Sulfamic acid as an efficient and recyclable catalyst for the ring opening of epoxides with amines and anilines: An easy synthesis of β-amino alcohols under solvent-free conditions

Sulfamic acid as an efficient and recyclable catalyst for the ring opening of epoxides with amines and anilines: An easy synthesis of β-amino alcohols under solvent-free conditions

Abstract

Application of sulfamic acid as an efficient and green catalyst for the ring opening of epoxides by aliphatic and aromatic amines under solvent-free conditions is described. In this process the use of basic neutralization agent was not required due to the intrinsic zwitterionic property of sulfamic acid. The salient features of this methodology are cheaper process, easy availability of the catalyst, versatility, and the catalyst can be recovered after completion of the reaction and can be recycled without affecting the catalytic property.