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Adobe Acrobat can capture web pages/sites and save them as PDF files. as for shrinking them down, export the page from acrobat as an eps file this will import into any good vector program or Photoshop (v6 can load PDF files direct I think)

An easy way to do this would be to create thumbnails of each page using a screen capture program. It would take a bit more time than say Acrobat, but the screen capture program that I use is free so its a great tradeoff.