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They received a highly unusual private tour of the Queen's official residence, according to reports.

No members of the royal family were present for the visit.

Normally the palace is open for tours only for a few weeks in July and August.

Earlier yesterday Angelina — who is divorcing her husband Brad Pitt — admitted she had "butterflies" before taking a lesson with postgraduate students at the LSE’s Centre for Women, Peace and Security.

She told them about her experience in the field as a UN special envoy and how sexual violence is used as a tool of war.

Also while in London, Angelina launched a campaign against rape in war alongside William Hague in a discussion panel organised by the Foreign and Commonwealth Office.

As Lord Hague said many are at risk of sexual assaults in war zones, Angelina said there was "much more to do".

Five years on from the launch of the Preventing Sexual Violence Initiative, the Hollywood star called for more prosecutions, increased evidence gathering and better training for armies.

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UN special envoy Angelina waved to fans as she arrived at the top London universityCredit: Eyevine

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The star spoke of her experiences of meeting women in war zonesCredit: Eyevine

She said: "All of us involved in PSVI are proud of the work so far.

"But with much more to do we are very focused on the next steps: taking the tools that have been developed into the field to help document crimes and support prosecutions, working with militaries to change doctrine and training, and pushing for the implementation of laws to protect the very vulnerable victims".

Angelina, special envoy of the UN High Commissioner for Refugees, launched the campaign against rape in war with Lord Hague, then Foreign Secretary, in 2012.