Abstract

We report the effect of polarity of self-assembledmonolayers on magnetic properties and morphology of a deposited magnetic material. Sputtering of permalloy on a patterned structure of self-assembledmonolayers(SAMs), with and terminal groups, results in the formation of a film on regions and clusters on regions. Further investi-gations reveal that the cluster formation gives rise to superparamagnetism, while the film shows usual ferromagnetic behavior. The observed contrast in morphology and magnetism of permalloy is attributed to different growth mechanisms arising from the difference in reactive nature of the terminal functional groups of the SAMs.