Segura, who is 31, is perhaps best known for his unification victory over Ivan Calderon in August of 2010, the first career loss for the Puerto Rican legend.

Segura also stopped Calderon in the third round of their rematch in April of 2011, but suffered the second loss of his own career by eighth-round stoppage against Brian Viloria in December of 2011. Segura was coming off a unanimous decision loss to Edgar Sosa in May.

Meanwhile, Gonzalez, 22, had last been in the ring for a unanimous decision over Francisco Perez in April.

Monday’s Golden Boy Live! series, which will air twice a month on Fox Sports 1 and be promoted by Golden Boy Promotions, will be headlined by Brooklyn middleweight Danny Jacobs (25-1, 22 KOs) against Giovanni Lorenzo (32-5, 24 KOs) at the Best Buy Theater in midtown Manhattan.