12. The dye transfer sheet for heat-sensitive transfer recording according to claim 1, wherein said dye is of the formula: ##STR592## wherein R.sup.6, R.sup.7 and R.sup.8 each represents C.sub.1 -C.sub.4 alkyl.

13. The dye transfer sheet for heat-sensitive transfer recording according to claim 1, wherein said dye is of the formula: ##STR593##

14. The dye transfer sheet for heat-sensitive transfer recording according to claim 1, wherein said dye is a mixture of a dye [A] of the formula ##STR594## wherein R.sup.25, R.sup.26 and R.sup.27 each represents C.sub.1 -C.sub.8 straight-chainor branched-chain alkyl and a dye [B] of the formula: ##STR595## wherein R.sup.28, R.sup.29 and R.sup.30 each represents C.sub.1 -C.sub.8 each represents straight-chain or branched-chain alkyl.

15. The dye transfer sheet for heat-sensitive transfer recording according to claim 14, wherein the dye [A] accounts for 5-95% by weight and the dye [B] accounts for 95-5% by weight.

17. The dye transfer sheet for heat-sensitive transfer recording according to claim 14, wherein the mixture comprises a dye of the structural formula: ##STR596## and a dye of the structural formula: ##STR597##

18. The dye transfer sheet for heat-sensitive transfer recording according to claim 1, wherein the base film is of a tissue paper.

19. The dye transfer sheet for heat-sensitive transfer recording according to claim 1, wherein the base film is a flim of a polyester, polyamide or polyimide.

20. The dye transfer sheet for heat-sensitive transfer recording according to claim 19, wherein the base film is a film of a polyethylene terephthalate or polyimide.

21. The dye transfer sheet for heat-sensitive transfer recording according to claim 1, wherein the base film is a plastic film providing a heat-resistive layer on a back face thereof.

22. The dye transfer sheet for heat-sensitive transfer recording according to claim 1, wherein the base film has a thickness of 3 to 50 .mu.m.

23. The dye transfer sheet for heat-sensitive transfer recording according to claim 1, wherein the ink layer has a thickness of 0.1 to 5 .mu.m.

24. The dye transfer sheet for heat-sensitive transfer recording according to claim 1, wherein the ink layer is formed on the base film with an ink which is prepared by dissolving or dispersing the dye of the formula [I] together with a binderin a water or an organic solvent followed by drying thereof.

Description:

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to a dye transfer sheet for use in sublimation heat-sensitive transfer recording.

The heat-sensitive transfer recording process is considered more advantageous as compared with other processes since the maintenance and operation of the device are easier and the device and expendable supplies are less expensive.

The heat-sensitive transfer process is roughly classified into two processes, that is, a molten heat-sensitive transfer recording process which comprises heating a transfer sheet having a heat-melting ink layer formed on a base film by aheat-sensitive head to melt said ink thereby transfer recording onto a recording body, and a sublimation heat-sensitive transfer recording process which comprises heating a transfer sheet having an ink layer containing a sublimable dye formed on a basefilm to sublime the dye thereby transfer recording onto a recording body.

And, said sublimation heat-sensitive transfer recording process is believed suitable for full color recording since it is possible to control the amount of the dye to be sublimed and transferred by controlling the energy applied to theheat-sensitive head and hence gradation expression is easy.

In general, full color recording is conducted by using tricolor dyes, that is, a cyan color dye, a magenta dye and a yellow color dye, and sometimes, four color dyes, that is, these three plus a black color dye, but in order to obtain full colorrecording having good color reproducibility, the following requirements must be satisfied: the respective dyes easily sublime under the operational conditions of the heat-sensitive recording head, do not undergo thermal decomposition under theoperational conditions of the heat-sensitive recording head, have preferred hues for color reproduction, have great molecular absorption coefficients, are stable against light, moisture, chemicals etc., are easily sythesized, have excellent adaptabilityto inks, etc.

However, no conventional cyan dye has satisfied the above requirements.

Accordingly, one object of this invention aims to provide cyan color dyes which fulfill such requirements that they easily sublime under the operational conditions of the heat-sensitive recording head, do not undergo thermal decomposition underthe operational conditions of the heat-sensitive recording head, are stable against light, are easily synthesized, are readily and uniformly dissolved or dispersed to prepare an ink of a high concentration, etc. Another object of this invention is toprovide a dye transfer sheet which has an ink layer containing such cyan color dyes coated on a base film.

In the above formula [III], examples of the substituents for the substituted alkyl include alkoxy, hydroxy, aryl etc. Of the dyes of the above formula [III], especially preferred are those wherein --X, --Y, --Z.sup.3 and --Z.sup.4 are eachhydrogen, methyl, methoxy, ethoxy, chlorine, bromine or trifluoromethyl, --R.sup.9 and --R.sup.10 are each hydrogen, hydroxyalkyl, aralkyl or C.sub.1 -C.sub.6 alkyl, --B.sup.1 is ##STR10## and --R.sup.11 and --R.sup.12 are each C.sub.1 -C.sub.4 alkyl. ##STR11## wherein --X, --Y, --R.sup.8, --R.sup.9 and --R.sup.10 are as defined above, and --Z.sup.5 and --Z.sup.6 each represents alkyl optionally substituted by fluorine, alkoxy or halogen.

In the above formula [IV], examples of the substituents for the substituted alkyl represented by --R.sup.8, --R.sup.9 and --R.sup.10 include alkoxy, alkoxyalkoxy, aryl, aryloxy, tetrahydrofurfuryl, alkylcarbonyloxy, alkoxycarbonyl,alkoxycarbonyloxy, hydroxy, cyano, halogen etc. Of the dyes of the above formula [IV], especially preferred are those wherein --X and --Y are each hydrogen, methyl, methoxy, ethoxy, chlorine, bromine or trifluoromethyl, --Z.sup.5 and --Z.sup.6 are eachmethyl, methoxy, ethoxy, chlorine, bromine or trifluoromethyl, --R.sup.8 is C.sub.1 -C.sub.6 alkyl, trifluoromethyl, perfluoroethyl or perfluoropropyl, and --R.sup.9 and --R.sup.10 are each hydrogen, hydroxyalkyl, aralkyl or C.sub.1 -C.sub.6 alkyl. ##STR12## wherein --Z.sup.1 and --Z.sup.2 are as defined above, --B.sup.2 represents ##STR13## each represents C.sub.1 -C.sub.8 substituted or unsubstituted alkyl.

In the above formula [V], examples of the substituents for the substituted alkyl represented by --R.sup.13, --R.sup.14 and --R.sup.15 include halogen, vinyl, alkoxy etc. Of the dyes of the above formula [V], especially preferred are those wherein--B.sup.2 is ##STR14## --Z.sup.1 and --Z.sup.2 are each hydrogen, methyl, trifluoromethyl, methoxy, chlorine, bromine, ##STR15## --R.sup.13, --R.sup.14 and --R.sup.15 are each C.sub.1 -C.sub.6 alkyl, trifluoromethyl, perfluoroethyl or perfluoropropyl,--R.sup.3, --R.sup.4 and --R.sup.5 are each hydrogen or methyl, and --X and --Y are each hydrogen, methyl, trifluoromethyl, methoxy, ethoxy, chlorine or bromine. ##STR16## wherein --B.sup.2, --X and --Y are as defined above, --B.sup.3 is as defined for--B.sup.2, and --R.sup.16 and --R.sup.17 are each hydrogen or C.sub.1 -C.sub.8 substituted or unsubstituted alkyl. In the above formula [VI], examples of the substitutents for the substituted alkyl represented by --R.sup.13, --R.sup.14, --R.sup.16 and--R.sup.17 include halogen, alkoxy, vinyl, hydroxy, aryl etc. Of the dyes of the above formula [VI], especially preferred are those wherein --X and --Y are each hydrogen, methyl, methoxy, ethoxy, chlorine, bromine or trifluoromethyl, --R.sup.16 and--R.sup.17 are each hydrogen, hydroxyalkyl, aralkyl or C.sub.1 -C.sub.6 alkyl, --B.sup.2 and --B.sup.3 are each ##STR17## and --R.sup.13 and --R.sup.14 are each C.sub.1 -C.sub.4 alkyl or halogenated alkyl. ##STR18##

Further, the dyes to be used in the preparation of the dye transfer sheet of this invention may be used in combination.

For example, there may be used mixtures of dyes [A] of the following formula [XIII]. ##STR25## wherein R.sup.25, R.sup.26 and R.sup.27 each represents C.sub.1 -C.sub.8 straight-chain or branched-chain alkyl and dyes [B]of the following formula[XIV]: ##STR26## wherein R.sup.28, R.sup.29 and R.sup.30 each represents C.sub.1 -C.sub.8 straight-chain or branched-chain alkyl.

In the above general formula [XIII] and [XIV], preferred combinations are those wherein R.sup.25 and R.sup.28 are each C.sub.1 -C.sub.4 straight-chain or branched-chain alkyl, and R.sup.26, R.sup.27, R.sup.29 and R.sup.30 are each C.sub.1-C.sub.4 straight-chain alkyl, and especially preferred is a mixture of a dye of the following structural formula: ##STR27## and a dye of the following structural formula: ##STR28##

The mixing ratio (by weight) of these dyes is suitably such that the former ranges from 5 to 95% and the latter ranges from 95 to 5%, especially preferably the former ranges from 30 to 70% and the latter ranges from 70 to 30%.

The dyes for heat-sensitive transfer recording of the above general formula [I] of this invention may be produced by, for example, the following process:

That is, a phenol of the following general formula [a]: ##STR29## wherein --B, --Z.sup.1 and --Z.sup.2 are as defined above and an aniline of the following general formula [b]:

wherein --K is as defined above are heated in the presence of silver nitrate, thereby a dye for heat-sensitive transfer recording of the above formula [I] of this invention may be produced.

For applying the dyes of the above formula [I] to prepare the dye transfer sheet of this invention in the sublimation heat-sensitive transfer recording process, the dye may be dissolved, or dispersed in a fine particle form, in a medium togetherwith a binder to prepare an ink, then said ink is coated on a base film and dried, thereby a transfer sheet is prepared.

As the binder for the preparation of the ink, there may be used water-soluble resins such as cellulosic type, acrylic acid type, starch type etc.; resins soluble in water or organic solvents, such as acrylic resins, methacrylic resins,polystyrene, polycarbonates, polysulfones, polyether sulfones, polyvinylbutyral, ethyl cellulose, acetyl cellulose etc.; and the like. In the case of the resin soluble in organic solvents, it may be used not only as a solution in an orgnic solvent butalso in the form of an aqueous dispersion.

As a base film according to the present invention, the film should satisfy the properties such that the film is dense and thin in order to improve a thermal conductivity; is excellent in heat resistance; has smooth and lubricating surface inorder to coat a uniform transfer layer thereover and in order to intimately contact with a thermal head; protects ink to be blotted onto the back face of the film, so forth.

As an embodiment of the base film used for the transfer sheet, tissue paper such as condenser paper, glassine paper, etc. and a film of a plastic having good heat resistance, e.g. polyesters, polyamides, polyimides etc. are suitable, and thethickness of said base film is suitably in the range of 3-50 .mu.m. Among such films, those of polyethylene terephthalate and polyimide are more preferred.

As the method for coating the ink on the base film, it may be conducted by using a reverse roll coater, a gravure coater, a rod coater, an air doctor coater etc., and the thickness of the ink coated layer after drying may suitably be in the rangeof 0.1-5 .mu.m (Yuji Harazaki, published from Maki Shoten in 1979, "Coating Method").

The dye transfer sheet of the present invention basically comprises a color layer containing the aforementioned dye on the surface of the base film and optionally may further comprise a heat-resisting and lubricating layer on the back face of thebase film in order to improve running characteristics and heat-resisting properties. These heat-resisting and lubrication layer may be provided by coating the back face of the base film with an inactive inorganic compound such as fine silica powder,etc.; and additives such as a lubricant; incorporated with resins such as epoxy type, acryl type, urethane type, polycarbonate type, etc.

Since the dyes for heat-sensitive transfer recording of the above formula [I] of this invention have a brilliant cyan color, they are suitable for obtaining full color recording having good color reproducibility by combining with appropriatemagenta and yellow color dyes, and further since they easily sublime and have great molecular absorption coefficients, it is possible to obtain recording having a high color density at a high speed without imposing much burden on the heat-sensitive head. Further, since they are stable against heat, light, moisture, chemicals etc., they do not undergo thermal decomposition during transfer recording and also the obtained recording has excellent storage stability. Furthermore, since the dyes of the aboveformula [I] are good in solubility in organic solvents and dispersibility in water, it is easy to prepare a uniformly dissolved or dispersed ink of a high concentration, and by using such an ink, a transfer sheet of this invention on which the dye hasbeen uniformly coated at a high concentration may be obtained. Therefore, by using such a transfer sheet of this invention, recording having excellent uniformity and color density may be obtained.

Still further, where a mixture of the dyes of the above general formula [XIII] and [XIV] is used, since the dyes do not separate when an ink of a high concentration is prepared or the ratio to the binder is increased, it is possible to prepare amore uniformly dissolved ink at a high concentration as compared with the cases where the respective dyes are used singly, and by using such an ink, a transfer sheet of this invention on which the mixed dye has been uniformly coated at a highconcentration may be obtained. In addition, by using this transfer sheet of this invention cyan color transfer recording having neither unevenness of the image nor abrasion staining may be obtained.

This invention is more particularly describedby the following examples, but it should be noted that this invention be not restricted by these examples.

The mixture of the above composition was treated by a paint conditioner for 10 minutes to prepare an ink. The dye and the resin had been completely dissolved and thus it was possible to obtain an ink in a uniform solution.

(ii) Preparation of a Transfer Sheet

The aforsaid ink was coated on a polyimide film (15 .mu.m thick) using a bar coater (produced by RK Print Coat Instruments Co., (No. 1) and dried in air, to obtain a transfer sheet.

(iii) Transfer Recording

The ink coated surface of the aforesaid transfer sheet was overlapped with a recording body, and recording was effected using a heat-sensitive head under the following conditions thereby it was possible to obtain uniform brilliant cyan colorrecording having a high color density of 1.40.

The color density was measured by using a densitometer Model RD-514 manufactured by Macbeth Co., U.S.A. (filter: latten No. 25).

A light fastness test was conducted on the obtained recording using a carbon arc fade-o-meter (manufactured by Suga Tester Co., Ltd.) at a black panel temperature of 63.+-.2.degree. C. to find that there was hardly decoloration or change incolor after exposure to light for 40 hours.

The dye used in this example was produced as follows:

3.0 g of acetamidophenol of the following structural formula: ##STR31## and 4.3 g of a compound of the following structural formula: ##STR32## were added to 150 ml of ethanol, stirred at room temperature, and then a solution of 3.4 g of silvernitrate in 15 ml of water was added dropwise. Thereafter, 15 ml of a 28% ammonia water was added thereto, further a solution of 10.5 g of silver nitrate in 10 ml of water was added dropwise, and the reaction was effected at 30.degree.-40.degree. C. for3 hours. After completion of the reaction, it was extracted with chloroform, the solvent was distilled off, and the residue was purified by column chromatography, to obtain 5.2 g (yield 80% based on the theoretical yield) of a purified product of anindoaniline type dye of the following structural formula: ##STR33## The dye thus obtained had a melting point of 128.degree.-130.degree. C. and a maximum absorption wavelength (chloroform) of 656 nm.

EXAMPLE 2

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was replaced by the dyes set forth in Table 1 respectively,thereby brilliant cyan color recording having the color density set forth in Table 1 was obtained in each case.

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was replaced by a dye of the following structural formula:##STR107## thereby it was possible to obtain uniform brilliant cyan color recording having a high color density of 1.40.

A light fastness test was conducted on the obtained recording according to the procedures described in Example 1 to find that there was hardly decoloration or change in color after exposure to light for 40 hours. Further, the transfer sheet andthe recording were both stable against heat and moisture, and were excellent in dark place storability.

The dye used in this example was produced as follows:

150 ml of ethanol was added to 3.7 g of 2-methylsulfonylaminophenol of the following structural formula: ##STR108## and 5.24 g of a compound of the following structural formula: ##STR109## stirred at room temperature, and then a solution of 3.4 gof silver nitrate in 15 ml of water was added dropwise. 15 ml of a 28% ammonia water was added thereto, further a solution of 1.5 g of silver nitrate in 10 ml of water was added dropwise, and the reaction was effected at 30.degree.-40.degree. C. for 3hours. After completion of the reaction, it was extracted with chloroform, the solvent was distilled off, and the residue was purified by column chromatography using chloroform to obtain 5.27 g (yield 76% based on the theoretical yield) of a purifiedproduct of an indoaniline type dye of the following structural formula: ##STR110## The dye thus obtained had a melting pont of 135.degree.-137.degree. C. and a maximum absorption wavelength (chloroform) of 640 nm.

EXAMPLE 4

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was replaced by the dyes set forth in Table 2 respectively,thereby brilliant cyan color recording having the color density set forth in Table 2 was obtained in each case.

The results of a light fastness test on the obtained recording and a dark place storability test on the transfer sheet and the recording were both good.

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was replaced by a dye of the following structural formula:##STR204## thereby it was possible to obtain uniform brilliant cyan color recording having a high color density of 1.40.

A light fastness test was conducted on the obtained recording according to the procedures described in Example 1, to find that there was hardly decoloration or change in color after exposure to light for 40 hours. Further, the transfer sheet andthe recording were both stable against heat and moisture, and were excellent in dark place storability.

The dye used in this example was produced as follows:

150 ml of ethanol was added to 3.28 g of 5-methyl-2-acetamidophenol of the following structural formula: ##STR205## and 5.24 g of a sulfate salt of a compound of the following structural formula: ##STR206## stirred at room temperature, and then asolution of 3.4 g of silver nitrate in 15 ml of water was added dropwise. 15 ml of a 28% ammonia water was added thereto, further a solution of 10.5 g of silver nitrate in 10 ml of water was added dropwise, and the reaction was effected at30.degree.-40.degree. C. for 3 hours. After completion of the reaction, it was extracted with chloroform, the solvent was distilled off, and the residue was purified by column chromatography using chloroform to obtain 5.6 g (yield 82% based on thetheoretical yield) of a purified product of an indoaniline type dye of the following structural formula: ##STR207## The maximum absorption wavelength of the above dye was 637 nm (chloroform).

EXAMPLE 6

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was replaced by the dyes set forth in Table 3 respectively,thereby brilliant cyan color recording having the color density set forth in Table 3 was obtained in each case.

The results of a light fastness test on the obtained recording and a dark place storability test on the transfer sheet and the recording were both good.

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was replaced by a dye of the following structural formula:##STR278## thereby it was possible to obtain uniform brilliant cyan color recording having a high color density. The color density of the obtained recording was 1.25.

A light fastness test was conducted on the obtained recording according to the procedures described in Example 1, to find that there was hardly decoloration or change in color after exposure to light for 40 hours. Further, the transfer sheet andthe obtained recording were both stable against heat and moisture, and were excellent in dark place storability.

The dye used in this example was produced as follows:

3.0 g of 2-acetamidophenol of the following structural formula: ##STR279## and 5.1 g of a compound of the following structural formula: ##STR280## were added to 200 ml of methanol, stirred at room temperature, and then a solution of 3.4 g ofsilver nitrate in 15 ml of water was added dropwise. 15 ml of a 28% ammonia water was added thereto, further a solution of 10.5 g of silver nitrate in 10 ml of water was added dropwise, and the reaction was effected at 30.degree.-40.degree. C. for 3hours. After completion of the reaction, it was extracted with chloroform, the solvent was distilled off, and the residue was purified by column chromatography using chloroform to obtain 5.3 g (yield 73% based on the theoretical yield) of a purifiedproduct of an indoaniline type dye of the following structural formula: ##STR281## The maximum absorption wavelength of the above dye was 652 nm (chloroform).

EXAMPLE 8

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was placed by the dyes set forth in Table 4 respectively,thereby brilliant cyan color recording having the color density set forth in Table 4 was obtained in each case.

The results of a light fastness test on the obtained recording and a dark place storability test on the transfer sheet and the recording were both good.

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was replaced by a dye of the following structural formula:##STR345## thereby it was possible to obtain uniform brilliant cyan color recording having a high color density of 1.30.

A light fastness test was conducted on the obtained recording according to the procedures described in Example 1 to find that there was hardly decoloration or change in color after exposure to light for 40 hours. Further, the transfer sheet andthe recording were both stable against heat and moisture, and were excellent in dark place storability.

The dye used in this example was produced as follows:

300 ml of ethanol was added to 4.1 g of 2,5-bis-acetamidophenol of the following structural formula: ##STR346## and 5.3 g of a compound of the following structural formula: ##STR347## stirred at room temperature, and then a solution of 3.4 g ofsilver nitrate in 15 ml of water was added dropwise. 15 ml of a 28% ammonia water was added thereto, further a solution of 10.5 g of silver nitrate in 10 ml of water was added dropwise, and the reaction was effected at 30.degree.-40.degree. C. for 3hours. After completion of the reaction, it was extracted with chloroform, the solvent was distilled off, and the residue was purified by column chromatography using chloroform to obtain 5.7 g (yield 78% based on the theoretical yield) of a purifiedproduct of an indoaniline type dye of the following structural formula: ##STR348## The mass spectrum of the above dye was m/e=368, and its maximum absorption wavelength was 634 nm (chloroform).

EXAMPLE 10

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was replaced by the dyes set forth in Table 5 respectively,thereby brilliant cyan color recording having the color density set forth in Table 5 was obtained in each case.

The results of a light fastness test on the obtained recording and a dark place storability test on the transfer sheet and the recording were both good.

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was replaced by a dye of the following structural formula:##STR434## thereby it was possible to obtain uniform brilliant cyan color recording having a high color density of 1.40.

Further, a light fastness test was conducted on the obtained recording according to the procedures described in Example 1 to find that there was hardly decoloration or change in color after exposure to light for 40 hours.

The dye used in this example was produced as follows:

3.1 g of phenol compound of the following structural formula: ##STR435## and 4.3 g of a compound of the following structural formula: ##STR436## were added to 150 ml of ethanol, stirred at room temperature, and then a solution of 3.4 g of silvernitrate in 15 ml of water was added dropwise. Thereafter, 15 ml of a 28% ammonia water was added thereto, further a solution of 10.5 g of silver nitrate in 10 ml of water was added dropwise, and the reaction was effected at 30.degree.-40.degree. C. for3 hours. After completion of the reaction, it was extracted with chloroform, the solvent was distilled off, and then the residue was purified by column chromatography using chloroform, to obtain a purified product of an indoaniline compound of thefollowing structural formula: ##STR437## The maximum absorption wavelength (chloroform) of this product was 659 nm.

EXAMPLE 12

The indoaniline compounds set forth in Table 6 below were produced according to the procedures described in Example 11. The maximum absorption wavelength (chloroform) of each obtained indoaniline compound is shown in Table 6.

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 1 except that the dye used in Example 1 was replaced by the indoaniline compounds set forth inTable 6 as the dyes respectively, thereby it was possible to obtain uniform brilliant cyan color recording having the color density set forth in Table 6 in each case.

A light fastness test was conducted on the obtained recording according to the procedures described in Example 1 to find that there was hardly decoloration or change in color.

The mixture of the above composition was treated by a paint conditioner for 10 minutes to prepare an ink. The dye and the resin had been completely dissolved and thus it was possible to obtain an ink in a uniform solution of a highconcentration.

(ii) Preparation of a Transfer Sheet

The aforesaid ink was coated on a polyimide film (15 .mu.m thick) using a bar coater (produced by RK Print Coat Instruments Co., No. 1) and dried in hot air at 60.degree. C., thereby there was no separation of the dye and it was possible toobtain a uniformly coated transfer sheet.

(iii) Transfer Recording

Transfer recording was conducted according to the transfer recording procedures described in Example 1 using the transfer sheet obtained above and the recording body described in Example 1, thereby it was possible to obtain uniform brilliant cyancolor recording having a high color density of 1.80 without unevenness in the image.

A light fastness test was conducted on the obtained recording according to the procedures described in Example 1 to find that there was hardly decoloration or change in color after exposure to light for 40 hours.

COMPARATIVE EXAMPLES 1 & 2

Inks were prepared by procedures similar to those described in Example 13 except that 14 g of the mixed dye used in Example 13 was replaced by 14 g of the dye [A.sup.1 ] alone (Comparative Example 1) and 14 g of the dye [B.sup.1 ] alone(Comparative Example 2) respectively. With each ink, a part of the ink did not dissolve and thus remained undissolved. Each ink was coated on a base film and dried, but there was remarkable separation of the dye, and thus a non-uniform transfer sheetwas merely obtained. Thereafter, transfer recording was conducted using each obtained transfer sheet, but there was only obtained cyan color transfer recording with unevenness of the image and also distinct abrasion staining.

EXAMPLE 14

Preparation of the ink, preparation of the transfer sheet and transfer recording were carried out according to the procedures described in Example 13 except that the mixed dye used in Example 13 was replaced by the mixed dye set forth in Table 7,and as a result, it was possible to prepare inks of high concentrations, to obtain uniformly coated transfer sheets without separation of any ink and to obtain cyan color recording having the high color density set forth in Table 7.

The mixture of the above composition was treated by a paint conditioner for 10 minutes to prepare an ink. The dye and the resin had been completely dissolved and thus it was possible to obtain an ink in a uniform solution of a highconcentration.

(ii) Preparation of a Transfer Sheet

The aforesaid ink was coated on a condenser paper sheet using a bar coater (produced by RK Print Coat Instruments Co., No. 1) and dried in hot air at 60.degree. C., thereby there was no separation of the dye and it was possible to obtain auniformly coated transfer sheet.

(iii) Transfer Recording

Transfer recording was conducted according to the procedures described in Example 1 using the transfer sheet obtained above and the recording body described in Example 1, thereby it was possible to obtain uniform brilliant cyan color recordinghaving a high color density of 1.80 without unevenness of the image.

COMPARATIVE EXAMPLES 3 & 4

Inks were prepared by procedures similar to those described in Example 15 except that 14 g of the mixed dye used in Example 15 was replaced by 14 g of the dye [A.sup.2 ]alone (Comparative Example 3) and 14 g of the dye [B.sup.2 ]alone(Comparative Example 4) respectively. The obtained inks showed remarkable separation of the dye and gave non-uniform transfer sheets. Using these transfer sheets, transfer recording was conducted, but there was merely obtained cyan color transferrecording having much unevenness of the image and also distinct abrasion staining.

The mixture of the above composition was treated by a paint conditioner for 10 minutes to prepare an ink. The dye and the resin had been completely dissolved and thus it was possible to obtain an ink in a uniform solution of a highconcentration.

(ii) Preparation of a Transfer Sheet

The aforesaid ink was coated on a condenser paper sheet using a bar coater (produced by RK Print Coat Instruments Co., No. 1) and dried in hot air at 60.degree. C., thereby there was no separation of the dye and it was possible to obtain auniformly coated transfer sheet.

(iii) Transfer Recording

Transfer recording was conducted according to the procedures described in Example 1 using the transfer sheet obtained above and the recording body described in Example 1, thereby it was possible to obtain uniform brilliant cyan color recordinghaving a high color density of 1.70 without unevenness of the image.

COMPARATIVE EXAMPLES 5 & 6

Inks were prepared by procedures similar to those described in Example 16 except that 10 g of the mixed dye used in Example 16 was replaced by 10 g of the dye [A.sup.3 ] alone (Comparative Example 5) and 10 g of the dye [B.sup.3 ] alone(Comparative Example 6) respectively. Each obtained ink showed remarkable separation of the ink, and the obtained sheets were non-uniform sheets. Thereafter, using these transfer sheets, transfer recording was conducted merely to obtain cyan colortransfer recording with unevenness of the image and distinct abrasion staining.

EXAMPLE 17

A preparation of a transfer sheet according to the Example 1, paragraph (ii) was repeated except that a polyethylene terephthalate film (6 .mu.m thick), a back face of which was treated so as to provide heat-resisting and lubricating properties,was used as a base film in place of a polyimide film.

A transfer recording according to Example 1, paragraph (iii) was effected using the transfer sheet, thus formed, to obtain uniform brilliant cyan color recording having a high color density of 1.50.

The heat-resisting and lubricating treatments were effected by coating a polyethylene terephthalate film with a solution comprising 8 parts by weight of a polycarbonate resin, 1 part by weight of a phosphate ester type surfactant and 91 parts byweight of toluene followed by drying thereof. A thickness of dried heat-resisting and lubricating film was about 0.5 .mu.m.

EXAMPLE 18

Preparation of the transfer sheet and transfer recording according to Example 17 were repeated except that the dyes set forth in Table 8 were used in place of the dye used in the Example 17, thereby brilliant cyan color recording having the colordensity set forth in Table 8 was obtained in each case.

While the invention has been described in detail and with references to specific embodiment thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit andscope thereof.