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Ashwagandha and Holy Basil both have cumulative effects. Which type of ginseng are you taking?
In terms of synergy they all should go pretty well together. They're all adaptogens except for l-theanine, meaning they will help your body deal with stress. L-theanine is pretty calming though, so that should help you out mentally. I've had good experience with Bacopa too.

I would ditch the Ginseng and the Rhodiola if you plan on taking this stack continually - I've had brilliant effects from Ashwagandha despite taking it continually for years (!), whereas Ginseng seems to work better ingested for an extra boost in intervals of about a month or so max a couple of times a year. Rhodiola is again best taken in intervals but seems plain flaky in its effects on me; similar reports from members here if you search the Supplements forum. Good luck with it and thanks for reminding me of wanting to add Holy Basil to my own stack!