Avengers Vs. X-Men: Versus (2012) #5

Summary

Hawkeye threatens to plant an arrow in Psylocke's head and ends up tagging Angel in the chest. Emma tends to Angel in the infirmary and tells Angel that the battle with Hawkeye hasn't ended.
This issue suggests this was one of the motivations behind Emma toasting Hawkeye in Avengers vs X-Men #7.