Prophetic Commentary on the Qur'an (Tafseer of the Prophet
(pbuh))

Bukhari :: Book 6 :: Volume 60 :: Hadith 386

Narrated Abdullah:

The first Sura in which a prostration was mentioned, was Sura
An-Najm (The Star). Allah's Apostle prostrated (while reciting it),
and everybody behind him prostrated except a man whom I saw taking
a hand-full of dust in his hand and prostrated on it. Later I saw
that man killed as an infidel, and he was Umaiya bin Khalaf.