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Author

Yu, Yifu

Wu, Xue-Jun

Zhao, Meiting

Ma, Qinglang

Chen, Junze

Chen, Bo

Sindoro, Melinda

Yang, Jian

Han, Shikui

Lu, Qipeng

Zhang, Hua

Date of Issue

2017

School

School of Materials Science and Engineering

Abstract

The incorporation of metal–organic frameworks (MOFs) into membrane-shaped architectures is of great importance for practical applications. The currently synthesized MOF-based membranes show many disadvantages, such as poor compatibility, low dispersity, and instability, which severely limit their utility. Herein, we present a general, facile, and robust approach for the synthesis of MOF-based composite membranes through the in situ growth of MOF plates in the channels of anodized aluminum oxide (AAO) membranes. After being used as catalysis reactors, they exhibit high catalytic performance and stability in the Knoevenagel condensation reaction. The high catalytic performance might be attributed to the intrinsic structure of MOF-based composite membranes, which can remove the products from the reaction zone quickly, and prevent the aggregation and loss of catalysts during reaction and recycling process.