Now, when you click on that bookmark, Firefox will go "real fullscreen", hiding all toolbars. To get them back, you will have to press ESC.

Now, there is a bit of a snag. That preference in about:config: is set to true by default for a reason: it is a bit unsafe to allow any website to use fullscreen-enabling javascript. For this reason I would suggest to only do this for limited periods, then switch it back once you're done.

Long-winded explanation

FF has a preference, browser.fullscreen.autohide, that in theory should govern the behaviour of toolbars when going fullscreen. It is set to true by default, meaning toolbars should disappear. However, for some reason this property has (almost) always failed to work on MacOS/OSX builds of Firefox.

There used to be a few extensions that corrected that behaviour, but they've all gone away when Firefox switched to WebExtension APIs, which basically sandboxed extensions more rigidly and blocked them from changing the browser interface as deeply as they could before. This was the price for the dramatic performance improvement seen in Firefox 57+.

This workaround hence relies on the new Fullscreen WebAPI, which is supposed to be a new, standard way to enable fullscreen via Javascript on any browser (well, any browser that implements it - just a few at the moment). However, because of security concerns, this API is locked down by default; so, in order to use it, we first have to relax checks as described above. Once that is done, we can launch a bit of JS from a bookmark that triggers "real" fullscreen.