WASHINGTON — The FBI has released declassified photos, videos and other documents collected during the decade-long surveillance of 10 Russian “deep cover” spies who were arrested and deported last year.

One video showed Anna Chapman, a 28-year-old spy whose nude pictures and racy romances made her an instant tabloid sensation, meeting in a New York coffee shop in June 2010 with an undercover U.S. agent.

A second video shows Ms. Chapman browsing in a department store while a “Russian government official” waits for her outside, the FBI said. Other videos show three other agents arrested along with Ms. Chapman.

The surveillance photos showed other members of the ring in various public places, meeting other members, walking through the streets alone, and one of them at their Harvard graduation ceremony.