Tb3+, Eu3+ codoped NaGd(MoO4)2 phosphors were prepared by the method of hydrothermal pro- cess. The structure of the phosphors was characterized by the X-ray diffraction (XRD), which was corresponded to JCPDS card with # 25-0828. The photoluminescence properties of the prepared products were characterized by the excitation and emission spectra. The energy transfer from Tb3+ to Eu3+ in NaGd(MoO4)2 phosphors was confirmed.