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Black 2 White 2
One
Trade in Nimbasa City

It's the dropped item event. You speak to either Yancy/ Curtis, and after enough calls they will offer to trade with you.

Also, you can't find Spiritomb in Dream World if you use a B2W2 account; you need use a BW account to find one in DW. So if you have a previous game, then you could transfer one. Otherwise, Yancy/ Curtis is the only way to get a Spiritomb in game.