If you can't find this listed in the Library (the first option in the menu bar on the left), you should edit your Preferences in the main iTunes menu to make sure Books are selected.

4. Make sure you can see your PDF via a file browser (such as Finder on Mac or Explorer on Windows) or as an icon on the desktop. You need to be able to see both iTunes and the PDF you want to move to your iPhone at the same time.

5. Drag and drop the PDF into your iTunes Book library (the PDF will now appear in both places).

6. Plug your iPhone into your computer and then select it in the Devices menu on iTunes. If your phone is already plugged in, you just need to select it.

7. Click on the Books tab in the resulting phone screen within iTunes. You'll find "Books" in the bar across the top of the main frame.

8. Check the Sync Books checkbox, if it isn't already enabled. You can choose either to sync all books (meaning all seen in your iTunes Book Library will be uploaded to your iPhone) or to sync selected books (meaning only the books that you check off will be uploaded to your iPhone).

9. Click the Apply button. The phone will automatically sync with iTunes.