Though Sir Sean Connery returned to the tux in his penultimate Bond outing in 1971's Diamonds Are Forever, we're certain Orlebar Brown's cotton-terry shirt would've kept him cool while shooting in the film's Palm Springs and Las Vegas locations. Part of the brand's collaboration with 007, it's designed with safari-style patch pockets and has a camp collar that'll look even more relaxed with a few buttons undone. Shown here with Orlebar Brown shorts, Mulo sneakers, Peyote Bird bracelet.