Gerecke, Andreas C.

Hungerbuehler, Konrad

Abstract [en]

Fluorotelomer alcohols (FTOHs) and perfluorooctane sulfonamides (FOSAs) are present in consumer products and are semi-volatile precursors of persistent perfluoroallcyl acids (PFAAs). The high variability of levels of FrOHs and FOSAs in products makes it difficult to derive FTOH- and FOSA-emissions from urban areas based on emission factors. Here we used a multimedia mass balance model that describes the day-night cycle of semi-volatile organic chemicals in air to interpret measurements of 8:2 FTOH, 10:2 FTOH, MeFOSA and EtFOSA from a sampling campaign in summer 2010 in Zurich, Switzerland. The estimated emission source strength of the four substances follows the sequence: 8:2 FTOH (2.6 g/h) > 10:2 FTOH (0.75 g/h) > MeFOSA (0.08 g/h) > EtFOSA (0.05 g/h). There is no FTOHs- or FOSAs-related industry in Zurich. Accordingly, our estimates are representative of diffusive emissions during use and disposal of consumer products, and describe noticeable sources of these PFASs to the environment.