Yeah he tried to Validate by Online.Actually there were so many invoices
due to that he did online validation instead of manul validation,and even
for online validation also the same error message populated.

Validate program completed with warning indicates there are some invoices are not validated due to what so ever the reason. Valid invoices are already validated. Now to identify this, you might get output of this program or the log may says about those particular invoices.

Validation fails due to so many reasons like exchange rate not available etc.
There could be other possibility of some distribution lines may be deleted.

So please evaluate this by running validation from those individual invoice and fix it

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