The 82-year-old Dame hit the royal premiere of the latest James Bond movie Spectre at the Royal Albert Hall in London on Monday night and rocked the red carpet in a show-stopping black gown and white fur.

It wasn't the appearance of 007 himself - Daniel Craig - that got the legend going though instead it was the arrival of dashing Prince Harry.

Joan Collins hits James Bond, but it's not 007 that caught her eye (Image: REX)

Taking to Twitter Joan gushed over the currently single prince and teased that he had the distinct look of the super sleuth.

She wrote: "I think Harry's looking very #007 ish! "

Harry hit the royal premiere alongside his brother Prince William and sister-in-law Duchess of Cambridge. Once again the Prince was playing gooseberry for the night - so maybe he'll be thankful for a bit of attention from Joan?

Prince Harry does his best Daniel Craig impression as he arrives on the red carpet (Image: Getty)

The silver-screen goddess was looking incredible as she stepped out on the red carpet. Dripping in pearls and diamonds Dame Joan gave the Bond girls a run for their money in her off the shoulder black gown with knee high split.

The 82-year-old looked amazing in her daring black gown (Image: REX)

David Walliams, Chris Evans and Ronan Keating were amongst the celebrities who joined stars of the film Daniel Craig, Naomie Harris, Monica Bellucci and Christoph Waltz for the premiere of Sam Mendes' highly-anticipated follow up to 2012's Skyfall.