FRAZER HARRISON/GETTY IMAGESJesse James and Kat Von D make their red carpet debut together at the opening for Von .'s Wonderland Gallery in West Hollywood Thursday night.

Kat Von D, the tattooed star of “L.A. Ink," and committed philanderer Jesse James, made their first appearance together on the red carpet Thursday night for the opening of Von D's Wonderland Galley.

She tells People.com that she’s in love with James. “I don’t hang out with anybody unless I am in love,” she told the magazine. She says she first may have realized the relationship was becoming serious while they were playing “Scrabble.” “It was something like that – when we both realized how nerdy we were.”

James, who just finalized his divorce from Sandra Bullock in June, didn’t gush, but told the magazine he was happy.