Jolie's Madonna outrage

The couple - who are currently in India filming 'A Mighty Heart' - have allegedly been left "shocked" after Madonna blasted their involvement in the building of an Indian orphanage.

A source told Britain's Star magazine: "Angelina is shocked. She can't believe it. She was like, 'Where did that come from?' It seemed like a personal attack.

"Madonna's remarks just sound nasty. Angelina thinks the worst part of it all is that Madonna could have used the opportunity to say something that could actually be of benefit to someone."

As well as reportedly criticising Brad and Angelina's work with orphanages, Madonna - who has sparked controversy after adopting a Malawian baby called David - also seemed to trivialise Angelina's role as a UN Goodwill Ambassador.

The 48-year-old pop superstar said: "I'm not interested in going in there like an idiot and going, 'OK, I'm going to build ten orphanages and I'll see you guys later'."

"I could've joined the UN and become an ambassador, visited various countries and just showed up and smiled and looked concerned. But that's not getting to the root of the problem. And neither is building orphan care centres."