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From Airport
You can either take the Metro or Bus (E95). Both leave you at Syntagma Square on Amalias avenue. Walk to number 38 and turn in right onto Periandrou street. When on Periandrou street take the 1st left and you will see Dioscouros in front of you

Or you can get a taxi, which will cost between 30 - 40 euros

Port:
Train. Get the train to Monastiraki (green Line). From there change to the blue line and its one stop to Syntagma. This leaves you on on Amalias avenue. Walk to number 38 and turn in right onto Periandrou street. When on Periandrou street take the 1st left and you will see Dioscouros in front of you