At 5-9, the diminutive outfielder earned the nickname "Toy Cannon" for his powerful arm. He debuted with the Colt .45s in 1963.

Wynn finished his career with a .250 batting average, 291 homers and 964 RBIs. After his run with the Astros, he was a two-time All-Star with the Dodgers and played for the Braves, Yankees and Brewers.

His No. 24 was retired by the Astros in 2005 and in 2019 he was a part of the inaugural Astros Hall of Fame class.

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Wynn was serving as a community outreach executive with the Astros at the time of his death.