quantization

0.1 Introduction

Quantization is understood as the process of defining a formal correspondence between a quantum system operator (such as the quantum Hamiltonian operator) or quantum algebra and a classical system operator (such as the Hamiltonian) or a classical algebra, such as the Poisson algebra. Theoretical quantum physicists often proceed in two ‘stages’, so that both first and second quantization procedures were reported in QFT, for example. Generalized quantization procedures involve asymptotic morphisms and Wigner–Weyl–Moyal quantization procedures or noncommutative ‘deformations’ of C*-algebras (http://planetmath.org/CAlgebra3) associated with quantum operators on Hilbert spaces (as in noncommutative geometry). The non-commutative algebra of quantum observable operators is a
Clifford algebra (http://planetmath.org/CliffordAlgebra), and the associated
C*-Clifford algebra (http://planetmath.org/CCliffordAlgebra) is a fundamental concept of modern mathematical treatments of quantum theories. Note, however, that classical systems, including Einstein’s general relativity are commutative (or Abelian) theories, whereas quantum theories are intrinsically non-commutative (or non-Abelian), most likely as a consequnece of the non-comutativity of quantum logics and the Heisenberg uncertainty principle of quantum mechanics.

This definition is quite broad, and as a result there are many approaches to quantization, employing a variety of techniques. It should be emphasized the result of quantization is not unique; in fact, methods of quantization usually possess inherent ambiguities, in the sense that, while performing quantization, one usually must make choices at certain points of the process.

Classical systems

Definition 1.

A classical system is a triplet(M,ω,H), where (M,ω) (the phase space) is a symplectic manifold and H (the Hamiltonian) is a smooth function on M.

Quantum systems

Definition 3.

If (ℋ,H^) is a quantum system, ℋ is referred to as the (quantum) phase space and H^ is referred to as the Hamiltonian operator.

Definition 4.

1.

A quantum state is a vector Ψ in ℋ.

2.

A quantum observable is a self-adjoint linear operator A on ℋ.

The space of quantum observables is denoted 𝒪⁢(ℋ). If A and B are in 𝒪⁢(ℋ), then

(i⁢ℏ)-1⁢[A,B]:=(i⁢ℏ)-1⁢(A⁢B-B⁢A)

(2)

is in 𝒪⁢(ℋ) (Planck’s constantℏ appears as a scaling factor arising from physical considerations). The operation(i⁢ℏ)-1⁢[⋅,⋅] thus gives 𝒪⁢(ℋ) the structure of a Lie algebra.

The time evolution of a quantum observable is described by the equation

d⁢Ad⁢t=iℏ⁢[H^,A].

(3)

Equation (3) is equivalent to the time-dependent Schrödinger’s equation

i⁢ℏ⁢d⁢Ψd⁢t=H^⁢Ψ.

(4)

The problem of quantization

The problem of quantization is to find a correspondence between a quantum system and a classical system; this is clearly not always possible. Thus, specific methods of quantization describe several ways of constructing a pair (ℋ,H^) from a triplet (M,ω,H). Furthermore, in order to give physical meaning to the observables in the quantum system, there should be a map