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Classifications

C07C49/385—Saturated compounds containing a keto group being part of a ring

C07C49/417—Saturated compounds containing a keto group being part of a ring polycyclic

C07C49/423—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system

C07C49/453—Saturated compounds containing a keto group being part of a ring polycyclic a keto group being part of a condensed ring system having three rings

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring

C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups

C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds

C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation

C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen

C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C2601/00—Systems containing only non-condensed rings

C07C2601/12—Systems containing only non-condensed rings with a six-membered ring

C07C2601/14—The ring being saturated

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C2601/00—Systems containing only non-condensed rings

C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C2602/00—Systems containing two condensed rings

C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common

C07C2602/04—One of the condensed rings being a six-membered aromatic ring

C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C2602/00—Systems containing two condensed rings

C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common

C07C2602/04—One of the condensed rings being a six-membered aromatic ring

C07C2602/10—One of the condensed rings being a six-membered aromatic ring the other ring being six-membered, e.g. tetraline

Claims (4)

Translated from Japanese

一般式ＣnＨ2n+2（ｎ＝１〜３０）で表されるアルカン、一般式ＣnＨ2n+1Ｒ（ｎ＝１〜３０、Ｒはエステル基又は芳香族基を示す）で表される置換アルカン、一般式ＣnＨ2n（ｎ＝５〜３０）で表されるシクロアルカン、一般式ＣnＨ2n-1Ｒ（ｎ＝５〜３０、Ｒはエステル基又は芳香族基を示す）で表される置換シクロアルカン、及び芳香環とシクロアルカン環がそれぞれオルト位で縮合している縮合環化合物からなる群から選択される化合物を酸素酸化する方法において、Table withgeneral formula CnH2n+ 2 alkane represented by (n = 1 to 30), the general formula C n H 2n + 1 R ( n = 1~30, R represents an ester group or an aromatic group) substituted alkanoic being the general formula C n H 2n (n = 5~30 ) represented by cycloalkane general formula C n H 2n-1 R ( n = 5~30, R is an ester group or an aromatic group a method of oxygen oxidation substituted cycloalkane represented by shown), and a compound selected from the group consisting of fused ring compound in which an aromatic ring and a cycloalkane ring are condensed at each ortho,ニトリル類、芳香族アミン類及び第３級アミン類からなる群から選択される含窒素化合物 、アルデヒド類、並びに銅系触媒の存在下で反応させることを特徴とする前記化合物の酸化方法。Nitriles, aromatic amines and nitrogen-containing compound selected from tertiary group consisting of amines, oxidation process of the compound which comprises reacting in the presence of aldehydes, as well as copper-based catalyst.

銅系触媒が銅無機塩または銅配位性化合物である請求項１に記載の酸化方法。 The oxidizing method according to claim 1 copper-based catalyst is a copper inorganic salts or Dohai coordinating compound.

アルデヒド類が脂肪族あるいは芳香族アルデヒド類である請求項１又は２に記載の酸化方法。 The oxidizing method according to claim 1 or 2 aldehyde is an aliphatic or aromatic aldehyde.

前記化合物を酸素酸化することによってアルコールおよびケトンを生成する請求項１乃至３のいずれかに記載の酸化方法。 The oxidizing method according to any one of claims 1 to 3 to produce an alcohol and a ketone by oxygen oxidizing the compound.

JP2000218512A2000-07-192000-07-19 A method of oxidizing a compound with a presence aldehyde copper-based catalyst comprising a copper salt and a nitrogen-containing compound ActiveJP3574844B2
(en)