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Abstract:

The invention relates to a method for treating wastes, in particular from
the production of mineral fibres such as fibreglass wool or rock fibres
associated with organic binders and optionally with water or other metal
and/or organic matters consisting in fusing a waste mass (9) by supplying
a pure oxygen or an oxygen-enriched air in order to obtain a mineral
material usable in the form of a vitreous raw material for glass melting
and in inputting energy by means of at least one burner submerged under
the waste mass (9). A device for carrying out said method is also
disclosed.

Claims:

1-14. (canceled)

15: A method for treating waste to obtain a mineral material useable as a
vitreous raw material in a glass melting process, comprising a step for
melting a waste mass by the input, to said waste mass, of pure oxygen or
oxygen-enriched air through feeding means, characterized in that energy
is also added via at least one burner submerged under the waste mass,
said burner being a device supplying at least one oxidizer and at least
one gaseous fuel in which, or directly after which, these reactants are
blended in order to create an exothermic combustion reaction and in that
said means for feeding pure oxygen or oxygen-enriched air are placed on
the support for said waste mass, said waste being of the glass wool or
rock wool fiber type combined with organic binders and optionally water
or other metallic and/or organic materials.

16: The method as claimed in claim 15, characterized in that the melting
step uses an input of oxygen-enriched air containing at least 40% oxygen.

17: The method as claimed in claim 15, characterized in that the
combustion gases are discharged from at least one burner directly
submerged in said waste mass.

18: The method as claimed in claim 15, characterized in that said
submerged burner(s) is/are controlled in order to preserve the waste mass
in the form of a stable heap above the burners.

19: A device for implementing the method as claimed in claim 15,
characterized in that it comprises a vessel built of refractory materials
forming a hearth (3), walls (2) and a roof (4), a support (3, 12) for the
heap of fibrous waste (9) on which means for feeding pure oxygen or
oxygen-enriched air (8) are placed, and at least one submerged burner
(11) placed on the hearth (3) and/or on a wall (2), said burner being a
device supplying at least one oxidizer and at least one gaseous fuel in
which, or directly after which, these reactants are blended in order to
create an exothermic combustion reaction.

20: The device as claimed in claim 19, characterized in that said support
for the heap of fibrous waste (9) consists of the hearth (3) of said
device.

21: The device as claimed in claim 19, characterized in that said burners
(11) are arranged in a zone substantially vertically below the top of the
heap of fibrous waste.

22: The device as claimed in the claim 21, characterized in that said
burners (11) are distributed symmetrically about a vertical axis passing
through the top of the heap of fibrous materials.

23: The device as claimed in the claim 22, characterized in that said
burners are at least three in number and their total makes an odd number.

24: The device as claimed in claim 19, characterized in that said support
for the heap of fibrous waste (9) consists of a grille (12) located above
the hearth (3).

25: The device as claimed in claim 24, characterized in that said grille
(12) is made from a metallic material cooled by water circulation.

26: The device as claimed in claim 25, characterized in that said grille
(12) consists of tubes comprising two cylindrical and concentric lines,
one internal line fed with oxygen and one external line used for cooling
by water circulation, branch connections being placed at regular
intervals in the internal line to supply the furnace with oxygen.

27: The device as claimed in claim 19, characterized in that said
burner(s) (11) is/are composed of a cooling system of the water box type
and a central line supplied with gaseous fuel around which one or more
lines are placed concentrically, supplied with oxidizer or oxygen, all of
these cylindrical section lines terminating in the burner nozzle.

Description:

[0001]The present invention relates to a method and a device for treating
waste, particularly waste from mineral fiber production, for obtaining a
mineral material useable as vitreous raw material in a glass melting
process.

[0002]It relates more particularly to a method for treating waste from
mineral fiber production, particularly of the fiberglass or rock wool
type combined with organic binders and optionally with water or other
metallic and/or organic materials.

[0003]The various steps in the production of mineral wool generate a
certain quantity of waste. This waste may originate, for example, from
cutting the products, and therefore it contains large quantities of
organic matter, such as resins called "binders" that are used for the
mechanical cohesion of fibrous mats, and optionally, large quantities of
water. Other types of material may be combined with the mineral fibers,
for example, paper films, based on aluminum or bituminous, elements of
wooden pallets, etc.

[0004]The direct remelting of this waste in mineral wool production
furnaces has proved to be unfeasible in practice because it presents many
drawbacks. First, the fibrous structure of the mineral wool pad makes
these products extremely thermally insulating, which is the reason for
their use but also makes their melting difficult and very costly, in
terms of time and energy. Due to their low density, the fibrous products
also tend to float on the surface of the glass bath, making them
difficult to incorporate. Furthermore, the large quantity of water and
the high enthalpy of vaporization of this water incurs high energy costs,
either directly in the furnace, or in an optional prior oven drying step.
Finally, the high content of organic matter and hence of reducing agents,
disturbs the glass melting and refining process, entailing the addition
of large quantities of oxidizing agents such as sodium nitrate, thereby
generating nitrogen oxide emissions detrimental to the environment, or
manganese oxide, which risks unacceptably coloring the glass.

[0005]A method and a device suitable for recycling mineral wool waste by
melting have been proposed in patent publication EP-A-0 389 314. They
consist in conveying to the mass of fibrous waste pure oxygen or
oxygen-enriched air (containing at least 40% oxygen) and in thereby
causing the combustion of the organic binders, which, when the adiabatic
temperature is sufficient, generates sufficiently intense heat to melt
the mineral material. This method thus serves to separate the organic
matter from the mineral materials (which can then be used as raw material
in a melting furnace), generally without external supply of energy,
because the heat is only provided by the combustion of the organic
matter. In such a device, oxygen feeding means are placed on the hearth,
under the waste heap.

[0006]During the industrial use of such a process, called the "Oxymelt"
process, and to increase the specific output of such furnaces (the
specific output is defined as the furnace output, expressed in tonnes of
waste treated per day, related to the melt surface area in m2), it
has proved necessary to supply part of the energy via overhead burners
located above the waste heap. These burners nevertheless have the
drawback of locally increasing the temperature of the furnace walls and
roof, and hence the wear of the refractories forming these walls and this
roof. Moreover, the glass formed is reduced (characterized by a high
"redox" close to 1), entailing the use of oxidizing agents during its
subsequent use as cullet (generally in contents up to 5 to 20% of the
batch). The term "redox" means here the molar content of ferrous iron of
the glass related to its total iron molar content. This term reflects the
redox state of the glass, which strongly influences its physicochemical
properties.

[0007]The present invention therefore proposes to improve this method,
hence to increase its specific output without increasing the temperature
of the walls and of the roof, and to lower the redox of the glass formed.

[0008]The primary subject of the invention is a method for treating waste,
particularly waste from mineral fiber production, comprising a step for
melting a waste mass by the input, to said waste mass, of pure oxygen or
oxygen-enriched air through feeding means, in order to obtain a mineral
material useable as batch material in a glass melting process,
characterized in that energy is also added via at least one burner
submerged under the waste mass and in that said means for feeding pure
oxygen or oxygen-enriched air are placed on the support for said waste
mass.

[0009]The waste is advantageously of the glass wool or rock wool fiber
type combined with organic binders and optionally water or other metallic
and/or organic materials. However, other types of waste combining at
least partially vitrifiable mineral materials and organic matter may also
be treated by the inventive method.

[0010]In the context of the invention, the expression "submerged burners"
means here burners configured so that the flames they generate and the
combustion gases produced develop within the very mass of materials being
processed. Generally, they are positioned flush with or project slightly
from the side walls or the hearth of the reactor used, and are aimed at
the mass of materials to be processed. In the context of the present
invention, the combustion gases are thereby discharged from at least one
submerged burner into the waste mass, directly (the combustion gases are
accordingly actually emitted inside the waste mass) and/or indirectly
(the combustion gases are not emitted directly into the waste mass but
develop later inside said mass). The term "burner" means here also a
device supplying at least one oxidizer and at least one gaseous fuel in
which, or directly after which, these reactants are blended in order to
create an exothermic combustion reaction. This accordingly excludes
devices sometimes termed burners although they supply only one or the
other of the reactants (fuel or oxidizer).

[0011]The expression "means for feeding oxygen or oxygen-enriched air"
means here devices, such as injectors, nozzles or more simply orifices,
terminating in the waste mass and serving exclusively to supply said
waste mass directly with pure oxygen or with oxygen-enriched air. Since
the oxygen flows directly into the waste mass, the oxygen or
oxygen-enriched air is thus fed directly into this very waste mass,
permitting a uniform distribution of the oxidizing gas. These feeding
means are therefore distinct from the submerged burners, the present
invention using the combination of the two means, that is the means for
feeding oxygen or oxygen-enriched air on the hand, and the or each
submerged burner on the other. These feeding means are placed on the
support of the waste mass to be treated, said support preferably being
substantially horizontal.

[0012]The operating principle of a submerged burner furnace for glass
melting is already known, and has been described particularly in
documents WO 99/35099 and WO 99/37591: it consists in carrying out the
combustion directly in the mass of batch materials to be melted, by
injecting the fuel (generally gas of the natural gas type) and oxidizer
(generally air or oxygen) via burners placed below the level of the melt,
hence into the liquid glass bath. This type of submerged combustion
causes, by convection, intensive mixing of the materials being melted,
thereby permitting a rapid melting process.

[0013]The use of a submerged burner furnace for inerting waste is known
from patent application WO 02/48612, but the recyling of fibrous
materials by such a method is not considered therein. Submerged
combustion in fact presupposes the presence of a glass bath in which the
flame can develop. A person skilled in the art is therefore encouraged to
believe that the addition of a burner actually into a heap of fibrous
material will mainly generate strong flights and projections of fibers
and considerable energy losses.

[0014]The inventors have nevertheless succeeded in demonstrating that the
combination of at least one submerged burner with the oxygen feeding
means of the "Oxymelt" type of device did not generate significant
flights and also they significantly increased the specific output of the
device, without major heat losses and while decreasing the quantity of
oxygen necessary for melting.

[0015]A second particularly surprising advantage of the inventive method
has been observed by the inventors. It turned out that an energy input
via at least one submerged burner, instead of increasing the furnace
temperatures, as may have been anticipated, decreases these temperatures
on the contrary, thereby significantly lengthening the life of the
furnace. The lower furnace temperature in fact has the advantage that the
infiltration of glass into the interstices of the furnace refractories is
lower, the infiltrated molten mass solidifying faster due to the lower
temperature and plugging the interstices at a level closer to the furnace
interior. It can be considered that this effect is a corollary of the
effect of increasing the specific output: since the heap of fibrous
materials is converted into molten material faster, the latter removes
the energy faster. In the context of the inventive method, the melting
temperature (measured at the furnace roof) is advantageously lower than
1200° C., even lower than or equal to 1150° C.

[0016]Obtaining such low temperatures can offer the possibility of
constructing the furnace with less efficient and hence substantially
cheaper refractory materials.

[0017]Moreover, this lowering of the temperature also has a direct
beneficial effect of decreasing the redox of the glass formed. It is in
fact known that high temperatures increase the stability of reduced
species in the glass. By its implementation at lower temperatures, the
inventive method thus serves to achieve the desired goal of oxidizing the
glass.

[0018]Thanks to the use of at least one submerged burner, it is also no
longer necessary to use overhead burners positioned above the heap of
fibrous waste. Accordingly, the inventive method generally does not use
such overhead burners.

[0019]The burners are preferably arranged in a zone substantially
vertically below the top of the fibrous waste heap. They may, for
example, be distributed symmetrically about a vertical access passing
through the top of the heap of fibrous materials. They are advantageously
at least two in number, or even three, and are selected preferably to
make an odd number higher than one to distribute the power of the
combustion gases at several points of the heap. The submerged burner(s)
is/are thereby advantageously controlled in order to preserve the waste
mass in the form of a stable heap above the burners. The presence of a
single burner vertically below the top of the heap of fibrous materials
risks, for example, having the consequence of destabilizing said heap,
the burner possibly thereby being exposed, causing a poor transfer of
heat to the fibrous waste and a possible overheating of the furnace roof
and/or walls.

[0020]The burner geometry may be that described in patent document EP-A-0
966 406 or an equivalent geometry. The burner can thus be composed of a
cooling system of the water box type and a central line fed with gaseous
fuel of the natural gas type (or other gaseous fuel or fuel oil) around
which one or more lines is/are concentrically arranged, supplied with
oxidizer (for example oxygen), all these cylindrical section lines
terminating in the burner nozzle.

[0021]The waste introduced generally consists of glass fibers possibly
having a composition of the type described in document EP 412 878. The
content of binding organic materials (resins) is generally about 5 to
10%, expressed as dry weight of the total weight of the fibers. They may
contain a variable content of other materials (finishing films, packing
materials, etc.).

[0022]A further subject of the invention is a device suitable for
implementing the method described above.

[0023]This device is a furnace comprising a vessel consisting of
refractory materials forming a hearth, walls and a roof, further
comprising a support of the heap of fibrous waste on which are placed
means for feeding pure oxygen or oxygen-enriched air, and at least one
submerged burner placed on the hearth and/or on a wall. This support is
preferably substantially horizontal.

[0024]In a first embodiment of the inventive device, the support of the
waste may be the hearth of the furnace.

[0025]However, a second embodiment of the inventive device consists in
supporting the fibrous waste by a grille located above the hearth. This
grille is advantageously a grille of metallic material cooled by water
circulation. It may, for example, consist of tubes comprising two
cylindrical or concentric lines, one internal line fed with oxygen and
one external line serving for cooling by water circulation, branch
connections being placed at regular intervals in the internal line to
supply the furnace with oxygen. An input of pure oxygen or
oxygen-enriched air directly into the waste mass is thereby guaranteed.
In implementing the method using this embodiment of the inventive device,
the hot gases issuing from the merged combustion contribute to the
melting of the heap of fibrous waste, the molten materials accordingly
flowing between the meshes of the grille to form a glass bath in which
the flames of the submerged burners develop. An additional advantage
associated with the use of this particular device resides in the fact
that the redox of the glass formed and collected in the bath is
controllable by the stoichiometry of the flame, at least one submerged
burner. The more or less oxidizing nature of the flame may, in effect, be
directly controlled by adjusting the proportion of oxidizer (generally
oxygen) in relation to that of the fuel (for example methane, also called
"natural gas"). When the oxidizer is oxygen (O2) and the fuel is
methane (CH4), the O2/CH4 mole ratio is preferably higher
than or equal to 2, particularly higher than or equal to 2.1, or even to
2.2, in order to guarantee a reduction of the redox.

[0026]The glass formed can particularly be much more oxidized than in the
embodiment in which the hearth is the support of the heap of fibrous
waste. Without being bound by any scientific theory whatsoever, it is
conceivable that the presence of a glass bath, in which the residence
time of the glass is high, enables the glass to reach a thermodynamic
equilibrium imposed by the combustion gases of the submerged burner(s).
In the case in which the hearth of the furnace is the support of the
fibrous waste heap, the residence time of the molten materials is
probably very short due to the virtual absence of a glass bath, and both
the more or less oxidizing nature of the submerged flames and the
oxidizing nature of the oxygen introduced into the furnace at the level
of the hearth play a lesser role on the redox state of the final glass.

[0027]The present invention will be better understood from a reading of
the detailed description below of nonlimiting exemplary embodiments
illustrated by the figures appended hereto:

[0028]FIGS. 1a and 1b illustrate cross sections along respectively
vertical and horizontal planes of a device for implementing the "Oxymelt"
process as described by patent document EP-A-0 389 314.

[0029]FIGS. 2a and 2b illustrate cross sections along respectively
vertical and horizontal planes of an embodiment of the device for
implementing the inventive method.

[0030]FIG. 3 illustrates a cross section along a vertical plane of the
second embodiment of the device for implementing the inventive method.

[0031]FIGS. 1a and 1b show the device known from EP-A-0 389 314. The
device 1 comprises a cylindrical vessel constructed of refractory
materials consisting of walls 2, a hearth 3 and a roof 4. The device 1
also comprises a charging zone 5, a stack 6 for extracting the flue gases
to a pollution control device not shown, a furnace outlet 7 comprising a
channel in the lower part whereof is placed an orifice for pouring the
molten materials, pure oxygen (or oxygen-enriched air) injectors 8 placed
on the hearth 3 of the furnace (said hearth serving as a horizontal
support of the heap of fibrous waste) and two overhead burners 10.

[0032]This device serves to implement a continuous method defined by the
following steps: [0033]the waste is introduced via the charging zone 5
using a feed screw with a diameter of 50 cm in the form of coarsely
crushed materials comprising glass wool fibers and mixed with organic or
inorganic products such as synthetic resins based on phenol and
formaldehyde acting as binder, paper or aluminum films, etc., and forming
a heap 9 on the hearth 3 of the furnace, [0034]the oxygen injectors 8
supply the oxidizer which reacts exothemically with the fuel formed by
the organic part of the waste. In the case in which the adiabatic
temperature is higher than 1200° C., the heat liberated by the
reaction is insufficient to melt the fibrous materials. The overhead
burners 10 are also in operation to increase the output of the device
thanks to an additional energy input, [0035]the fibrous mass thus gives
rise to a molten mass which trickles in the form of a thin film having a
viscosity of 100 to 1000 poise to the outlet 7 of the furnace to flow
into the flow orifice provided at the base of said outlet 7,
[0036]simultaneously, the combustion gases and flue gases are extracted
via the stack 6.

[0037]Such an industrial device has a surface area of 3 m2 capable of
heating 18 tonnes of waste from glass wool production daily, thanks to an
oxygen input of 250 Sm3 per hour, and an energy input of 200 kW via
the two overhead burners 10. The furnace temperature (measured at the
roof) during normal operation is 1230° C.

[0038]FIGS. 2a and 2b show one embodiment of the inventive device. The
overhead burners 10 are no longer present here. However, three submerged
burners 11 are placed on the hearth 3 of the furnace. These three burners
11 are substantially arranged symmetrically about a vertical axis passing
through the top of the heap of fibrous materials 9. They are supplied
with methane and oxygen, in a stoichiometric ratio, and the combustion
gases (that is the combustion reaction products) are emitted and develop
within the waste mass.

[0039]The invented device serves to implement a method which is different
from the method known from document EP-A-0 389 314, and described above,
in the absence of an energy input via overhead burners 10 and in the step
in which the submerged burners serve to increase the specific output
while decreasing the operating temperatures.

[0040]In the context of the present invention, the addition of the three
submerged burners 11, placed on the hearth 3 of the furnace, serves to
increase the quantity of waste treated to 24 tonnes per day, representing
an increase of about 33%, for a power input of 240 kW. Since the overhead
burners are no longer used, the energy consumption has only increased
slightly compared with the improved device. However, the furnace
temperature has sharply decreased, falling from 1230° to
1150° C. The oxygen consumption has decreased by 30%.

[0041]Knowing the content of combustible materials in the waste
introduced, and the efficiency of the furnace in this given operating
mode, the furnace can be controlled by adjusting the oxygen content of
the flue gases leaving the furnace, which can be measured in a flue gas
discharge zone. In the embodiment shown here, the oxygen content of the
flue gases is regulated at 15% by volume.

[0042]FIG. 3 illustrates a second embodiment of the inventive device. The
heap of fibrous waste 9 is supported here by a metal grille 12 allowing
the flow of the molten materials. This grille 12 also replaces the
injectors 8 in that it constitutes the means for supplying oxygen for the
combustion of the organic products present in the waste. In this
embodiment of the inventive method, the submerged burners 11 discharge at
a certain distance below the bottom level of the heap, so that a glass
bath is located above the submerged burners 11. The combustion gases are
therefore not emitted directly into the waste mass, but develop later
within said mass. The residence time of the glass in this device can be
substantially increased compared with the first embodiment, whereof the
implementing device is illustrated by FIG. 2 and the redox of the glass
can be adjusted by changing the O2/CH4 molar ratio.