SharePoint 2010 - Export Encryption Key

I am currently trying to export my encryption key from SharePoint 2010. This environment was setup by someone who has now left the business and I am not sure which account was used that has access to the MIIS database.

The account I am trying to use has full access to all SQL databases within SharePoint but I am receiving the following error message when trying to export the database.

"The Credentials do not have access to the MIIS database"

My question is, is there anyway to find out what account was used for this, or is there a way of adding a new account into the MIIS Database rights area?

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