Rice U. chemists create 3-D printed graphene foam

Nanotechnologists from Rice University and China’s Tianjin University have used 3-D laser printing to fabricate centimeter-sized objects of atomically thin graphene.

The research could yield industrially useful quantities of bulk graphene and is described online in a new study in the American Chemical Society journal ACS Nano.

Scanning electron microscope (left) and transmission electron microscope (right) images of 3-D printed graphene foam. The inset (right) is a selected area defraction pattern used to confirm that the material is graphene. (Image courtesy of Yilun Li/Rice University)

“This study is a first of its kind,” said Rice chemist James Tour, co-corresponding author of the paper. “We have shown how to make 3-D graphene foams from nongraphene starting materials, and the method lends itself to being scaled to graphene foams for additive manufacturing applications with pore-size control.”

Graphene, one of the most intensely studied nanomaterials of the decade, is a two-dimensional sheet of pure carbon that is both ultrastrong and conductive. Scientists hope to use graphene for everything from nanoelectronics and aircraft de-icers to batteries and bone implants. But most industrial applications would require bulk quantities of graphene in a three-dimensional form, and scientists have struggled to find simple ways of creating bulk 3-D graphene.

For example, researchers in Tour’s lab began using lasers, powdered sugar and nickel to make 3-D graphene foam in late 2016. Earlier this year they showed that they could reinforce the foam with carbon nanotubes, which produced a material they dubbed “3-D rebar graphene” that could retain its shape while supporting 3,000 times its own weight. But making 3-D rebar graphene was no simple task. It required a pre-fabricated 3-D mold, a 1,000-degree Celsius chemical vapor deposition (CVD) process and nearly three hours of heating and cooling.

3-D graphene foam objects are produced by shining a laser on a mixture of powdered sugar and nickel powder. The laser is moved back and forth to melt sugar in a 2-D pattern, and nickel acts as a catalyst to spur the growth of graphene foam. The process is repeated with successive layers of powder to build up 3-D objects. (Image courtesy of Tour Group/Rice University)

In the latest study, a team from Tour’s lab and the labs of Rice’s Jun Luo and Tianjin’s Naiqin Zhao adapted a common 3-D selective laser sintering technique to make fingertip-size blocks of graphene foam. The process is conducted at room temperature. No molds are required and the starting materials are powdered sugar and nickel powder.

“This simple and efficient method does away with the need for both cold-press molds and high-temperature CVD treatment,” said co-lead author Junwei Sha, a former visiting student in Tour’s lab who is now a graduate student at Tianjin. “We should also be able to use this process to produce specific types of graphene foam like 3-D printed rebar graphene as well as both nitrogen- and sulfur-doped graphene foam by changing the precursor powders.”

Three-D laser printers work differently than the more familiar extrusion-based 3-D printers, which create objects by squeezing melted plastic through a needle as they trace out two-dimensional patterns. In 3-D selective laser sintering, a laser shines down onto a flat bed of powder. Wherever the laser touches powder, it melts or sinters the powder into a solid form. The laser is rastered, or moved back and forth, line by line to create a single two-dimensional slice of a larger object. Then a new layer of powder is laid over the top of that layer and the process is repeated to build up three-dimensional objects from successive two-dimensional layers.

The new Rice process used a commercially available CO2 laser. When this laser was shone onto the sugar and nickel powder, the sugar was decomposed into carbon source and the nickel acted as a catalyst. Graphene formed as the mixture cooled after the laser had moved on to the next spot, and Sha and colleagues conducted an exhaustive study to find the optimal amount of time and laser power to maximize graphene production.

James Tour

The foam created by the process is a low-density, 3-D form of graphene with large pores that account for more than 99 percent of its volume.

The research was supported by the Air Force Office of Scientific Research and its Multidisciplinary University Research Initiative, the China Scholarship Council, the State Key Program of National Natural Science of China, the National Natural Science Foundation of China, the Special Foundation for Science and Technology Major Program of Tianjin and Universal Laser Systems.