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In the book Youth Concerns by bishop Moussait saysWhy do priests wear black hats and black clothes:

The priest's hat is shaped like a dome, representing the fact that the priest belongs to the church. As for the black clothes, there are 3 types of people who wear black: the lawyers, the judges, and the university professors. Thus the priest wears black because he is a lawyer who defends us before God, he is a judge who hears our confessions and gives us the absolution, and he is a professor who teaches us Christianity.