Forget solid, liquid, and gas: there are in fact more than 500 phases of matter. In a major paper in a recent issue of Science, Perimeter Faculty member Xiao-Gang Wen reveals a modern reclassification of all of them.Condensed matter physics — the branch of physics responsible for discovering and describing most of these phases — has traditionally classified phases by the way their fundamental building blocks — usually atoms — are arranged. The key is something called symmetry.

Artist’s impression of a string-net of light and electrons. String-nets are a theoretical kind of topologically ordered matter. (Credit: Xiao-Gang Wen/ Perimeter Institute)

To understand symmetry, imagine flying through liquid water in an impossibly tiny ship: the atoms would swirl randomly around you and every direction — whether up, down, or sideways — would be the same. The technical term for this is “symmetry” — and liquids are highly symmetric. Crystal ice, another phase of water, is less symmetric. If you flew through ice in the same way, you would see the straight rows of crystalline structures passing as regularly as the girders of an unfinished skyscraper. Certain angles would give you different views. Certain paths would be blocked, others wide open. Ice has many symmetries — every “floor” and every “room” would look the same, for instance — but physicists would say that the high symmetry of liquid water is broken.

Classifying the phases of matter by describing their symmetries and where and how those symmetries break is known as the Landau paradigm. More than simply a way of arranging the phases of matter into a chart, Landau’s theory is a powerful tool which both guides scientists in discovering new phases of matter and helps them grapple with the behaviours of the known phases. Physicists were so pleased with Landau’s theory that for a long time they believed that all phases of matter could be described by symmetries. That’s why it was such an eye-opening experience when they discovered a handful of phases that Landau couldn’t describe.

Beginning in the 1980s, condensed matter researchers, including Xiao-Gang Wen — now a faculty member at Perimeter Institute — investigated new quantum systems where numerous ground states existed with the same symmetry. Wen pointed out that those new states contain a new kind of order: topological order. Topological order is a quantum mechanical phenomenon: it is not related to the symmetry of the ground state, but instead to the global properties of the ground state’s wave function. Therefore, it transcends the Landau paradigm, which is based on classical physics concepts.

Topological order is a more general understanding of quantum phases and the transitions between them. In the new framework, the phases of matter were described not by the patterns of symmetry in the ground state, but by the patterns of a decidedly quantum property — entanglement. When two particles are entangled, certain measurements performed on one of them immediately affect the other, no matter how far apart the particles are. The patterns of such quantum effects, unlike the patterns of the atomic positions, could not be described by their symmetries. If you were to describe a city as a topologically ordered state from the cockpit of your impossibly tiny ship, you’d no longer be describing the girders and buildings of the crystals you passed, but rather invisible connections between them — rather like describing a city based on the information flow in its telephone system.

This more general description of matter developed by Wen and collaborators was powerful — but there were still a few phases that didn’t fit. Specifically, there were a set of short-range entangled phases that did not break the symmetry, the so-called symmetry-protected topological phases. Examples of symmetry-protected phases include some topological superconductors and topological insulators, which are of widespread immediate interest because they show promise for use in the coming first generation of quantum electronics.

In the paper featured in Science, Wen and collaborators reveal a new system which can, at last, successfully classify these symmetry-protected phases.

Using modern mathematics — specifically group cohomology theory and group super-cohomology theory — the researchers have constructed and classified the symmetry-protected phases in any number of dimensions and for any symmetries. Their new classification system will provide insight about these quantum phases of matter, which may in turn increase our ability to design states of matter for use in superconductors or quantum computers.

This paper is a revealing look at the intricate and fascinating world of quantum entanglement, and an important step toward a modern reclassification of all phases of matter.