I have checked AD dosent seem to be anything different from the users that can access to the ones that cant . I have created a shortcut on the domain admin account to mail and pasted on the c drive logged in as a user and opened the shortcut wich appers to work that should be ok for now

Follows users to other PC's? Sound like a permission issue, are they domain admins or power users? I would compare the ones that work to the ones that don't in AD and see if there is anything different.

I have checked AD dosent seem to be anything different from the users that can access to the ones that cant . I have created a shortcut on the domain admin account to mail and pasted on the c drive logged in as a user and opened the shortcut wich appers to work that should be ok for now

You could try going through Control Panel \ User Accounts and Family Safety \ Mail \ E-mail Accounts and create a new account there.

If you have configured an e-mail account and the problem is still there you
might want to go to the Control Panel \ User Accounts and Family Safety \
Mail \ Show Profiles \ and remove the current profile and create a new one
with a new name.

If you haven't already, try opening the mail client once before going to the control panel to open Mail settings. I haven't tested with Office 2010, but with 2003 and 2007 we have to first let Outlook initialise before we can go to the settings to add the exchange accounts.

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