Squeezed Crystals Deliver more Volts

High-performance piezoelectric materials used today, such as those in probes for medical ultrasound, are specially grown crystals of mixed composition known as “solid solutions,” making them difficult to study and expensive to manufacture. But a research team led by Ronald Cohen and Russell Hemley of the Carnegie Institution’s Geophysical Laboratory report that at high pressure pure crystals of lead titanate show the same transitions seen in more complex materials. Moreover, theory predicts that lead titanate under pressure has the largest piezoelectric response of any material known. This suggests the exciting possibility of low-cost but extremely high-performance piezoelectrics.

“The most useful piezoelectric materials have a critical range of compositions called the morphotopic phase boundary, where the crystal structure changes and the piezoelectric properties are maximal,” says Muhtar Ahart, a co-author of the study. “These are usually complex, engineered, solid solutions. But we showed that a pure compound can display a morphotopic phase boundary under pressure.”

For the study, the researchers placed powdered crystals of lead titanate in a device called a diamond anvil cell, which can generate pressures exceeding those at the center of the Earth. They monitored the changes in crystal structure with pressure using high-energy X-ray beams of the Advanced Photon Source at Argonne National Laboratory in Illinois. Using this data and calculations based on first-principle theoretical computations, the researchers were able to determine the piezoelectric properties of the pure crystals at different pressures.

“It turns out that complex microstructures or compositions are not necessary to obtain strong piezoelectricity,” says Ahart.