In this exclusive clip from the Charlie Sheen comedy's Season 1 DVD (available Tuesday, Jan. 8.), Sheen, Blair and executive producer Bruce Helford share behind-the-scenes scoop from Blair's audition for the role of Kate, Charlie's therapist, best friend whom he's also sleeping with. "I remember she read with her legs over his legs," Helford says. "We were almost kind of embarrassed to be in the room because it was that kind of chemistry between them."

Blair remembers taking things even further. "I took the opportunity to flirt with Charlie," she says. "There were a couple choices I made: I think I unbuckled Charlie's belt, I recall, and Bruce very sweetly afterwards was like, 'Hmm, you don't like have to do that as a character.'"

What did Sheen have to say about working with Blair? And which co-star thinks there might be more going on than meets the eye between the on-screen duo? Watch the clip to find out!

Anger Management: Season One comes out on DVD Tuesday, Jan. 8. Season 2 premieres on Thursday, Jan. 17 at 9/8c.