As of at least ver 1.8.11 there is no way to add a user on the Windows side. It tries to auto connect but if that fails there is no way to create a new account to be able to manually enter the IP address. I had to dig up an old Bluetooth dongle and create a new user with bluetooth then manually put in the IP address. Frustrating.

Also dual sim phones are still a problem for mpe. No way to control which IMEI is active and then mpe syncs to two different users on the Windows side. Makes for a terrible mess with syncing photos. Google fi phones have this issue. Masking some of the IMEI would fix this issue. Or allowing two IMEIs for the same user. Noted in the forum years ago. Still No fix.

I help others use this program, if the dual IMEI issue was fix I would love to use it myself.