The US supreme court has ruled unanimously that natural human genes cannot be patented, a decision that scientists and civil rights campaigners said removed a major barrier to patient care and medical innovation.

After completing a medical and the requisite paperwork on Tuesday to seal the deal, Di María said: “I am absolutely delighted to be joining Manchester United. I have thoroughly enjoyed my time in Spain and there were a lot of clubs interested in me, but United is the only club that I would have left Real Madrid for.