Long Stokes shifts and vibronic couplings in perfluorinated polyanilines.

Chemical communications (Cambridge, England) 53 (2017) 2602-2605

P Dallas, I Rašović, T Puchtler, RA Taylor, K Porfyrakis

We report the effect of surfactant addition on the optical properties of perfluorinated polyanilines synthesized through liquid-liquid interfaces. We obtained very long Stokes shifts, 205 nm, for oligomers derived from a hydrofluoroether-water system in the presence of Triton X-100 as a surfactant, and vibronic fine features from a toluene-water system.