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I thought there was a train to Vilafranca de Penedes, but now I cannot find it on the renfe site. Am I missing something? IF I can get to Vilafranca itself, is it easy to find a taxi to take me the remaining fre km to the winery?

I think you won't have too much trouble with a taxi. Just in case, bring the winery's phone number with you. If you've been waiting for a while and no taxi comes, you can call Torres and ask them to call a taxi for you.