First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Ingestion

Sore throat. Aspiration hazard!

Do not eat, drink, or smoke during work.

Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer immediately for medical attention.

SPILLAGE DISPOSAL

CLASSIFICATION & LABELLING

Personal protection: chemical protection suit and filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

According to UN GHS Criteria

WARNING

May be harmful if swallowedCauses skin irritationCauses eye irritationMay cause allergic skin reactionMay be harmful if swallowed and enters airways

TransportationUN Classification

STORAGE

Store only if stabilized. Keep in the dark. Cool. Ventilation along the floor.

Chemical dangersThe substance will polymerize due to heating, on contact with peroxides, and under the influence of light. Heating may cause violent combustion or explosion. This produces acrid smoke. The substance may spontaneously polymerize if it is not stabilized.

Effects of short-term exposureThe substance is substance irritating to the eyes, skin and respiratory tract. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis.

Inhalation riskNo indication can be given about the rate at which a harmful concentration of this substance in the air is reached.

Effects of long-term or repeated exposureRepeated or prolonged contact may cause skin sensitization. See Notes.

OCCUPATIONAL EXPOSURE LIMITS

MAK sensitization of skin (SH)

ENVIRONMENT

NOTES

Boiling Point cannot be experimentally determined: at 1013 hPa polymerization occurs at elevated temperatures, other boiling point: 67 C at 4.6 hPa.Methacrylates are normally stabilized by addition of phenolic inhibitors during transport and storage.An added stabilizer or inhibitor can influence the toxicological properties of this substance; consult an expert.May cause cross sensitization towards other acrylates.

ADDITIONAL INFORMATION

EC Classification
Symbol: Xi; R: 36/38-43; S: (2)-26-28; Note: D

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