IMO this is something your accountant should provide for you along with general advice on your tax planning for your business and your potential exit strategy if you were to finish contracting (assuming you are an IT contractor as you mention Pathway).

The dividend payment of £39,980 is grossed up by 100/90 to show a gross amount of £44,422.22 - you then receive a notional credit of £4,442.22 resulting in the net amount you gave. So no further tax due on the basic rate income as it is charged on dividends at 10% but you have your 10% notional tax paid already.

So your tax bill we be calculated as follows:

First £5,220 0%

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The dividend payment of £39,980 is grossed up by 100/90 to show a gross amount of £44,422.22 - you then receive a notional credit of £4,442.22 resulting in the net amount you gave. So no further tax due on the basic rate income as it is charged on dividends at 10% but you have your 10% notional tax paid already. Its only the higher rate amount that is subject to additonal tax.