NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools.

Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

PREVENT GENERATION OF MISTS!

SYMPTOMS

ACUTE HAZARDS

FIRST AID

Inhalation

Cough. Drowsiness.

Use ventilation, local exhaust or breathing protection.

Fresh air, rest.

Skin

Redness. Dry skin.

Protective gloves.

Remove contaminated clothes. Rinse and then wash skin with water and soap.

Eyes

Redness.

Wear safety spectacles.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Ingestion

Drowsiness. Laboured breathing. Nausea.

Rinse mouth. Do NOT induce vomiting. Refer for medical attention .

SPILLAGE DISPOSAL

CLASSIFICATION & LABELLING

Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Remove all ignition sources. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.

According to UN GHS Criteria

TransportationUN Classification
UN Hazard Class: 3; UN Pack Group: II

STORAGE

Fireproof. Separated from strong oxidants. Cool. Well closed. Store only if stabilized.

Routes of exposureThe substance can be absorbed into the body by inhalation and by ingestion.

Effects of short-term exposureThe substance is irritating to the eyes, skin and respiratory tract. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. The substance may cause effects on the central nervous system.

Inhalation riskA harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.

Effects of long-term or repeated exposureThe substance defats the skin, which may cause dryness or cracking.

Occupational exposure limits

TLV: 300 ppm as TWA

ENVIRONMENT

NOTES

An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.Check for peroxides prior to distillation; render harmless if positive.

ADDITIONAL INFORMATION

EC Classification

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