In the romantic shot, the 34-year-old actress stands wistfully on the balcony of an historic building overlooking the Palazzo Pisani-Moretta and the Grand Canal; Depp, 46, stands in the background. (See more set shots at PopSugar.com!)

On Tuesday, Jolie waved to fans and blew kisses from the balcony. She and beau Brad Pitt have rented out a 15th century palazzo, where they'll stay with their six kids during the film's three-month shoot.