The fact that the host reveals one of the wrong answers AFTER you choose your initial answer does something really cool!

I think the easiest way to think of it is this:
1.) In order to win by switching your answer, all you have to do is choose a WRONG answer initially.
2.) You have a 2/3 chance of choosing a wrong answer initially!
3.) You have a 2/3 chance of choosing the right door by switching!

Another way of looking at it is this:
1.) The door you initially choose has a 1/3 chance of being correct. Each of the other two doors still have a 1/3 chance of being correct at this point.
2.) However, the host REVEALS one of these two other doors as wrong, meaning that door now has a 0/3 chance of being correct!
3.) So now there is 2/3 of a chance needing to be assigned to a door still… The last remaining door that you would switch to is the door that now has that 2/3 chance of being correct!