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Where are the great female supervillains?

Hell, once a villainess gets too popular, they soften her image and even occasionally turn her into an anti-hero, which is what happened to Poison Ivy, Catwoman, Harley Quinn, and Emma "White Queen" Frost. Meanwhile, the other villainesses are minor threats, unless they team up with other, invariably male villains like the Legion of Doom or Masters of Evil.