Theories of chemical structure were first developed by August Kekule, Archibald Scott Couper, and Aleksandr Butlerov, among others, from about 1858. These theories were first to state that chemical compounds are not a random cluster of atoms and functional groups, but rather had a definite order defined by the valency of the atoms composing the molecule, giving the molecules a three dimensional structure that could be determined or solved.

Identification (literature)

Identification is a term used in literary and film studies to describe a psychological relationship between the reader of a novel and a character in the book, or between a spectator in the audience and a character on screen. In both cases, readers and spectators see themselves in the fictional character.

Identification is usually supposed to be largely unconscious: a reader may be aware that she likes a given character, but not that she actually sees that character as an alter ego, a version of her, or a projection of her aspirations for herself. It would be a mistake to think all heroes foster identification, or that all villains inhibit identification—many, perhaps even most, characters elicit some degree of identification on the part of the reader or spectator. In film, Alfred Hitchcock exploited the traits of casual identification with specific moments, even when the character was villainous. In Psycho (1960), Hitchcock explained that as the character Norman Bates (Anthony Perkins) was disposing of the car containing Marion Crane's body in a swamp, for a brief moment he had the car stop sinking. "When Perkins is looking at the car sinking in the pond... the public are thinking, 'I hope it goes all the way down!' It's a natural instinct."

Biotic reef

There is a variety of biotic reef types, including oyster reefs, but the most massive and widely distributed are tropical coral reefs. Although corals are major contributors to the framework and bulk material comprising a coral reef, the organisms most responsible for reef growth against the constant assault from ocean waves are calcareous algae, especially, although not entirely, species of coralline algae.

Veins are classically thought of as being the result of growth of crystals on the walls of planarfractures in rocks, with the crystal growth occurring normal to the walls of the cavity, and the crystal protruding into open space. This certainly is the method for the formation of some veins. However, it is rare in geology for significant open space to remain open in large volumes of rock, especially several kilometers below the surface. Thus, there are two main mechanisms considered likely for the formation of veins: open-space filling and crack-seal growth.

Open space filling

Open space filling is the hallmark of epithermal vein systems, such as a stockwork, in greisens or in certain skarn environments. For open space filling to take effect, the confining pressure is generally considered to be below 0.5 GPa, or less than 3-5 kilometers. Veins formed in this way may exhibit a colloform, agate-like habit, of sequential selvages of minerals which radiate out from nucleation points on the vein walls and appear to fill up the available open space. Often evidence of fluid boiling is present. Vugs, cavities and geodes are all examples of open-space filling phenomena in hydrothermal systems.

Reef knot

The reef knot, or square knot, is an ancient and simple binding knot used to secure a rope or line around an object. It is sometimes also referred to as a Hercules knot. The knot is formed by tying a left-handed overhand knot and then a right-handed overhand knot, or vice versa. A common mnemonic for this procedure is "right over left; left over right", which is often appended with the rhyming suffix "... makes a knot both tidy and tight". Two consecutive overhands of the same handedness will make a granny knot. The working ends of the reef knot must emerge both at the top or both at the bottom, otherwise a thief knot results.

Although the reef knot is often seen used for tying two ropes together, it is not recommended for this purpose because of the potential instability of the knot, and over-use has resulted in many deaths (see #Misuse as a bend).

Naming

The reef knot is at least between 4,000 and 9,000 years old. The name "reef knot" dates from at least 1794 and originates from its common use to reef sails, that is to tie part of the sail down to decrease its effective surface area in strong winds. To release the knot a sailor could collapse it with a pull of one hand; the sail's weight would make the collapsed knot come apart. It is specifically this behavior which makes the knot unsafe for connecting two ropes together.