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I have used Nikwax Base Wash in the past. Pretty effective in removing the smell build up associated with polyester type materials. Make sure you get the BASE wash rather than the other ones (tech wash etc), as this is meant for the dri fit type base layers rather than the waterproof clothing that the other types are meant for.

I'm only spraying febreeze onto the armpit area after I wear the shirt and before I put it into the dirty laundry basket until the next wash. I don't think anyone wants a pic of my hairy armpits anyways.