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THE world’s most unlikely womanizer has struck again. Zach Braff – who’s locked lips with Drew Barrymore, Mandy Moore, Bonnie Somerville and scores of New York beauties – took “Roswell” star Shiri Appleby to the Four Seasons on Hawaii’s Big Island over Labor Day weekend, where they were “making out all over the place.” Our spy added, “She even got on top of him at one point. It was the middle of the day.” A rep for Braff didn’t return e-mails for comment. Also in Hawaii were Leonardo DiCaprio and Lukas Haas, who celebrated Tobey Maguire‘s marriage to Jen Meyer.