well first of all, id prob go with a body suit for the arms and legs. too much chance of it rubbing off durin the day. u can put it on then paint on the black stripes too!
as for the face and neck, id use ben nye hydra color (the one u mix w water to paint on) instead of cream, so it wont rub off as fast. paint the orange then wait for a little bit (it has to be completely dry) then paint the black stripes. seal w their finishing spray (2-3 coats!!!!!)

for the eye area, id use a little eyeliner to make it pop, cause depending on ur eye color, it might drown out ur eyes