured by Senju Metal Industry Co., Ltd.) having a composition similar to that of commercial product D. The mean pore diameter of the porous glass membrane which was used was 10.61 .mu.m.

To evaluate the extent of surface oxidation, the heat of oxidation was measured using a differential scanning calorimeter (DSC). The solder particles were placed in a sample cup along with toluene, and the cup was put in a DSC sample chamber. High-purity nitrogen gas was passed through the chamber, which was held at 30.degree. C. After the toluene had evaporated and the calorimetric balance had become stable, air was passed through the chamber, and the heat of oxidation of the sample wasmeasured. The results were that the heat of oxidation generated was 15.9 J/g for commercial product C, 101.3 J/g for sample E, 23.0 J/g for commercial product D, and 94.8 J/g for sample F.

Converting into the heat of oxidation per unit surface area, the values were 1.1 kJ/m.sup.2 for commercial product C, 5.1 kJ/m.sup.2 for sample E, 1.3 kJ/m.sup.2 for commercial product D, and 4.7 kJ/m.sup.2 for sample F. These results indicatethat surface oxidation is proceeds very little with the solid spherical metal particles manufactured according to the method of the present invention, compared with the commercial products.

EXAMPLE 5

In a conventional membrane emulsification method applied to an oil-water dispersion system, the membrane is preferentially wetted by the continuous liquid phase rather than by the dispersed phase. Therefore, in the case where the continuousliquid phase is an oil phase, the surface of a porous glass membrane must be modified to be hydrophobic. In contrast, in accordance with the present invention, as long as the membrane is made of a material that is not wetted by the liquid metal, it ispossible to perform membrane emulsification in order to form a metal-oil emulsion even if the membrane is not subjected to special treatment to make it hydrophobic. To verify this and clarify the effects of a surfactant used as a dispersant,monodisperse solid spherical particles were prepared using the following procedure.

A low-melting metal of 50 Bi/26.7 Pb/13.3 Sn/10 Cd (tradename "U-alloy 70" manufactured by Nilaco Corporation) having a melting point of 70.degree. C. was used as a metal, toluene was used as an oil, and a tetraglycerol-condensed ricinolateester ("TGCR" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) or a sorbitan monooleate ester ("Span 80" manufactured by Wako Pure Chemical Industries, Ltd.) was used at a concentration of 2 wt % as an oleophilic surfactant.

A porous glass membrane having a mean pore diameter 2.52 .mu.m (of the CaO--B.sub.2O.sub.3--SiO.sub.2--Al.sub.2O.sub.3--Na.sub.2O--MgO type, tradename "SPG" manufactured by Miyazaki Prefecture Industrial Technology Center) was made hydrophobicwith a silicone resin (sold under the tradename "KP-18C" by Shin-Etsu Chemical Co., Ltd.), and membrane emulsification was carried out using this hydrophobic membrane with the above-mentioned "Span 80" and an apparatus as shown in FIG. 2. Thetemperature of the upper vessel 8 was set at about 80.degree. C., and that of the lower vessel 11 was set at room temperature.

Separately, the same membrane as above which had not been made hydrophobic (i.e., a hydrophilic membrane) was provided for use to perform membrane emulsification in the same manner as described above using the above-mentioned "TGCR" as anoleophilic surfactant. On the other hand, membrane emulsification was carried out in the same manner as above using the above-mentioned hydrophobic membrane and the above-mentioned "Span 80" as an oleophilic surfactant. Furthermore, membraneemulsification was carried out in the same manner as above using the above-mentioned hydrophilic membrane and the above-mentioned "TGCR" as an oleophilic surfactant.

The results were that in all cases, membrane emulsification started at a pressure of 0.56 to 0.58 MPa and monodisperse solid spherical metal particles having a mean particle diameter of 7.0 to 7.1 .mu.m and a high sphericity were obtained. Itwas thus verified that with the present invention, membrane emulsification can be carried out even if the membrane surface is not modified.

EXAMPLE 6

Spherical metal particles were produced using a low-melting metal and an aqueous phase as a continuous liquid phase.

A low-melting metal of 44.7 Bi/22.6 Pb/8.3 Sn/5.3 Cd/19.1 In (tradename "U-alloy 47" manufactured by Nilaco Corporation) having a melting point of 46.8.degree. C. was used as a metal in combination with a porous glass membrane having a mean porediameter of 2.52 .mu.m (of the CaO--B.sub.2O.sub.3--SiO.sub.2--Al.sub.2O.sub.3--Na.sub.2O--MgO type, tradename "SPG" manufactured by Miyazaki Prefecture Industrial Technology Center). Using as a continuous liquid phase (1) an aqueous solution containing0.5 wt % sodium dodecyl sulfate (SDS) (manufactured by Wako Pure Chemical Industries, Ltd.) as a water-soluble surfactant, (2) an aqueous 2 wt % solution of 60 mole-polyoxyethylene-added hardened castor oil (sold under the tradename "HCO-60" by NikkoChemicals Co., Ltd.), and (3) an aqueous 2 wt % solution of a 25 mole-polyoxyethylene-added alkyl ether (sold under the tradename "BL-25" by Nikko Chemicals Co., Ltd.), monodisperse solid spherical particles were prepared in each case via an M/W(metal/water) emulsion formed by membrane emulsification. An apparatus as shown in FIG. 2 was used, with the liquid temperature being set at about 60.degree. C. The membrane emulsification was carried out in the same manner as in Example 1 except forthe above-described conditions.

The results were that for all of the above-mentioned systems (1) to (3), the membrane emulsification started at a pressure of 0.56 to 0.58 MPa to produce monodisperse solid spherical metal particles having a mean particle diameter of 7.0 to 7.1.mu.m and a high sphericity.

EXAMPLE 7

Spherical metal particles having a relatively small particle diameter were produced using different liquids for the continuous phase.

A porous glass membrane having a mean pore diameter of 0.30 .mu.m and a 90% pore diameter to 10% pore diameter ratio of 1.22 (tradename "SPG" manufactured by Miyazaki Prefecture Industrial Technology Center) was used in combination with alead-containing solder having a melting point of 183.degree. C. (sold under the tradename "SN63" by Senju Metal Industry Co., Ltd., composition: 63 Sn/37 Pb) as a metal.

The following two systems were prepared as a continuous liquid phase to perform membrane emulsification.

A first system was prepared using liquid paraffin as a continuous phase liquid and a sucrose erucate ester (sold under the tradename "ER290" by Mitsubishi-Kagaku Foods Corporation) as an oil-soluble dispersant. Since this ester undergoes thermaldecomposition at about 183.degree. C. to cause dispersion stability to deteriorate, the membrane emulsification was carried out while the ester was continuously replenished. Other conditions were the same as in Example 1.

In a second system, a polyethylene glycol having a degree of polymerization of 600 was used as a continuous phase liquid, and a decaglycerol stearate ester (sold under the tradename "SWA-10D" by Mitsubishi-Kagaku Foods Corporation) was used as adispersant. Other conditions were the same as in Example 1.

With both of the continuous liquid phases, monodisperse lead solder spherical particles having a mean particle diameter of 0.85 .mu.m were obtained. It was thus verified that according to the present invention, particles having a mean particlediameter of less than 1 .mu.m can be manufactured and that either an oil-soluble or a water-soluble dispersant can be used.

EXAMPLE 8

Spherical metal particles having a relatively large particle diameter were produced.

The above-mentioned "U-alloy 47" was used as a low-melting metal, and a commercially available kerosene was used to form a continuous liquid phase along with an oleophilic surfactant "TGCR" as a dispersant. The manufacturing apparatus used formembrane emulsification was an apparatus as shown in FIG. 3 in which the system was heated at about 60.degree. C.

Four types of porous membrane were used: a porous glass membrane of flat membrane type having a mean pore diameter of 18.8 .mu.m (membrane G), a flat porous glass membrane prepared by subjecting membrane G to alkali etching to make the mean porediameter larger (membrane H), an epoxy resin flat membrane having a mean pore diameter of 100 .mu.m in which pores passed through the membrane perpendicular to the membrane surfaces (membrane I), and a stainless steel flat membrane having slit-shapedthrough holes measuring 50 .mu.m in width and 10 .mu.m in length (membrane J). Membrane J was coated with a fluorinated silane compound (sold under the tradename "KBM7803" by Shin-Etsu Chemical Co., Ltd.). The ratios of 90% pore volume to 10% porevolume of these membranes were 1.40 for membrane G and 1.62 for membrane H and were estimated at about 1.0 for both of membranes I and J.

The results were that monodisperse solid spherical metal particles of high sphericity were obtained in each case, with the mean particle diameter being 53 .mu.m for membrane G, 140 .mu.m for membrane H, 300 .mu.m for membrane I, and 35 .mu.m formembrane J. The results of observing the monodisperse solid spherical particles obtained with membrane G under an optical microscope are shown in FIG. 11. These results show that the manufacturing method of the present invention is capable of not onlycontrolling the particle diameter to be within the range of 1 to 100 .mu.m but also producing larger monodisperse solid spherical particles.