Administrative data

First-aid measures

Description of first aid measures General Advice:In case of exposure seek medical advice.If person is unconscious and breathing place in recovery position.If person is not breathing give artificial respiration and immediately seek medical advice.In the event of exposure by inhalation:If breathed in, move person into fresh air. If not breathing, give artificial respiration. Immediately seek medical advice.In the event of splashes or contact with eyes:Rinse cautiously with fresh, clean water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing withwater for 15 minutes holding the eyelids open.If there is any redness, pain or visual impairment seek medical attention.In the event of splashes or contact with skin:Remove contaminated clothing and wash the skin thoroughly with soap and water.Watch out for any remaining product between skin and clothing, watches, shoes, etc.If the contamination is to a large area and/or there is damage to the skin, seek medical advice immediately.In the event of swallowing:Seek medical advice immediately. Show the label.Do not induce vomiting.Do not give the patient anything orally.If the quantity is small (no more than one mouthful), rinse the mouth with water and seek medical advice.

Fire-fighting measures

1. Extinguishing mediaSuitable methods of extinctionIn the event of a fire, use:Water spray, alcohol-resistant foam, dry chemical or CO2 extinguisher.Unsuitable methods of extinctionIn the event of a fire, do not use:None.

2 Special hazards arising from the substance or mixtureA fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.Do not breathe in smoke.In the event of a fire, the following may be formed:- Carbon monoxide (CO)- Carbon dioxide (CO2)- Hydrogen chloride (HCl)- Hydrogen bromide (HBr)

3 Advice for firefightersDue to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel are to be equipped withbreathing apparatus.Use water to cool unopened containers.

Accidental release measures

For non- emergency personnelUse personal protective equipment.Avoid any contact with the skin and eyes. Avoid breathing vapours, mist or gas.If a large quantity has been spilt, evacuate all personnel and only allow intervention by trained operators equipped with safetyequipment.

For emergency respondersEmergency responders must use suitable personal protective equipment.

2. Environmental precautionsPrevent any material from entering drains or waterways. Discharge into the environment must be avoided.

3. Methods and material for containment and cleaning upPick up without creating dust. Keep in suitable closed containers for disposal according to local regulations

Handling and storage

Requirements relating to storage premises apply to all facilities where the substance is handled.

1. Precautions for safe handlingAvoid contact with skin and eyes. Always wash hands after handling.Remove and wash contaminated clothing before re-using. Avoid inhalation of vapour or mist.Do not allow material to enter drains or waterways.

Fire preventionHandle in well-ventilated areas.Keep away from sources of ignition. Take measures to prevent the build-up of electrostatic charge.Prevent access by unauthorised personnel.

Marine transport (IMDG)

Air transport ICAO/IATA

Additional transport information

Additional transport information

Exempt from transport classification and labelling

Exposure controls / personal protection

1. Control parametersContains no substances with occupational exposure limit values.

2. Exposure controlsHandle in accordance with good industrial hygiene and safety practice. Ensure that there is adequate ventilation, especially in confinedareas. Never eat, drink or smoke during use. Wash hands before breaks and at the end of workday.

Use personal protective equipment that is clean and has been properly maintained. Store personal protective equipment in a clean place, away from the work area. Remove and wash contaminated clothing before re-using

Hand protectionAvoid skin contact.Use suitable protective gloves that are resistant to chemical agents in accordance with EU Directive 89/686/EEC and standard EN374. Gloves must be selected according to the application and duration of use at the workstation in question: other chemical products that may be handled, necessary physical protection (cutting, pricking, heat protection), level of dexterity required.Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.Wash and dry hands.

Body protectionAvoid skin contact.Wear suitable impervious protective clothing selected according to the concentration and amount of the substance at the specificworkstation.Work clothing worn by personnel shall be laundered regularly.

Respiratory protectionAvoid breathing vapours or mist.If the ventilation is insufficient, wear appropriate breathing apparatus.Where air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN14387) respirator cartridges as a backup to standard exposure controls. If the respirator is the sole means of protection, use a full-face supplied air respirator.

Stability and reactivity

1. ReactivityThe product is stable under normal conditions of use.

2. Chemical stabilityThis substance is stable under the recommended handling and storage conditions in Section 7.

Disposal considerations

Proper waste management of the substance and/or its container must be determined in accordance with Directive 2008/98/EC.

1. Waste treatment methodsContact a licensed professional waste disposal service to dispose of this material. Offer surplus and non-recyclable solutions to alicensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

Waste:Waste management must be carried out without endangering human health, without harming the environment and, in particular, without risk to water, air, soil, plants or animals.Recycle or dispose of waste in compliance with current legislation via a certified collector or company. Do not contaminate the ground or water with waste, do not dispose of waste into the environment.

Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.

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