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Dr. Blight hatches a plan with Duke Nukem, Looten Plunder, Sly Sludge, and Verminous Skumm to steal the Planeteers' rings so that she can use her latest invention to create their evil copies. Succeeding in stealing the rings, they create the rings of Deforestation, Super Radiation, Smog, Toxics and Hate. They also discover that by combining these five polluting powers, they create Captain Pollution, their newest weapon against Captain Planet and the Planeteers. To complicate matters, they trick a lone soldier, Commander Clash, into thinking the Planeteers are enemies.

Captain Planet: The health of our planet relies on the health of it's people.Wheeler: To reach the highest heights...Linka: ...and win the fight to save our planet...Ma-Ti: ...we must have strength...Kwame: ...endurance...Gi: ... and courage!Wheeler: Our minds...Linka: ...and our bodies must be in shape!Commander Clash: Stay fit!Captain Planet: The power is yours!