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Mulvey used a personal interest in skateboarding to work as a stunt double about two years prior to winning the role of Drazic in Heartbreak High.[1] His first role was of a victim of a robbery in a police training video.[2]

In 2004, he re-entered the spotlight for the release of Thunderstruck.

Mulvey was born in Auckland, New Zealand, and moved to Australia when he was 8, growing up in the northern suburbs of Sydney.[1]
Mulvey was injured in a serious car accident in 2003,[13] in a head-on collision at 100 km/h, or 62mp/h. He was trapped in the vehicle for almost an hour until he could be freed from the wreckage. The midsection of his face collapsed, an incision was made from ear to ear over the top of his scalp, his face "pulled down" and 17 titanium plates were then inserted to repair the fractures to his face and jaw. His left knee and ankle were also badly fractured.

He married Rachel Thomas, an academic and musician, in Byron Bay in 2010.[14]