Carbon dioxide

Carbon dioxide is an atmospheric gas comprised of one carbon and two oxygen atoms. It is a very widely known chemical compound and it is frequently called by its formula CO2. In its solid state, it is commonly known as dry ice.

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Carbon dioxide is a colorless gas which, when inhaled at high concentrations (a dangerous activity because of the associated asphyxiation risk), produces a sour taste in the mouth and a stinging sensation in the nose and throat. These effects result from the gas dissolving in the mucous membranes and saliva, forming a weak solution of carbonic acid.

Its density at 25 °C is 1.98 kg m−3, about 1.5 times that of air. The carbon dioxide molecule (O=C=O) contains two double bonds and has a linear shape. It has no electrical dipole. As it is fully oxidized, it is not very reactive and, in particular, not flammable.

At temperatures below −78 °C, carbon dioxide condenses into a white solid called dry ice. Liquid carbon dioxide forms only at pressures above 5.1 atm; at atmospheric pressure, it passes directly between the gaseous and solid phases in a process called sublimation.

Test For Carbon Dioxide.
When a lighted splint is inserted into a test tube containing carbon dioxide, the flame is immediately extinguished, as carbon dioxide does not support combustion. (Certain fire extinguishers contain carbon dioxide to extinguish the flame). Of course if you are genuinely unsure what gas you are testing (hydrogen, natural gas etc) igniting with a lighted splint may not be a good idea. This method is inconclusive because other gases can quench a flame.

To further confirm that the gas is carbon dioxide, the gas may be bubbled into calcium hydroxide solution (Lime water). The calcium hydroxide turns milky because of the formation of calcium carbonate.

Liquid and solid carbon dioxide are important refrigerants, especially in the food industry, where they are employed during the transportation and storage of ice cream and other frozen foods. Solid carbon dioxide is called "dry ice" and is used for small shipments where refrigeration equipment is not practical.

Carbon dioxide is used to produce carbonatedsoft drinks and soda water. Candy called Pop Rocks is pressurized with carbon dioxide gas at about 600 PSI. When you put the candy in your mouth, it melts (just like other hard candy) and releases the gas bubbles with an audible "pop". Traditionally, the carbonation in beer and sparkling wine comes about through natural fermentation, but some manufacturers carbonate these drinks artificially.

Carbon dioxide extinguishes flames, and some fire extinguishers, especially those designed for electrical fires, contain liquid carbon dioxide under pressure.

Carbon dioxide also finds use as an atmosphere for welding, although in the welding arc, it reacts to oxidize most metals. Use in the automotive industry is common despite significant evidence that welds made in carbon dioxide are brittler than those made in more inert atmospheres, and that such weld joints deteriorate over time because of the formation of carbonic acid. It is used as a welding gas primarily because it is much less expensive than more inert gases such as argon or helium.

Liquid carbon dioxide is a good solvent for many organic compounds, and is used to remove caffeine from coffee. First, the green coffee beans are soaked in water. The beans are placed in the top of a column that's seventy feet high. The carbon dioxide fluid at about 93 degrees Cel. enters at the bottom of the column. The caffeine diffuses out of the beans and into the carbon dioxide.

Carbon dioxide is commonly injected into or adjacent to producing oil wells. It will act as both a pressurizing agent and, when dissolved into the underground crude oil, will significantly reduce its viscosity, enabling the oil to flow more rapidly through the earth to the removal well. In mature oil fields, extensive pipe networks are used to carry the carbon dioxide to the injection points.

Dry ice at normal pressures does not melt into liquid carbon dioxide but rather sublimates directly into carbon dioxide gas at −78.5 °C (−109.3 °F). Hence it is called "dry ice" as opposed to normal "wet" ice (frozen water).

Dry ice is produced by compressing carbon dioxide gas to a liquid form, removing the heat produced by the compression (see Charles' law), and then letting the liquid carbon dioxide expand quickly. This expansion causes a drop in temperature so that some of the CO2 freezes into "snow", which is then compressed into pellets or blocks.

Producing "dry ice fog" for special effects. When dry ice is put into contact with water, the frozen carbon dioxide sublimates into a mixture of cold carbon dioxide gas and cold humid air. This causes condensation and the formation of fog; see fog machine. The effect of fog by the mixture of dry ice with water, is best formed when the water is warm, rather than cold.

Tiny pellets of dry ice (instead of sand) are shot at a surface to be cleaned. Dry ice is not as hard as sand, but it speeds processing by sublimating to a gas and does not produce nearly as much lung-damaging dust.

Because of its particular characteristics, dry ice requires special precautions when handling. It is extremely cold and there should be no direct contact with skin (i.e., wear proper insulating gloves). It is constantly sublimating to carbon dioxide gas, so it cannot be stored in a sealed container as the pressure buildup will quickly cause the container to explode. The sublimated gas must be ventilated; otherwise, it may fill the enclosed space and create a suffocation hazard. Special care for ventilating vehicles is needed as well because of the small space. People who handle dry ice should also be aware that carbon dioxide is heavier than air and will sink to the floor.

The RCRS on the space shuttle Orbiter uses a two-bed system that provides continuous removal of CO2 without expendable products. Regenerable systems allow a shuttle mission a longer stay in space without having to replenish its sorbent canisters. Older lithium hydroxide (LiOH)-based systems, which are non-regenerable, are being replaced by regenerable metal-oxide-based systems. A metal-oxide-based system primarily consists of a metal oxide sorbent canister and a regenerator assembly. This system works by removing carbon dioxide using a sorbent material and then regenerating the sorbent material. The metal-oxide sorbent is regenerated by pumping air heated to around 400 °F at 7.5 scfm through its canister for 10 hours. [7]

One has to be very careful in selecting biofuels, in view of the remarks, of Mr. Pachauri, (whose panel shared the Nobel prize with former U.S. Vice President Al Gore last year). His, some remarks are quoted below:

The United States is the world's biggest producer of biofuels, derived mostly from corn.

"Several questions have arisen on even the emissions implication of that route, and the fact that this has clearly raised prices of corn."

Scientists say some kinds of biofuel generate as much carbon dioxide (CO2) as the fossil fuels they replace.