The ground electronic state of the $C_{3}Kr$ van der Waals complex has been studied by the wavelength-resolved emission from the $\tilde{A}$ state. The vibrational levels of the $C_{3}Kr$ complex have been compared with those of the $C_{3}Ar$ to ensure the spectral assignments of these two complexes. The perturbation of the $C_{3}$ bending vibration (both in-plane and out-of-plane bending motion) by the rare gas atom has been observed; the vibrational amplitude of the $C_{3}$ bending motion of the complex becomes more restricted than the monomer.

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195712 bytes

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English

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Ohio State University

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THE PERTURBATION OF $C_{3}$ BY THE RARE GAS ATOM STUDIED BY THE SPECTROSCOPY OF THE $C_{3}$ --- AR/KR COMPLEX

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article

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