Direct synthesis of organochlorosilanes by the reaction of metallic silicon with hydrogen chloride and alkene/alkyne

Abstract

Organosilicon compounds were directly synthesized from metallic silicon, alkene/alkyne and HCl, EtHSiCl2 being obtained with 47% selectivity from Si, C2H4 and HCl at 513 K, and CH2=CHSiHCl2 and EtHSiCl2 with 39 and 23% selectivity, respectively, when C2H2 was used in place of C2H4.

title = "Direct synthesis of organochlorosilanes by the reaction of metallic silicon with hydrogen chloride and alkene/alkyne",

abstract = "Organosilicon compounds were directly synthesized from metallic silicon, alkene/alkyne and HCl, EtHSiCl2 being obtained with 47% selectivity from Si, C2H4 and HCl at 513 K, and CH2=CHSiHCl2 and EtHSiCl2 with 39 and 23% selectivity, respectively, when C2H2 was used in place of C2H4.",

T1 - Direct synthesis of organochlorosilanes by the reaction of metallic silicon with hydrogen chloride and alkene/alkyne

AU - Okamoto, Masaki

AU - Onodera, Satoshi

AU - Yamamoto, Yuji

AU - Suzuki, Eiichi

AU - Ono, Yoshio

PY - 1998/6/21

Y1 - 1998/6/21

N2 - Organosilicon compounds were directly synthesized from metallic silicon, alkene/alkyne and HCl, EtHSiCl2 being obtained with 47% selectivity from Si, C2H4 and HCl at 513 K, and CH2=CHSiHCl2 and EtHSiCl2 with 39 and 23% selectivity, respectively, when C2H2 was used in place of C2H4.

AB - Organosilicon compounds were directly synthesized from metallic silicon, alkene/alkyne and HCl, EtHSiCl2 being obtained with 47% selectivity from Si, C2H4 and HCl at 513 K, and CH2=CHSiHCl2 and EtHSiCl2 with 39 and 23% selectivity, respectively, when C2H2 was used in place of C2H4.