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H01L—SEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR

H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof

H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof

H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70

H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics

H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors

C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL

C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material

H01L—SEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR

H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof

H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof

H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer, carrier concentration layer

H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer, carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials

H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in H01L21/20 - H01L21/268

H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current

H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation

H01L21/28506—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers

H01L21/28512—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic System

H01L21/28518—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic System the conductive layers comprising silicides

H—ELECTRICITY

H01—BASIC ELECTRIC ELEMENTS

H01L—SEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR

H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof

H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof

H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70

H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics

H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors

H01L21/76841—Barrier, adhesion or liner layers

H01L21/76843—Barrier, adhesion or liner layers formed in openings in a dielectric

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

Abstract

The present invention provides a method of forming a contact structure comprised of: a silicon substrate, a titanium silicide layer, a barrier (i.e., TiN or TiNO), and a metal layer (e.g., Al or W). There are three embodiments of the invention for forming the titanium silicide layer and two embodiments for forming the barrier layer (TiN or TiNO). The first embodiment for forming a TiSix layer comprises three selective deposition steps with varying TiCl4: SiH4 ratios. After the TiSix contact layer is formed a barrier layer and a metal plug layer are formed thereover to form a contact structure. The method comprises forming a barrier layer 140 over the silicide contact layer 126; and forming a metal plug 160 over the TiN barrier layer 140. The metal plug 160 is composed of Al or W.

Description

This is a division of patent application Ser. No. 08/954,047, filing date Oct. 20, 1997, now U.S, Pat. No. 5,856,237 Insitu Formation Of Tisi2/Tin Bi-Layer Structures Using Self-Aligned Nitridation Treatment On Underlying Cvd-Tisi2 Layer, assigned to the same assignee as the present invention.

BACKGROUND OF THE INVENTION

1) Field of the Invention

This invention relates generally a semiconductor device and a method for manufacturing and more particularly to a structure of a MOS transistor having a metal silicide film formed on a source and a drain region and a method for manufacturing the MOS transistor and more particularly to a method for forming a metal silicide contact to a substrate and more specifically to a multilayered device metallization suitable for use in small geometry semiconductor devices and to methods for its fabrication.

2) Description of the Prior Art

There is a trend in the semiconductor industry toward fabricating larger and more complex functions on a given semiconductor chip. The larger and more complex functions are achieved by reducing device sizes and spacing and by reducing the junction depth of regions formed in the semiconductor substrate. Among the feature sizes which are reduced in size are the width and spacing of interconnecting metal lines and the contact openings through which the metalization makes electrical contact to device regions As the feature sizes are reduced, new problems arise which must be solved in order to economically and reliably produce the semiconductor devices.

As both the contact size and junction depth are reduced, a new device metallization process is required to overcome the problems which are encountered. Historically, device interconnections have been made with aluminum or aluminum alloy metallization. Aluminum, however, presents problems with junction spiking which result from dissolution of silicon in the aluminum metallization and aluminum in the silicon. This problem is exacerbated with the small device sizes because the shallow junction is easily shorted and because the amount of silicon available to satisfy the solubility requirements of the aluminum metallization is only accessed through the small contact area, increasing the resultant depth of the spike. Adding silicon to the aluminum metallization has helped to solve this problem, but has, in turn, resulted in silicon precipitation and other problems.

A variety of solutions have been attempted to overcome the problems inherent with aluminum metallization. For example, the device region exposed through a contact opening has been metallized with chemical vapor deposited (CVD) tungsten. The tungsten is deposited by the reduction of WF6 with hydrogen. The WF6, however, initially reacts with the silicon surface, employing silicon from the contact area in the region. This results in what has become known in the literature as “worm holes” or tunnels in the silicon which can also cause shorting of the underlying junction. The use of sputtered instead of CVD tungsten would overcome the problem of reaction with the silicon, but sputtered tungsten is unable to reduce any native oxide film which may be present on the surface of the device region. The remaining oxide film results in high contact resistance. A further attempt at solving this problem has employed the use of a reactive silicide to make the initial contact to the device region. The silicide is then contacted with aluminum. The suicide makes a low resistance contact to the silicon, but the silicide-aluminum contact has the same problem as does the use of aluminum directly on the silicon. Silicon from the suicide and from the underlying junction dissolves in the aluminum, resulting in aluminum spikes through the underlying junction.

Another problem which is exacerbated by the shrinking device sizes is that of unreliable step coverage by the device metallization as it traverses steps in the device topography and especially as the metallization traverses into the contact openings. It is therefore especially beneficial if the contact metallization provides a relatively planar surface to which the interconnect metallization can be applied.

As shown in FIG. 5A, a conventional method of forming a contact is by sputtering a Ti/TiN layer 200 over the isolation layer 20 sidewalls of a contact opening 20A and over a substrate surface. However the sputtered Ti/TiN layer 200 provides poor step coverage especially on the bottom.

As shown in FIG. 5B, the Ti/TiN layer 200 in the contact hole 20A takes up space and makes filling the contact hole 20A more difficult. The TiN layer 200 overhangs 215 the opening. This overhang 215 makes the void 211 problem in the metal plug 210 worse. Also, at the TiSix 214 at the bottom in incomplete thus causing high contact resistance and yield problems. At the corners, leakage 216 (Worm holes) also occur. WF6 attacks the uncapped underlying Si to form worm holes 216 or insufficient corner coverage of TiN barrier results in formation of volatile TiF4 gas and/or TiFx (x=1 to 3) higher resistance solid compound. The former TiF4 will cause volcano formation and the latter (TiFx) leads to high resistance contacts.

The following U.S. patents show related processes and contact structures. U.S. Pat. No. 5.103,272 (Nishiyama) shows a TiSix layer and a TiN layer. The TiN layer is formed using an N2I/I. U.S. Pat. No. 4,851,369(Ellwanger et al.) forming an interconnect comprising a TiSix covered by a W plug. U.S. Pat. No. 5,545,592(Lacoponi) shows a method of forming a contact using a TiSix and a TiN layer. U.S. Pat. No. 4,926,237(Sun et al.) shows a contact using TiSix, TiN and a W plug.

There still exist a need for an improved contact method and structure.

SUMMARY OF THE INVENTION

It is an object of the present invention to provide a method for fabricating a contact structure consisting of a silicon substrate, a titanium silicide layer, a barrier layer (TiN or TiNO layer), and a metal layer (e.g., Al or W).

It is an object of the present invention to provide a method for fabricating a contact structure consisting of a silicon substrate, a titanium silicide layer, a barrier layer (TiN or TiNO layer), and a metal layer (e.g., Al or W) wherein said titanium silicide layer is selectively deposited on the substrate surface.

It is another object of the present invention to provide a method for fabricating a contact structure consisting of a silicon substrate, a titanium silicide layer, a TiN barrier layer, and a metal layer (e.g., Al or W) wherein the TiN layer is formed by a self-aligned nitridation process.

It is another object of the present invention to provide a method for fabricating a contact structure consisting of a silicon substrate, a titanium silicide layer, a TiNO barrier layer, and a metal layer (e.g., Al or W) wherein the TiNO layer is formed by a nitration process using a N and O containing gas.

It is yet another object of the present invention to selectively form TiSi2 on doped silicon regions and form TiN insitu so that the TiSix/TiN formation are performed in one reaction chamber.

It is yet another object of the present invention to form TiSi2 and TiN over the doped Silicon areas and in salicided structures.

To accomplish the above objectives, the present invention provides a method of forming a contact structure comprising of: a silicon substrate, a titanium silicide layer, a barrier layer (i.e., TiN or TiNO), and a metal layer (e.g., Al or W). There are three embodiments of the invention for forming the titanium suicide layer and two embodiments for forming the barrier layer.

The first embodiment for forming selectively depositing a TiSix layer comprising the steps of:

b) FIG. 1A—insitu clean the substrate 10 using of a gas selected from the group consisting of SiH4 and H2 for plasmaless cleaning or conventional dep dual frequency Ar or Ar/H2 soft sputter etch cleaning;

e) FIG. 1D—selectively depositing a third titanium silicide TiSi2 layer 30C at an intermediate TiCl4/SiH4 flow and using a chloride containing gas of a material selected from the group consisting of HCL and ClF3; the first, second, and third titanium silicide layers forming a Titanium silicide contact layer 30.

The second embodiment for forming selectively depositing a TiSix layer comprising the steps of:

f) Step 5—selectively depositing second titanium silicide (TiSi2 ) layer 32B over the first titanium silicide layer 32A using a selective deposition process with an intermediate TiCl4/SiH4 flow ratio and using a chloride containing gas of a material selected from the group consisting of HCL and ClF3; the first and second titanium silicide layers forming a titanium silicide contact layer.

The third embodiment for forming selectively depositing a TiSix layer comprising the steps of:

a) FIG. 3A—forming first insulating layer 20 having a contact opening 20A on a substrate;

b) insitu cleaning the substrate 10 using of a gas selected from the group consisting of SiH4 and H2;

c) insitu depositing a first TiSix/Ti layer 3435A over the first insulating layer 20 and the substrate 10 using a plasma enhanced chemical vapor deposition process at a temperature less than 600 ° C. using TiCl4 and H2 gasses;

d) FIG. 3B etching the Ti layer 34 using a TiCl4 plasma to remove the Ti layer 34 over the first insulating layer 20; the TiSix layer 35A composed of C49-TiSix;

The three embodiments for forming the Titanium silicide contact layer has many advantages over the conventional TiSix processes.

(1) Because the TiSix layer is selectively deposited on the contact area, a wet etch is eliminated and 2 RTP steps are eliminated. The first RTP forms C49-TiSi2 and wet etch to remove unreacted Ti. This is followed with a second RTP to form C54-TiS2. But the invention's direct CVD TiSi2 can selectively form C54 TiSi2.

(4) Low cost of ownership—The invention eliminates the two RTP steps, 1 wet etch steps of the previous salicide process and also the TiN deposition step.

After the TiSix contact layer is formed over the substrate preferably using one of the above three embodiments, a barrier layer and a metal plug layer are formed thereover to form a contact structure. The method of forming a contact structure (composed of a Titanium slicide layer /(TiN or TiNO)bilayer) for contacting a substrate of a semiconductor device; comprising the steps of:

c) forming a metal plug 160 over the TiN barrier layer 140; the metal plug 160 composed of a material selected from the group consisting of Al and W.

In the fourth embodiment of the invention, the barrier layer is composed of TiN and the barrier layer is formed using a self-aligned nitridation treatment performed insitu using a nitrogen containing gas of N2 or NH3, using a plasma process.

In the fifth embodiment of the invention, the barrier layer composed of Ti—N—O and the barrier layer is formed using a of a process selected from the group consisting of (1) nitridation in a nitrogen and oxygen containing ambient and (2) a two step nitridation and oxidation treatment.

The present invention has a novel in-situ and self-aligned nitridation on TiSi2 top surface to produce an insitu TiSi2/TiN bi-layer selective deposition. Furthermore, the TiSi2/TiN bi-layer can cover entirely the diffusion regions as well as poly-gate to form low resistant self-aligned silicide barrier structure.

The invention provide the following benefits.

(1) The invention reduces the number of process steps by performing the in-situ nitridation treatment on TiSi2 just after the selective TiSi2 CVD process step via plasma nitridation or RTN to combine the salicide and TiN deposition process steps.

(2) The process of the invention eliminates the poor step coverage problem caused by TiN deposition.

(3) The TiSi2/TiN is sequentially formed in one chamber under vacuum, suppresses the contamination path and protects the TiSi2.

(4) TiSi2/TiN is formed before the dielectric deposition, the Tin aye can improve the TiSi2 thermal stability and reduce the contact RIE damage.

BRIEF DESCRIPTION OF THE DRAWINGS

The features and advantages of a semiconductor device according to the present invention and further details of a process of fabricating such a semiconductor device in accordance with the present invention will be more clearly understood from the following description taken in conjunction with the accompanying drawings in which like reference numerals designate similar or corresponding elements, regions and portions and in which:

FIGS. 1A through 1E are cross sectional views for illustrating a first embodiment for form the titanium silicide layer according to the present invention.

FIGS. 2A through 2F are cross sectional views for illustrating a first embodiment for form the titanium silicide layer according to the present invention.

FIGS. 3A through 3D are cross sectional views for illustrating a third embodiment for forming the titanium silicide layer according to the present invention.

FIGS. 4A through 4F are cross sectional views for illustrating the 4th and 5th embodiments for forming the Barrier layer and plug over a titanium silicide layer according to the present invention.

FIGS. 5A and 5B are cross sectional views for illustrating a contact structure according to the prior art.

FIG. 6 is a graph of showing the three SiCl3 to SiH4 flow ratio regimes (A, B and C) of the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

The present invention will be described in detail with reference to the accompanying drawings. The present invention provides a method of forming a contact structure comprising a silicon surface (e.g., substrate or gate), a titanium silicide layer, a barrier layer (i.e., TiN or TiNO), and a metal layer (e.g., Al or W). There are three embodiments of the invention for forming the titanium silicide layer and two embodiments for forming the barrier layer which are disclosed below. See table 1 below:

TABLE 1

Overview of the Invention - Embodiments Of The Invention

OVERVIEW OF THE INVENTION

SELECTIVE TiSi2 FORMATION

3 Embodiments

(1) 3 step TiSix Selective

(2) Selective Si Growth with

(3) Ti Dep/Plasma Etch/RTA

deposition-

Etch back and TiSix Selective

FIGS. 4A to 4F

FIGS. 1A to 1D

Dep

FIGS. 2A to 2E

BARRIER LAYER FORMATION

2 Embodiments -

See FIGS. 4A to 4F.

(4) TiN barrier layer

(5) TiNO barrier layer

METAL PLUG FORMATION

A1 or W plug

The following information applies to all three embodiments for forming the TiSix layer. The TiSix deposition processes for the first three embodiments use varying ratios of reactant gasses to form TiSx layer that are either, deposit Si (Regime A), not deposit Si (Regime B), or consume Silicon (Regime C). FIG. 6 the tables below explain this process.

FIG. 6 shows a graph of the TiCl4 flow rates vs SiH4 flow rates.

TABLE 3

Regimes of TiCl4 to SiH4 flow ratios shown in FIG. 6

Regime A

represents the TiCl4 to SiH4 flow ratios that TiSi2 will selectively deposit with the

underlying Si layer.

Regime B

represents the optimal regime between regime A and C. In Regime C, TiSi2 can

selectively deposit and consume the Si approximately equal to the is supplied from the

SiH4 (or SiH2Cl2) decomposition.

Regime C

represents the TiCl4 to SiH4 flow ratios that TiSi2 will selectively deposit without

the Si layer and will consume more Si (from under the TiSi2 layer) rather than the Si

supplied by SiH4 decomposition.

TABLE

Preferred Flow ratios for the 3 regimes - for all Three embodiments

Part 1- 1st

Tgt

embodiment -

flow

selective TiSix

Low

Tgt

Hi

Low

tgt

Hi

Low

TiCl4/

contact layer

Temp

Temp

temp

Press

Press

Press

flow

SiH4

Hi

formation

(C °)

(C °)

(C °)

(mtorr)

(mtorr)

(mtorr)

ratio

ratio

flow

lower TiCl4/SiH4

500

700

1000

50

2 torr

50 torr

0.005

0.01

0.08

flow ratio -

mtorr

Regime A

intermediate

500

700

1000

50

2 torr

50 torr

0.08

0.1

0.02

TiCl4/SiH4 flow

mtorr

ratio -

Regime B

higher TiCl4/SiH4

500

700

1000

50

2 torr

50 torr

0.2

0.05

10

flow ratio -

mtorr

Regime C

The three regimes (A, B and C) apply to all three embodiments of the invention. In addition the reactant gasses can be either TiCl4 /SiH4 or TiCl4/SiH2Cl2.

As shown in FIG. 6, the slopes of lines L1 and L2 are dependent on various process parameters like temperature, pressure, plasma (on or off). The deposition processes for steps 2 through 4 (for all three embodiments) can be RTCVD, low pressure chemical vapor deposition (LPCVD), or plasma enhanced chemical vapor deposition (PECVD).

II. First Embodiment for Forming Selectively Depositing a TiSix Layer

The table below summarized the important steps and low/high process parameters for the first embodiment. See FIGS. 2A-2E.

TABLE 2

1st Embodiment - Summary Of Steps And Preferred Process Limits

Part 1- 1st

embodiment

selective TiSix

Low

Tgt

Hi

Low

Tgt flow

contact layer

Temp

Temp

temp

Press

tgt Press

Hi Press

Low flow

TiCl4/SiH4

Hi

formation

(C °)

(C °)

(C °)

(mtorr)

(mtorr)

(mtorr)

ratio

ratio

flow

Step 1- insitu

650

720

750

0.1 mtorr

1

mtorr

5

mtorr

0

0

0

clean - SiH4

step 2- 1st TiSi2

500

700

1000

50 mtorr

2

torr

50

torr

0.005

0.01

0.08

selective

deposition - lower

TiCl4/SiH4 flow

ratio -

Regime A

step 3- 2nd TiSi2

500

700

1000

50 mtorr

2

torr

50

torr

0.2

0.05

10

selective

deposition - higher

TiCl4/SiH4 flow

ratio -

Regime C

Step 4- 3rd TiSi2

500

700

1000

50 mtorr

2

torr

50

torr

0.08

0.1

0.02

selective

deposition -

intermediate

TiCl4/SiH4 flow

ratio - Regime B

For the first embodiments (See table above) steps 1 though 4 are preferably preformed at a pressure between about 0 and 10 torr and at a temperature between about 400 and 800° C.

The first embodiment for selectively depositing a TiSix layer is shown and described in FIGS. 1A to 1D. As shown in FIG. 1A, first insulating layer 20 having a contact opening 20A is formed on a substrate 10. Substrate 10 is understood to possibly include a semiconductor wafer, active and passive devices formed within the wafer and layers formed on the wafer surface. The term “substrate” is mean to include devices formed within a semiconductor wafer and the layers overlying the wafer. The term “substrate surface” is meant to include the upper most exposed layers on a semiconductor wafer, such as a silicon surface, an insulating layer and metallurgy lines.

The first insulating layer 20 can be formed on any insulating material including silicon oxide, silicon oxynitride and silicon nitride and any combination of insulative layers. The contact opening an be over the substrate, gate structure or any other device.

Next, still referring to FIG. 1A, the substrate is preferably insitu cleaned using of a gas selected from the group consisting of SiH4 and H2.

Turning to FIG. 1B, a selectively deposited silicon layer 29 and a first titanium silicide (TiSi2) layer 30A are deposited at a lower TiCl4/SiH4 flow ratio—Regime A. The silicon layer 29 is co-deposited under the TiSi2 layer 30A. See the table above for preferred parameter limits. The deposition processes for steps 2 through 4 (for all three embodiments) can be RTCVD, low pressure chemical vapor deposition (LPCVD), or plasma enhanced chemical vapor deposition (PECVD).

Referring to FIG. 1C, a second titanium silicide (TiSi2 ) layer 30B selectively deposited at a higher TiCl4/SiH4 flow ratio (Regime C) as shown in the table above. This higher ratio provides higher selectivity. The silicon layer 29 beneath the TiSi2 layer 30B is consumed by this second TiSi2 deposition step. The silicon layer 29 beneath the TiSi2 layer 30B prevents the undesirable consumption of the substrate by this second TiSi2 deposition step.

As shown in FIG. 1D, a third titanium silicide TiSi2 layer 30C is selectively depositing at an intermediate TiCl4/SiH4 flow ratio as shown in the table above using a chloride containing gas of a material selected from the group consisting of HCL and ClF3. This maintains the selectivity and provides a smooth TiSi2 surface. This step also improves the loading effect in selective deposition.

The first, second, and third titanium silicide layers make up a Titanium silicide contact layer 30C.

The second embodiment for selectively depositing a TiSix layer is shown and described in FIGS. 2A to 2E. As shown in FIG. 1A, first insulating layer 20 having a contact opening 20A is formed on a substrate 10.

TABLE

Embodiment 2 - Summary Of Steps And Preferred Process Limits

Embodiment 2 -

selective TiSix

Low

Tgt

Hi

Tgt gas

contact layer

Temp

Temp

temp

Low

tgt

High

Low gas

flow

Hi gas

formation

(C °)

(C °)

(C °)

Press

Press

Press

flow

ratio

flow

Step 1- insitu

650

720

750

0.1

mtorr

1

mtorr

5

mtorr

0

0

0

clean (SiH4)

step 2- Si

400

700

1000

1

torr

1.8

torr

100

torr

SiH4 or

SiH4 or

SiH4 or

Selective

SiH2Cl2

SiH2Cl2

SiH2Cl2

deposition layer

10 sccm

80 sccm

100 sccm

40 SiH4 or

SiH2Cl2 gas

step 3- Etch Si on

600

700

800

50

mtorr

2

torr

50

torr

oxide/nitride

surface with HCl

or ClF3

Step 4- 1st TiSi2

500

700

1000

50

mtorr

2

torr

50

torr

TiCl4/ SiH4

TiCl4/ SiH4

TiCl4/ SiH4

selective

ratio 0.2

ratio 0.5

ratio 10

deposition - low

TiCl4/SiH4 flow

ratio - Regime A

Step 5- 1st TiSi2

500

700

1000

50

2

torr

50

torr

TiCl4/ SiH4

TiCl4/ SiH4

TiCl4/ SiH4

selective

ratio = 0.01

ratio = 0.1

ratio = 0.2

deposition -

intermediate

TiCl4/SiH4 flow

ratio - Regime B

As shown in FIG. 2A, a first insulating layer 20 having a contact opening 20A is formed on a substrate 10. Next, the substrate is preferably cleaned using of a gas selected from the group consisting of SiH4 and H2.

As shown in FIG. 2B, (step 2-) a silicon layer 40 is selectively deposited over the substrate 10 in the contact opening 20A. The silicon layer 40 preferably has a thickness in a range of between about 50 and 500 Å. The silicon layer 40 can be an epitaxial layer. The deposition can also form Si particles 42 on the insulating layer 20.

As shown in FIG. 2C (step 3) the Si nuclei 42 on the oxide/nitride surface 20 formed by the selectivity loss in the Si selective deposition (step 2) are etched away by using a gas off HCL, ClF3, C2F6 or SiF4. The etch will not significantly attack the Si layer 40 due to the robust Si crystal structure. This etch step guarantee's the selectivity of the Silicon deposition on the Si surfaces and not on the insulating layer.

As shown in FIG. 2D, ( Step 4) a first titanium silicide (TiSi2 ) layer 32A is selectively deposited over the Si silicon layer 40 in the contact opening. The first titanium silicide (TiSi2) layer 32A is preferably deposited with a high TiCl4 To SiH4 (or SiH2Cl2) flow ratio (Regime C). The first titanium silicide (TiSi2) layer 32A preferably has a thickness in a range of between about 50 and 600 Å.

As shown in FIG. 2E, (Step 5) a second titanium silicide (TiSi2) layer 32B is selectively deposited over the first titanium silicide layer 32A using a selective deposition process with an intermediate TiCl4/SiH4 flow ratio (Regime B). The process also preferably uses a chloride containing gas of a material selected from the group consisting of HCL and ClF3. These HCL and ClF3 gases maintain the selectivity and smooth the final TiSi2 surface 32B. The first 32A and second titanium silicide layers 32B form a titanium silicide contact layer 32.

IV. Third Embodiment for Forming Selectively Depositing a TiSix Layer

The third embodiment for forming selectively depositing a TiSix layer begins by forming first insulating layer 20 having a contact opening 20A on a substrate as shown in FIG. 3A.

The substrate 10 is insitu cleaned using of a gas selected from the group consisting of SiH4 and H2.

A first TiSix layer 35A and a Ti layer 34 is insitu deposited over the first insulating layer 20 and the substrate 10 using a plasma enhanced chemical vapor deposition process at a temperature less than 600 ° C. using TiCl4 and H2 gasses. The first C49-TiSi2 layer 35A is formed on the substrate 10 surface. The Ti layer 34 is formed over the insulating layer 20.

As shown in FIG. 3B, the Ti layer 34 is etched preferably using TiCl4 to remove the Ti layer 34 over the first insulating layer 20. The TiCl4 does not significantly etch the TiSi2 layer 35A. The TiSix layer 35A composed of C49-TiSi2. See table above for process parameters. The C49-TiSi2 layer is deposited at a lower temperature, has a much lower etch rate in TiCl4 compared to pure Ti, and has smaller grains of C49 compared to C54 so can obtain a smoother surface. (C49 resistivity=60 to 12 μ ohms-cm vs C54 resistivity=12 to 20 μ ohms-cm.

As shown in FIG. 3C, the first TiSi2 layer is rapid thermal annealed (RTA) forming a titanium silicide contact layer 35B over the substrate in the contact opening. The Titanium silicide contact layer 35B is now composed of C54-TiSix. The C54-TiSi2 layer 35B has a significantly lower resistivity.

TABLE

Embodiment 3 - Summary of steps and process Limits

Hi

Lo

Low

Tgt

Hi

Low

tgt

Pres

flow

Embodiment 3

Temp

Temp

temp

Press

Press

sure

ratio

Tgt flow

Hi flow

Step 1- insitu

350

570

650

1 torr

5 torr

20

TiCl4 /H2

TiSix/TiPECVD dep

torr

step 2-TiC4 Plasma

300

570

750

1 torr

5 torr

20

1 sccm

3 sccm TiCl4

50

Selective Ti Etch

torr

TiCl4

sccm

TiCl4

step 3- RTA to form

600

750

950

C54-TiSi2

V. Part 2—Salicide Process—a Barrier Layer and a Metal Plug are Formed Over The TiSix Contact Layer

After the TiSix contact layer is formed over the substrate preferably using one or the above three embodiments, a barrier layer and a metal plug layer are formed thereover to form a contact structure. The invention has 2 preferred embodiments (4 and 5) for forming the barrier layer. See FIGS. 4A through 4F.

A titanium silicide contact layer 126 is formed on the substrate in the contact opening on the exposed substrate and polysilicon gate 118 surfaces. The TiSix contact layer 126 is formed over the substrate preferably using one of the above three embodiments. The TiSi2 layer is either selectively or blank deposition on the S/D and gate regions using PE-CVD or RT-CVD.

As shown in FIG. 4B, a barrier layer 140 is now formed over the silicide contact layer 126. The barrier layer is preferably formed of TiN or Ti—N—O.

In the fourth preferred embodiment, the barrier layer is composed of TiN. The barrier layer is formed using a self-aligned nitridation treatment performed insitu using a nitrogen containing gas of a material selected from the group consisting of N2 or NH3, using a plasma process (PECVD).

In the fifth preferred embodiment, the barrier layer is composed of Ti—N—O. The barrier layer is formed using a of a process selected from the group consisting of (1) RTA-CVD nitridation in a nitrogen (N2) and oxygen (O2) containing ambient and (2) RTA a two step nitridation and oxidation treatment.

As shown in FIG. 4C, a dielectric (IDL1—inter dielectric layer 1) layer 150 is formed over the substrate surface. Simultaneously, the TiN/TiSix layers 126 and 140 are annealed.

As shown in FIG. 4D, a contact hole 150A is formed exposing the TiN/TiSix layers 126140.

As shown in FIG. 4E-1, a metal plug 160 is formed over the TiN barrier layer 140. The metal plug 160 composed of a material selected from the group consisting of Al and W.

Alternately, as shown in FIG. 4F, a TiN liner 156 can over the IDL layer 150. A W or Al plug 160 can be formed in the contact hole 150A.

The invention's self-aligned Barrier layer has many advantages over Conventional Processes. The invention provides a simplified integration process for TiSi2/TiN in situ formation. The invention's TiSi2/TiN depositions can be performed in situ in one reactor to increase throughput. The invention's TiSi2/TiN depositions do not have the conventional step-coverage problems. The invention can be used with an ultra-thin or without liner/glue-layer to reduce the difficulties of following plug-filling into high aspect-ratio features. The invention allows the use of thicker TiN film to resist contact RIE overetch in salicide process. The invention Post-anneals the TiSix/TiN layers in situ in the following ILD deposition. The eliminates a Post anneal step. The invention's in situ TiN formation can be acted as protection cap to prevent oxidation or contamination on underlying TiSi2 layer.

In the above description numerous specific details are set forth such as flow rates, pressure settings, thicknesses, etc., in order to provide a more thorough understanding of the present invention. It will be obvious, however, to one skilled in the art that the present invention may be practiced without these details. In other instances, well know process have not be described in detail in order to not unnecessarily obscure the present invention.

While the invention has been particularly shown and described with reference to the preferred embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made without departing from the spirit and scope of the invention.

Claims (9)

What is claimed is:

1. A method of forming a titanium silicide contact on a substrate; comprising the steps of:

a) forming first insulating layer having a contact opening on a substrate;

b) insitu depositing a first C49-TiSi2 layer over said substrate and depositing a Ti layer over said first insulating layer;

c) etching said Ti layer to remove said Ti layer over said first insulating layer;

d) rapid thermal annealing said first C49-TiSi2 layer forming a titanium contact layer over said substrate in said contact opening; said Titanium silicide contact layer composed of C54-TiSi2.

2. The method of claim 1 wherein step (b) includes using a plasma enhanced chemical vapor deposition process at a temperature less than 600 ° C. using TiCl4 and H2 gasses.

3. The method of claim 1 wherein step (c) is preformed using a TiCl4 plasma at a temperature between 300 and 750° C., a pressure between 1 torr and 20 torr and a TiCl4 flow between 1 sccm and 50 sccm.

4. The method of claim 1 wherein step (d) is performed at temperature between 600 and 950° C.

5. A method of forming a contact structure composed of a Titanium silicide layer/TiN bi-layer for contacting a substrate of a semiconductor device; comprising the steps of

a) forming a titanium silicide contact layer on said substrate in said contact opening; said first insulating layer formed in a chamber;

b) forming a barrier layer over said silicide contact layer; said barrier layer is composed of TiN and said barrier layer is formed using a self-aligned nitridation treatment performed insitu using a nitrogen containing gas of a material selected from the group consisting of N2 or NH3, using a plasma process; steps (a) and (b) are performed sequentially in said chamber;

c) forming a metal plug over said TiN barrier layer ; said metal plug composed of a material selected from the group consisting of Al and W.

6. The method of claim 5 wherein said titanium silicide contact layer is formed by

a) providing a first insulating layer having a contact opening over a substrate;

b) simultaneously selectively depositing a silicon layer and an overlying first titanium silicide layer at a low TiCl4 to Si containing gas flow ratio between about 0.05 to 0.08;

c) selectively depositing a second titanium silicide layer over said first titanium silicide layer so that said second titanium silicide layer consumes said silicon layer; said second titanium silicide layer formed at a high TiCl4 to Si containing gas flow ratio between about 0.2 and 10, whereby the high TiCl4 to Si containing gas flow ratio causes said second titanium silicide layer to consume said silicon layer;

d) selectively depositing a third titanium silicide TiSi2 layer over said second titanium silicide layer at an intermediate TiCl4 to Si containing gas flow ratio between about 0.08 and 0.2 and using a chloride containing gas of a material selected from the group consisting of HCL and ClF3; said first, second, and third titanium silicide layers forming a titanium silicide contact layer.

7. So the method of claim 5 wherein said titanium silicide contact layer is formed by

a) forming first insulating layer having a contact opening over a substrate;

b) selectively depositing a silicon layer over said substrate in said contact opening;

c) etching said silicon layer using a gas of a material selected from the group consisting of HCL, ClF3, C2F6 and SiF4;

d) selectively depositing a first titanium silicide layer over said silicon layer in said contact opening; said first titanium silicide layer deposited with an intermediate TiCl4 to Si containing gas flow ratio between about 0.2 and 10;

e) selectively depositing a second titanium silicide layer over said first titanium silicide layer using a selective deposition process with an intermediate TiCl4 to Si containing gas flow ratio and using a chloride containing gas of a material selected from the group consisting of HCL and ClF3; said first and second titanium suicide layers forming a titanium silicide contact layer.

8. The method of claim 5 wherein said titanium silicide contact layer is formed by forming first insulating layer having a contact opening on a substrate;

a) insitu depositing a first C49-TiSix layer over said substrate and depositing a Ti layer over said first insulating layer;

b) etching said Ti layer to remove said Ti layer over said first insulating layer;

c) rapid thermal annealing said first C49-TiSi2 layer forming a titanium silicide contact layer over said substrate in said contact opening; said Titanium silicide contact layer composed of C54-TiSi2.

9. A method of forming a contact structure composed of a Titanium silicide layer/Ti—O—N barrier layer for contacting a substrate of a semiconductor device; comprising the steps of:

a) forming a titanium silicide contact layer on said substrate in said contact opening;

b) forming a barrier layer over said silicide contact layer; said barrier layer is composed of Ti—N—O and said barrier layer is formed using a nitridation in a nitrogen and oxygen containing ambient; and

c) forming a metal plug over said TiN barrier layer; said metal plug composed of a material selected from the group consisting of Al and W.