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No.

Reasons:

Their tiers. If ones in OU or in higher tiers are included in a team with some of the NU ones, your team will be destroyed.

Similar roles. They won't be very good in a team together due to their similar roles; most of them have one or two particularly high stats and the rest are average, making your team lack some vital roles.

They're often outclassed. A team of multiple Pokemon and not Eeeveelutions works better due to the fact that some of them are strongly outclassed by other members of their type. There are better Pokemon to suit a team than some of the Eeveelutions.

To answer your sub-question, sort of. Their types vary and on one team there will likely be a type to cover everything excepting Dragons (Glaceon is a rare sight). However their lack of dual types means they loss some important types meaning they can be unsuccessful competitively.

No. They have great synergy, but just no. There are way better Pokemon to replace it. there are only like 4 great eevee Pokemon and they are jolteon vaporeon espeon and umbreon. Leafeon is pretty good but there are way better tanks. I would suggest using a regualar team. They get outclassed for exampe flareon is supposed to be a physical attac right? It has a poor physical movepool and other Pokemon can outclass it. take heatran for exampe. It isn't a physical attacker, but it has high special defense ike flareon and high attacing stats. Wouldn't you rather use heatran than flareon?