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Williams is the new face of Louis Vuitton

The actress is set to star in the luxury brand's autumn/winter 2013-2014 campaign.

In the photos, which can be seen on Women's Wear Daily's website, the My Week With Marilyn star is pictured in a black Louis Vuitton dress wearing deep red lipstick with her cropped blonde hair stylishly tousled.

The images, taken by photographer Peter Lindbergh, were created to promote two new Louis Vuitton bags, the W and the Capucines.

The campaign is set to break in Maire Claire France on August 2.

Williams is a big fan of Louis Vuitton having worn a dress by the brand to the 2012 Oscars.

This is not the 32-year-old's first time fronting a fashion campaign having modelled for Band of Outsiders' spring 2012 collection.