We have investigated the electronic properties of the oxide film and anodic oxidation mechanism. Iron was oxidized by two reaction pathways depending on pH. The oxide film has showed the electronic properties of n-type semiconductor based on the Mott-Schottky equation.

Ultrasonic velocity and density measurements have been undertaken for a number of binary liquid mixtures involving different commercial solvent extractants, LIX reagents. The binary mixtures under investigation have been classified under two categories such as polar-polar, and polar-non-polar types. Different theories and relations such as Schaaff's Collision Factor Theory (CFT), Nomoto's relation (NOM), and Van Dael & Vangeel ideal mixing relation (IMR) have been used to evaluate the velocity theoretically for all these binary systems. The relative merits of afore-mentioned theories and relations compared to experimental values of velocity have been discussed in terms of percentage variations. However, the CFT and Nomoto's relation show better agreement with the experimental findings than the ideal mixing relation for all the systems under investigation.

The critical micelle concentration (CMC) and the counter-ion binding constant (B) for the mixed micellizations of TTAB (tetradecyltrimethylammonium bromide) with other surfactants (DTAB, CTAB, Tween-20, Tween-40, and Tween-80) in aqueous solution of 4-chlorobenzoic acid (0.5 mM) at were determined as a function of (the overall mole fraction of TTAB) by using the spectrophotometric method and the conductivity method. Various thermodynamic parameters (, , , , , and ) were calculated for each mixed surfactant system and compared with the other mixed surfactant systems by means of the equations derived from the nonideal mixed micellar model. The results show that TTAB/DTAB mixed system has a great positive deviation from the ideal mixed micellar model and the other mixed systems have great negative deviations from the ideal mixed model.

Solid acid Mo(VI)/ with 2-10% Mo(VI) was coated on honeycomb monoliths by impregnation method. These catalytic materials were characterized by BET, -TPD/n-butylamine back titration, PXRD and SEM techniques. Phenyl salicylate (Salol) was synthesized via transesterification of methyl salicylate and phenol over these catalytic materials. An excellent yield (91.0%) of salol was obtained under specific reaction conditions. The effect of poisoning of acid sites of the catalytic material by adsorbing different bases and its effect on total surface acidity, powder XRD phases and catalytic activity was studied. A triangular correlation between the surface acidity, powder XRD phases and catalytic activity of Mo(VI)/ was observed. The thermally regenerated catalytic material was reused repeatedly with a consistent high yield of salol.

A sol-gel derived carbon composite electrodes (CCEs) were fabricated by mixing horseradish peroxidase (HRP), sol of tetraethoxysilane (TESO), and graphite powder. The HRP solution was added to the sol solution of TEOS, and then graphite powder was added to this mixture. The resulting carbon ceramic network effectively encapsulated HRP and shows a catalytic reduction starting at -0.2 V for . The optimum conditions for determination have been characterized with respect to the enzyme loading ratio and pH. The linear range and detection limit of detection were from 0.2 mM to 2.2 mM and 0.035 mM, respectively. The common electroactive interferences such as ascorbic acid, acetaminophene, and uric acid were not affected upon the response to at the HRP biosensor due to low detection potential.

Quinine quantitative analysis, photo-bleaching, fluorescence quenching, and urine analysis have been performed by means of a UV-LED fluorometer, which can be easily built and used in a high-school laboratory. The quinine detection range is estimated to be 0.05-80 ppm, enough for many classroom luminescence experiments. The quinine content in commercial tonic water is determined from the calibration curve, and UV photo-bleaching of this anti-malarial drug is demonstrated with clear wavelength dependence. Halide quenching of quinine fluorescence is also observed and the increase in quenching efficiency in the order of , , and is evident. Urine analyses for the student volunteers have been carried out and the results clearly reveal excretion of the ingested quinine. The student participants are exuberant throughout the course of this study and sense the practices resourceful.

The HF (Hollow fiber) extraction method was optimized to analysis seven species of pesticides in aqueous sample and analyzing samples by GC/MS. Hollow fiber extraction showed good efficiency when it was conducted under these conditions: organic solvent was toluene and agitation speed was 1200 rpm. The 15% concentration of NaCl was optimized when it was experimented between 5% and 25%. The equilibrium time was determined at 15 minutes. The pH 5 showed the best effect on the extraction efficiency. The linearities of calibration curves of seven species were good with correlation of regression () over 0.995 when they were experimented over a concentration range of to . The analytical data exhibited the detection of limits (LODs) range of to and the limit of quantification (LOQs) range of to . The optimized HF-LPME extraction method provides a simple and effective preparation and requires small amount of organic solvents and samples compared to conventional pre-treatment methods.

Preparation of (AlPMo) salts, supported on mesostructured SBA-15 silica, by the reaction deposition strategy causes the formation of isolated AlPMo nanocrystals inside the nanotubular channels. The remarkable characteristic of the SBA-15 structure is that all the cylindrical pores are connected by some small channels. This makes the whole pore system in SBA-15 three-dimensional. We have used 2D hexagonal SBA-15 silicas as hard templates for the nanofabrication of AlPMo salt nanocrystal. The oxidation of alcohols occurs effectively and selectively with as the oxidant. AlPMo salt nanocrystal was used as the catalyst.

The copolymerization of triacetoxyvinylsilane, EGDMA (ethylene glycol dimethacrylate as a cross-linker), HEMA (2-hydroxyethyl methacrylate), MMA (methyl methacrylate), MA (methacrylic acid) was performed in the presence of AIBN (2,2'-azobisisobutyronitrile) as an initiator. Measurement of the physical properties of the resulting copolymers showed that water content, refractive index, visible ray transmittance, and tensile strength were in the range of 35.63~32.44%, 1.4382~1.4480, 89.0~92.5% and 0.346~0.674 kgf, respectively. The values of tensile strength of copolymers-containing hexamethylene diisocyanate were higher than those of the copolymers containing triacetoxyvinylsilane. From the results we came to the conclusion that the produced copolymers are suitable for the application of ophthalmic contact lens with high tensile strength, wettability and duraility.

3-(Perfluorooctyl)propan-2-ol was synthesized using an alcoholization process. The synthesis consisted of two steps: (1) addition of the olefin propylene to perfluorooctyl iodide to yield the corresponding iodo-adduct perfluorooctyl propyl iodide and (2) hydrolysis of the adduct reacted with water and dimethylformamide to yield the final product. The adduct and product were analyzed using gas chromatography to determine the yield and purity. The optimal conditions for each step of the process were determined, and a 93% yield of adduct and 95% yield of final product was achieved.

Ba-ferrite () nanoparticles were synthesized by chemical coprecipitation method in an aqueous solution. The particle size and the crystallization temperature of the Ba-ferrite nanoparticles were controlled varying the precipitation temperature. The precipitate that was prepared at showed the crystal structure of Ba-ferrite in X-ray diffraction when it was calcined at the temperature above , whereas what was prepared at showed the crystallinity when it was calcined at the temperature higher than about . The particle sizes of the synthesized Ba-ferrite were in a range of about 20-30 nm when it was prepared by being precipitated at and calcined at . When the precipitation temperature increased, the particle size also increased even at the same calcination temperature. The magnetic properties of the Ba-ferrite nanoparticles were also controlled by the synthetic condition of precipitation and calcination temperature. The coercive force could be appreciably lowered without a loss of saturation magnetization when the Ba-ferrite nanoparticles were prepared by precipitation and calcination both at low temperatures.

We investigated pre-service science teachers' understanding of and problem-solving ability with regard to chemistry concepts in the high school curriculum. For this purpose, we used related certain items and analyzed the results. We found that in the case of all items, some pre-service science teachers, who do not have clear concepts, selected incorrect answers. The in-depth interviews we conducted with the participants revealed some of the causes for the results obtained. First, although pre-service science teachers have better concepts as compared to high school students, they have the same misconceptions as students with regard to some concepts. Second, although they are familiar with the general definitions or meanings of scientific concepts, they do not understand the specific content that is emphasized in the curriculum. Moreover, they tend to solve problems by the information visually conceived. Third, although they know the necessity of general concepts related to problem solving, they sometimes fail to apply inquiry skills and tend to suggest concepts from the higher education curriculum that are not helpful for solving problems.

In this research, the textbook contents related to the ionization degree of strong acid in water were analyzed from 1945 year syllabus to chemistry II textbook in 2009 revised curriculum. Fifty chemistry teachers' cognition related to the species of strong acid in water, and the relationship between the degree of ionization was surveyed by a questionnaire and interviews. As results, most of the teachers thought the species of strong acid in water based on the degree of ionization represented on the chemistry II textbooks. They didn't recognize the conflict of the degree of ionization and definition of strong acid on the textbooks, and then they awakened the conflict, they could not solve the problem.

The college of education should support pre-service teachers to learn knowledge of their major and develop the ability of presenting or teaching the knowledge. The pre-service teachers may have many opportunities of presentations to develop the ability of teaching. Some college of education provide such opportunities in the 'seminar' course. In this study we investigated the pre-service teachers' perceptions on the seminar where they present contents of their major, developed the framework to analyze and evaluated the seminar presentation ability, and explored the change of presentation ability through a case study. Pre-service teachers perceived that from the seminar they could develop the presentation skill and understand the scientific contents more deeply. However they pointed out the difficulty of understanding others' presentations, discussing on the contents and interpreting the English paper. We developed the presentation analysis framework including the evaluation elements, the evaluation items, and the evaluation methods according to the progress of a seminar presentation. Using this framework we evaluated and compared the development of seminar presentation ability of a per-service teacher both quantitatively and qualitatively. We discussed the educational implication of this study such as the suggestion for the effective management of a seminar and the usage of the presentation analysis framework.

This study is examined for the effects of question generating strategy and feedback(teacher feedback and student peer reviews) on science achievement, self-efficiency and perception of the class in the middle school. Three classes of middle school 1st grade in a city were sampled for the study. The students in comparative group took traditional lessons and solved questions presented on worksheets distributed by a teacher. On the other hand, the students in the experimental groups 1 and 2 generated and solved questions by themselves after traditional lessons and then participated in the activity with peer's feedback and teacher's feedback, respectively. A self-efficiency test had been conducted before the treatments and the various tests such as achievement, self-efficiency and the perception of the class were carried out after treatments. The statistical results were analysed by ANCOVA, MANCOVA and t-test. The results of this study were as follows: First, there was significant difference between the control and experimental groups in the science achievement test (p.05). Second, both of the experimental groups showed enhanced self-efficiency compared with comparative group (p