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Narrative:THE PLT DEPARTED KNOXVILLE IN VFR CONDS. THERE WAS AN AREA OF IFR WX TO THE NORTH & NORTHWEST OF KNOXVILLE. THE WX WAS FORECAST TO BE MARGINAL ALONG HIS ROUTE OF flight. THE PLT RPRTD HE WANTED TO DEPART KNOXVILLE ON A HEADING OF 360 DEG & WOULD BE AT 2500'. THE MAX ELEV FOR THE SECTOR JUST NORTH OF KNOXVILLE WAS 3900'. THE 1349 EDT WX AT THE DEPARTURE airport (MCGHEE TYSON, ELEV 981') WAS 1900' OVERCAST, VISIBILITY 10 MI WITH RAIN & FOG. SUBSEQUENTLY, THE ACFT COLLIDED WITH MOUNTAINOUS TERRAIN AT AN ELEV OF 2350', APRX 27 MI NORTH OF MCGHEE TYSON. WITNESSES NEAR THE CRASH SITE INDICATED THE MOUNTAINS WERE OBSCURED BY CLOUDS, FOG & RAIN. CAUSE: