The principal objective of the present study is to compute the thermodynamic performance of window air conditioner based on standard vapour compression refrigeration cycle using R22, R407C and nineteen refrigerant mixtures. In this work nineteen R290/R1270 blends at different compositions are developed. A MATLAB code is developed to compute the thermodynamic performance parameters of all the studied refrigerants at condensing and evaporating temperatures of 54.4°C and 7.2°C respectively. The performance parameters are cooling effect, compressor work, COP, compressor discharge temperature, power per ton of refrigeration and volumetric cooling capacity respectively. Analytical results revealed that COP of new binary mixture R290/R1270 (90/10 by mass %) is 2.82% higher among R22, R407C and nineteen studied refrigerants. Energy required by the compressor per ton of refrigeration for R290/R1270 (90/10 by mass %) is 2.73% lower among R22, R407C and nineteen studied fluids. The discharge temperature of the compressor for all the nineteen investigated blends are reduced by 6.0-8.9oC compared to R22. Overall thermodynamic performance of window air conditioner with R290/R1270 (90/10 by mass %) is better than R22 with significant savings in energy consumption and hence it is an energy efficient ecofriendly refrigerant mixture as a drop in substitute to R22.

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