A liquid in a gravitational field will form a free surface if unconfined from above.
Under mechanical equilibrium this free surface must be perpendicular to the forces acting on the liquid; if not there would be a force along the surface, and the liquid would flow in that direction. Thus, on the surface of the Earth, all free surfaces of liquids are horizontal unless disturbed (except near solids dipping into them, where surface tension distorts the surface in a region called the meniscus).

In a free liquid that is not affected by outside forces such as a gravitational field, internal attractive forces only play a role (e.g. Van der Waals forces, hydrogen bonds). Its free surface will assume the shape with the least surface area for its volume: a perfect sphere. Such behaviour can be expressed in terms of surface tension. It can be demonstrated experimentally by observing a large globule of oil placed below the surface of a mixture of water and alcohol having the same density so the oil has neutral buoyancy.