"The trick to win over the audience is my fan," said Chen. "It's very fierce if I get it right."

Photo: CBS

Chen will employing all her tricks in The Talk's second annual "Rocktober Lip Sync War" episode on Monday, in which the co-hosts compete against each other dressed as some of music's biggest icons. This installment offers a special treat, as Lip Sync Battle's LL Cool J will host.