Fan, ChaoLv, Xin-YangXiao, Li-JunXie, Jian-HuaZhou, Qi-LinAlkenyl
Exchange of Allyl­amines via Nickel(0)-Catalyzed
C–C Bond CleavageA functional group
exchange reaction between allyl­amines
and alkenes via nickel-catalyzed CC bond cleavage and formation
was developed. This reaction provides a novel protocol, which does
not require the use of unstable imine substrates, for the synthesis
of allyl­amines, which are widely used in the production of fine
chemicals, pharmaceuticals, and agrochemicals.alkene;pharmaceutical;Allyl;group exchange reaction;chemical;novel protocol;imine substrates;synthesis;allyl;nickel-catalyzed;agrochemical;formation;Cleavage;Alkenyl Exchange;Bond;cleavage;bond2019-02-08