Just built a new desktop. On every startup, after sign on as admin or otherwise I get a beep 2 warnings one says CLI.EXE failed to load or something like that, then a second cli.exe failed. I exit them and everything seems to work just fine.

you don't really need that .exe and can remove it by unchecking it in msconfig

cli - cli.exe - Process Information

Process File: cli or cli.exe
Process Name: ATI Catalyst

Description:
cli.exe is installed alongside ATI's range of graphics cards with the Catalyst hardware driver range. Installs a easy-to-access taskbar icon for access to diagnostics features. This is a non-essential process. Disabling or enabling this is down to user preference