There may have been an ulterior motive to her head-turning ensemble: Angelina Jolie was at the award show too (although Jen's ex-husband Brad Pitt was nowhere to be seen). In fact, this was the first event the two women have attended together in six years, according to the Daily Mail.

Aniston styled her showstopping outfit with gold necklaces that accentuated her decolletage as well as satin pumps and beachy waves.