Study on Metal-Induced Reactions of α-Diazocarbonyl Glucosides8888-889510.1021/jo300986chttp://dx.doi.org/10.1021/jo300986cConversions of diazocarbonyl carbohydrate compounds catalyzed by a series of rhodium and copper catalysts in conventional heating or microwave conditions were investigated. C?H insertion product was obtained in the presence of Rh2(OAc)4. Intermolecular reactions rather than intramolecular reactions occurred in the presence of copper catalysts.7720octobre 19, 2012Journal of Organic ChemistryJ. Org. Chem.0022-3263ZhuGuanLi-HeZhangPierreSinaÿYongminZhang