Foundations of colloid science, Volume 2

From inside the book

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Page 705It turns out that for the hard sphere fluid the compressibility result is an
overestimate of the pressure while the virial result is an underestimate. An
heuristic equation constructed by Carnahan and Starling (see Hansen and
McDonald 1976) p 1 ...

Page 844Re-work their derivation to obtain the correct results. Check your answer by
taking limiting cases which reduce to the known monodisperse result (e.g. by
letting both diameters tend to the same size or by letting the density of one
component ...

Page 893A combination of B, and C, for example would give a result like that shown in Fig.
15.4.6, which resembles very closely the potential energy diagram for the classic
kinetically stabilized lyophobic colloid (Chapter 7) when the steric or hydration ...