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Abstract:

A liquid treatment apparatus includes a substrate retaining unit, a
rotational driving unit configured to rotate the substrate retaining
unit; and a nozzle disposed below a lower surface of the substrate, the
nozzle having first ejection ports provided to eject a chemical liquid
and second ejection ports provided to eject a rinsing fluid towards the
lower surface of the substrate. The nozzle comprises a first portion and
a second portion each extending from a position opposing to a peripheral
portion of the substrate towards a position opposing to a central portion
of the substrate. At least part of the first ejection ports are arranged
in the first portion. At least part of the second ejection ports are
arranged in the second portion. The first portion and the second portion
are arranged to form a V-shaped figure.

Claims:

1. A liquid treatment apparatus comprising: a substrate retaining unit
comprising a retaining member configured to hold a peripheral edge of a
substrate to retain the substrate horizontally; a rotational driving unit
configured to rotate the substrate retaining unit; and a nozzle disposed
below a lower surface of the substrate retained by the substrate
retaining unit, the nozzle comprising a plurality of first ejection ports
provided to eject a chemical liquid towards the lower surface of the
substrate retained by the substrate retaining unit and a plurality of
second ejection ports provided to eject a rinsing fluid towards the lower
surface of the substrate retained by the substrate retaining unit;
wherein: the nozzle comprises a first portion extending from a position
opposing to a peripheral portion of the substrate towards a position
opposing to a central portion of the substrate retained by the substrate
retaining unit, the plurality of first ejection ports are arranged
between a position opposing to a peripheral portion of the substrate
towards a position opposing to a central portion of the substrate
retained by the substrate retaining unit, and at least part of the
plurality of first ejection ports are arranged in the first portion; the
nozzle comprises a second portion extending from a position opposing to a
peripheral portion of the substrate towards a position opposing to a
central portion of the substrate retained by the substrate retaining
unit, the plurality of second ejection ports are arranged between a
position opposing to a peripheral portion of the substrate towards a
position opposing to a central portion of the substrate retained by the
substrate retaining unit, and at least part of the plurality of second
ejection ports are arranged in the second portion; the first portion and
the second portion are arranged to form a V-shaped figure; and the first
portion is disposed at an angular position advanced through an angle from
the second portion in a rotating direction of the substrate rotated by
the rotational driving unit.

2. The liquid treatment apparatus according to claim 1, wherein the angle
is an acute angle.

3. The liquid treatment apparatus according to claim 1, wherein each of
the first ejection ports is configured to eject the chemical liquid
towards the lower substrate surface in a direction inclined to the
rotating direction of the substrate rotated by the rotation driving unit.

4. The liquid treatment apparatus according to claim 1, wherein each of
the second ejection ports is configured to eject, as the rinsing fluid,
at least one of deionized water (DIW) and droplets of a mixture of DIW
and an inert gas, towards the substrate.

5. The liquid treatment apparatus according to claim 4, wherein each of
the second ejection ports is configured to eject the DIW towards the
lower surface of the substrate in a direction inclined to the rotating
direction of the substrate rotated by the rotation driving unit, when the
second ejection ports eject the DIW as the rinsing fluid.

6. A liquid treatment apparatus comprising: a substrate retaining unit
comprising a retaining member configured to hold a peripheral edge of a
substrate to retain the substrate horizontally; a rotational driving unit
configured to rotate the substrate retaining unit; and a nozzle disposed
below a lower surface of the substrate retained by the substrate
retaining unit, the nozzle comprising a plurality of first ejection ports
provided to eject a chemical liquid towards the lower surface of the
substrate retained by the substrate retaining unit and a plurality of
second ejection ports provided to eject a rinsing fluid towards the lower
surface of the substrate retained by the substrate retaining unit;
wherein: the nozzle comprises a first portion extending from a position
opposing to a peripheral portion of the substrate towards a position
opposing to a central portion of the substrate retained by the substrate
retaining unit, the plurality of first ejection ports are arranged
between a position opposing to a peripheral portion of the substrate
towards a position opposing to a central portion of the substrate
retained by the substrate retaining unit, and at least part of the
plurality of first ejection ports are arranged in the first portion; the
nozzle comprises a second portion extending from a position opposing to a
peripheral portion of the substrate towards a position opposing to a
central portion of the substrate retained by the substrate retaining
unit, the plurality of second ejection ports are arranged between a
position opposing to a peripheral portion of the substrate towards a
position opposing to a central portion of the substrate retained by the
substrate retaining unit, and at least part of the plurality of second
ejection ports are arranged in the second portion; the first portion and
the second portion are arranged to form a V-shaped figure with the first
and second portions making an acute angle therebetween; and each of the
first ejection ports arranged in the first portion is configured to eject
the chemical liquid in a direction away from the second portion.

7. The liquid treatment apparatus according to claim 6, wherein each of
the second ejection ports is configured to eject, as the rinsing fluid,
at least one of deionized water (DIW) and droplets of a mixture of DIW
and an inert gas, towards the substrate.

8. The liquid treatment apparatus according to claim 7, wherein each of
the second ejection ports is configured to eject the DIW towards the
lower surface of the substrate in a direction approaching the first
portion.

9. A liquid treatment method comprising: providing a liquid treatment
apparatus according to claim 1; retaining a substrate in a horizontal
posture by the substrate retaining unit; rotating the substrate retained
by the substrate retaining unit, with the first portion of the nozzle
being disposed at an angular position advanced through an angle from the
second portion in a rotating direction of the substrate; supplying a
chemical liquid from the first ejection ports of the nozzle to a lower
surface of the substrate; and thereafter supplying a rinsing fluid from
the second ejection ports of the nozzle to the lower surface of the
substrate.

10. The liquid treatment method according to claim 9, further comprising:
cleaning the first portion of the nozzle with the rinsing fluid ejected
from the second ejection port.

Description:

CROSS-REFERENCE TO RELATED APPLICATION

[0001] This application is based on and claims the benefit of priorities
from Japanese Patent Application No. 2011-013458 filed on Jan. 25, 2011,
the entire contents of which are incorporated herein by reference.

TECHNICAL FIELD

[0002] The present disclosure relates to a liquid treatment apparatus and
a liquid treatment method used to conduct liquid treatment such as
cleaning and etching for substrates by supplying a treatment liquid to a
lower surface of the substrate while spinning it.

BACKGROUND ART

[0003] In a semiconductor manufacturing process, substrates such as
semiconductor wafers are subjected to cleaning or etching with use of a
chemical liquid in order to remove undesired films adhering to the front
or back surface of the wafer (e.g., oxide films, nitride films, or resist
films having been used as a mask).

[0004] US2007/0275562A discloses a substrate treatment apparatus that
executes the aforementioned chemical-liquid cleaning process and the
successive rinsing process continuously. The substrate treatment
apparatus includes a spin head for retaining a wafer at its peripheral
edge and rotating the wafer, and a spray head provided on the spin head
to supply a treatment fluid upon a lower surface of the wafer.

[0005] In the substrate treatment apparatus described in US2007/0275562A,
during chemical liquid treatment, a chemical liquid sprayed upon the
lower wafer surface from a bar-shaped member for spraying chemical liquid
may drop due to gravity and adhere onto another bar-shaped member for
spraying rinsing liquid. In addition, rotation of the spin head and the
wafer causes an airflow which affects the sprayed chemical liquid to flow
in the rotating direction of the wafer. This may also result in the
adhesion of chemical liquid onto the bar-shaped member for spraying
rinsing liquid. If the chemical liquid adheres on the bar-shaped member
for spraying rinsing liquid, the chemical liquid possibly contaminates
the rinsing liquid. If the adhering chemical liquid dries, it may become
a cause of particles.

DISCLOSURE SUMMARY

[0006] The present disclosure provides a liquid treatment apparatus that
prevents or reduces adhesion of a chemical liquid, which have been once
ejected from an ejecting member for chemical liquid ejection to a lower
surface of a substrate, onto another jetting member for ejecting a
rinsing fluid.

[0007] In one embodiment, there is provided a liquid treatment apparatus
including: a substrate retaining unit comprising a retaining member
configured to hold a peripheral edge of a substrate to retain the
substrate horizontally; a rotational driving unit configured to rotate
the substrate retaining unit; and a nozzle disposed below a lower surface
of the substrate retained by the substrate retaining unit, the nozzle
comprising a plurality of first ejection ports provided to eject a
chemical liquid towards the lower surface of the substrate retained by
the substrate retaining unit and a plurality of second ejection ports
provided to eject a rinsing fluid towards the lower surface of the
substrate retained by the substrate retaining unit; wherein: the nozzle
comprises a first portion extending from a position opposing to a
peripheral portion of the substrate towards a position opposing to a
central portion of the substrate retained by the substrate retaining
unit, the plurality of first ejection ports are arranged between a
position opposing to a peripheral portion of the substrate towards a
position opposing to a central portion of the substrate retained by the
substrate retaining unit, and at least part of the plurality of first
ejection ports are arranged in the first portion; the nozzle comprises a
second portion extending from a position opposing to a peripheral portion
of the substrate towards a position opposing to a central portion of the
substrate retained by the substrate retaining unit, the plurality of
second ejection ports are arranged between a position opposing to a
peripheral portion of the substrate towards a position opposing to a
central portion of the substrate retained by the substrate retaining
unit, and at least part of the plurality of second ejection ports are
arranged in the second portion; the first portion and the second portion
are arranged to form a V-shaped figure; and the first portion is disposed
at an angular position advanced through a certain angle from the second
portion in a rotating direction of the substrate rotated by the
rotational driving unit.

[0008] In another embodiment, there is provided a liquid treatment method
including: providing the foregoing liquid treatment apparatus; retaining
a substrate in a horizontal posture by the substrate retaining unit;
rotating the substrate retained by the substrate retaining unit, with the
first portion of the nozzle being disposed at an angular position
advanced through an angle from the second portion in a rotating direction
of the substrate; supplying a chemical liquid from the first ejection
ports of the nozzle to a lower surface of the substrate; and thereafter
supplying a rinsing fluid from the second ejection ports of the nozzle to
the lower surface of the substrate.

[0009] According to the foregoing embodiments, a chemical liquid ejected
from the first portion is less likely to reach the second portion,
whereby preventing or reducing contamination of the second portion with
the chemical liquid. In addition, the first portion can be cleaned by the
rinsing fluid ejected from the second portion. The nozzle can thus be
kept clean.

[0010] In another embodiment, there is provided a liquid treatment
apparatus including: a substrate retaining unit comprising a retaining
member configured to hold a peripheral edge of a substrate to retain the
substrate horizontally; a rotational driving unit configured to rotate
the substrate retaining unit; and a nozzle disposed below a lower surface
of the substrate retained by the substrate retaining unit, the nozzle
comprising a plurality of first ejection ports provided to eject a
chemical liquid towards the lower surface of the substrate retained by
the substrate retaining unit and a plurality of second ejection ports
provided to eject a rinsing fluid towards the lower surface of the
substrate retained by the substrate retaining unit; wherein: the nozzle
comprises a first portion extending from a position opposing to a
peripheral portion of the substrate towards a position opposing to a
central portion of the substrate retained by the substrate retaining
unit, the plurality of first ejection ports are arranged between a
position opposing to a peripheral portion of the substrate towards a
position opposing to a central portion of the substrate retained by the
substrate retaining unit, and at least part of the plurality of first
ejection ports are arranged in the first portion; the nozzle comprises a
second portion extending from a position opposing to a peripheral portion
of the substrate towards a position opposing to a central portion of the
substrate retained by the substrate retaining unit, the plurality of
second ejection ports are arranged between a position opposing to a
peripheral portion of the substrate towards a position opposing to a
central portion of the substrate retained by the substrate retaining
unit, and at least part of the plurality of second ejection ports are
arranged in the second portion; the first portion and the second portion
are arranged to form a V-shaped figure with the first and second portions
making an acute angle therebetween; and each of the first ejection ports
arranged in the first portion is configured to eject the chemical liquid
in a direction away from the second portion.

BRIEF DESCRIPTION OF THE DRAWINGS

[0011]FIG. 1 is a top plan view of a liquid treatment system which
includes substrate cleaning apparatuses in one embodiment;

[0012]FIG. 2A is a vertical cross sectional view showing the
configuration of the substrate cleaning apparatus in a state where a lift
pin plate and a cleaning liquid supply pipe are located at their lowered
positions;

[0013]FIG. 2B is a vertical cross sectional view showing the
configuration of the substrate cleaning apparatus in a state where the
lift pin plate and the cleaning liquid supply pipe are located at their
raised positions;

[0014]FIG. 2C is a top plan view of the substrate cleaning apparatus in a
state where a wafer is retained by a substrate retaining member and fixed
retaining members as shown in FIG. 2A;

[0015]FIG. 3. is a perspective view showing the configuration of the lift
pin plate of the substrate cleaning apparatus shown in FIGS. 2A and 2B;

[0016]FIG. 4 is a perspective view showing the configuration of a
retaining plate of the substrate cleaning apparatus shown in FIGS. 2A and
2B;

[0017]FIG. 5 is an enlarged vertical cross sectional view showing the
configuration of a connecting member extending downward from the lift pin
plate and a hollow accommodation member extending downward from the
retaining plate and accommodating the connecting member in the substrate
cleaning apparatus shown in FIGS. 2A and 2B;

[0018]FIG. 6 is an enlarged vertical cross sectional view showing the
configuration of the substrate retaining member provided on the retaining
plate in the substrate cleaning apparatus shown in FIGS. 2A and 2B;

[0019]FIG. 7 is an enlarged vertical cross sectional view showing a state
where the lift pin plate has been moved downward from the state shown in
FIG. 6;

[0020]FIG. 8 is an enlarged vertical cross sectional view showing a state
where the lift pin plate has been moved further downward from the state
shown in FIG. 7;

[0021]FIG. 9 is a perspective view showing the configuration of a
treatment fluid supply pipe and bar-shaped nozzle in the substrate
cleaning apparatus shown in FIGS. 2A and 2B, and the configuration of a
lifting mechanism for vertically moving them;

[0022] FIG. 10A is a plan view showing the V-shaped nozzle;

[0023] FIG. 10B is a schematic plan view illustrating a positional
relationship between the V-shaped nozzle, lift pins, and a transport arm
at a time when the wafer is transferred between the lift pin plate and
the transport arm;

[0024] FIG. 11 is for explanation of the configuration and the function of
a first bar-shaped portion of the V-shaped nozzle, wherein (a) is a
cross-sectional view taken along line XIa-XIa in FIG. 10A showing the
internal structure of the first bar-shaped portion, and (b) is a
schematic view showing the condition of SPM ejected out from the first
bar-shaped portion;

[0025]FIG. 12 is for explanation of the configuration and the function of
a second bar-shaped portion of the V-shaped nozzle, wherein (a) is a
cross-sectional view taken along line XIIa-XIIa in FIG. 10A showing the
internal structure of the second bar-shaped portion, (b) is a schematic
view showing the condition of DIW ejected out from the second bar-shaped
portion, and (c) is a schematic view showing the condition of a mist of a
fluid mixture of DIW and N2 gas ejected from the second bar-shaped
portion;

[0026]FIG. 13 is a cross-sectional view taken along line XIII-XIII in
FIG. 10A showing the structure of a central portion of the V-shaped
nozzle;

[0027] FIG. 14 is a cross-sectional view taken along line XIV-XIV in FIG.
10A to show the structure of the central portion of the V-shaped nozzle;
and

[0028]FIG. 15 is a schematic plan view showing spots on the lower wafer
surface formed by a treatment fluid ejected from the V-shaped nozzle.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0029] An embodiment of a liquid treatment apparatus will be described
with reference to the accompanying drawings. First, a liquid treatment
system including a substrate cleaning apparatus in one embodiment of a
liquid treatment apparatus will be described below with reference to FIG.
1. As shown in FIG. 1, the liquid treatment system includes: mounting
tables 101 each for mounting thereon a carrier accommodating a
semiconductor wafer W (i.e., substrate to be processed) (hereinafter,
simply referred to as "wafer W") which is transported thereto from the
outside of the system; a transport arm 102 for removing the wafer W from
the carrier; a shelf unit 103 for placing thereon the wafer W removed
from the carrier by the transport arm 102; and a transport arm 104 for
receiving the wafer W from the shelf unit 103 and for transporting the
wafer W to the substrate cleaning apparatus 10. As shown in FIG. 1, a
plurality of (ten, in the embodiment of FIG. 1) liquid treatment
apparatuses and two wafer reversers 105 are installed in the liquid
treatment system. The transport arm 104 has substantially a U-shape in
top plan view, and is shaped such that transport arm 104 does not touch
the lift pins 22 (described later) and a V-shaped nozzle 60 (also
described later) when the transport arm 104 places the wafer W onto or
remove the wafer W from the lift pins 22 (see FIG. 10B).

[0030] Next, a schematic configuration of one substrate cleaning apparatus
10 is described below with reference to FIGS. 2A and 2B. The substrate
cleaning apparatus 10 has a chamber 12 (only shown in FIG. 2A), and
within the chamber 12, a retaining plate 30 for retaining the wafer W; a
lift pin plate 20 provided above the retaining plate 30 and including
lift pins 22 to support the wafer W from below; a rotational driving unit
39 equipped with an electric motor or the like to rotate the retaining
plate 30; a treatment fluid supply pipe 40 routed through a through-hole
30a formed centrally in the retaining plate 30 and a through-hole 20a
formed centrally in the lift pin plate 20; a V-shaped nozzle 60 for
spraying, towards a lower surface of the wafer W, a treatment fluid
supplied via the treatment fluid supply pipe 40; and a cover member 80
incorporating a heater which is movable to a position near the upper
surface of the wafer W retained by the retaining plate 30 so as to shroud
the upper wafer W surface. The lift pin plate 20 is constructed to rotate
in association with the retaining plate 30 during treatment. In the
ceiling of the chamber 12, a fan filter unit (FFU) 14 is provided to
generate a downward flow of clean air in the chamber 12. An inner
sidewall of the chamber 12 (i.e., the right inner sidewall in FIG. 2A) is
provided with a wafer loading/unloading port (not shown) that includes a
shutter member (also not shown), through which the transport arm 104
retaining the wafer W enters the chamber. In FIG. 2A, the ceiling of the
chamber 12 is illustrated at a lower position than a position where it
actually resides for convenience sake. In an actual case the ceiling is
at a height such that the transport arm 104 is able to move up as shown
in FIG. 2B and the cover member 80 can shift to its upper position.

[0031] The lift pin plate 20, the treatment fluid supply pipe 40, and the
V-shaped nozzle 60 can be moved vertically in a relative fashion with
respect to the retaining plate 30. FIG. 2A shows a state where the lift
pin plate 20, the treatment fluid supply pipe 40, and the V-shaped nozzle
60 are positioned at their respective lower positions. FIG. 2B shows a
state where the lift pin plate 20, the treatment fluid supply pipe 40,
and the V-shaped nozzle 60 are positioned at their respective upper
positions. The lift pin plate 20, the treatment fluid supply pipe 40, and
the V-shaped nozzle 60 move up and down between their lower positions
shown in FIG. 2A and their upper positions shown in FIG. 2B. The cover
member 80 is at a treating position (lower position) in FIG. 2A. In FIG.
2B, the cover member 80 is not shown but it is actually present at its
standby position (upper position) above the wafer W illustrated with
double-dashed lines.

[0032] Next, each constituent element of the substrate cleaning apparatus
10 is described in detail. As shown in FIG. 3, the lift pin plate 20 has
a disk-like shape with the through-hole 20a formed in its central
portion. An annular protrusion 20b is provided around the through-hole
20a to prevent a liquid on the lift pin plate 20 from entering the
through-hole 20a. The treatment fluid supply pipe 40 is routed through
the through-hole 20a. The lift pin plate 20 comprises thereon a plurality
of (in the present example, four) lift pins 22 near its peripheral edge.
In this embodiment, as shown in FIG. 2C, four lift pins 22 are paired
into two pairs. One of the pair, lift pins 22a and 22a' (the two located
on the left in FIG. 2C) are arranged at an interval such that the two
lines connecting the lift pins 22a and 22a' with the center of the plate
20 form an acute angle of 30 degrees. The other pair, lift pins 22b and
22b' (the two located on the right in FIG. 2C) are arranged at an
interval such that the two lines connecting the lift pins 22b and 22b'
with the center of the plate 20 form an obtuse angle of 120 degrees. The
four lift pins 22 are disposed line-symmetrically with respect to an
imaginary line passing through the center of the wafer W and extending in
a horizontal direction in FIG. 2C. Such layout not only enables the lift
pins 22 to stably support the wafer W but also allows the U-shaped
transport arm 104 to enter beneath the wafer W for loading/unloading
(from the right to the left in FIG. 2C) without being obstructed by the
lift pins 22 (see FIGS. 2B and 10B). The lower surface of the lift pin
plate 20 has a plurality of, for example three, rod-like connecting
members 24 extending downward. The lower surface of the plate 20 here
indicates the surface opposite to the surface having the lift pins 22.
The connecting members 24 are arranged near the peripheral edge of the
plate 20 at equal intervals in the circumferential direction of the plate
20.

[0033] As shown in FIG. 4, the retaining plate 30 has a disk-like shape
with the through-hole 30a formed in its central portion. The treatment
fluid supply pipe 40 is routed through the through-hole 30a. A rotary cup
36 is attached to the retaining plate 30 via a connecting member 38 as
shown in FIG. 2A. When the lift pin plate 20, the treatment fluid supply
pipe 40, and the bar-shaped nozzle 60 are at their lowered positions, the
rotary cup 36 encircles the peripheral edge of the wafer W retained by
the retaining plate 30. As shown in FIGS. 2A and 2C, two fixed retaining
members 37 are attached to the rotary cup 36 to retain the wafer W. The
detailed function of the fixed retaining members 37 will be described
later. Instead of attaching the fixed retaining members 37 to the rotary
cup 36, they may be connected to the retaining plate 30, or may be
directly attached to the connecting member 38. If the fixed retaining
members 37 are attached directly to the connecting member 38, the fixed
retaining members 37 can be enhanced in strength against a force applied
from a horizontal direction.

[0034] A hollow rotating shaft 34 is attached to the central portion of
the lower surface of the retaining plate 30 (i.e., the surface opposite
to the surface equipped with the rotary cup 36) to extend downward
therefrom. The treatment fluid supply pipe 40 is accommodated in the
cavity of the hollow rotating shaft 34. The rotating shaft 34 is
supported by a bearing (not shown) and is rotated by the rotational
driving unit 39 comprising an electric motor and so on. The rotational
driving unit 39 rotates the rotating shaft 34, thus rotating the
retaining plate 30 as well.

[0035] As shown in FIG. 4, three through-holes 30b (connecting member
through-holes) are formed in the retaining plate 30. The connecting
members 24 coupled to the lift pin plate 20 are each inserted slidably in
the through-hole 30b. The connecting members 24 connect the retaining
plate 30 and the lift pin plate 20 for their integral rotation while
preventing relative rotation between them; the connecting members 24
permit relative vertical movement between the retaining plate 30 and the
lift pin plate 20. The through-holes 30b are arranged in the retaining
plate 30 at equal angular intervals on a circumference on the retaining
plate 30. In addition, on the lower surface of the retaining plate 30,
the through-holes 30b are provided with three accommodation members 32
having a cylindrical shape. The accommodation members 32 extend downward
from the lower surface of the retaining plate 30 and accommodate the
connecting members 24 extending downward from the lower surface of the
lift pin plate 20. The accommodation members 32 are arranged at equal
angular intervals on a circumference near a peripheral area of the
retaining plate 30.

[0036] Referring to FIG. 5, a further detailed description will be made
for the connecting members 24 extending downward from the lower surface
of the lift pin plate 20, and the accommodation members 32 extending
downward from the lower surface of the retaining plate 30. As shown in
FIG. 5, the cylindrical accommodation member 32 has an inside diameter
slightly greater than an outside diameter of the connecting member 24.
The connecting member 24 can move in a longitudinal direction of the
accommodation member 32 (i.e., vertical direction in FIG. 5) in the
accommodation member 32. As shown in FIG. 2A, when the lift pin plate 20
is at its lowered position, the connecting member 24 is completely
received in the accommodation member 32. Meanwhile, as shown in FIG. 2B,
when the lift pin plate 20 is at its raised position, only a lower
portion of the connecting member 24 is received in the accommodation
member 32. The connecting member 24 passes through the through-hole 30b
in the retaining plate 30 and protrudes upward from the retaining plate
30.

[0037] As shown in FIG. 5, a spring 26 is installed in the cavity of the
accommodation member 32 in a compressed state. The lower end of the
spring 26 is connected to the bottom of the connecting member 24 while
its upper end is connected to the lower surface of the retaining plate 30
in the vicinity of the through-hole 30b. Thus, the spring 26 urges the
connecting member 24 downward. In other words, force of the spring 26 to
return from the compressed state to an original state exerts a downward
force upon the connecting member 24 (i.e., force to move downward from
the retaining plate 30).

[0038] As shown in FIGS. 2A and 2B, an outer cup 56 is provided outside
the rotary cup 36 to surround the retaining plate 30 and the rotary cup
36. In addition, a drainage tube 58 is connected to the outer cup 56.
During cleaning of a wafer W, used cleaning liquid scatters outward from
the wafer W due to its rotation. The scattered liquid will be received by
the outer cup 56 and is drained through the drainage tube 58.

[0039] As can be seen in FIG. 2A, a movable, substrate retaining member 31
for supporting the wafer W from the lateral side of the wafer W is
provided on the retaining plate 30. When the lift pin plate 20 is at its
lowered position as in FIG. 2A, the substrate retaining member 31
supports the wafer W from its lateral side. When the lift pin plate 20 is
at its raised position as shown in FIG. 2B, the substrate retaining
member 31 is separated away from the wafer W. The operation of the
substrate retaining member 31 will be described more specifically with
reference to FIG. 2C. During wafer cleaning, the wafer W is retained by
the substrate retaining member 31 and the two fixed retaining members
(i.e., non-movable, substrate-retaining members) 37. At this time, the
substrate retaining member 31 presses the wafer W against the two fixed
retaining members 37. That is, the substrate retaining member 31 applies
to the wafer W a leftward force to press the wafer W against the fixed
retaining members 37. In the illustrated embodiment, since the wafer W is
retained by two fixed retaining members 37 and only one movable
substrate-retaining member 31, the configuration for retaining the wafer
W can be more simplified as compared with a configuration employing a
plurality of movable substrate retaining members 31 with no fixed
retaining member 37.

[0040] Then, the configuration of the substrate retaining member 31 will
be detailed below referring to FIGS. 6 to 8. FIG. 6 shows a state where
the lift pin plate 20 is moving from its raised position as in FIG. 2B to
its lowered position as in FIG. 2A. FIG. 7 shows a state where the lift
pin plate has moved more downward from the state shown in FIG. 6. FIG. 8
shows a state where the lift pin plate 20 has moved further downward from
the state of FIG. 7 to reach the lowered position as shown in FIG. 2A.

[0041] As shown in FIGS. 6 to 8, the substrate retaining member 31 is
supported by the retaining plate 30 via an axle 31a. More specifically, a
bearing unit 33 is attached to the retaining plate 30, and an axle
receiving hole 33a of the bearing unit 33 receives the axle 31a. The axle
receiving hole 33a is an elongated hole extending in a horizontal
direction, and the substrate retaining member 31 can move horizontally
along the axle receiving hole 33a. The substrate retaining member 31 can
thus swing around the axle 31a accommodated within the axle receiving
hole 33a of the bearing unit 33.

[0042] A spring member 31d such as a torsion spring is wound around the
axle 31a of the substrate retaining member 31. The spring member 31d is
adapted to impart the substrate retaining member 31 a force to rotate the
substrate retaining member 31 around the axle 31a in the clockwise
direction in FIGS. 6 to 8. Thus, when no force is applied to the
substrate retaining member 31, the substrate retaining member 31 inclines
with respect to the retaining plate 30, as shown in FIG. 2B. A substrate
retaining portion 31b (described later) of the substrate retaining member
31, provided to hold the wafer W from its lateral side, then moves away
from a central portion of the retaining plate 30.

[0043] The spring member 31d has a linear portion extending outward from
the axle 31a to an inner wall 33b of the bearing unit 33. The linear
portion is engaged with the inner wall 33b, thereby pushing back the axle
31a towards the center of the retaining plate 30. The axle 31a is thus
constantly pushed towards the center (leftward in FIGS. 6 to 8) of the
retaining plate 30 by the linear portion of the spring member 31d. When
the movable substrate retaining member 31 and the fixed retaining members
37 are supporting a wafer W having a relatively small diameter, the axle
31a is positioned in the axle receiving hole 33a at a position nearer to
the center (left side) of the retaining plate 30, as shown in FIGS. 6 to
8. When the movable substrate-retaining member 31 and the fixed retaining
members 37 is supporting a wafer W having a relatively large diameter,
the axle 31a moves rightward along the axle receiving hole 33a from the
position shown in FIGS. 6 to 8, against the force applied by the linear
portion of the spring member 31d. The magnitude of the wafer diameter
(small/large diameter) here refers to a magnitude that falls within a
tolerance range.

[0044] The substrate retaining member 31 has, in addition to the substrate
retaining portion 31b that retains the wafer W from its lateral side, a
pressure receiving member 31c at the side opposite to the substrate
retaining portion 31b with respect to the axle 31a. The pressure
receiving member 31c is set between the lift pin plate 20 and the
retaining plate 30. When the lift pin plate 20 is at or near the lowered
position, the lower surface of the lift pin plate 20 pushes the
pressure-receiving member 31c downward as shown in FIGS. 6 to 8.

[0045] While the lift pin plate 20 moves from its raised position to its
lowered position, the lower surface of the lift pin plate 20 pushes the
pressure receiving member 31c downward. Then, the substrate retaining
member 31 rotates counterclockwise around the axle 31a (in a direction
shown by the arrows in FIGS. 6 to 8). This rotation of the substrate
retaining member 31 around the axle 31a renders the substrate retaining
portion 31b to approach the wafer W from its lateral side. The wafer W is
held from its lateral side by the substrate retaining member 31, as the
lift pin plate 20 reaches the lowered position as in FIG. 8. At this time
when the wafer W is held at its lateral side by the substrate retaining
member 31, the wafer W is separated from the tip of each lift pin 22 and
is held above the lift pins 22. Depending on the size of the wafer W, the
axle 31a may slide rightwards along the axle receiving hole 33a from the
position shown in FIGS. 6 to 8, against the force applied by the linear
portion of the spring member 31d. Therefore, the wafer W can be held from
its lateral side without deforming nor damaging it even if the substrate
retaining member 31 and the fixed retaining members 37 hold a relatively
large wafer W, because the substrate retaining member 31 can shift in the
horizontal direction.

[0046] By employing such substrate retaining member 31, the substrate
cleaning apparatus 10 do not need a special driving mechanism (motive
energy source) for driving a substrate retaining member 31. The substrate
retaining member 31 of the retaining plate 30 can retain and release a
wafer W just by vertically moving the lift pin plate 20 using a vertical
driving unit 50 (described later). The configuration of the substrate
cleaning apparatus 10 can thus be simplified. It also reduces the time
lag between the timing of raising and lowering of the lift pin plate 20
and the timing of the action of the substrate retaining member 31,
whereby improving throughput.

[0047] As shown in FIGS. 2A and 2B, the treatment fluid supply pipe 40 is
arranged to pass through both the through-hole 20a in the lift pin plate
20 and the through-hole 30a in the retaining plate 30. The treatment
fluid supply pipe 40 is arranged such that it does not rotate when the
lift pin plate 20 and the retaining plate 30 rotate. A plurality of (six,
in the illustrated embodiment), fluid supply passages for supplying
treatment fluids to the V-shaped nozzle 60 are accommodated inside the
treatment fluid supply pipe 40. The six fluid supply passages are: a
first fluid supply passage 40a (also termed as "sulfuric acid supply
passage"); a second fluid supply passage 40b (also termed as "hydrogen
peroxide solution supply passage"); a third fluid supply passage 40c
(also termed as "first DIW supply passage"); a fourth fluid supply
passage 40d (also termed as "first N2 gas supply passage"); a fifth
fluid supply passage 40e (also termed as "second DIW supply passage");
and a sixth fluid supply passage 40f (also termed as "second N2 gas
supply passage"). These six fluid supply passages extend in a vertical
direction inside the treatment fluid supply pipe 40. The V-shaped nozzle
60 which will be detailed later is attached on the upper end of the
treatment fluid supply pipe 40.

[0049] The first fluid supply mechanism 70a is for supplying sulfuric acid
(H2SO4) and is hereinafter referred to as the sulfuric acid
supply mechanism 70a. The sulfuric acid supply mechanism 70a is connected
to a sulfuric acid supply source 71a via a line 74a which is provided
with, from the upstream, a variable throttle valve 72a and an open/close
valve 73a.

[0050] The second fluid supply mechanism 70b is for supplying hydrogen
peroxide solution (H2O2) and is hereinafter referred to as the
hydrogen peroxide solution supply mechanism 70b. The hydrogen peroxide
solution supply mechanism 70b is connected to a hydrogen peroxide
solution supply source 71b via a line 74b which is provided with, from
the upstream, a variable throttle valve 72b and an open/close valve 73b.

[0051] The third fluid supply mechanism 70c is for supplying de-ionized
water (DIW) as a rinsing liquid and is hereinafter referred to as the
first DIW supply mechanism 70c. The first DIW supply mechanism 70c is
connected to a first DIW supply source 71c via a line 74c which is
provided with, from the upstream, a variable throttle valve 72c and an
open/close valve 73c.

[0052] The fourth fluid supply mechanism 70d is for supplying an inert gas
such as N2 gas and is hereinafter termed as the first N2 gas
supply mechanism 70d. The first N2 gas supply mechanism 70d is
connected to a first N2 gas supply source 71d via a line 74d which
is provided with, from the upstream, a variable throttle valve 72d and an
open/close valve 73d.

[0053] The fifth fluid supply mechanism 70e is for supplying de-ionized
water (DIW) as a rinsing liquid and is hereinafter referred to as the
second DIW supply mechanism 70e. The second DIW supply mechanism 70e is
connected to a second DIW supply source 71e via a line 74e which is
provided with, from the upstream a variable throttle valve 72e and an
open/close valve 73e.

[0054] The sixth fluid supply mechanism 70f is for supplying inert gas
such as N2 gas and is hereinafter referred to as the second N2
gas supply mechanism 70f. The second N2 gas supply mechanism 70f is
connected to a second N2 gas supply source 71f via a line 74f which
is provided with, from the upstream, a variable throttle valve 72f and an
open/close valve 73f.

[0055] The sulfuric acid supply source 71a, for instance, may be
constructed from a tank equipped with a heater and a device for
delivering heated sulfuric acid from the tank. Since the hydrogen
peroxide solution is supplied at an ordinary temperature, the hydrogen
peroxide solution supply source 71b may be constructed from a tank and a
device for delivering the hydrogen peroxide solution at an ordinary
temperature from the tank.

[0056] As shown in FIGS. 2A, 2B, and 9, the vertical driving unit 50 is
connected with the treatment fluid supply pipe 40 via a connecting member
52. The vertical driving unit 50 is configured to move the treatment
fluid supply pipe 40 vertically. That is, by raising/lowering the
connecting member 52, the vertical driving unit 50 moves the treatment
fluid supply pipe 40 and bar-shaped nozzle 60 connected to the connecting
member 52. More specifically, the vertical driving unit 50 raises/lowers
the treatment fluid supply pipe 40 and the bar-shaped nozzle 60 between
their lowered positions as in FIG. 2A and their raised positions as in
FIG. 2B.

[0057] As shown in FIG. 9, the treatment fluid supply pipe 40 is further
attached with a first interlocking member 44. Three rod-shaped second
interlocking members 46 are connected to the first interlocking member 44
to extend upward therefrom. The second interlocking members 46 are
arranged to correspond to the connecting members 24 extending downward
from the lift pin plate 20. The outer diameter of the second interlocking
member 46 is smaller than the inner diameter of the cylindrical
accommodation member 32. That is to say, each second interlocking member
46 is arranged to contact the bottom of one connecting member 24 so that
the second interlocking member 46 can push the connecting member 24
upward within the accommodation member 32, as shown in FIG. 2B.

[0058] Accordingly, when the vertical driving unit 50 moves the treatment
fluid supply pipe 40 upward from the state shown in FIG. 2A, the first
interlocking member 44 and second interlocking members 46 joined with the
treatment fluid supply pipe 40 also moves upward so that the second
interlocking members 46 push the connecting members 24 upward inside the
accommodation members 32, whereby the lift pin plate 20 moves integrally
with the treatment fluid supply pipe 40 so that the lift pin plate 20,
the treatment fluid supply pipe 40, and the bar-shaped nozzle 60 thus
reach their raised positions as in FIG. 2B. On the other hand, when the
vertical driving unit 50 moves the treatment fluid supply pipe 40
downward from the state shown in FIG. 2B, since the spring 26 set within
the accommodation member 32 constantly applies a downward force to the
connecting member 24, the connecting member 24 descends downward
integrally with the interlocking member 46 with its bottom being in
contact with the top of the second interlocking member 46. The lift pin
plate 20, the treatment fluid supply pipe 40, and the bar-shaped nozzle
60 thus reach their respective lowered positions as in FIG. 2A.

[0059] The lift pin plate 20 adjoins the retaining plate 30 when the lift
pin plate 20 is positioned at its lowered position, as shown in FIG. 2A.
In the illustrated embodiment, the lift pin plate 20 is rested on and
supported by the retaining plate 30. On the other hand, the lift pin
plate 20 is separated from the retaining plate 30 when the lift pin plate
20 is positioned at its raised position, as shown in FIG. 2B. The wafer W
is then supported by the lift pins 22 and can be removed therefrom.

[0060] As mentioned above, the liquid treatment apparatus includes an
interlocking mechanism having the first interlocking member 44 and the
three second interlocking members 46 for integrally raising and lowering
the lift pin plate 20, the treatment fluid supply pipe 40, and the
bar-shaped nozzle 60. The liquid treatment apparatus also includes a
lifting mechanism for integrally raising and lowering the lift pin plate
20, the treatment fluid supply pipe 40, and the bar-shaped nozzle 60
relative to the retaining plate 30 by employing the first interlocking
member 44, the three second interlocking members 46, the vertical driving
unit 50 and the connecting member 52.

[0061] Next, the configuration of the V-shaped nozzle 60 is described with
reference to FIGS. 2A, 2B, 9, and 10A and 10B. The V-shaped nozzle 60 has
a first bar-shaped portion 60A, a second bar-shaped portion 60B, and a
central portion 60C. The first bar-shaped portion 60A and the second
bar-shaped portion 60B are each connected to the central portion 60C in
an arrangement such that the two form a V-shaped figure. The first
bar-shaped portion 60A extends from a position opposing to a peripheral
portion of the wafer W towards a position opposing to the central portion
of the wafer W. Similarly, the second bar-shaped portion 60B extends from
a position opposing to a peripheral portion of the wafer W towards a
position opposing to the central portion of the wafer W. The V-shaped
nozzle 60 is attached on the upper end of the treatment fluid supply pipe
40 at its central portion 60C. The central portion 60C also serves as a
cover member for covering the through-hole 20a in the lift pin plate 20.
The bar-shaped portions 60A and 60B extend from the central portion 60C
radially outward of the lift pin plate 20, that is, radially outward of
the wafer W, and terminate just short of an imaginary circumference on
which the lift pins 22 are arranged. This ensures that the bar-shaped
portions 60A, 60B would not interfere with the lift pins 22 during
treatment (during treatment, the V-shaped nozzle 60 does not rotate while
the lift pin plate 20 rotates).

[0062] In the embodiment of FIG. 10A, the first bar-shaped portion 60A and
the second bar-shaped portion 60B form an angle of 30 degrees, for
example (not limited to this angle). Therefore, by setting the lift pin
plate 20 and the retaining plate 30 at certain angular positions, the
lift pins 22a, 22a' can be set in positions at which extended lines of
the first and the second bar-shaped portion 60A, 60B respectively meet
with the lift pins 22a, 22a'. A clearance between the lower wafer W
surface and the V-shaped nozzle 60 is very narrow as can be seen in FIG.
2B. In terms of avoiding collision between the transport arm 104 and the
V-shaped nozzle 60, it is thus preferable that the transport arm 104 and
the V-shaped nozzle 60 do not overlap in a top plan view during wafer
loading/unloading. If the lift pins 22a, 22a' and the first and second
bar-shaped portion 60A, 60B are in a positional relationship as shown in
FIG. 10A, the transport arm 104 can be easily inserted under the wafer
without contacting the four lift pins nor the V-shaped nozzle 60 as in
FIG. 10B. When the transport arm 104 is inserted under the wafer, the two
distal end of the arm 104 pass through outside of the lift pins 22a, 22a'
and inside the lift pins 22b, 22b'. The above is one advantage obtained
by arranging the first bar-shaped portion 60A and the second bar-shaped
portion 60B into the V-shaped configuration.

[0063] As shown in FIGS. 11(a) and 12(a), the first bar-shaped portion 60A
and the second bar-shaped portion 60B have a cross-sectional shape
resembling an airfoil. In the illustrated liquid treatment apparatus, the
wafer W rotates in a direction of the arrow R in FIGS. 11(a), 12(a) with
respect to the bar-shaped portions 60A and 60B. This rotation generates
an airflow in the direction of the arrow R between the lower wafer W
surface and the lift pin plate 20. The airflow passes though the space
above the bar-shaped portions 60A, 60B with the cross section of an
airfoil to improve the flow of the liquid. More specifically, as the
airflow passes through the space between the rear of the bar-shaped
portions 60A, 60B and the wafer W, the airflow is narrowed down. The
airflow will be accelerated and also rectified to a direction towards the
lower wafer W surface. Such airflow assists the treatment liquid (e.g., a
chemical liquid) collided with the lower wafer W surface to spread more
smoothly over the surface. In addition, since the bar-shaped portion 60A
has the cross section like an airfoil, vibration of the bar-shaped
portion 60A due to the airstream can be suppressed to a minimum.

[0064] The V-shaped nozzle 60 includes a plurality of first ejection ports
61 arranged between a position opposing to a central portion of the wafer
W and a position opposing to a peripheral portion of the wafer W. The
first ejection ports 61 are for ejecting high-temperature SPM (a mixture
of sulfuric acid and a hydrogen peroxide solution) towards the wafer W.
The first ejection ports 61 are arranged in a row in a longitudinal
direction of the first bar-shaped portion 60A from the central portion
60C to the distal end of the first bar-shaped portion 60A. The V-shaped
nozzle 60 also includes a plurality of second ejection ports 62 arranged
between a position opposing to a central portion of the wafer W and a
position opposing to a peripheral portion of the wafer W. The second
ejection ports 62 are for ejecting a mist of a fluid mixture of DIW
(deionized water) and N2 gas or only DIW towards the wafer W. The
second ejection ports 62 are arranged in a row in a longitudinal
direction of the second bar-shaped portion 60B from the central portion
60C to a distal end of the second bar-shaped portion 60B. In addition,
the V-shaped nozzle 60 includes a third ejection port 63 in the central
portion 60C. The third ejection port 63 is for ejecting DIW towards the
central portion of the wafer W. The V-shaped nozzle 60 further includes a
fourth ejection port 64 in the central portion 60C. The fourth ejection
port 64 is for ejecting N2 gas towards the central portion of the
wafer W. The fourth ejection port 64 is positioned almost directly below
the center of the wafer W retained by the retaining plate 30.

[0065] Diameters of the first and second ejection ports 61, 62 and those
of the ejecting passages 67a, 67b, 68a, 68b connected to the ejection
ports 61, 62 are small (about 0.3 to 0.5 mm). Therefore the liquid
becomes electrically charged due to friction caused by the liquid passing
through the ejection ports and the ejecting passages. This may be
prevented by forming the V-shaped nozzle 60 from an electrically
conductive material such as PFA containing carbon fibers.

[0066] As shown in FIG. 14, the treatment fluid supply pipe 40 has, at its
upper end, a head 41 of an enlarged diameter. The central portion 60C of
the V-shaped nozzle 60 is coupled to the head 41 of the treatment fluid
supply pipe 40 by a screw not shown.

[0067] As shown in FIG. 14, as the central portion 60C and the head 41
become coupled together, the second DIW supply passage 40e extending
vertically inside the treatment fluid supply pipe 40 communicates with an
ejecting passage 63a extending vertically inside the central portion 60C.
The DIW can thus be fed via the second DIW supply passage 40e to the
third ejection port 63 and ejected towards the lower surface of the wafer
W. The third ejection port 63 has a shape that ensures the DIW ejected
therefrom to reach the wafer center We on the lower wafer W surface. The
second N2 gas supply passage 40f extending vertically inside the
treatment fluid supply pipe 40 and an ejecting passage 64a extending
vertically inside the central portion 60C are also communicated with each
other as the central portion 60C is coupled to the head 41. The N2
gas can thus be supplied via the second N2 gas supply passage 40f to
the fourth ejection port 64 and ejected towards the lower surface of the
wafer W.

[0068] In addition, when the central portion 60C is coupled to the head
41, the first DIW supply passage 40c extending vertically inside the
treatment fluid supply pipe 40 communicates with a fluid passageway (DIW
passageway) 65b formed in the V-shaped nozzle 60, and the first N2
gas supply passage 40d extending vertically inside the treatment fluid
supply pipe 40 communicates with a fluid passageway (N2 gas
passageway) 66b formed in the V-shaped nozzle 60, as shown in FIG. 13. As
indicated by dashed lines in FIG. 10A, the DIW passageway 65b and the
N2 gas passageway 66b are parallel to each other and extend
horizontally from the central portion 60C of the V-shaped nozzle 60 to
the distal end of the second bar-shaped portion 60B in the longitudinal
direction.

[0069] Although not illustrated in details, when the central portion 60C
is coupled to the head 41, the sulfuric acid supply passage 40a extending
vertically inside the treatment fluid supply pipe 40 also communicates
with a fluid passageway (sulfuric acid passageway) 65a formed in the
V-shaped nozzle 60, and the hydrogen peroxide solution supply passage 40b
extending vertically inside the treatment fluid supply pipe 40
communicates with a fluid passageway (hydrogen peroxide solution
passageway) 66a formed in the V-shaped nozzle 60. As indicated by dashed
lines in FIG. 10A, the sulfuric acid passageway 65a and the hydrogen
peroxide solution passageway 66a are parallel to each other and extend
horizontally from the central portion 60C of the V-shaped nozzle 60 to
the distal end of the second bar-shaped portion 60A in the longitudinal
direction.

[0070] As shown in FIG. 11(a), in the central portion 60C and in the first
bar-shaped portion 60A of the V-shaped nozzle 60, one ejection port 61 is
connected with one sulfuric acid ejecting passage 67a and one hydrogen
peroxide solution ejecting passage 68a which are each connected to the
sulfuric acid passageway 65a and the hydrogen peroxide solution
passageway 66a, respectively. The hydrogen peroxide solution ejecting
passage 68a meets the sulfuric acid ejecting passage 67a at a position
before the ejection port 61 where the sulfuric acid ejecting passage 67a
ends. Thus, a fluid mixture of sulfuric acid and a hydrogen peroxide
solution, that is, the SPM is ejected from each ejection port 61. As
shown in FIG. 11(b), each ejection port 61 is preferably configured to
eject the SPM in a direction inclined to the rotating direction R of the
wafer W. In other words, it is preferable that a vector V61 representing
the direction in which the SPM is ejected has a component of the rotating
direction R of the wafer W. This suppresses bouncing (splash-back) of the
SPM upon its collision with the lower wafer W surface and in turn reduces
waste and increases effectiveness of SPM usage. Since the vector
indicating the ejecting direction of the SPM has the component of the
rotating direction of the wafer W, the ejected SPM is less likely to drop
from the wafer W onto the V-shaped nozzle 60. This is because the SPM
tends to drop from the wafer W at the instant and immediately after the
SPM has reached the wafer W. The fact that the vector representing the
ejecting direction of the SPM has the component of the rotating direction
of the wafer W (in other words, the SPM is ejected in a direction away
from the second bar-shaped portion 60B) is also advantageous in that
undesirable adhesion of the SPM onto the second bar-shaped portion 60B
can be prevented or suppressed. Incidentally, most of the ejection ports
61 are preferred to be formed so that the vector V61 indicating the
ejecting direction of the SPM from the ejection ports 61 has the
component of the wafer rotational direction and the vector V61 is
oriented in a direction orthogonal to the longitudinal direction of the
first bar-shaped portion 60A. On the other hand, one radially outermost
ejection port 61'' or some ejection ports 61 including the port 61'' may
instead be configured to eject SPM in a direction such that the vector
V61 representing the ejecting direction has a component of a radially
outward direction as the arrow V61e in FIG. 10A. Used SPM can then be
swept away from the wafer W smoothly. In addition, one radially innermost
ejection port 61' or some ejection ports 61 including the port 61' may be
formed to eject SPM in a direction such that a vector V61 representing
the ejecting direction is oriented radially inward as shown by the arrow
V61c in FIG. 10A. This ensures that there is no non-treated region in the
central portion of the wafer W.

[0071] As shown in FIG. 12(a), at the central portion 60C and second
bar-shaped portion 60B of the V-shaped nozzle 60, each ejection port 62
is connected with one DIW ejecting passage 67b and one N2 gas
ejecting passage 68b which are each communicated with the DIW passageway
65b and the N2 gas passageway 66b, respectively. The DIW ejecting
passage 67b includes a curved deflection face 67c near the ejection port
62 where the DIW ejecting passage 67b terminates. The N2 gas
ejecting passage 68b meets the DIW ejecting passage 67b in the vicinity
of the lower end of the deflection face 67c. When DIW is supplied from
the DIW passageway 65b via the DIW ejecting passage 67b while N2 gas
is not supplied or slightly supplied, the DIW will be curved by the
deflection face 67c. The DIW will be ejected from the ejection port 62 as
shown in FIG. 12(b), in a direction inclined to the rotational direction
R of the wafer W. In other words, a vector V62 indicating the direction
in which the DIW is ejected from each ejection port 61 has a component of
the rotational direction R of the wafer W.

[0072] Next, when both the N2 gas and the DIW are supplied from the
N2 gas passageway 66b via the N2 gas ejecting passage 68b and
from the DIW passageway 65b via the DIW ejecting passage 67b, the DIW
flow and the N2 gas flow collides at the junction of the DIW
ejecting passage 67b and the N2 gas ejecting passage 68b. The two
fluids will be mixed to form a mist (droplets) of a mixture of the DIW
and the N2 gas. Since the DIW is mixed with the N2 gas before
reaching the deflection face 67c, the direction of ejection is slightly
affected by the deflection lace 67c. The mist will be ejected upward from
the ejection port 62 while spreading in a fan-like form as in FIG. 12(c).
A vector V62' representing the ejecting direction (major direction) of
the mist substantially is oriented to the upright direction and has a
small component of the wafer rotational direction R (i.e., the angle
between the ejecting direction and the lower wafer W surface is large).
However, this is preferable in this case because the cleaning effect of
the mist relies on the collision energy of the mist. It is also
preferable if the vector V62' representing the ejecting direction (major
direction) of the mist has a component of a direction opposite to the
rotational direction R of the wafer. Similarly to the case of the SPM
ejection, one radially outermost ejection port 62'' or some ejection
ports 62 including the port 62'' are configured to eject DIW or the mist
in a direction such that a vector V62 (V62') representing the ejecting
direction has a component of a radially outward direction as shown by
arrow V62e in FIG. 10A. Further, one radially innermost ejection port 62'
or some ejection ports 62 including the port 62' are preferred to be
formed to eject DIW or the mist in a direction such that a vector V62
representing the ejecting direction is oriented radially inward as shown
by arrow V62c in FIG. 10A. As previously mentioned, since cleaning with
the mist is done by applying the wafer W the collision energy of the
mist, it is especially desirable that the ejection ports 62 is configured
such that all area of the wafer W surface to be treated (the whole lower
surface) is directly beaten with the mist.

[0073] The bottom wall of the V-shaped nozzle 60 which is also the bottom
wall of the DIW passageway 65b is provided with a plurality of DIW
ejection ports 69 as shown in FIG. 12(a). The DIW ejection ports 69 are
disposed over an entire length of the DIW passageway 65b at predetermined
intervals. These DIW ejection ports 69 are used to eject DIW as an
apparatus cleaning liquid. The DIW is ejected from each DIW ejection port
69 to the surface of the lift pin plate 20, flows towards the outside due
to centrifugal force and subsequently scatters outward from the lift pin
plate 20. This flow of DIW washes away undesired substances such as SPM
and reaction products of SPM and the resist film, whereby cleaning the
surface of the lift pin plate 20. There may be another DIW passageway
formed inside the V-shaped nozzle 60 independently of the DIW passageway
65b to supply DIW from the DIW ejection ports 69.

[0074] The plurality of ellipses in FIG. 15 each represent an area where
an ejected treatment fluid (SPM, DIW) covers on the lower surface of the
wafer W at the instant of reaching the surface (this area is hereinafter
also referred to as "spot"). After reaching the lower surface of the
wafer W, the treatment fluid ejected from the ejection port 61 or 62
spreads on the surface due to factors such as a centrifugal force of the
wafer W rotation and the pressure of jetting from the ejection port 61,
62. Since the treatment fluids are ejected out obliquely upward from the
ejection ports 61 and 62, the shapes of the spots are elliptical. On the
other hand, the two-fluid spray forms a circular spot having a relatively
large diameter. The pitch P between the centers of elliptical spots is
equivalent to an arrangement pitch of the ejection ports 61 and 62. Since
an ejected treatment fluid diffuses before reaching the wafer, a minor
axis of each ellipse has a length B greater than a diameter of the
ejection port 61 or 62. Length A of a major axis of the ellipse is much
greater than the diameter of the ejection port 61. Since the energy of
collision between the two-fluid spray and the wafer W is an important
factor for two-fluid spray jetting, the ejection ports 61, 62 are thus
preferred to be designed so that adjacent spots have an overlapped
portion having a length of L therebetween. In the case of ejecting a
chemical liquid such as SPM, it is also preferable to configure the
ejection ports 61, 62 in such a way that adjacent spots have an
overlapped portion of a length L for the sake of achieving uniform
treatment. However, if the chemical liquids forming adjacent spots are to
merge immediately, the adjacent spots need not overlap with each other.

[0075] As shown in FIGS. 10A and 10B, the V-shaped nozzle 60 includes the
first bar-shaped portion 60A and second bar-shaped portion 60B arranged
in a V-shaped figure. The first bar-shaped portion 60A having the
ejection ports 61 for jetting SPM is arranged at a position advanced or
rotated through an acute angle (30 degrees in the illustrated embodiment)
in the rotational direction R of the wafer W from the second bar-shaped
portion 60B for ejecting DIW or the two-fluid spray including DIW. This
layout is advantageous in terms of maintaining the V-shaped nozzle 60
clean. There is an airflow traveling in the wafer rotation direction R
under the lower surface of the wafer W, with which the liquids ejected
from the ejection ports 61 and 62 flows. Part of the liquids ejected from
the ejection ports 6.1, 62 and reach the wafer W will drop therefrom due
to gravity. If the positions of the first bar-shaped portion 60A and
second bar-shaped portion 60B were reversed from those shown in FIG. 10A,
the SPM ejected from the first bar-shaped portion 60A and reaction
products are more likely to adhere to the second bar-shaped portion 60B
for ejecting DIW or the two-fluid spray. This is unfavorable hence the
SPM and reaction products contaminate the rinsing fluid supplied from the
second bar-shaped portion 60B. On the other hand, if the first bar-shaped
portion 60A and the second bar-shaped portion 60B are arranged as shown
in FIG. 10A, the first bar-shaped portion 60A can be cleaned by the DIW
or DIW-containing two-fluid spray ejected from the second bar-shaped
portion 60B. Thus, it is desirable to arrange the first bar-shaped
portion 60A at a position advanced through a small angle (30 degrees in
the illustrated embodiment) in the wafer rotational direction R from the
second bar-shaped portion 60B. In other words, the second bar-shaped
portion 60B is desired to be arranged at a position advanced through a
large angle (330 degrees in the illustrated embodiment) in the wafer
rotational direction R from the first bar-shaped portion 60A.

[0076] The substrate cleaning apparatus 10 includes a controller 100 that
controls the whole operation of the apparatus. The controller 100
controls operation of all functional components of the substrate cleaning
apparatus 10 (e.g., the rotational driving unit 39, the vertical driving
unit 50, the first to sixth fluid supply mechanisms 70a to 70f, and a
power supply for a LED lamp 83 described later, etc.). The controller 100
can be implemented with hardware such as a general-purpose computer, and
a program as software for controlling the computer (apparatus control
program, processing recipe, etc.). The software may be stored in a
hard-disk drive or other storage medium fixedly provided in the computer,
or may be stored in a storage medium removably set in the computer such
as a CD-ROM, DVD, flash memory. Such a storage medium is denoted with
reference number 106. Upon receipt of instructions from a user interface
(not shown), a processor 107 calls up a required processing recipe from
the storage medium 106 and executes the recipe. The controller 100
thereby controls and operates the functional components of the substrate
cleaning apparatus 10 to perform a predetermined process (treatment).
Alternatively, the controller 100 may be a system controller that
controls the whole operations of the liquid treatment system shown in
FIG. 1.

[0077] Next, the cover member 80 will be described. As shown in FIG. 2A,
the cover member 80 includes a disk-like main body 81 having a diameter
at least greater than that of the wafer W. The disk-like main body 81
preferably has a shape and dimensions sufficient to completely cover the
upper opening of the rotational cup 36, and further preferably has a
shape and dimensions sufficient to completely cover the upper opening of
the outer cup 56. The cover member 80 in the illustrated embodiment is
formed in a disk-like shape having a diameter somewhat greater than that
of the upper opening of the outer cup 56. A hole 87, vertically passing
through the cover member 80, is formed in the central portion of the
cover member 80.

[0078] As schematically shown in FIG. 2A, the cover member 80 incorporates
LED lamps 83 for heating the wafer W. The illustrated embodiment employs
a LED lamp array including the plurality of LED lamps 83. The LED lamp 83
employed here is one that radiates light of a wavelength suitable for
heating the wafer W, for example, a wavelength of 880 nm. The LED lamp 83
is covered and protected by a cover 84 made from quartz, which transmits
the light of wavelength 880-nm and has high corrosion-resistant. Although
FIG. 2A presents a case where one LED lamp array with a size generally
equal to that of the wafer W is provided, the present invention is not
limited to this. An example of an alternative configuration is such that
has one or a plurality of LED lamp arrays provided at a position opposing
to the central portion of the wafer, one or a plurality of LED lamp
arrays provided at a position opposing to the peripheral portion of the
wafer, and one or a plurality of LED lamp arrays provided at a position
opposing to an intermediate portion of the wafer, that is, the portion
between the wafer center and the wafer periphery. In this configuration,
the temperature of the wafer W can be controlled differently area-by-area
(i.e., so-called zone control) by controlling each LED lamp array
independently. Incidentally, the outer circumferential portion of the
wafer W is likely to be cooled by the airflow caused by the rotation of
the wafer W. With regard of this, it is preferable to increase the output
power of the LEDs or the number thereof (the number of light-emitters) as
approaching closer to the wafer edge in order to heat the wafer W
uniformly.

[0079] The main body 81 comprises therein above the LED lamp 83 a cooling
medium passageway 82a to cool and protect the LED lamp 83 that are
heat-sensitive. The cooling medium passageway 82a may be configured in a
helical or concentric form or other forms in a plane view. The cooling
medium passageway 82a is connected to a cooling medium supply source 82e
(CM) (e.g., cooling water supply source) via a cooling medium supply tube
82b. The cooling medium supply tube 82b is equipped with, from the
upstream, a variable throttle valve 82d and an open/close valve 82c. The
cooling medium passageway 82a is also connected with a cooling medium
discharging tube (not shown) to discharge cooling medium that has been
heated through heat exchange. A power unit 85b supplies electric power to
the LED lamp 83 via a cable 85a.

[0080] A vertical driving mechanism 86 for moving the cover member 80
vertically is provided to the apparatus. By driving the vertical driving
mechanism 86, the cover member 80 can move between a "treating position"
and a "stand-by position". The "treating position" is a position near and
above the wafer W proximate to and directly above the wafer W. The
"stand-by position" is a position further above the wafer W indicated by
double-dashed line in FIG. 2B and far enough from the wafer W so that the
cover member 80 does not obstruct the loading/unloading of the wafer W.
The vertical driving mechanism 86 includes an arm 86a jointed to the
center of the upper surface of the cover member 80 and an air cylinder
86b having its upper end of cylinder rod connected to the arm 86a.

[0081] Next, a series of process steps of a cleaning treatment (process)
performed by the substrate cleaning apparatus 10 for removing undesired
resist films from a wafer surface will be described.

[0082] <Wafer Loading and Placing Step>

[0083] First, the vertical driving mechanism 86 moves the lift pin plate
20, the treatment fluid supply pipe 40, and the V-shaped nozzle 60, to
their respective upper positions shown in FIG. 2B. Next, as indicated by
double-dashed lines in FIG. 2B, a wafer W is carried in from the outside
of the substrate cleaning apparatus 10 by the transport arm 104 and the
wafer W is rested onto the lift pins 22 of the lift pin plate 20. The
vertical driving unit 50 then moves the treatment fluid supply pipe 40
and the V-shaped nozzle 60 from the upper positions to the lower
positions. At this time, since the spring 26 disposed inside the
accommodation member 32 constantly exerts a downward force upon the
connecting member 24, the lift pin plate 20 also moves from the upper
position to the lower position together with the treatment fluid supply
pipe 40. The lower surface of the lift pin plate 20 pushes down the
pressure-receiving member 31c of the substrate retaining member 31 from
the state of FIG. 6. The substrate retaining member 31 in turn rotates
around the axle 31a in the counterclockwise direction of FIG. 6 to move
the substrate retaining portion 31b towards the wafer W from its lateral
side as shown in FIG. 7, whereby the substrate retaining member 31 and
the fixed retaining member 37 hold the wafer W from its lateral side as
shown in FIG. 8. The retained wafer W is then lifted upward to leave the
lift pin 22. Before the wafer W is carried into the substrate cleaning
apparatus 10, the wafer W is reversed by a reverser 105 (see FIG. 1) so
that its "front surface" (the surface on which patterns are to be formed)
comes to the "lower surface" and its "back surface" (the surface on which
no patterns are to be formed) comes to the "upper surface". The wafer W
is retained in this state by the retaining plate 30. In the present
description, the term "upper surface" (or "lower surface") simply means a
face that is facing upward (downward) at a particular point in time.

[0084] <SPM Cleaning Step>

[0085] Next as shown in FIG. 2A, the cover member 80 held upwards at the
stand-by position is lowered to the treating position near the wafer W to
shroud the upside of the wafer W. Then, the rotational driving unit 39 is
actuated to rotate the retaining plate 30. At this time, the connecting
members 24 extending downward from the lower surface of the lift pin
plate 20 are accommodated in the accommodation members 32 extending
downward from the lower surface of the retaining plate 30. The lift pin
plate 20 thus rotates together with the retaining plate 30 to rotate the
wafer W as well. During the rotation, the treatment fluid supply pipe 40
and the V-shaped nozzle 60 attached thereto remain still and do not
rotate. Simultaneously with or after the start of wafer rotation, the LED
lamp 83 inside the cover member 80 is energized to heat the wafer W from
its back surface (i.e., a surface on which no device is formed) which is
the upper surface of the wafer W. The wafer W may be heated to about
200° C. for example. After the wafer W reaches a predetermined
temperature, sulfuric acid heated to about 150° C. is supplied
from the sulfuric acid supply mechanism 70a to the sulfuric acid supply
passage 40a, and also a hydrogen peroxide solution at an ordinary
temperature is supplied from the hydrogen peroxide solution supply
mechanism 70b to the hydrogen peroxide solution supply passage 40b. The
supplied sulfuric acid and hydrogen peroxide solution are mixed at a
position just before the ejection port 61 as shown in FIG. 11(b) to be
ejected as SPM towards the lower surface of the wafer W. The mixing of
the sulfuric acid and hydrogen peroxide solution causes the mixture
thereof to rise in temperature due to reaction heat. The temperature of
the SPM ejected from the ejection port 61 is nearly 180° C. Resist
films on the wafer W is lifted off (peeled off) by the ejected SPM. As
the SPM having a temperature lower than that of the wafer W is ejected
upon the wafer W, the temperature of the wafer W would decrease. The SPM
is thus preferable to be ejected intermittently. The removed resist films
and reaction products flow together with the SPM radially outward along
the lower surface of the wafer W due to the centrifugal force, flow
outside of the wafer W, are received by the rotational cup 36 to change
its flowing direction downward, and are discharged from a waste liquid
tube 58 connected to the bottom of the outer cup 56. At this time, fumes
are generated in the space below the wafer W. The fumes do not diffuse
into the chamber 12 above the wafer W because the cover member 80 covers
the upside of the rotation cup 36, the outer cup 56, and the wafer W. The
fumes are drawn into the waste liquid tube 58 connected to a factory
exhaust line (at a slightly negative pressure) and are discharged with
the waste SPM liquid. In the space between the upper surface of the wafer
W and the lower surface of the cover member 80, an airflow (flow of a
gas) F1 directed to the outside of the wafer W causes due to rotation of
the wafer W (see FIG. 2A). The airflow F1 generates a negative pressure
near the central portion of the wafer W. The hole 87 provided centrally
in the cover member 80 functions as an air intake which brings clean air
above the cover member 80 into the space between the wafer W and the
cover member 80. The air that has been taken in flows in the direction of
the airflow F1 and is deflected downward (see arrow F2) by the inner
surface of the rotation cup 36, then discharged from the slightly
depressurized waste liquid tube 58 provided at the bottom of the outer
cup 56. The airflows indicated by the arrows F1 and F2 act as a shield to
prevent the fumes around the lower surface of the wafer W from diffusing
into a space higher than the wafer W. Thus, the diffusion of the fumes
into the chamber 12 can be suppressed more effectively. Alternatively, a
mechanism for supplying an inert gas such as N2 gas may be connected
to an upper end of the hole 87 to feed the N2 gas into the space
between the wafer W and the cover member 80 thereby forming gas flows
like those shown by the arrows F1 and F2.

[0086] <First Rinsing Step>

[0087] After performing SPM cleaning for a predetermined time, the SPM
ejection from the ejection port 61 as well as the wafer heating by the
LED lamp 83 are stopped. While the wafer is kept rotating, the second DIW
supply mechanism 70e feeds DIW to the second DIW supply passage 40e at a
relatively high flow rate (e.g., 1,500 ml per minute). The DIM is then
ejected towards the central portion of the wafer W from the ejection port
63 provided in the central portion 60C of the V-shaped nozzle 60. The DIW
flows radially outward along the lower surface of the wafer W due to
centrifugal force, flows out of the wafer W, is received by the rotation
cup 36 to change its flowing direction downward, and is discharged from
the waste liquid tube 58 connected at the bottom of the outer cup 56.
Residues of SPM and resists on the lower surface of the wafer W are thus
removed by the DIW flowing radially outward along the surface.

[0088] <Mist Ejecting Step>

[0089] After performing the first DIW rinsing process for a predetermined
time, DIW ejection from the ejection port 63 is stopped. While the wafer
is kept rotating, DIW is supplied at a flow rate of, for example, about
100 to 300 ml per minute from the first DIW supply mechanism 70c to the
first DIW supply passage 40c and also N2 gas is supplied from the
first N2 gas supply mechanism 70d to the first N2 gas supply
passage 40d. As shown in FIG. 12(c), the supplied DIW and N2 gas are
mixed at a position just before the ejection port 62 and then ejected
towards the lower surface of the wafer W as a mist (droplets) of a fluid
mixture of the diffused DIW and N2 gas. Collision energy of the mist
removes substances such as resist residues, particles, left on the lower
surface of the wafer W. After the DIW sprayed as a mist reaches the lower
surface of the wafer W, the DIW flows radially outward along the lower
surface of the wafer W due to centrifugal force, flows out of the wafer
W, is received by the rotation cup 36 to change its flowing direction
downward, and is discharged from the waste liquid tube 58 connected at
the bottom of the outer cup 56. The N2 gas is also discharged from
the waste liquid tube 58. The mist jetting process may be regarded as a
rinsing process as well.

[0090] <Second DIW Rinsing Step>

[0091] After performing the mist ejecting step for a predetermined time,
the mist ejection from the ejection port 62 is stopped. While the wafer W
is kept rotating, second DIW rinsing is conducted in the same manner as
the first DIW rinsing process.

[0092] <N2 Spin-Drying Step>

[0093] After performing the second DIW rinsing step for a predetermined
time, the DIW ejection from the ejection port 63 is stopped. While the
wafer is kept rotating (the rotation speed is preferably increased),
N2 gas is supplied from the second N2 gas supply mechanism 70f
through the second N2 gas supply passage 40f to the ejection port 64
which is provided in the central portion 60C of the V-shaped nozzle 60.
The N2 gas is then ejected towards the central portion of the wafer
W, whereby the DIW remaining on the lower surface of the wafer W is spun
off by the centrifugal force, and the N2 gas promotes the drying.

[0094] <Wafer Unloading Step>

[0095] After N2 spin-drying, wafer rotation is stopped and the cover
member 80 is lifted up to return to the stand-by position. The vertical
driving unit 50 moves the treatment fluid supply pipe 40 and the V-shaped
nozzle 60 from the lower positions to the upper positions. At this time,
each second interlocking member 46 pushes up one connecting member 24 so
that the lift pin plate 20 moves upwards in association with the
treatment fluid supply pipe 40 from the lower position to the upper
position. The substrate retaining member 31 rotates about the axle 31a in
the clockwise direction of FIG. 6 (the direction opposite to the arrow in
FIG. 6) due to the bias force applied by the spring member 31d. The
substrate retaining member 31 moves away laterally from the wafer W and
the wafer W is then supported from its backside by the lift pins 22.
After the lift pin plate 20, the treatment fluid supply pipe 40, and the
V-shaped nozzle 60 have reached the respective upper positions as in FIG.
2B, the transport arm 104 carries away the wafer W from the lift pins 22.
The wafer W is taken out or unloaded from the substrate cleaning
apparatus 10 and is reversed upside down by the reverser 105. The cover
member 80 may be set back to the stand-by position at any timing after
the SPM cleaning step.

[0096] Of the ejecting passages 67a, 67b, 68a, 68b, the N2 gas
ejecting passage 68b is a passage that delivers gas. When the supply of
N2 gas to the N2 gas ejecting passage 68b is cut off, the
external atmosphere of the nozzle tends to enter the N2 gas ejecting
passage 68b. This does not occur with the other ejecting passages that
feed liquids because the liquid remain inside the passages even after the
supply of liquid is cut off. If an SPM atmosphere, for example, enters
the N2 gas ejecting passage 68b, it is unfavorable because a mist of
the DIW ejected afterwards would be contaminated. In order to prevent
this, preferably, a slight amount of N2 gas is constantly fed
through the N2 gas ejecting passage 68b so that the N2 gas
constantly flows out from each ejection port 62. Similarly, it is as well
preferable to make a slight amount of N2 gas constantly flow out
from the ejection port 64 in order to maintain the cleanliness inside the
ejection port 64.

[0097] In the above embodiment, the first bar-shaped portion 60A and
second bar-shaped portion 60B of the nozzle 60 are arranged into the
V-shaped figure. If the rotating direction of the wafer W during
treatment is set as appropriate, the chemical liquid ejected from the
first bar-shaped portion 60A is less likely to drop on the second
bar-shaped portion 60B, whereby preventing or suppressing contamination
of the second bar-shaped portion 60B with the chemical liquid. In
addition, part of the rinsing fluid ejected from the second bar-shaped
portion 60B reaches the first bar-shaped portion 60A and cleans it. Thus,
the nozzle 60 can be maintained clean.

[0098] Further, according to the embodiment, when resist films or other
residues on the wafer W is to be removed by high temperature SPM
cleaning, chemical liquid (SPM) is supplied to the target face (the face
to be treated) of the wafer with the target face turned down and the
upside of the wafer W being shrouded with the cover member 80
incorporating the heater-heating LED lamp 83. This configuration prevents
fumes of the treatment liquid and gas or mist derived from the target
object generated below the wafer W from diffusing into the upper region
of the wafer. Parts disposed in the upper region of the wafer W such as
the chamber inner wall and the internal components of the chamber would
not be contaminated nor corroded by the fumes, whereby preventing
generation of substances which may contaminate the wafer. Further, the
heater incorporated within the cover member 80 heats the wafer substrate
to promote the treatment. Since the cover member possesses both the fume
shutting off function and the wafer heating function, the number of
components can be reduced. In the foregoing embodiment, a cup (the outer
cup 56) surrounds the wafer W, so that a substantially closed space
communicating with an exhaust line is defined on the lower side of the
wafer W. Since SPM cleaning is conducted in this closed space, diffusion
of the fumes into the upper region of the wafer W can be prevented, and
thus contamination or corrosion of the parts disposed in the upper region
such as the chamber inner wall or the internal components of the chamber
can be prevented. Particularly in the foregoing embodiment, since the
upside of the cup is also covered with the cover member, leakage of the
fumes can be reliably prevented.

[0099] The apparatus according to the embodiment employs the nozzle
including the plurality of ejection ports 61 (62) arranged between a
position opposing to the central portion of the wafer W and a position
opposing to the peripheral portion of the wafer W, and configured to
eject the same kind of treatment fluid from the plurality of ejection
ports 61 (62). Thus, the lower surface of the wafer W can be treated with
high in-plane uniformity.

[0100] The nozzle 60 is configured to form SPM by mixing sulfuric acid and
hydrogen peroxide solution immediately before the ejection. This means
that heat generated by mixing the sulfuric acid and the hydrogen peroxide
solution causes immediately before the SPM is ejected. The sulfuric acid
and the hydrogen peroxide solution can be supplied to a position just
before the ejection ports 61 at a lower temperature, as compared with a
case where the mixing is done beforehand. Consequently, the load on the
supply lines for feeding the sulfuric acid and the hydrogen peroxide
solution can be reduced.

[0101] Since the wafer W is heated by the LED lamps which emit light of a
predetermined wavelength, the temperature of the wafer can be rapidly
increased.

[0102] In the foregoing embodiment, the lift pin plate 20, the treatment
fluid supply pipe 40, and the V-shaped nozzle 60 move vertically relative
to the retaining plate 30, and the lift pins 22 for supporting the wafer
W from below are provided on the lift pin plate 20. Accordingly, in
contrast to a conventional apparatus having lift pins which are to be
retreated through through-holes formed in a bottom plate to a space below
the bottom plate, there will be no or less cleaning liquid left on the
lift pins 22 after drying a wafer W, preventing the cleaning liquid from
adhering to the back surface of the wafer after the liquid treatment.
This is because the lift pins 22 rotate integrally with the lift pin
plate 20. In addition, by rotating the lift pins 22 together with the
lift pin plate 20, droplets of cleaning liquid remained on the lift pins
22 can be reduced, which allows the back surface of the wafer W to have
thereon even less droplets of the cleaning liquid after treatment. The
central portion 60C of the V-shaped nozzle 60 is formed so as to close
the through-hole 20a in the lift pin plate 20. This prevents the
treatment liquid from entering the through-hole 20a provided to pass the
treatment fluid supply pipe 40. Additionally, the treatment fluid supply
pipe 40 and the V-shaped nozzle 60 move in vertical directions in
association with the lift pin plate 20 so that when the treatment fluid
supply pipe 40 and the lift pin plate 20 are moved up or down, the
central portion 60C of the V-shaped nozzle 60 blocks the through-hole 20a
in the lift pin plate 20. Entry of the treatment liquid into the
through-hole 20a can be further prevented.

[0103] The rotation cup 36 disposed on the retaining plate 30 prevents
cleaning liquid from scattering externally from the rotating wafer W
during cleaning. Further, due to the substrate retaining member 31
attached on the retaining plate 30, the wafer W can be stably retained
during rotation by supporting the wafer from its lateral side.

[0104] The foregoing embodiment may be modified as follows.

[0105] In the foregoing embodiment, removal of resist films and other
substances were done by performing sequentially the chemical liquid
cleaning step using SPM, the first DIW rinsing step, the mist ejecting
step using DIW and N2 gas, the second DIW rinsing step, and the
N2 spin drying step, in that order. However, the treatment conducted
by a substrate treatment apparatus in the foregoing embodiment is not
limited to this. For example, chemical liquid cleaning step may be
performed as a wet etching process using a mixed acid (a mixture of
sulfuric acid and nitric acid). In this case, the rinsing step, the mist
ejecting step, and the N2 spin drying process may be performed in
manner as previously mentioned.

[0106] The first or second DIW rinsing step may be omitted. Any other
appropriate inert gas may be used instead of N2 gas.

[0107] Heating lamps other than the LED lamps, for instance halogen lamps,
may be employed to heat the wafer. However, LED lamps are more preferred
in terms of heating efficiency and space efficiency.

[0108] The foregoing embodiment employs an assembly comprising the lift
pin plate 20 and the retaining plate 30 integrated with the rotation cup
36, as the substrate retaining unit of a so-called "spin chuck", in other
words a mechanism for retaining and rotating the wafer. However, the
V-shaped nozzle 60 of the foregoing embodiment may be combined with any
of various types of spin chucks to construct a liquid treatment apparatus
as long as the spin chuck is configured to hold the peripheral edge of
the wafer.