Restaurant Startup In the season finale of the unscripted series, a chef and his wife have created a successful snout-to-tail catering company compete with a recently divorced couple running a small anchovy-themed pop-up for a chance to fund a new eatery. 7 p.m. CNBC

Food Fighters In this new episode an Army sergeant, the father of seven, displays his culinary skills as he goes up against professional chefs including Cat Cora. 8 p.m. NBC

The iHeartradio Album Release Party With Maroon 5Adam Levine and fellow members of Maroon 5 mark the release of "V," the group's fifth studio album. 8 p.m. KTLA

Fashion Police This new episode looks at fashions from the Primetime Emmys and MTV's Video Music Awards. 8 p.m. E!

Pretty Little Liars In the midseason finale, the Liars may have to put their trust in an unreliable ally as Alison (Sasha Pieterse) leads them down a dangerous path. Lucy Hale and Troian Bellisario also star. 8 and 10 p.m. Family

Face Off In this new episode teams must re-imagine characters from "The Wonderful World of Oz," as if they were in "Alice's Wonderland." 9 p.m. Syfy

Rizzoli & Isles While the city is in the grip of a heat wave, Jane and Maura (Angie Harmon, Sasha Alexander) find a man who died in a bathtub full of ice in this new episode. 9 p.m. TNT

Royal Pains In this new episode a man's (Ryan McCartan) sore wrist turns out to be something more serious than a simple sprain. With Mark Feuerstein and guest star Gillian Alexy. 9 p.m. USA

Tyrant In the season finale, Barry (Adam Rayner) receives news that threatens to destroy everything he's worked for and Jamal's (Ashraf Barhom) suspicions lead him to question the loyalty of those closest to him. 10 p.m. FX

Sullivan & Son In this new episode Jack (Dan Lauria) shows Steve (Steve Byrne) what life would have been like if he hadn't been around for some crucial moments in the lives of his family and friends. 10 p.m. TBS

Time Team America In the first of two new specials, the scientists go to Georgia in search of the location of Camp Lawton, where thousands of Union soldiers were kept prisoner as the Civil War neared its end. In the seconds, they document one of the earliest settlements in North America, a village near Mesa Verde, Colo. 8 and 9 p.m. KOCE