From the answer:
There is not Two Separate transactions: "I realize these are two separate transactions."... The Payroll Deduction would be linked not to Liability; link it back into the expense account you already paid out of = internal reimbursement.

From the answer:
Welcome to the Intuit Community, paulprestera .... I'd be glad to walk you through creating a paycheck.... After paying your quarterly taxes, you can always go back to the Payday tab to run your payroll.