The objects created with the Part Workbench are relatively simple; they are intended to be used with boolean operations (unions and cuts) in order to build more complex shapes. This modeling paradigm is known as the constructive solid geometry (CSG) workflow, and it was the traditional methodology used in early CAD systems. On the other hand, the PartDesign Workbench provides a more modern workflow to constructing shapes: it uses a parametrically defined sketch, that is extruded to form a basic solid body, which is then modified by parametric transformations (feature editing), until the final object is obtained.

Part objects are more complex than mesh objects created with the Mesh Workbench, as they permit more advanced operations like coherent boolean operations, modifications history, and parametric behaviour.

The Part Workbench is the basic layer that exposes the OCCT drawing functions to all workbenches in FreeCAD

At a very high level, topology tells what pieces an object is made of, and the logical relationships between them. A shape is made of a certain set of faces. A face is bounded by a certain set of edges. Two faces are adjacent if they share a common edge.

Topology alone does not tell you the size, curvature, or 3D locations of any of those pieces. However, each piece of topology does knows about it's underlying geometry. A face knows what surface it lies on. An edge knows what curve it lies on. The geometry knows about curvature and location in space. - Source

Thus, Topology defines the relationship between simple geometric entities, which can be linked together to represent complex shapes. - Modeling Data User's Guide