Supergirl Winn (Jeremy Jordan) has a conflict of interest when his father (Henry Czerny) — alias the villainous Toyman — escapes from prison and wants help in this new episode. Melissa Benoist and Calista Flockhart also star. 8 p.m. CBS

Kids Baking Championship Hosts Valerie Bertinelli and Duff Goldman ask the remaining eight bakers to incorporate chilies, peppers, cayenne and more hot and spicy ingredients into their chocolate creations in this new episode. 8 p.m. Food

Telenovela A hurricane keeps the cast on the set together, and since they're all on strict diets anyway, tempers flare. Eva Longoria, Izzy Diaz, Jadyn Douglas, Amaury Nolasco and Alex Meneses star in this new episode. 8:30 p.m. NBC

Scorpion Jeff Fahey guest stars as Sylvester's (Ari Stidham) estranged father, a military veteran who needs the team's help, in dealing with a threat posed by an African dictator, who supposedly has gotten hold of a weapon of mass destruction. Elyes Gabel and Katharine McPhee also star. 9 p.m. CBS

War & Peace This new six-part adaptation of the Tolstoy novel set in Russia at the time of the Napoleonic Wars stars Paul Dano, Lily James, James Norton, Jim Broadbent and Gillian Anderson. 9 p.m. A&E, History and Lifetime

Could I Live There? "Whirling Through Istanbul" A mesmerizing dance performance sways a family to relocate to a magical city in this season premiere. 9 p.m. Travel