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Glenn Power from the CFMEU said Rio Tinto's decision to pay union members lower redundancies than those on individual agreements highlighted its anti-union agenda.

"Workers don't take the prospect of strike action lightly," Mr Power said in a statement on Monday.

"But when faced with a much lower redundancy package than someone they've worked alongside for years, these workers are determined to tell Rio that the company can't get away with this parting shot of discrimination."