It's the first Miraval vintage stamped by the Hollywood couple, in a joint venture with established vintner Marc Perrin. The back label reads "bottled by Jolie-Pitt and Perrin."

The Perrin family spokesman says the first 6,000 bottles put on sale online Thursday were bought within five hours. The wine sold for €105 ($139) for a 6-bottle case. There was no immediate comment from publicists for Pitt and Jolie.

The wine, in a bottom-heavy, champagne-like bottle, goes on sale to restaurants and wholesalers later this month.