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If you generate a private key or address from a tool designed for bitcoin, they will not work on a MultiChain blockchain created with the default parameters. If you want your MultiChain blockchain to support bitcoin-compatible addressing, you need to change these parameters in params.dat to the values shown, before starting the chain:

I'm afraid this question is a bit out of our scope here. You would need to understand more about the HD wallet's scheme and features to obtain from it a regular (private key, address) pair, then ensure that address has the appropriate permissions on the blockchain and send a transaction using one of its unspent outputs. MultiChain doesn't currently have any built-in HD support.