Claims:

1. An article of manufacture comprising(a) a dyed cotton fabric and,
deposited thereon,(b) from 0.05% by weight to 1% by weight, based on the
cotton fabric of at least one compound selected from the group consisting
of formulae (A*) to (BB*)whereinE is alkoxy of 1 to 18 carbon atoms,
cycloalkoxy of 5 to 12 carbon atoms or aralkoxy of 7 to 15 carbon atoms,
or E is --O-T-(OH)b,T is a straight or branched chain alkylene of 1
to 18 carbon atoms, cycloalkylene of 5 to 18 carbon atoms,
cycloalkenylene of 5 to 18 carbon atoms, a straight or branched chain
alkylene of 1 to 4 carbon atoms substituted by phenyl or by phenyl
substituted by one or two alkyl groups of 1 to 4 carbon atoms;b is 1, 2
or 3 with the proviso that b cannot exceed the number of carbon atoms in
T, and when b is 2 or 3, each hydroxyl group is attached to a different
carbon atoms of T;R is hydrogen or methyl; andin formula (A*) n is 1 or
2,when n is 1,R1 is hydrogen, alkyl of 1 to 18 carbon atoms, alkenyl
of 2-18 carbon atoms, propargyl, glycidyl, alkyl of 2 to 50 carbon atoms
interrupted by one to twenty oxygen atoms, said alkyl substituted by one
to ten hydroxyl groups or both interrupted by said oxygen atoms and
substituted by said hydroxyl groups, orR1 is alkyl of 1 to 4 carbon
atoms substituted by a carboxy group or by --COOZ where Z is hydrogen,
alkyl of 1 to 4 carbon atoms or phenyl, or where Z is said alkyl
substituted by --(COO.sup.-)nMn+ where n is 1-3 and M is a
metal ion from the 1 st, 2nd or 3rd group of the periodic table or is Zn,
Cu, Ni or Co, or M is a group Nn+(R2)4 where R2 is
alkyl of 1 to 8 carbon atoms or benzyl,when n is 2,R1 is alkylene of
1 to 12 carbon atoms, alkenylene of 4 to 12 carbon atoms, xylylene or
alkylene of 1 to 50 carbon atoms interrupted by one to twenty oxygen
atoms, substituted by one to ten hydroxyl groups or both interrupted by
said oxygen atoms and substituted by said hydroxyl groups;in formula
(B*), m is 1 to 4, andwhen m is 1,R2 is alkyl of 1 to 18 carbon
atoms, alkyl of 3 to 18 carbon atoms interrupted by --COO--, alkyl of 3
to 18 carbon atoms substituted by COOH or COO--, or R2 is
--CH2(OCH2CH2)nOCH3 where n is 1 to 12,
orR2 is cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 12 carbon
atoms, or said aryl substituted by one to four alkyl groups of 1 to 4
carbon atoms, orR2 is --NHR3 where R3 is alkyl of 1 to 18
carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 12 carbon
atoms, or said aryl substituted by one to four alkyl of 1 to 4 carbon
atoms, orR2 is --N(R3)2 where R3 is as defined
above,when m is 2,R2 is alkylene of 1 to 12 carbon atoms, alkenylene
of 4 to 12 carbon atoms, xylylene, alkylene of 2 to 12 carbon atoms
interrupted by --COO--, alkylene of 3 to 18 carbon atoms substituted by
COOH or COO--, or R2 is
--CH2(OCH2CH2)nOCH2-- where n is 1 to 12,
orR2 is cycloalkylene of 5 to 12 carbon atoms, aralkylene of 7 to 15
carbon atoms or arylene of 6 to 12 carbon atoms, orR2 is
--NHR4NH-- where R4 is alkylene of 2 to 18 carbon atoms,
cycloalkylene of 5 to 12 carbon atoms, aralkylene of 8 to 15 carbon atoms
or arylene of 6 to 12 carbon atoms, orR2 is
--N(R3)R4N(R3)-- where R3 and R4 are as defined
above, orR2 is --CO--, --NH--CO--NH--, or
--N(R3)--CO--N(R3)--,when m is 3,R2 is alkanetriyl of 3 to
8 carbon atoms or benzenetriyl, orwhen m is 4,R2 is alkanetetrayl of
5 to 8 carbon atoms or benzenetetrayl,in formula (C*),R10 is
hydrogen, alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon
atoms, aralkyl of 7 to 15 carbon atoms, alkanoyl of 2 to 18 carbon atoms,
alkenoyl of 3 to 5 carbon atoms or benzoyl,x is 1 or 2, andwhen x is
1,R11 is hydrogen, alkyl of 1 to 18 carbon atoms, alkenyl of 2 to 18
carbon atoms, propargyl, glycidyl, alkyl of 2 to 50 carbon atoms
interrupted by one to twenty oxygen atoms, said alkyl substituted by one
to ten hydroxyl groups or both interrupted by said oxygen atoms and
substituted by said hydroxyl groups, orR11 is alkyl of 1 to 4 carbon
atoms substituted by a carboxy group or by --COOZ where Z is hydrogen,
alkyl of 1 to 4 carbon atoms or phenyl, or where Z is said alkyl
substituted by --(COO.sup.-)nMn+ where n is 1-3 and M is a
metal ion from the 1 st, 2nd or 3rd group of the periodic table or is Zn,
Cu, Ni or Co, or M is a group Nn.sup.+ (R2)4 where R2 is
hydrogen, alkyl of 1 to 8 carbon atoms or benzyl, orwhen x is 2,R11
is alkylene of 1 to 12 carbon atoms, alkenylene of 4 to 12 carbon atoms,
xylylene or alkylene of 1 to 50 carbon atoms interrupted by one to twenty
oxygen atoms, substituted by one to ten hydroxyl groups or both
interrupted by said oxygen atoms and substituted by said hydroxyl
groups,in formula (D*), y is 1 to 4,R10 is as defined above,and
R12 is defined as R2 above,in formula (G*),Q1 is
--NR41-- or --O--,E1 is alkylene of 1 to 3 carbon atoms, or
E1 is --CH2--CH(R42)--O-- where R42 is hydrogen,
methyl or phenyl, or E1 is --(CH2)3--NH-- or E1 is a
direct bond,R40 is hydrogen or alkyl of 1 to 18 carbon
atoms,R41 is hydrogen, alkyl of 1 to 18 carbon atoms, cycloalkyl of
5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, aryl of 6 to 10
carbon atoms, or R41 is --CH2--CH(R42)--OH where R42
is as defined above,in formula (I*),this formula denotes a recurring
structural unit of a polymer where T. is ethylene or 1,2-propylene or is
the repeating structural unit derived from an alpha-olefin copolymer with
an alkyl acrylate or methacrylate, and whereq is 2 to 100,Q1 is
--N(R41)--or --O-- where R41 is as defined above,in formula
(J*),r is 1 or 2,T7 is as defined for R1 when n is 1 or 2 in
formula (A*),preferably T7 is octamethylene when r is 2,wherein in
formulas (Y*) to (BB*),n is 2 to 3,G1 is hydrogen, methyl, ethyl,
butyl or benzyl,m is 1 to 4,x is 1 to 4,when x is 1, R1 and R2
are independently alkyl of 1 to 18 carbon atoms, said alkyl interrupted
by one to five oxygen atoms, said alkyl substituted by 1 to 5 hydroxyl
groups or said alkyl both interrupted by said oxygen atoms and
substituted by said hydroxyl groups; cycloalkyl of 5 to 12 carbon atoms,
aralkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon atoms or said
aryl substituted by one to three alkyl of 1 to 8 carbon atoms, or R1
is also hydrogen, or R1 and R2 are together tetramethylene,
pentamethylene, hexamethylene or 3-oxapentamethylene,when x is 2,R1
is hydrogen, alkyl of 1 to 8 carbon atoms, said alkyl interrupted by one
or two oxygen atoms, said alkyl substituted by a hydroxyl group, or said
alkyl both interrupted by one or two oxygen atoms and substituted by a
hydroxyl group,R2 is alkylene of 2 to 18 carbon atoms, said alkylene
interrupted by one to five oxygen atoms, said alkylene substituted by 1
to 5 hydroxyl groups or said alkylene both interrupted by said oxygen
atoms and substituted by said hydroxyl groups; o-, m- or p-phenylene or
said phenylene substituted by one or two alkyl of 1 to 4 carbon atoms,
orR2 is
--(CH2)kO[(CH2)kO].sub.h(CH2)k-- where k is
2 to 4 and h is 1 to 40, orR1 and R2 together with the two N
atoms to which they are attached are piperazin-1,4-diyl,when x is
3,R1 is hydrogen,R2 is alkylene of 4 to 8 carbon atoms
interrupted by one nitrogen atom,when x is 4,R1 is hydrogen,R2
is alkylene of 6 to 12 carbon atoms interrupted by two nitrogen
atoms,R3 is hydrogen, alkyl of 1 to 8 carbon atoms, said alkyl
interrupted by one or two oxygen atoms, said alkyl substituted by a
hydroxyl group, or both interrupted by one or two oxygen atoms and
substituted by a hydroxyl group,p is 2 or 3,HY is an inorganic or organic
acid; wherein the total charge of cations is equal to the total charge of
anions; andY is phosphate, phosphonate, carbonate, bicarbonate, nitrate,
chloride, bromide, bisulfite, sulfite, bisulfate, sulfate, borate,
formate, acetate, benzoate, citrate, oxalate, tartrate, acrylate,
polyacrylate, fumarate, maleate, itaconate, glycolate, gluconate, malate,
mandelate, tiglate, ascorbate, polymethacrylate, a carboxylate of
nitrilotriacetic acid, a carboxlylate of
hydroxyethylethylenediaminetriacetic acid, a carboxylate of
ethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, a carboxylate of
diethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, alkylsulfonate, arylsulfonate, or
alkyl-substituted arylsulfonate.

2. A stabilized article according to claim 1 wherein the compounds are
selected from the group consisting of formulae (A*), (B*), (C*), (D*),
(Q*), (R*), (Y*), and (Z*),whereinE is alkoxy of 1 to 10 carbon atoms,
cycloalkoxy of 5 to 8 carbon atoms or aralkoxy of 7 to 12 carbon atoms,
or E is --O-T-(OH)b,T is a straight or branched chain alkylene of 1
to 10 carbon atoms, cycloalkylene of 5 to 10 carbon atoms,
cycloalkenylene of 5 to 10 carbon atoms, a straight or branched chain
alkylene of 1 to 4 carbon atoms substituted by phenyl or by phenyl
substituted by one or two alkyl groups of 1 to 4 carbon atoms;b is 1, 2
or 3 with the proviso that b cannot exceed the number of carbon atoms in
T, and when b is 2 or 3, each hydroxyl group is attached to a different
carbon atoms of T;R is hydrogen;in formula (A*), n is 1 or 2,when n is
1,R1 is hydrogen, alkyl of 1 to 6 carbon atoms, alkenyl of 2-6
carbon atoms, propargyl, glycidyl, alkyl of 2 to 20 carbon atoms
interrupted by one to ten oxygen atoms, said alkyl substituted by one to
five hydroxyl groups or both interrupted by said oxygen atoms and
substituted by said hydroxyl groups, orR1 is alkyl of 1 to 4 carbon
atoms substituted by a carboxy group or by --COOZ where Z is hydrogen or
alkyl of 1 to 4 carbon atoms,when n is 2,R1 is alkylene of 1 to 8
carbon atoms, alkenylene of 4 to 8 carbon atoms, alkylene of 1 to 20
carbon atoms interrupted by one to ten oxygen atoms, substituted by one
to five hydroxyl groups or both interrupted by said oxygen atoms and
substituted by said hydroxyl groups,in formula (B*), m is 1 or 2,when m
is 1,R2 is alkyl of 1 to 4 carbon atoms or R2 is
CH2(OCH2CH2)nOCH3 where n is 1 to 12, orR2
is phenyl, or said phenyl substituted by one to three methyl groups,
orR2 is --NHR3 where R3 is alkyl of 1 to 4 carbon atoms or
phenyl, or said phenyl substituted by one or two methyl groups,when m is
2,R2 is alkylene of 1 to 8 carbon atoms, alkenylene of 4 to 8 carbon
atoms, or R2 is --CH2(OCH2CH2)nOCH2-- where
n is 1 to 12, orR2 is --NHR4NH-- where R4 is of 2 to 6
carbon atoms, aralkylene of 8 to 15 carbon atoms or arylene of 6 to 12
carbon atoms, orR2 is --CO-- or --NHCONH--,in formula (C*),R10
is hydrogen or, alkanoyl of 1 to 3 carbon atoms,x is 1 or 2,when x is
1,R11 is hydrogen, alkyl of 1 to 6 carbon atoms or glycidyl,
orR11 is alkyl of 1 to 4 carbon atoms substituted by a carboxy group
or by COOZ where Z is hydrogen or alkyl of 1 to 4 carbon atoms,when x is
2,R11 is alkylene of 1 to 6 carbon atoms,in formula (D*),R10 is
hydrogen,y is 1 or 2,R12 is defined as R2 above,in formula (Y*)
and (Z*),x is 1 or 2,when x is 1,R1 and R2 are independently
alkyl of 1 to 4 carbon atoms or R1 and R2 are together
tetramethylene, or pentamethylene,R2 is hydrogen or alkyl of 1 to 4
carbon atoms, said alkyl group substituted by a hydroxyl group,when x is
2,R1 is hydrogen, alkyl of 1 to 4 carbon atoms, said alkyl
substituted by a hydroxyl group,R2 is alkylene of 2 to 6 carbon
atoms,R3 is as defined above,HY is an inorganic or organic acid;
wherein the total charge of cations is equal to the total charge of
anions; andY is phosphate, phosphonate, carbonate, bicarbonate, chloride,
bromide, bisulfate, sulfate, borate, formate, acetate, benzoate, citrate,
oxalate, tartrate, acrylate, fumarate, maleate, itaconate, glycolate,
gluconate, malate, mandelate, tiglate, ascorbate, a carboxylate of
nitrilotriacetic acid, a carboxylate of
hydroxyethylethylenediaminetriacetic acid, a carboxylate of
ethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, a carboxylate of
diethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, alkylsulfonate, arylsulfonate, or
alkyl-substituted arylsulfonate.

3. A stabilized article according to claim 2 wherein the compounds are
selected from the group consisting of formulae (A*), (B*), (C*), (D*),
(Q*), and (R*),whereinE is alkoxy of 1 to 10 carbon atoms, cycloalkoxy of
5 to 8 carbon atoms or aralkoxy of 7 to 12 carbon atoms, or E is
--O-T-(OH)b,T is a straight or branched chain alkylene of 1 to 10
carbon atoms, cycloalkylene of 5 to 10 carbon atoms, cycloalkenylene of 5
to 10 carbon atoms, a straight or branched chain alkylene of 1 to 4
carbon atoms substituted by phenyl or by phenyl substituted by one or two
alkyl groups of 1 to 4 carbon atoms;b is 1, 2 or 3 with the proviso that
b cannot exceed the number of carbon atoms in T, andwhen b is 2 or 3,
each hydroxyl group is attached to a different carbon atoms of T;R is
hydrogen,in formula (A*),n is 1,R1 is hydrogen, alkyl of 1 to 4
carbon atoms, glycidyl, alkyl of 2 to 4 carbon atoms interrupted by one
or two oxygen atoms, said alkyl substituted by one or two hydroxyl groups
or both interrupted by said oxygen atoms and substituted by said hydroxyl
groups, orR1 is alkyl of 1 to 4 carbon atoms substituted by --COOZ
where Z is hydrogen or alkyl of 1 to 4 carbon atoms,in formula (B*),m is
1 or 2,R2 is alkyl of 1 to 4 carbon atoms or R2 is
CH2(OCH2CH2)nOCH3 where n is 1 to 4,when m is
2,R2 is alkylene of 1 to 8 carbon atoms,in formula (C*),R10 is
hydrogen or alkanoyl of 1 or 2 carbon atoms,x is 1 or 2,when x is
1,R11 is hydrogen, alkyl of 1 to 4 carbon atoms or glycidyl,R11
is alkyl of 1 to 4 carbon atoms substituted by COOZ where Z is hydrogen
or alkyl of 1 to 4 carbon atoms,when x is 2,R11 is alkylene of 1 to
6 carbon atoms,in formula (D*),R10 is hydrogen,y is 1 or 2,R12
is defined as R2 above;HY is an inorganic or organic acid; wherein
the total charge of cations is equal to the total charge of anions; andY
is phosphate, phosphonate, carbonate, bicarbonate, chloride, bromide,
bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate,
tartrate, ascorbate, acrylate, fumarate, maleate, itaconate, glycolate,
gluconate, malate, mandelate, tiglate, a carboxylate of nitrilotriacetic
acid, a carboxylate of hydroxyethylethylenediaminetriacetic acid, a
carboxylate of ethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, a carboxylate of
diethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, alkylsulfonate, arylsulfonate, or
alkyl-substituted arylsulfonate.

6. A stabilized article according to claim 1 further comprising(c) one or
more compounds selected from the group consisting of the ultraviolet
light absorbers, antioxidants, tocopherol, tocopherol acetate, hindered
amine light stabilizers, complex formers, optical brighteners,
surfactants, and polyorganosiloxanes.

7. A stabilized article according to claim 6 where the ultraviolet light
absorbers are selected from the group consisting of 2H-benzotriazoles,
s-triazines, benzophenones, alpha-cyanoacrylates, oxanilides,
benzoxazinones, benzoates, and alpha-alkyl cinnamates.

8. A method of stabilizing a dyed cotton fabric, which comprises
incorporating therein or applying thereto one or more compounds of the
formulae A* to BB* according to claim 1.

Description:

[0001]This application is a divisional of U.S. application Ser. No.
11/201,377, filed Aug. 10, 2005, pending, which claims benefit under 35
USC 119(e) of U.S. provisional application No. 60/603,590, filed Aug. 23,
2004, the disclosure of which is hereby incorporated by reference.

[0002]The present invention relates to the use of certain sterically
hindered amine salt compounds for the protection of body care products,
household products, textiles and fabrics against the deleterious effects
of light, heat and oxygen.

[0003]The stabilized compositions for example comprise dyes that are
stabilized against color change.

BACKGROUND

[0004]WO 00/25730 and WO 00/25731 are aimed at the stabilization of body
care and household products.

[0011](b) an effective stabilizing amount of one or more compounds of
formula (I)

whereinG1 and G2 are independently alkyl of 1 to 4 carbon atoms
or are together pentamethylene; Z1 and Z2 are each methyl, or
Z1 and Z2 together form an unsubstituted linking moiety or a
linking moiety substituted by one or more groups selected from an ester,
ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or an urethane
group;E is alkoxy of 1 to 18 carbon atoms, cycloalkoxy of 5 to 12 carbon
atoms or aralkoxy of 7 to 15 carbon atoms, or E is --O-T-(OH)b,T is
a straight or branched chain alkylene of 1 to 18 carbon atoms,
cycloalkylene of 5 to 18 carbon atoms, cycloalkenylene of 5 to 18 carbon
atoms, a straight or branched chain alkylene of 1 to 4 carbon atoms
substituted by phenyl or by phenyl substituted by one or two alkyl groups
of 1 to 4 carbon atoms;b is 1, 2 or 3 with the proviso that b cannot
exceed the number of carbon atoms in T, and when b is 2 or 3, each
hydroxyl group is attached to a different carbon atoms of T; andHY is an
inorganic or organic acid; wherein the total charge of cations is equal
to the total charge of anions.

[0019]For instance, Z1 and Z2 as a linking moiety are a chain of 2 or 3
carbon atoms or 1 or 2 carbon atoms and a nitrogen or oxygen atom forming
together with the remaining structure in formula (I) a saturated
unsubstituted 5- or 6-membered heterocyclic ring or a 5- or 6-membered
heterocyclic ring substituted by one or more groups selected from an
ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or an
urethane group. The substituents in Z1 and Z2 themselves may contain
hindered amine moieties. For example, the compounds of the formula (I)
contain 1-4 hindered amine or hindered ammonium groups. For instance, the
compounds of formula (I) contain 1 or 2 hindered amine or hindered
ammonium moieties.

[0020]Any group denoted as aryl mainly means C6-C12aryl; for
example, aryl is phenyl or naphthyl; for instance, aryl is phenyl.

[0024]Aralkyl or aralkoxy is, for example, phenylalkyl or phenylalkoxy,
which is alkyl or alkoxy substituted by phenyl. Examples for phenylalkyl
or phenylalkoxy are, within the definitions given, benzyl, benzyloxy,
alpha-methylbenzyl, alpha-methylbenzyloxy, cumyl, or cumyloxy.

[0027]A group denoted as acyl is mainly R(C═O)--, where R is an
aliphatic or aromatic moiety.

[0028]An aliphatic or aromatic moiety, such as mentioned above or other
definitions, mainly is an aliphatic or aromatic
C1-C30hydrocarbon; examples are aryl, alkyl, cycloalkyl,
alkenyl, cycloalkenyl, bicycloalkyl, bicycloalkenyl, and combinations of
these groups.

[0029]Examples for acyl groups are alkanoyl of 2 to 12 carbon atoms,
alkenoyl of 3 to 12 carbon atoms, or benzoyl.

[0032]The alkyl groups in the different substituents may be linear or
branched.

[0033]Examples for alkenyl groups with 2 to 4 carbon atoms are ethenyl,
propenyl, or butenyl. Examples for alkyl groups with 1 to 4 carbon atoms
interrupted by one or two oxygen atoms are --CH2--O--CH3,
--CH2--CH2--O--CH3,
--CH2--CH2--O--CH2--CH3,
--CH2--O--CH2--CH2--O--CH3 or
--CH2--O--CH2--O--CH3.

[0035]Examples of especially suited compounds of component (b) formula (I)
are selected from the group consisting of formulae A* to EE* and (III) to
(IIIc):

whereinE is alkoxy of 1 to 18 carbon atoms, cycloalkoxy of 5 to 12 carbon
atoms or aralkoxy of 7 to 15 carbon atoms, or E is --O-T-(OH)b,T is
a straight or branched chain alkylene of 1 to 18 carbon atoms,
cycloalkylene of 5 to 18 carbon atoms, cycloalkenylene of 5 to 18 carbon
atoms, a straight or branched chain alkylene of 1 to 4 carbon atoms
substituted by phenyl or by phenyl substituted by one or two alkyl groups
of 1 to 4 carbon atoms;b is 1, 2 or 3 with the proviso that b cannot
exceed the number of carbon atoms in T, and when b is 2 or 3, each
hydroxyl group is attached to a different carbon atoms of T;R is hydrogen
or methyl; andin formula (A*) n is 1 or 2,when n is 1,R1 is
hydrogen, alkyl of 1 to 18 carbon atoms, alkenyl of 2-18 carbon atoms,
propargyl, glycidyl, alkyl of 2 to 50 carbon atoms interrupted by one to
twenty oxygen atoms, said alkyl substituted by one to ten hydroxyl groups
or both interrupted by said oxygen atoms and substituted by said hydroxyl
groups, orR1 is alkyl of 1 to 4 carbon atoms substituted by a
carboxy group or by --COOZ where Z is hydrogen, alkyl of 1 to 4 carbon
atoms or phenyl, or where Z is said alkyl substituted by
--(COO.sup.-)nMn+ where n is 1-3 and M is a metal ion from the
1st, 2nd or 3rd group of the periodic table or is Zn, Cu, Ni or Co, or M
is a group Nn+ (R2)4 where R2 is alkyl of 1 to 8
carbon atoms or benzyl,when n is 2,R1 is alkylene of 1 to 12 carbon
atoms, alkenylene of 4 to 12 carbon atoms, xylylene or alkylene of 1 to
50 carbon atoms interrupted by one to twenty oxygen atoms, substituted by
one to ten hydroxyl groups or both interrupted by said oxygen atoms and
substituted by said hydroxyl groups;in formula (B*), m is 1 to 4, andwhen
m is 1,R2 is alkyl of 1 to 18 carbon atoms, alkyl of 3 to 18 carbon
atoms interrupted by --COO--, alkyl of 3 to 18 carbon atoms substituted
by COOH or COO--, or R2 is
--CH2(OCH2CH2)nOCH3 where n is 1 to 12,
orR2 is cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 12 carbon
atoms, or said aryl substituted by one to four alkyl groups of 1 to 4
carbon atoms, orR2 is --NHR3 where R3 is alkyl of 1 to 18
carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aryl of 6 to 12 carbon
atoms, or said aryl substituted by one to four alkyl of 1 to 4 carbon
atoms, orR2 is --N(R3)2 where R3 is as defined
above,when m is 2,R2 is alkylene of 1 to 12 carbon atoms, alkenylene
of 4 to 12 carbon atoms, xylylene, alkylene of 2 to 12 carbon atoms
interrupted by --COO--, alkylene of 3 to 18 carbon atoms substituted by
COOH or COO--, or R2 is
--CH2(OCH2CH2)nOCH2-- where n is 1 to 12,
orR2 is cycloalkylene of 5 to 12 carbon atoms, aralkylene of 7 to 15
carbon atoms or arylene of 6 to 12 carbon atoms, orR2 is
--NHR4NH-- where R4 is alkylene of 2 to 18 carbon atoms,
cycloalkylene of 5 to 12 carbon atoms, aralkylene of 8 to 15 carbon atoms
or arylene of 6 to 12 carbon atoms, orR2 is
--N(R3)R4N(R3)-- where R3 and R4 are as defined
above, or

R2 is --CO--, --NH--CO--NH--, or --N(R3)--CO--N(R3)--,

[0036]when m is 3,R2 is alkanetriyl of 3 to 8 carbon atoms or
benzenetriyl, orwhen m is 4,R2 is alkanetetrayl of 5 to 8 carbon
atoms or benzenetetrayl,in formula (C*),R10 is hydrogen, alkyl of 1
to 18 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aralkyl of 7 to
15 carbon atoms, alkanoyl of 2 to 18 carbon atoms, alkenoyl of 3 to 5
carbon atoms or benzoyl,x is 1 or 2, andwhen x is 1,R11 is hydrogen,
alkyl of 1 to 18 carbon atoms, alkenyl of 2 to 18 carbon atoms,
propargyl, glycidyl, alkyl of 2 to 50 carbon atoms interrupted by one to
twenty oxygen atoms, said alkyl substituted by one to ten hydroxyl groups
or both interrupted by said oxygen atoms and substituted by said hydroxyl
groups, orR11 is alkyl of 1 to 4 carbon atoms substituted by a
carboxy group or by --COOZ where Z is hydrogen, alkyl of 1 to 4 carbon
atoms or phenyl, or where Z is said alkyl substituted by
--(COO.sup.-)nMn+ where n is 1-3 and M is a metal ion from the
1st, 2nd or 3rd group of the periodic table or is Zn, Cu, Ni or Co, or M
is a group Nn+ (R2)4 where R2 is hydrogen, alkyl of 1
to 8 carbon atoms or benzyl, orwhen x is 2,R11 is alkylene of 1 to
12 carbon atoms, alkenylene of 4 to 12 carbon atoms, xylylene or alkylene
of 1 to 50 carbon atoms interrupted by one to twenty oxygen atoms,
substituted by one to ten hydroxyl groups or both interrupted by said
oxygen atoms and substituted by said hydroxyl groups,in formula (D*), y
is 1 to 4,R10 is as defined above,and R12 is defined as R2
above,in formula (E*), k is 1 or 2,when k is 1,R20 and R21 are
independently alkyl of 1 to 12 carbon atoms, alkenyl of 2 to 12 carbon
atoms or aralkyl of 7 to 15 carbon atoms, or R20 is also hydrogen,
orR20 and R21 together are alkylene of 2 to 8 carbon atoms or
said alkylene substituted by hydroxyl, or are acyloxy-alkylene of 4 to 22
carbon atoms, orwhen k is 2,R20 and R21 are together
(--CH2)2C(CH2--)2,in formula (F*),R30 is
hydrogen, alkyl of 1 to 18 carbon atoms, benzyl, glycidyl, or alkoxyalkyl
of 2 to 6 carbon atoms,g is 1 or 2,when g is 1, R31 is defined as
R1 above when n is 1,when g is 2, R31 is defined as R1
above when n is 2,in formula (G*),

Q1 is --NR41-- or --O--,

[0037]E1 is alkylene of 1 to 3 carbon atoms, or E1 is
--CH2--CH(R42)--O-- where R42 is hydrogen, methyl or
phenyl, or E1 is --(CH2)3--NH-- or E1 is a direct
bond,R40 is hydrogen or alkyl of 1 to 18 carbon atoms,R41 is
hydrogen, alkyl of 1 to 18 carbon atoms, cycloalkyl of 5 to 12 carbon
atoms, aralkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon atoms, or
R41 is --CH2--CH(R42)--OH where R42 is as defined
above,in formula (H*), p is 1 or 2,T4 is as defined for R11
when x is 1 or 2,M and Y are independently methylene or carbonyl,
preferably M is methylene and Y is carbonyl,in formula (I*),this formula
denotes a recurring structural unit of a polymer where T1 is
ethylene or 1,2-propylene or is the repeating structural unit derived
from an alpha-olefin copolymer with an alkyl acrylate or methacrylate,
and whereq is 2 to 100,Q1 is --N(R41)-- or --O-- where R41
is as defined above,in formula (J*),r is 1 or 2,T7 is as defined for
R1 when n is 1 or 2 in formula (A*), preferably T7 is
octamethylene when r is 2,in formula (L*), u is 1 or 2,T13 is as
defined for R1 when n is 1 or 2 in formula (A*), with the proviso
that T13 is not hydrogen when u is 1,in formula (M*),E1 and
E2, being different, each are --CO-- or --N(E5)- where E5
is hydrogen, alkyl of 1 to 12 carbon atoms or alkoxycarbonylalkyl of 4 to
22 carbon atoms, preferably E is --CO-- and E2 is
--N(E5)-,E3 is hydrogen, alkyl of 1 to 30 carbon atoms, phenyl,
naphthyl, said phenyl or said naphthyl substituted by chlorine or by
alkyl of 1 to 4 carbon atoms, or phenylalkyl of 7 to 12 carbon atoms, or
said phenylalkyl substituted by alkyl of 1 to 4 carbon atoms,E4 is
hydrogen, alkyl of 1 to 30 carbon atoms, phenyl, naphthyl or phenylalkyl
of 7 to 12 carbon atoms, orE3 and E4 together are polymethylene
of 4 to 17 carbon atoms, or said polymethylene substituted by one to four
alkyl of 1 to 4 carbon atoms, preferably methyl,in formula (O*),R10
is as defined for R10 in formula (C*),in formula (P*),E6 is an
aliphatic or aromatic tetravalent radical, preferably neopentanetetrayl
or benzenetetrayl,in formula (T*),R51 is hydrogen, alkyl of 1 to 18
carbon atoms, cycloalkyl of 5 to 12 carbon atoms, or aryl of 6 to 10
carbon atoms,R52 is hydrogen or alkyl of 1 to 18 carbon atoms,
orR51 and R52 together of alkylene of 4 to 8 carbon atoms,f is
1 or 2,when f is 1,R50 is as defined for R11 in formula (C*)
when x is 1, or R50 is --(CH2)zCOOR54 where z is 1 to
4 and R54 is hydrogen or alkyl of 1 to 18 carbon atoms, or R54
is a metal ion from the 1st, 2nd or 3rd group of the periodic table or a
group --N(R55)4 where R55 is hydrogen, alkyl of 1 to 12
carbon atoms or benzyl,when f is 2,R50 is as defined for R11 in
formula (C*) when x is 2,in formula (U*),R53, R54, R55 and
R56 are independently alkyl of 1 to 4 carbon atoms or are together
pentamethylene,in formula (V*),R57, R58, R59 and R60
are independently alkyl of 1 to 4 carbon atoms or are together
pentamethylene,in formula (W*),R61, R62, R63 and R64
are independently alkyl of 1 to 4 carbon atoms or are together
pentamethylene,R65 is alkyl of 1 to 5 carbon atoms,M is hydrogen or
oxygen,wherein in formulas (Y*) to (BB*),n is 2 to 3,G1 is hydrogen,
methyl, ethyl, butyl or benzyl,m is 1 to 4,x is 1 to 4,when x is 1,
R1 and R2 are independently alkyl of 1 to 18 carbon atoms, said
alkyl interrupted by one to five oxygen atoms, said alkyl substituted by
1 to 5 hydroxyl groups or said alkyl both interrupted by said oxygen
atoms and substituted by said hydroxyl groups; cycloalkyl of 5 to 12
carbon atoms, aralkyl of 7 to 15 carbon atoms, aryl of 6 to 10 carbon
atoms or said aryl substituted by one to three alkyl of 1 to 8 carbon
atoms, or R1 is also hydrogen, or R1 and R2 are together
tetramethylene, pentamethylene, hexamethylene or 3-oxapentamethylene,when
x is 2,R1 is hydrogen, alkyl of 1 to 8 carbon atoms, said alkyl
interrupted by one or two oxygen atoms, said alkyl substituted by a
hydroxyl group, or said alkyl both interrupted by one or two oxygen atoms
and substituted by a hydroxyl group,R2 is alkylene of 2 to 18 carbon
atoms, said alkylene interrupted by one to five oxygen atoms, said
alkylene substituted by 1 to 5 hydroxyl groups or said alkylene both
interrupted by said oxygen atoms and substituted by said hydroxyl groups;
o-, m- or p-phenylene or said phenylene substituted by one or two alkyl
of 1 to 4 carbon atoms, orR2 is
--(CH2)kO[(CH2)kO].sub.h(CH2)k-- where k is
2 to 4 and h is 1 to 40, orR1 and R2 together with the two N
atoms to which they are attached are piperazin-1,4-diyl, when x is
3,R1 is hydrogen,R2 is alkylene of 4 to 8 carbon atoms
interrupted by one nitrogen atom,when x is 4,R1 is hydrogen,R2
is alkylene of 6 to 12 carbon atoms interrupted by two nitrogen
atoms,R3 is hydrogen, alkyl of 1 to 8 carbon atoms, said alkyl
interrupted by one or two oxygen atoms, said alkyl substituted by a
hydroxyl group, or both interrupted by one or two oxygen atoms and
substituted by a hydroxyl group,p is 2 or 3,in formula (DD*),m is 2 or
3,when m is 2,G is --(CH2CHR--O)rCH2CHR--, where r is 0 to
3, and R is hydrogen or methyl, andwhen m is 3, G is glyceryl,in formula
(EE*),G2 is --CN, --CONH2 or --COOG3 where G3 is
hydrogen, alkyl of 1 to 18 carbon atoms or phenyl,in formulae (III) to
(IIIc),

A11 is OR101 or NR111R112,

[0038]R101 is alkenyl of 2 to 4 carbon atoms, propargyl, glycidyl,
alkyl of 2 to 6 carbon atoms interrupted by one or two oxygen atoms,
substituted by one to three hydroxyl groups or both interrupted by said
oxygen atoms and substituted by said hydroxyl groups, or R101 is
alkyl of 1 to 4 carbon atoms substituted by carboxy or by the alkali
metal, ammonium or C1-C4alkylammonium salts thereof; or
R101 is alkyl substituted by COOE10 where E10 is methyl or
ethyl,R102 is alkyl of 3 to 5 carbon atoms interrupted by --COO-- or
by --CO--, or R102 is --CH2(OCH2CH2)cCOCH3
where c is 1 to 4; orR102 is --NHR103 where R103 is alkyl
of 1 to 4 carbon atoms,a is 2 to 4,when a is 2,T11 is
--(CH2CHR100--O)dCH2CHR100--, where d is 0 or 1,
and R100 is hydrogen or methyl,when a is 3, T11 is
glyceryl,when a is 4, T11 is neopentanetetrayl,b is 2 or 3,when b is
2,G11 is --(CH2CHR100--O)dCH2CHR100--,
where d is 0 or 1, and R100 is hydrogen or methyl, and when b is 3,
G11 is glyceryl;R111 is hydrogen, unsubstituted alkyl of 1 to 4
carbon atoms, alkyl of 1 to 4 carbon atoms substituted by one or two
hydroxyl, alkyl of 1 to 4 carbon atoms interrupted by one or two oxygen
atoms, or both substituted by one hydroxyl and interrupted by one or two
oxygen atoms,R112 is --CO--R113 where R113 has the same
meaning as R111, or R113 is NHR114, wherein R114 is
unsubstituted alkyl of 1 to 4 carbon atoms, alkyl of 1 to 4 carbon atoms
substituted by one or two hydroxyl, alkyl of 1 to 4 carbon atoms
substituted by alkoxy of 1 to 2 carbon atoms, or both substituted by one
hydroxyl and by alkoxy of 1 to 2 carbon atoms, orR111 and R112
together are --CO--CH2CH2--CO--, or (CH2)6CO--;HY is
an inorganic or organic acid; wherein the total charge of cations is
equal to the total charge of anions; andY is phosphate, phosphonate,
carbonate, bicarbonate, nitrate, chloride, bromide, bisulfite, sulfite,
bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate,
tartrate, acrylate, polyacrylate, fumarate, maleate, itaconate,
glycolate, gluconate, malate, mandelate, tiglate, ascorbate,
polymethacrylate, a carboxylate of nitrilotriacetic acid, a carboxlylate
of hydroxyethylethylenediaminetriacetic acid, a carboxylate of
ethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, a carboxylate of
diethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, alkylsulfonate, arylsulfonate, or
alkyl-substituted arylsulfonate.

[0039]Another embodiment of the instant invention is the compounds of
component (b) formula (I) selected from the group consisting of (A*),
(B*), (C*), (D*), (Q*), (R*), (Y*), and (Z*),

whereinE is alkoxy of 1 to 10 carbon atoms, cycloalkoxy of 5 to 8 carbon
atoms or aralkoxy of 7 to 12 carbon atoms, or E is --O-T-(OH)b,T is
a straight or branched chain alkylene of 1 to 10 carbon atoms,
cycloalkylene of 5 to 10 carbon atoms, cycloalkenylene of 5 to 10 carbon
atoms, a straight or branched chain alkylene of 1 to 4 carbon atoms
substituted by phenyl or by phenyl substituted by one or two alkyl groups
of 1 to 4 carbon atoms;b is 1, 2 or 3 with the proviso that b cannot
exceed the number of carbon atoms in T, and when b is 2 or 3, each
hydroxyl group is attached to a different carbon atoms of T;R is
hydrogen;in formula (A*), n is 1 or 2,when n is 1,R1 is hydrogen,
alkyl of 1 to 6 carbon atoms, alkenyl of 2-6 carbon atoms, propargyl,
glycidyl, alkyl of 2 to 20 carbon atoms interrupted by one to ten oxygen
atoms, said alkyl substituted by one to five hydroxyl groups or both
interrupted by said oxygen atoms and substituted by said hydroxyl groups,
orR1 is alkyl of 1 to 4 carbon atoms substituted by a carboxy group
or by --COOZ where Z is hydrogen or alkyl of 1 to 4 carbon atoms,when n
is 2,R1 is alkylene of 1 to 8 carbon atoms, alkenylene of 4 to 8
carbon atoms, alkylene of 1 to 20 carbon atoms interrupted by one to ten
oxygen atoms, substituted by one to five hydroxyl groups or both
interrupted by said oxygen atoms and substituted by said hydroxyl
groups,in formula (B*), m is 1 or 2,when m is 1,R2 is alkyl of 1 to
4 carbon atoms or R2 is CH2(OCH2CH2)nOCH3
where n is 1 to 12, orR2 is phenyl, or said phenyl substituted by
one to three methyl groups, orR2 is --NHR3 where R3 is
alkyl of 1 to 4 carbon atoms or phenyl, or said phenyl substituted by one
or two methyl groups,when m is 2,R2 is alkylene of 1 to 8 carbon
atoms, alkenylene of 4 to 8 carbon atoms, or R2 is
--CH2(OCH2CH2)nOCH2-- where n is 1 to 12,
orR2 is --NHR4NH-- where R4 is of 2 to 6 carbon atoms,
aralkylene of 8 to 15 carbon atoms or arylene of 6 to 12 carbon atoms, or

R2 is --CO-- or --NHCONH--,

[0040]in formula (C*),R10 is hydrogen or, alkanoyl of 1 to 3 carbon
atoms,x is 1 or 2,when x is 1,R11 is hydrogen, alkyl of 1 to 6
carbon atoms or glycidyl, orR11 is alkyl of 1 to 4 carbon atoms
substituted by a carboxy group or by COOZ where Z is hydrogen or alkyl of
1 to 4 carbon atoms,when x is 2,R11 is alkylene of 1 to 6 carbon
atoms,in formula (D*),R10 is hydrogen,y is 1 or 2,R12 is
defined as R2 above,in formula (Y*) and (Z*),x is 1 or 2,when x is
1,R1 and R2 are independently alkyl of 1 to 4 carbon atoms or
R1 and R2 are together tetramethylene, or
pentamethylene,R2 is hydrogen or alkyl of 1 to 4 carbon atoms, said
alkyl group substituted by a hydroxyl group,when x is 2,R1 is
hydrogen, alkyl of 1 to 4 carbon atoms, said alkyl substituted by a
hydroxyl group,R2 is alkylene of 2 to 6 carbon atoms,R3 is as
defined above,HY is an inorganic or organic acid; wherein the total
charge of cations is equal to the total charge of anions; andY is
phosphate, phosphonate, carbonate, bicarbonate, chloride, bromide,
bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate,
tartrate, acrylate, fumarate, maleate, itaconate, glycolate, gluconate,
malate, mandelate, tiglate, ascorbate, a carboxylate of nitrilotriacetic
acid, a carboxylate of hydroxyethylethylenediaminetriacetic acid, a
carboxylate of ethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, a carboxylate of
diethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, alkylsulfonate, arylsulfonate, or
alkyl-substituted arylsulfonate.

[0041]Still another embodiment of the instant invention is the compounds
of component (b) formula (I) selected from the group consisting of (A*),
(B*), (C*), (D*), (Q*), and (R*),

whereinE is alkoxy of 1 to 10 carbon atoms, cycloalkoxy of 5 to 8 carbon
atoms or aralkoxy of 7 to 12 carbon atoms, or E is --O-T-(OH)b,T is
a straight or branched chain alkylene of 1 to 10 carbon atoms,
cycloalkylene of 5 to 10 carbon atoms, cycloalkenylene of 5 to 10 carbon
atoms, a straight or branched chain alkylene of 1 to 4 carbon atoms
substituted by phenyl or by phenyl substituted by one or two alkyl groups
of 1 to 4 carbon atoms;b is 1, 2 or 3 with the proviso that b cannot
exceed the number of carbon atoms in T, and when b is 2 or 3, each
hydroxyl group is attached to a different carbon atoms of T;R is
hydrogen,in formula (A*),n is 1,R1 is hydrogen, alkyl of 1 to 4
carbon atoms, glycidyl, alkyl of 2 to 4 carbon atoms interrupted by one
or two oxygen atoms, said alkyl substituted by one or two hydroxyl groups
or both interrupted by said oxygen atoms and substituted by said hydroxyl
groups, orR1 is alkyl of 1 to 4 carbon atoms substituted by --COOZ
where Z is hydrogen or alkyl of 1 to 4 carbon atoms,in formula (B*),m is
1 or 2,R2 is alkyl of 1 to 4 carbon atoms or R2 is
CH2(OCH2CH2)nOCH3 where n is 1 to 4,when m is
2,R2 is alkylene of 1 to 8 carbon atoms,in formula (C*),R10 is
hydrogen or alkanoyl of 1 or 2 carbon atoms,x is 1 or 2,when x is
1,R11 is hydrogen, alkyl of 1 to 4 carbon atoms or glycidyl,R11
is alkyl of 1 to 4 carbon atoms substituted by COOZ where Z is hydrogen
or alkyl of 1 to 4 carbon atoms,when x is 2,R11 is alkylene of 1 to
6 carbon atoms,in formula (D*),R10 is hydrogen,y is 1 or 2,R12
is defined as R2 above;HY is an inorganic or organic acid; wherein
the total charge of cations is equal to the total charge of anions; andY
is phosphate, phosphonate, carbonate, bicarbonate, chloride, bromide,
bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate,
tartrate, ascorbate, acrylate, fumarate, maleate, itaconate, glycolate,
gluconate, malate, mandelate, tiglate, a carboxylate of nitrilotriacetic
acid, a carboxylate of hydroxyethylethylenediaminetriacetic acid, a
carboxylate of ethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, a carboxylate of
diethylenediaminetetraacetic acid, a carboxylate of
diethylenetriaminepentaacetic acid, alkylsulfonate, arylsulfonate, or
alkyl-substituted arylsulfonate.

[0096]The compounds of component (b) formula (I) can be prepared according
to methods known in the art or in analogy to those methods. For example,
these compounds may be prepared according to U.S. Pat. No. 6,392,041;
U.S. Pat. No. 6,586,507; U.S. Pat. No. 6,166,212; U.S. Pat. No.
5,374,729; U.S. Pat. No. 5,015,683; U.S. Pat. No. 5,021,483; U.S. Pat.
No. 4,921,962; U.S. Pat. No. 5,112,890; and, U.S. Pat. No. 5,204,473,
incorporated herein by reference.

[0098]The present invention pertains to a stabilized composition
comprising [0099](a) a body care product, household product, textile or
fabric, [0100](b) an effective stabilizing amount of one or more
compounds of formula (I), and [0101](c) one or more compounds selected
from the group consisting of the ultraviolet light absorbers,
antioxidants, tocopherol, tocopherol acetate, hindered amine light
stabilizers, complex formers, optical brighteners, surfactants, and
polyorganosiloxanes.

[0102]The additional additives of present component (c) are for example
those disclosed in co-pending U.S. application Ser. No. 09/830,788, filed
May 1, 2001 and 09/830,787, filed May 1, 2001, published as WO 00/25730
and WO 00/25731. The disclosures of these co-pending applications are
hereby incorporated by reference.

[0103]The UV absorbers are for example selected from group consisting of
the 2H-benzotriazoles, the s-triazines, the benzophenones, the
alpha-cyanoacrylates, the oxanilides, the benzoxazinones, the benzoates
and the alpha-alkyl cinnamates.

[0158]Additional suitable antioxidants are for example selected from the
hindered phenolic and benzofuranone stabilizers.

[0159]Suitable antioxidants are for example selected from the group
consisting of

[0160]The hindered amine light stabilizers (HALS) of component (c) are for
example known commercial compounds. They are for example selected from
the group consisting of
[0161]bis(2,2,6,6-tetramethylpiperidin-4-yl)sebacate,
bis(2,2,6,6-tetramethylpiperidin-4-yl)succinate,
bis(1,2,2,6,6-pentamethylpiperidin-4-yl)sebacate,
n-butyl-3,5-di-tert-butyl-4-hydroxybenzylmalonic
acid-bis(1,2,2,6,6-pentamethylpiperidyl)ester, the condensate of
1-hydroxyethyl-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid,
the condensate of
N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and
4-tert-octylamino-2,6-dichloro-1,3,5-s-triazine,
tris(2,2,6,6-tetramethyl-4-piperidyl)nitrilotriacetate,
tetrakis(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butanetetraoate,
1,1'-(1,2-ethanediyl)-bis(3,3,5,5-tetramethylpiperazinone),
4-benzoyl-2,2,6,6-tetramethylpiperidine,
4-stearyloxy-2,2,6,6-tetramethylpiperidine,
bis(1,2,2,6,6-pentamethylpiperidyl)-2-n-butyl-2-(2-hydroxy-3,5-di-tert-bu-
tylbenzyl)malonate,
3-n-octyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, the
condensate of
N,N-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and
4-morpholino-2,6-dichloro-1,3,5-triazine, the condensate of
2-chloro-4,6-di(4-n-butylamino-2,2,6,6-tetramethylpiperidyl)-1,3,5-triazi-
ne and 1,2-bis(3-aminopropylamino)ethane, the condensate of
2-chloro-4,6-di(4-n-butylamino-1,2,2,6,6-pentamethylpiperidyl)-1,3,5-tria-
zine and 1,2-bis(3-aminopropylamino)ethane,
8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro-[4.5]decane-2,4--
dione, 3-dodecyl-1-(2,2,6,6-tetramethyl-4-piperidyl)pyrrolidin-2,5-dione,
3-dodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidyl)-pyrrolidine-2,5-dione, a
mixture of 4-hexadecyloxy- and
4-stearyloxy-2,2,6,6-tetramethylpiperidine, the condensate of
N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and
4-cyclohexylamino-2,6-dichloro-1,3,5-triazine, the condensate of
1,2-bis(3-aminopropylamino)ethane and 2,4,6-trichloro-1,3,5-triazine and
4-butylamino-2,2,6,6-tetramethylpiperidine (CAS reg. No. [136504-96-6]);
(2,2,6,6-tetramethyl-4-piperidyl)-n-dodecylsuccinimide,
(1,2,2,6,6-pentamethyl-4-piperidyl)-n-dodecylsuccinimide,
2-undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-di-aza-4-oxo-spiro[4,5]decane,
the reaction product of
7,7,9,9-tetramethyl-2-cycloundecyl-1-oxa-3,8-diaza-4-oxospiro[4,5]decane
and epichlorohydrin,
tetra(2,2,6,6-tetramethylpiperidin-4-yl)-butane-1,2,3,4-tetracarboxylate,
tetra(1,2,2,6,6-pentamethylpiperidin-4-yl)-butane-1,2,3,4-tetracarboxylat-
e, 2,2,4,4-tetramethyl-7-oxa-3,20-diaza-21-oxo-dispiro[5.1.11.2]-heneicosa-
n, 8-acetyl-3-dodecyl-1,3,8-triaza-7,7,9,9-tetramethylspiro[4,5]-decane-2,-
4-dione,

[0171]The present body care products can be in the form of creams,
ointments, pastes, foams, gels, lotions, powders, make-ups, sprays,
sticks or aerosols. The present stabilizer systems may be present in the
oil phase or in the aqueous or aqueous/alcoholic phase.

[0172]The additives of component (b) are present, for example, in the body
care and household products in a concentration of about 5 to about 10000
ppm, based on the total formulation by weight, for example from about 10
to about 5000 ppm, for example from about 100 to about 5000 ppm. For
example the additives of component (b) are present in the body care and
household products in a concentration of about 5, 10, 15, 20, 25, 35, 40,
45 or 50 ppm, based on the total formulation by weight. For example, the
additives of component (b) are present from about 5 to about 5000 ppm in
the formulations (compositions) of this invention.

[0173]Laundry detergents, fabric softeners or other products, from which
the additives of component (b) are intended for deposition onto fabrics
with use, are considered household products of this invention, and the
above concentration levels also pertain thereto. The present additives of
component (b) are effective at stabilizing the laundry detergents and
fabric softeners, as well as the fabrics treated therewith.

[0174]Creams are oil-in-water emulsions containing more than 50% water.
The oil-containing base used therein is usually mainly fatty alcohols,
for example lauryl, cetyl or stearyl alcohol, fatty acids, for example
palmitic or stearic acid, liquid to solid waxes, for example
isopropylmyristate or beeswax and/or hydrocarbon compounds, such as
paraffin oil. Suitable emulsifiers are surfactants having primarily
hydrophilic properties, such as the corresponding non-ionic emulsifiers,
for example fatty acid esters of polyalcohols of ethylene oxide adducts,
such as polyglycerol fatty acid ester or polyoxyethylenesorbitan fatty
acid ether (Tween trademarks); polyoxyethylene fatty alcohol ether or
their esters or the corresponding ionic emulsifiers, such as the alkali
metal salts of fatty alcohol sulfonates, sodium cetyl sulfate or sodium
stearyl sulfate, which are usually used together with fatty alcohols,
such as cetyl alcohol or stearyl alcohol. In addition, creams contain
agents which reduce water loss during evaporation, for example
polyalcohols, such as glycerol, sorbitol, propylene glycol, and/or
polyethylene glycols.

[0175]Ointments are water-in-oil emulsions which contain up to 70%, for
instance not more than 20 to 50%, of water or of an aqueous phase. The
oil-containing phase contains predominantly hydrocarbons, such as
paraffin oil and/or solid paraffin which for instance contains hydroxy
compounds, for example fatty alcohol or their esters, such as cetyl
alcohol or wool wax for improving the water absorption. Emulsifiers are
corresponding lipophilic substances, such as sorbitan fatty acid ester.
In addition, the ointments contain moisturisers such as polyalcohols, for
example glycerol, propylene glycol, sorbitol and/or polyethylene glycol
as well as preservatives.

[0176]Rich creams are anhydrous formulations and are produced on the basis
of hydrocarbon compounds, such as paraffin, natural or partially
synthetic fats, for example coconut fatty acid triglycerides or, for
instance, hardened oils and glycerol partial fatty acid esters.

[0177]Pastes are creams and ointments containing powdered ingredients
which absorb secretions, for example metal oxides, such as titanium
dioxide or zinc oxide, and also tallow and/or aluminium silicates which
bind the moisture or the absorbed secretion.

[0179]Gels are, in particular, aqueous solutions or suspensions of active
substances in which gel formers are dispersed or swelled, in particular
cellulose ethers, such as methyl cellulose, hydroxyethyl cellulose,
carboxymethyl cellulose or vegetable hydrocolloids, for example sodium
alginate, tragacanth or gum Arabic and polyacrylate thickener systems.
The gels for example additionally contain polyalcohols, such as propylene
glycol or glycerol as moisturisers and wetting agents, such as
polyoxyethylenesobitan fatty acid ester. The gels furthermore contain
commercially available preservatives, such as benzyl alcohol, phenethyl
alcohol, phenoxyethanol and the like.

[0180]The following is a list of examples of body care products of this
invention and their ingredients:

[0181]The present body care products, household products, textiles and
fabrics have high stability towards color changes and chemical
degradation of the ingredients present in these products. For example,
present compositions that comprise a dye are found to have excellent
color stability.

[0182]Accordingly, the present invention further pertains to a stabilized
composition comprising [0183](a) a body care product, household
product, textile or fabric, [0184](b) an effective stabilizing amount of
one or more compounds of formula (I), and [0185](d) a dye.

[0192]Generally, for the coloration of household- and body care products
all substances are suitable which have an absorption in the visible light
of electromagnetic radiation (wavelength of ca. 4000 to 700 nm). The
absorption is often caused by the following chromophores:

[0195]The stabilizers of the present invention may be employed in fabric
treatment that takes place after use of the fabric, referred to as fabric
care. Such treatments include laundering, which uses detergents and/or
fabric conditioner, and the application of non-detergent based fabric
care products, such as spray-on products. When employed in this fashion,
the present stabilizers are intended for deposition onto the fabric and
used to protect the fabric, colorants and fragrances associated with said
these fabrics from environmental damage.

[0197]The present stabilizers are for example incorporated by dissolution
in an oil phase or alcoholic or water phase, where required at elevated
temperature.

[0198]The present invention also pertains to a method of stabilizing a
body care product, household product, textile or fabric, which comprises
incorporating therein or applying thereto one or more compounds of the
formulae (III) to (IIIc), for example one or more compounds of the
formulae A* to EE*.

[0199]In the case of stabilized fabrics, for example dyed fabrics, the
present stabilizers are applied thereto via deposition from for instance
detergents, fabric conditioners or non-detergent based fabric care
products.

[0200]The present fabrics are natural or synthetic, and may be woven or
nonwoven.

[0201]The present invention also pertains to a method of stabilizing a
body care product, household product, textile or fabric, each of which
contain a dye, which comprises incorporating therein or applying thereto
one or more compounds of the formulae (III) to (IIIc), for example one or
more compounds of the formulae A* to EE*. The stabilizers of formulae
(III) to (IIIc) are very effective towards the stabilization of dyes in
the present compositions.

[0202]The textiles of this invention are for example textile fiber
materials, for example nitrogen-containing or hydroxy-group-containing
fiber materials, for instance textile fiber materials selected from
cellulose, silk, wool, synthetic polyamides, leather and polyurethanes.
Included are cotten, linen and hemp, pulp and regenerated cellulose.
Included also are cellulosic blends, for example mixtures of cotton and
polyamide or cotton/polyester blends.

[0203]The additives of the present invention are for example applied to
textiles in a dyeing or printing process, or in a finishing process. For
instance, the additives may be applied as part of a dye formulation. The
additives may be applied to textiles for example in an ink-jet printing
process. The additives are for example applied as part of an aqueous dye
solution or printing paste. They may be applied in an exhaust method or
dyeing by the padder dyeing method, in which the textiles are impregnated
with aqueous dye solutions, which may contain salts, and the dyes and
additives are fixed, after an alkali treatment or in the presence of
alkali, if appropriate with the action of heat or by storage at room
temperature for several hours. After fixing, the dyeings or prints are
rinsed thoroughly with cold and hot water, if appropriate with the
addition of an agent which has a dispersing action and promotes diffusion
of the non-fixed portions.

[0204]The dye or ink formulations for application to textiles may comprise
further customary additives, for example surfactants, antifoams,
antimicrobials and the like, for example as disclosed in U.S. Pat. Nos.
6,281,339, 6,353,094 and 6,323,327, the disclosures of which are hereby
incorporated by reference.

[0209]4-Hydroxy-1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-
e (5 g, 0.02 mole), citric acid (1.43 g, 0.0067 mole) and methanol (50 g,
1.6 mole) are added to a round bottom flask. The mixture is stirred at
ambient temperature for 30 minutes to ensure complete dissolution. The
methanol is removed by distillation and the resulting solid product is
dried to constant weight. The title compound is obtained (6 g, 93% yield)
as a white solid with a melting point of 112-122 C whose structure is
consistent with HNMR. The HNMR spectrum indicates a ratio of about four
to one.

[0212]4-Hydroxy-1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-
e (5 g, 0.02 mole), citric acid (2.13 g, 0.01 mole) and methanol (50 g,
1.6 mole) are added to a round bottom flask. The mixture is stirred at
ambient temperature for 30 minutes to ensure complete dissolution. The
methanol is removed by distillation and the resulting solid product is
dried to constant weight. The title compound is obtained (6.4 g, 90%
yield) as a white solid with a melting point of 103-113 C whose structure
is consistent with HNMR. The HNMR spectrum indicates a ratio of about 2.5
to one.

[0215]4-Hydroxy-1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-
e (5 g, 0.02 mole), citric acid (4.29 g, 0.02 mole) and methanol (50 g,
1.6 mole) are added to a round bottom flask. The mixture is stirred at
ambient temperature for 30 minutes to ensure complete dissolution. The
methanol is removed by distillation and the resulting solid product is
dried to constant weight. The title compound is obtained (8.6 g, 92.5%
yield) as a white solid with a melting point of 93-110 C whose structure
is consistent with HNMR. The HNMR spectrum indicates a ratio of about one
to one.

[0218]4-Hydroxy-1-(2-hydroxy-2-methylpropoxy)-2,2,6,6-tetramethylpiperidin-
e (5 g, 0.02 mole), ascorbic acid (3.59 g, 0.02 mole) and methanol (200 g,
6.2 mole) are added to a round bottom flask. The mixture is stirred at
ambient temperature for 60 minutes to ensure complete dissolution. The
methanol is removed by distillation and the resulting solid product is
dried to constant weight. The title compound is obtained (8.1 g, 94%
yield) as a white solid with a melting point of 131-137 C whose structure
is consistent with HNMR. The HNMR spectrum indicates a ratio of about one
to one.

[0220]The instant compounds are added to a commercial shampoo formulation
and are evaluated for their ability to reduce the amount of dye fading
when the samples are exposed to fluorescent lighting. The instant
compounds (0.36 g) are dissolved in 5 mL of methanol which is then added
to 120 g of shampoo (Suave R Natural Fresh Mountain Strawberry Shampoo)
with agitation. The stabilized shampoo formulation is agitated for 15
minutes and put into 20 mL glass scintillation vials. These formulations
are weathered under fluorescent light aging at ambient temperature. The
CIEL*a*b coordinates before and after exposure are measured using X-Rite
938 Spectrodensitometer. Color change is expressed as Delta E (DE). The
color change is given by Delta E (DE) which is calculated by:

[0221]Compound A is 1-oxyl-2,2,6,6-tetramethyl-4-hydroxypiperidine which
is disclosed in WO 2003103622, the publication of U.S. Pat. app. No.
60/377,381, filed May 2, 2002, incorporated herein by reference.

[0222]The compounds according to this invention are able to improve
clearly the light fastness of shampoo formulations.

EXAMPLE 6

[0223]The instant compounds are added to a commercial shampoo formulation
and are evaluated for their ability to reduce the amount of dye fading
when the samples are exposed to fluorescent lighting. The instant
compounds (0.36 g) are dissolved in 5 mL of methanol which is then added
to 120 g of shampoo (Clairol® Herbal Essences Shampoo) with
agitation. The stabilized shampoo formulation is agitated for 15 minutes
and put into 20 mL glass scintillation vials. These formulations are
weathered under fluorescent light aging at ambient temperature. The
CIEL*a*b coordinates before and after exposure are measured using X-Rite
938 Spectrodensitometer. Color change is expressed as Delta E (DE).

[0224]Compound A is 1-oxyl-2,2,6,6-tetramethyl-4-hydroxypiperidine which
is disclosed in WO2003103622, the publication of U.S. Pat. app. No.
60/377,381, filed May 2, 2002, incorporated herein by reference.

[0225]The compounds according to this invention are able to improve
clearly the light fastness of shampoo formulations.

EXAMPLE 7

[0226]The instant compounds are added to a commercial mouthwash
formulation and are evaluated for their ability to reduce the amount of
dye fading when the samples are exposed to fluorescent lighting. The
instant compounds (0.36 g) are dissolved in 5 mL of methanol which is
then added to 120 g of mouthwash (Scope® Original Mint) with
agitation. The stabilized mouthwash formulation is agitated for 15
minutes and put into 20 mL glass scintillation vials. These formulations
are weathered under fluorescent light aging at ambient temperature. The
CIEL*a*b coordinates before and after exposure are measured using X-Rite
938 Spectrodensitometer. Color change is expressed as Delta E (DE).

[0227]Compound A is 1-oxyl-2,2,6,6-tetramethyl-4-hydroxypiperidine which
is disclosed in WO 2003103622, the publication of U.S. Pat. app. No.
60/377,381, filed May 2, 2002, incorporated herein by reference.

[0228]The compounds according to this invention are able to improve
clearly the light fastness of mouthwash formulations.

EXAMPLE 8

[0229]The instant compounds are added to a commercial mouthwash
formulation and are evaluated for their ability to reduce the amount of
dye fading when the samples are exposed to fluorescent lighting. The
instant compounds (0.36 g) are dissolved in 5 mL of methanol which is
then added to 120 g of mouthwash (Listerine® Tartar Control
Wintermint) with agitation. The stabilized mouthwash formulation is
agitated for 15 minutes and put into 20 mL glass scintillation vials.
These formulations are weathered under fluorescent light aging at ambient
temperature. The CIEL*a*b coordinates before and after exposure are
measured using X-Rite 938 Spectrodensitometer. Color change is expressed
as Delta E (DE).

[0230]Compound A is 1-oxyl-2,2,6,6-tetramethyl-4-hydroxypiperidine which
is disclosed in WO 2003103622, the publication of U.S. Pat. app. No.
60/377,381, filed May 2, 2002, incorporated herein by reference.

[0231]The compounds according to this invention are able to improve
clearly the light fastness of mouthwash formulations.

EXAMPLE 9

[0232]The instant compounds are added to a commercial shampoo formulation
and are evaluated for their ability to reduce the amount of dye fading
when the samples are exposed to fluorescent lighting. The instant
compounds are dissolved in a shampoo formulation with agitation.
3-(2H-benzotriazol-2-yl)-4-hydroxy-5-(1-methylpropyl)-benzenesulfonic
acid monosodium salt, a benzotriazole UV absorber, is added to the
shampoo formulation. These formulations are weathered under fluorescent
light at ambient temperature. The CIEL*a*b coordinates before and after
exposure are measured. The change in color is expressed by Delta E (DE).
The compounds according to this invention are quite efficacious in
improving light fastness of shampoo formulations.

EXAMPLE 10

[0233]The instant compounds are added to a commercial shampoo formulation
and are evaluated for their ability to reduce the amount of dye fading
when the samples are exposed to fluorescent lighting. The instant
compounds are dissolved in a shampoo formulation with agitation. An
s-triazine UV absorber is added to the shampoo formulation. These
formulations are weathered under fluorescent light at ambient
temperature. The CIEL*a*b coordinates before and after exposure are
measured. The change in color is expressed by Delta E (DE). The compounds
according to this invention are quite efficacious in improving light
fastness of shampoo formulations.

EXAMPLE 11

[0234]The instant compounds are added to a commercial shampoo formulation
and are evaluated for their ability to reduce the amount of dye fading
when the samples are exposed to fluorescent lighting. The instant
compounds are dissolved in a shampoo formulation with agitation. A
benzophenone UV absorber is added to the shampoo formulation. These
formulations are weathered under fluorescent light at ambient
temperature. The CIEL*a*b coordinates before and after exposure are
measured. The change in color is expressed by Delta E (DE). The compounds
according to this invention are quite efficacious in improving light
fastness of shampoo formulations.

EXAMPLE 12

[0235]The instant compounds are added to a commercial mouthwash
formulation and are evaluated for their ability to reduce the amount of
dye fading when the samples are exposed to fluorescent lighting. The
instant compounds are added to a mouthwash formulation with agitation.
3-(2H-benzotriazol-2-yl)-4-hydroxy-5-(1-methylpropyl)-benzenesulfonic
acid monosodium salt, a benzotriazole UV absorber, is added to the
mouthwash formulation. These formulations are weathered under fluorescent
lighting at ambient temperature. The CIEL*a*b coordinates before and
after exposure are measured. Color change is expressed as Delta E (DE).
The compounds according to this invention are quite efficacious in
improving light fastness of mouthwash formulations.

EXAMPLE 13

[0236]The instant compounds are added to a commercial mouthwash
formulation and are evaluated for their ability to reduce the amount of
dye fading when the samples are exposed to fluorescent lighting. The
instant compounds are added to a mouthwash formulation with agitation. An
s-triazine UV absorber is added to the mouthwash formulation. These
formulations are weathered under fluorescent lighting at ambient
temperature. The CIEL*a*b coordinates before and after exposure are
measured. Color change is expressed as Delta E (DE). The compounds
according to this invention are quite efficacious in improving light
fastness of mouthwash formulations.

EXAMPLE 14

[0237]The instant compounds are added to a commercial mouthwash
formulation and are evaluated for their ability to reduce the amount of
dye fading when the samples are exposed to fluorescent lighting. The
instant compounds are added to a mouthwash formulation with agitation. A
benzophenone UV absorber is added to the mouthwash formulation. These
formulations are weathered under fluorescent lighting at ambient
temperature. The CIEL*a*b coordinates before and after exposure are
measured. Color change is expressed as Delta E (DE). The compounds
according to this invention are quite efficacious in improving light
fastness of mouthwash formulations.

[0239]About 20 mL of each of the aqueous test formulations are placed in a
borosilicate glass bottle. The glass bottles are exposed in an Atlas
Ci-65 Xenon arc WeatherOmeter, AATCC Test Method 16. Color measurements
are performed on a Hunter Ultrascan XE spectrophotometer. Delta L, a and
b values are the difference between the initial values and the values at
each interval. It is seen that the stabilizers of the present invention
provide excellent color stability in personal care products.

[0241]About 20 mL of each of the aqueous test formulations are placed in a
borosilicate glass bottle. The glass bottles are exposed in an Atlas
Ci-65 Xenon arc WeatherOmeter, AATCC Test Method 16, option E. Color
measurements are performed on a Hunter Ultrascan XE spectrophotometer.
Delta L, a and b values are the difference between the initial values and
the values at each interval. It is seen that the stabilizers of the
present invention provide excellent color stability in personal care
products.

[0243]About 20 mL of each of the aqueous test formulations are placed in a
borosilicate glass bottle. The glass bottles are exposed in an Atlas
Ci-65 Xenon arc WeatherOmeter, AATCC Test Method 16. Color measurements
are performed on a Hunter Ultrascan XE spectrophotometer. Delta L, a and
b values are the difference between the initial values and the values at
each interval. It is seen that the stabilizers of the present invention
provide excellent color stability in personal care products.

[0245]About 20 mL of each of the aqueous test formulations are placed in a
borosilicate glass bottle. The glass bottles are also exposed to
accelerated fluorescent lighting, Philips, 40 Watt, Daylight Deluxe
(D65), full exposure to light. Color measurements are performed on a
Hunter Ultrascan XE spectrophotometer. Delta L, a and b values are the
difference between the initial values and the values at each interval. It
is seen that the stabilizers of the present invention provide excellent
color stability in personal care products.

[0247]About 20 mL of each of the aqueous test formulations are placed in a
borosilicate glass bottle. The glass bottles are also exposed to
accelerated fluorescent lighting, Philips, 40 Watt, Daylight Deluxe
(D65), full exposure to light. Color measurements are performed on a
Hunter Ultrascan XE spectrophotometer. Delta L, a and b values are the
difference between the initial values and the values at each interval. It
is seen that the stabilizers of the present invention provide excellent
color stability in personal care products.

[0249]About 20 mL of each of the aqueous test formulations are placed in a
borosilicate glass bottle. The glass bottles are also exposed to
accelerated fluorescent lighting, Philips, 40 Watt, Daylight Deluxe
(D65), full exposure to light. Color measurements are performed on a
Hunter Ultrascan XE spectrophotometer. Delta L, a and b values are the
difference between the initial values and the values at each interval. It
is seen that the stabilizers of the present invention provide excellent
color stability in personal care products.

EXAMPLE 21

[0250]The components of phase A are thoroughly mixed in a homogenizer for
10 min at 75-80° C. The water phase B, likewise heated to
75-80° C. beforehand, is slowly added and the mixture is
homogenized for 1 min. The mixture is cooled, with stirring, to
40° C. and then phases C and E are added and the mixture is
homogenized for 1 min. Subsequently, phase D is added and the mixture is
homogenized for 1/2 min and cooled, with stirring, to room temperature.

[0253]Excellent results are achieved for this example of a toilet water
formulation.

EXAMPLE 23

[0254]The hydroxypropyl cellulose is first predissolved in half of the
alcohol (Vortex mixer) and is charged with the aminomethylpropanol. The
other components--with the exception of the acrylate resin--are dissolved
in alcohol and this solution is added, with stirring, to the
hydroxypropyl cellulose. Subsequently, the acrylate resin is added and
stirred until completely dissolved. The UV absorber used is, for example,
benzophenone-4 is 5-benzoyl-4-hydroxy-2-methoxybenzenesulfonic acid,
sodium salt.

[0255]Excellent results are achieved for this example of a hair styling
spray formulation.

EXAMPLE 24

[0256]The components listed below are mixed, with stirring, at room
temperature until they are completely dissolved. The pH is 6.5. The UV
absorber is, for example,
2-(2-hydroxy-3-dodecyl-5-methylphenyl)-2H-benzotriazole.

[0261]Excellent results are achieved for this example of a glass detergent
formulation.

EXAMPLE 27

[0262]The instant stabilizers are each deposited (from water) on a dyed
cotton fabric at 0.05, 0.1, 0.2, 0.5 and 1.0 percent by weight, based on
the weight of the cotton. The dyed fabrics contain the following dyes at
0.05, 0.1, 0.2 and 0.5 percent by weight based on cotton. This results in
60 separate formulations for each dye listed:

[0264]The instant stabilizers and UV absorbers, for example
3-(2H-benzotriazol-2-yl)-4-hydroxy-5-(1-methylpropyl)-benzenesulfonic
acid monosodium salt, are each deposited (from water) on a dyed cotton
fabric at 0.05, 0.1, 0.2, 0.5 and 1.0 percent by weight, based on the
weight of the cotton. The dyed fabrics contain the following dyes at
0.05, 0.1, 0.2 and 0.5 percent by weight based on cotton. This results in
60 separate formulations for each dye listed: