Apparatus for making a rigid container by injection molding a parison having plural layers of polymers. The parison is blow molded to the final shape of the container. Control during injection is exercised over each of the plural polymers so as to produce uninterrupted layers extending throughout the walls of the parison and to insure that the interior layers are completely encapsulated within the outer layers.

Claim:

I claim:

1. Apparatus for making a multi-layer rigid article, comprising:

(A) an injection mold and a core pin which together define a cavity for molding a parison having a bottom portion, the cavity having an entrance at the bottom portion of the parison,

(1) an injection nozzle having an exit communicative with the entrance, a flow path for each of three polymer streams, and exit orifices for the polymer streams communicative with said nozzle exit,

(2) means for independently commencing in the nozzle exit the flow of a first polymer stream to become the inside surface layer of the parison and the flow of a second polymer stream to become the outside surface layer of the parison, and theflow of a third polymer stream between the first and second polymer streams to become an inner layer of the parison,

(3) means for independently controlling the flow of each of the three polymer streams relative to each other during each injection cycle,

(4) means for independently terminating the flow of each of the polymer streams, operable to terminate each or any of said polymer streams independently of one another and at predetermined including differing times during each injection cycle,

(5) means associated with the independent commencing means, the independent controlling means and the independent terminating means, for coordinating their respective functions in a predetermined manner during the injection cycle, to permittermination of the flow of the first polymer stream, then termination of the flow of the third polymer stream, and thereafter termination of the flow of the second polymer stream, to thereby enable the apparatus to provide the article with an inner layerformed from the third polymer stream that is continuous and is completely encapsulated within the surface layers,

(b) means for transferring the injection molded parison to a blow molding cavity having the configuration of the article,

(C) means for inflating the parison in the blow molding cavity to form the article.

2. The apparatus of claim 1 including means for introducing a fourth polymer stream between the third and first polymer streams and means for introducing a fifth polymer stream between the third and second polymer streams, and means forcontrolling and for terminating the flows of the fourth and fifth polymer streams.

3. Apparatus for making a multi-layer rigid container, comprising:

(A) an injection mold and a core pin which together define a cavity for molding a parison having a closed end, the cavity having an entrance for polymer at the closed end of the parison,

(1) an injection nozzle having an exit communicative with the entrance, a flow path for each of three polymer streams, and exit orifices for the polymer streams communicative with said nozzle exit,

(2) means for establishing in the entrance a flow of polymer comprising a central stream of a first polymer surrounded by an annular stream of a second polymer,

(3) means for establishing an annular stream of a third polymer between the first and second polymer streams, the third polymer stream being for forming an inner layer of the parison,

(4) means for independently controlling the flow of each of the three polymer streams until the cavity is nearly filled during the injection cycle,

(5) means for independently terminating the flow of each of the polymer streams,

(6) means associated with the establishing means and with the independent controlling means and the independent terminating means for coordinating their respective functions in a predetermined manner during the injection cycle, to permittermination of the flow of the first polymer stream, then termination of the flow of the third polymer stream, and then termination of the flow of the second polymer stream, to thereby enable the apparatus to provide the parison with an inner layerformed from the third polymer stream that is continuous and is completely encapsulated within surface layers formed from the first polymer stream and the second polymer stream,

(B) means for transferring the parison to a blow mold cavity,

(C) means for inflating the parison in the blow mold cavity to blow mold the parison into the finished container.

two core pins mounted on a plate which transverses to register either pin with the injection mold,

two blow molds for blow molding the parisons into the container, the blow molds being located to register one blow mold with one core pin when the other core pin is registered with the injection mold,

an injection nozzle in communication with the injection mold at the bottom portion of the parison, the nozzle having three concentric exit orifices for three polymer streams communicative with said nozzle exit, said three streams including afirst stream to become the inside surface layer of the parison, a second stream to become the outside surface layer of the parison, and a third stream between the two to become the inner layer of the parison,

a plurality of polymer injection means associated with the nozzle orifices,

control means to independently control the flow of each of the polymer streams as a function of time during the injection cycle, and to permit the independent termination of flows of each of the polymer streams, and

means associated with the control means for coordinating the flow and termination of flow of each of the polymer streams as a function of time during the injection cycle, to permit termination of the flow of the first polymer stream, thentermination of the flow of the third polymer stream, and thereafter termination of the flow of the second polymer stream, to thereby enable the apparatus to provide the parison and resulting container with an inner layer that is continuous and iscompletely encapsulated within the surface layers.

5. The apparatus of claim 4 wherein the plurality of injection means comprises a plurality of injection rams and a plurality of plasticators for supplying molten polymer to the injection rams, and wherein the control means control thedisplacement of the injection rams.

6. Apparatus for making a multi-layer rigid article, comprising:

(A) an injection mold and a core pin which together define a cavity for molding a parison having a bottom portion, the cavity having an entrance at the bottom portion of the parison,

(1) an injection nozzle having an exit communicative with the entrance, a flow path for each of three polymer streams, and exit orifices for the polymer streams communicative with said nozzle exit,

(2) means for independently commencing in the nozzle exit the flow of a first polymer stream to become the inside surface layer of the parison and the flow of a second polymer stream to become the outside surface layer of the parison, and theflow of a third polymer stream between the first and second polymer streams, to become an inner layer of the parison, said means for independently commencing the flows of the polymer streams being operable independently of each other at predeterminedincluding differing times during the injection cycle,

(3) means for independently controlling the rate of flow of each of the three polymer streams relative to each other during each injection cycle, to permit controlling and varying the relative thicknesses of the respective layers of andcontrolling and varying the location and thickness of the inner layer of the parison during the injection cycle,

(4) means for independently terminating the flow of each of the polymer streams, operable to terminate each or any of said polymer streams independently of one another and at predetermined including differing times during each injection cycle,

(5) means associated with the independent commencing means, the independent controlling means and the independent terminating means for coordinating their respective functions in a predetermined manner during the injection cycle, to permittermination of the flow of the first polymer stream, then termination of the flow of the third polymer stream, and thereafter termination of the flow of the second polymer stream to thereby enable the apparatus to provide the article with an inner layerformed from the third polymer stream that is continuous and is completely encapsulated within the surface layers,

(B) means for transferring the injection molded parison to a blow molding cavity having the configuration of the article,

(C) means for inflating the parison in the blow molding cavity to form the article.

7. Apparatus for making a multi-layer rigid container, comprising:

(A) an injection mold and a core pin which together define a cavity for molding a parison having a closed end, the cavity having an entrance for polymer at the closed end of the parison,

(1) an injection nozzle having an exit communicative with the entrance, a flow path for each of three polymer streams, and exit orifices for the polymer streams communicative with said nozzle exit,

(2) means for establishing in the entrance a flow of polymer comprising a central stream of a first polymer surrounded by an annular stream of a second polymer,

(3) means for establishing an annular stream of a third polymer between the first and second polymer streams,

(4) means for independently controlling the rate of flow of each of the three polymer streams until the cavity is nearly filled during the injection cycle, to permit controlling and varying the relative thicknesses of the respective layers of andcontrolling and varying the location and thickness of the inner layer of the parison during the injection cycle,

(5) means for independently terminating the flow of each of the polymer streams,

(6) means associated with the establishing means and with the independent controlling means and the independent terminating means for coordinating their respective functions during the injection cycle, to permit termination of the flow of thefirst polymer stream, then termination of the flow of the third polymer stream, and then termination of the flow of the second polymer stream, to thereby enable the apparatus to provide the parison with an inner layer formed from the third polymer streamthat is continuous and is completely encapsulated within surface layers formed from the first polymer stream and the second polymer stream,

(B) means for transferring the parison to a blow mold cavity,

(C) means for inflating the parison in the blow mold cavity to blow mold the parison into the finished container.

8. Apparatus for making an at least five layered rigid article, comprising:

(A) an injection mold and a core pin which together define a cavity for molding a parison having a bottom portion, the cavity having an entrance at the bottom portion of the parison,

(1) an injection nozzle having an exit communicative with the entrance, a flow path for each of five polymer streams, and exit orifices for the polymer streams communicative with said nozzle exit,

(2) means for independently commencing in the nozzle exit the flow of a first polymer stream to become the inside surface layer of the parison, and the flow of a second polymer stream to become the outside surface layer of the parison, and theflow of a third polymer stream between the first and second polymer streams to become an inner layer of the parison, and the flow of a fourth polymer stream between the first and third polymer streams, and the flow of a fifth polymer stream between thesecond and third polymer streams,

(3) means for independently controlling the flow of each of the five polymer streams relative to each other during each injection cycle,

(4) means for independently terminating the flow of each of the polymer streams,

(5) means associated with the independent commencing means, the independent controlling means and the independent terminating means for coordinating their respective functions in a predetermined manner during the injection cycle, to permittermination of the flow of the first polymer stream, then termination of the flow of the fourth and the third polymer streams, and thereafter termination of the flow of the fifth and the second polymer streams, to thereby enable the apparatus to providethe parison with an inner layer formed from the third polymer stream that is continuous and completely encapsulated within the surface layers,

(b) means for transferring the injection molded parison to a blow molding cavity having the configuration of the article,

(C) means for inflating the parison in the blow molding cavity to form the article.

9. Apparatus for making an at least five-layered rigid container, comprising:

(A) an injection mold and a core pin which together define a cavity for molding a parison having a closed end, the cavity having an entrance for polymer at the closed end of the parison,

(1) an injection nozzle having an exit communicative with the entrance, a flow path for each of five polymer streams, and exit orifices for the polymer streams communicative with said nozzle exit,

(2) means for establishing in the entrance a flow of polymer comprising a central stream of a first polymer surrounded by an annular stream of a second polymer,

(3) means for establishing an annular stream of a third polymer between the first and second polymer streams, the third polymer stream being for forming an inner layer of the parison, means for establishing a fourth polymer stream between thefirst and third polymer streams, and means for establishing a fifth polymer stream between the second and third polymer streams,

(4) means for independently controlling the flow of each of the five polymer streams until the cavity is nearly filled during the injection cycle,

(5) means for independently terminating the flow of each of the polymer streams,

(6) means associated with the establishing means and with the independent controlling means and the independent terminating means for coordinating their respective functions during the injection cycle, to permit termination of the flow of thefirst polymer stream, then termination of the flow of the fourth and the third polymer streams, and thereafter termination of the flow of the fifth and the second polymer streams, to thereby enable the apparatus to provide the parison with an inner layerformed from the third polymer stream that is continuous and completely encapsulated within surface layers.

(B) means for transferring the parison to a blow mold cavity,

(C) means for inflating the parison in the blow mold cavity to blow mold the parison into the finished container.

10. The apparatus of claims 1,3,4,6,7,8, or 9 wherein the means for coordinating permit the coordinated control and variation of the location and thickness of the respective streams relative to each other and of the layers relative to each otherin the parison.

11. The apparatus of claim 1 wherein the means for coordinating is also adapted for controlling and changing the thickness and location of the layer of the parison formed by the third polymer stream during the injection cycle.

12. The apparatus of claim 1 wherein said exit orifice for the third polymer stream defines a thin polymer stream to form a thin inner layer of said parison.

13. The apparatus of claim 11 wherein said exit orifice for the third polymer stream defines a thin polymer stream to form a thin inner layer of said parison.

14. The apparatus of claim 1 wherein the means for coordinating the establishment, control and termination of the three streams during each cycle, includes means for independently terminating the first polymer stream forming the first polymerlayer and for re-initiating the flow of said first polymer stream prior to terminating the flow of the polymer stream for forming the outside surface layer of the parison.

15. The apparatus of claim 3 wherein the means for coordinating is also adapted for controlling and varying the thickness and location of the layer of the parison formed by the third polymer stream during the injection cycle.

16. The apparatus of claim 3 wherein said exit orifice for the third polymer stream defines a thin polymer stream to form a thin inner layer of said parison.

17. The apparatus of claim 15 wherein said exit orifice for the third polymer stream defines a thin polymer stream to form a thin inner layer of said parison.

18. The apparatus of claim 3 wherein the means for coordinating the establishment, control and termination of the three streams during each cycle, includes means for independently terminating the first polymer stream forming the first polymerlayer and for re-initiative the flow of said first polymer stream prior to terminating the flow of the polymer stream for forming the outside surface layer of the parison.

Description:

BACKGROUND OF THEINVENTION

Food product rigid containers generally must be impermeable to oxygen. Most common structural polymers for rigid food containers are permeable to oxygen which invades the food product causing degradation or spoilage. Those polymers which aresufficiently impermeable to oxygen generally are not suitable alone for rigid containers for foods because they do not possess adequate structural properties, are moisture sensitive, or are not approved for or are of questionable safety when used incontact with foods. Ethylene vinyl alcohol copolymer (EVOH) is a transparent extrusible material possessing high impermeability to oxygen when dry, many times less permeable than acrylonitrile copolymers, but is very moisture sensitive. The oxygenbarrier properties of EVOH are markedly diminished in the presence of significant quantities of water. To be useful for food packaging, particularly where extended shelf life is required, EVOH must be kept dry as by total encapsulation within polymerswhich have good moisture barrier properties.

Many foods are processed in the container in a pressure cooker or retort. Retort conditions commonly are 250.degree. F. at 30 psia steam pressure. A rigid container must survive retort conditions. It must not permanently distort duringcooking or during cooling, and must not suffer an alteration of the desirable properties of its components. Polyolefins, particularly blends or copolymers of polypropylene and polyethylene, are well suited to manufacture of rigid containers and haveadequate physical properties to survive retorting. Polyolefins are relatively poor oxygen barriers, but are relatively good moisture barriers. The use of polyolefins with a central core of an oxygen barrier polymer is a desired goal of the foodpackaging industry.

Nohara et al. U.S. Pat. No. 3,882,259 discloses a three ply plastic bottle having a core of EVOH blended with Surlyn A brand ionomer resin and outer plies of polyethylene blended with Surlyn A. The Surlyn A ionomer is added to both the EVOH andthe polyethylene resin materials to improve adhesion between layers. The bottle is to be made by extrusion blow molding whereby the three layers are simultaneously extruded to produce a three ply tube. While still hot from extrusion, the tube ispinched together at the bottom to form a seal and inflated in a blow mold having the shape of the desired bottle.

Extrusion blow molding has four serious drawbacks when used to form multi-layer containers having a core ply of a moisture sensitive barrier material such as EVOH.

First, the pinch seal at the bottom leaves the core ply of EVOH exposed on the bottle exterior. Since EVOH and certain other barrier materials are adversely affected by moisture, exposure of the core ply at the container bottom renders thecontainer susceptible to loss of barrier quality by intrusion of moisture. The risk that the container exterior will encounter damp conditions in storage or transport is high and the resulting loss of barrier quality will degrade or spoil the food. Further, retort conditions are such that moisture from the steam will intrude into the barrier layer through the exposed barrier at the bottom.

Second, extrusion blow molding necessarily produces scrap as a result of the pinch sealing procedure. Since the scrap contains materials from each of the three layers, re-extrusion of the scrap is difficult and expensive.

Third, the pinch seal produces a bottom of non-uniform thickness and strength. The sealing takes place along a line between the abutting faces of the inner layer material. The seal line is bordered by regions of relatively thick material. Whenstretched during blow molding, the bottom varies in thickness in the vicinity of the pinch seal. Because of the thickness variation due to the pinch seal, the stiffness of the bottom is not uniform along all diameters. Consequently, the bottom does notevenly respond to expansion and contraction as the product changes in temperature. This lack of even response causes unpredictable performance of the container when retorted.

Fourth, the pinch seal may create an interruption in the barrier layer. If the inside surface layer is interposed between the barrier layer at the seal, a line lacking barrier material will result. The area of the interruption may be greatenough to allow sufficient oxygen to enter to be a problem.

Because of these disadvantages, extrusion blow molding cannot produce an entirely satisfactory three layer rigid container having a core barrier layer of a moisture sensitive polymer such as EVOH, particularly where the container is intended forretorting.

SUMMARY OF THE PRESENT INVENTION

The present invention is concerned with apparatus for making a plastic container by injection molding or by an injection blow molding technique which produces a container whose walls are multiple plies of different polymers. In particular, thecontainer walls comprise inner and outer layers of structural polymers such as polyolefins or a blend of polyolefins on either side of a core layer of a polymer having oxygen barrier properties such as EVOH.

Injection blow molding is a process whereby a preform or parison is formed by injection molding in a cavity. The parison is transferred to a blow mold cavity and blown to the shape of the desired container. The parison can be retained on thecore pin of the injection mold and transferred on the core pin to the blow molding cavity. The parison can be temperature conditioned before blow molding to achieve an optimum temperature or profile of temperatures. The core pin can be temperaturecontrolled and the exterior of the parison can be temperature conditioned by contact with air or other fluid such that blow molding occurs at optimal conditions. Orientation can be achieved as the parison is stretched during blow molding. Injectionblow molding produces no scrap and requires no pinch seal.

According to the present invention, polymer melts for the inside and outside surface layers and the core layer of the container walls are substantially simultaneously injected into a parison mold cavity through an injection nozzle having separatepassages for each polymer melt arranged to lead to coaxial annular nozzle orifices surrounding the central orifice. Additional layers or layers interposed between the surface and core layers can also be injected simultaneously to produce a containerwall having four or more layers.

The initiation, rate, and termination of flow for each layer are independently and continously controlled to provide control over the thickness of each layer and to insure that the core layer or layers are totally encapsulated between the surfacelayers. The injection molded parison is transferred on the core pin to a blow mold cavity having the shape of the container and is then blow molded into the finished container. Temperature conditioning of the parison just prior to blowing can result inbiaxial orientation of the various polymers to achieve desirable improvements in physical properties such as impermeability, clarity, tensile strength, impact strength, and resistance to creep. The resulting product has a barrier layer or layers whichextend without interruption throughout the container, yet are completely encapsulated within the material of the inside and outside surface layers. Since the barrier layer is protected from moisture by the moisture barrier properties of the surfacelayers, the oxygen barrier quality is preserved.

DESCRIPTION OF A PREFERRED EMBODIMENT

DRAWINGS

In the drawings:

FIG. 1 is a schematic view in cross-section of injection blow molding apparatus,

FIG. 2 is a schematic view of the apparatus of the present invention,

FIG. 3 is a simplified view of the injection apparatus of the present invention,

FIG. 4 is a schematic view illustrating the control system for one of the injection rams,

FIG. 5 is a plot of the position of one of the injection rams as a function of time,

FIG. 6 is a flow chart for the control system for the apparatus,

FIG. 7 is a plot of ram position as a function of time for three rams,

FIGS. 8-15 are views in cross-section taken through the nozzle and cavity showing the confluence of flow of the various layers at various times during the injection cycle,

FIG. 16 is a view in cross-section of the injection nozzle,

FIG. 17 is a view in cross-section of the parison, FIG. 18 is a view in cross-section of the finished container,

FIG. 19 is an enlarged view of a portion of a container wall having three layers,

FIG. 20 is a plot of the oxygen permeability of a barrier material as a function of moisture content, and

FIG. 21 is an enlarged view of a portion of a container wall having five layers.

The machine of the present invention injection molds a multi-layer parison from a plurality of polymers, each separately plasticated and fed to separateinjection rams. The rams each force a shot of polymer to appropriate nozzle passages which lead to the entrance to the injection mold cavity. Conditions are controlled to advance the several polymer melts substantially simultaneously in the die cavityunder non-turbulent flow conditions to preserve the polymers as discrete layers in the parison. The following detailed description explains how the foregoing is accomplished.

FIG. 1 shows a portion of the injection blow molding machine (IBM) of the present invention. Two core pins 10A, 10B are mounted on a transversely moveable plate 40 on the axially moveable platen 42 of the machine. Core pin 10A is positioned inan injection mold 20 while core pin 10B is positioned in a blow mold 30B. When plate 40 is traversed to the left, core pin 10A will be in blow mold 30A and core pin 10B will be in the injection mold 20. A parison is removed from the mold by axialretreat of the moveable platen 42 and the plate 40 with core pins 10 is traversed either left or right to the available blow mold. FIG. 1 shows blow mold 30A ready to receive the parison and shows blow mold 30B containing a parison 60B. Parison 60B isinflated with air to assume the shape of blow molding cavity 30B while parison 60A is being injected in cavity 20. The blow molds open as the platen retreats to eject the finished container. The plate 40 shuttles back and forth each cycle so that acontainer is blown simultaneously each time a parison is injected.

FIG. 2 shows the general layout of the injection blow molding machine and indicates the control means. Plasticators 82A, 82B, 82C feed three rams 70A, 70B, 70C for three polymer melts which are fed to a manifold block 75 which contains separatepassages leading to a multi-passage nozzle 50 for the injection mold 20. The platen 42 is moved axially of the mold by a hydraulic press 44. Control circuitry means for the press and blowing cycles are indicated at press control block 110. Amicroprocessor 100 is programmed to control the servo hydraulics 120 which control the individual injection rams and to command the press control block 110.

FIG. 3 shows one of the plural plasticators 82B for melting and supplying molten polymer B to an injection ram 70B. The plasticator 82B is a conventional reciprocating screw device which forces molten polymer into the cylinder 71B of the ramwhen manifold valve 84B is closed and manifold valve 85B is opened and the ram is retreated to the left by hydraulic actuator 72B. When the ram cylinder 71B is charged with molten resin, valve 85B is closed. Upon a control signal from themicroprocessor 100, valve 84B is opened and the servo control 120 for the ram causes the ram to advance to the right, according to a displacement-time schedule stored in the microprocessor program. A displacement transducer 76 provides an analog signalproportional to ram displacement to complete a feed-back loop for the servo 120. Polymer B forced according to the program flows past valve 84B through the manifold passages to the injection nozzle, through the nozzle passages and into the injectionmold cavity where polymer B becomes the outer layer of a parison 60.

FIG. 4 shows schematically the servo loop where the control signal from the microprocessor 100 (shown as voltage as a function of time) and a position signal from the displacement transducer 76 are algebraically combined in an amplifier 78 andthe resulting signal is used to control the hydraulic servo 120 for the hydraulic actuator 72. A typical ram position control signal is shown in FIG. 5. Since displacement is measured by transducer 76, the plot is in voltage as a function of time.

FIG. 6 is a flow chart of the system used to control the machine. The injection blow molding machine is indicated as IBM on the chart. Upon initiation of the cycle, the program checks positions of valves, rams, etc. and if all are proper,recharges the ram cylinders 71 from the plasticators 82. The IBM control circuit 110 provides an "inject" signal to the microprocessor 100. Injection is carried out according to the ram displacement-time schedule of the microprocessor and is terminatedat the end of the schedule. An "injection complete" signal is sent to the IBM. The control 110 then causes the IBM to traverse to place the parison in the blow mold and to procede with the blow molding phase. The machine continues to cycle throughthis sequence. Keyboard 115 may be used to change the displacement-time schedule or to shut down the machine.

FIG. 7 is a plot of ram displacement as a function of time for three rams. The positions of the rams are measured as the voltage analog output of the transducers 76 for each ram. The polymer for the inside surface layer is "A"; that for thecore layer "C"; and that for the outside surface layer is "B". In this figure an upward slope indicates a forward motion of the ram to deliver polymer, a horizontal slope indicates a stopped ram, and a downward slope indicates a retreat of the ram. Thesignificance of FIG. 7 is perhaps better understood by reference to FIGS. 8-15, which show the flow of the polymers at the exit of the nozzle 50 and the entrance 52 of the injection mold cavity 20 at the rounded bottom of the parison. FIGS. 8-15 aretaken at different times in the cycle and those times are keyed to FIG. 7.

FIG. 8 represents the conditions at the start of a cycle at time 0. The cavity 20 is empty. The entrance 52 of the cavity 20 initially contains only the polymers A and B for the inside and outside surface layers. The rams for polymers A and Bbegin to advance to force those polymers into the cavity. At about 100 milliseconds into the cycle the ram for the core layer, polymer C, begins to advance. FIG. 9 shows that polymer C has joined the flow stream in the entrance and polymer C is aboutto enter the cavity. FIG. 10, taken at about 520 milliseconds, shows the flow of the three polymers as the cavity continues to be filled. All three polymer layers must extend throughout the entire length of the parison. Since the flow in the moldcavity is laminar, the velocity in the middle of the stream is higher than the velocities at the cavity walls. Therefore, initiation of flow of polymer C is retarded enough (e.g., about 100 milliseconds) so that polymer C will reach the far end of thecavity just as the slower moving surface layers (A and B) reach the end. In this way, the far end of the parison, that which becomes the mouth end of the container, will have all layers present in their proper positions.

At about 1000 milliseconds into the injection cycle, the ram for polymer A (the inside surface layer) is stopped and the ram for polymer C (the core layer) can be accelerated slightly to achieve the desired thickness of material in the bottom ofthe container. Polymer A is necked down in the entrance 52 as is shown in FIG. 11 until it effectively is severed as shown in FIG. 12. At 110 milliseconds the ram for polymer C is stopped and the ram for polymer A is restarted. FIGS. 13 and 14 showpolymer A advancing to pinch off polymer C in the entrance, thereby pushing the last of polymer C into the cavity 20 with polymer A to bury or encapsulate to isolate polymer C from exposure at the surface of the parison. FIG. 15 shows polymer A knit topolymer B at the entrance to complete the encapsulation of polymer C and to return to the conditions at the start as shown in FIG. 8. At the time of FIG. 15 (1300 milliseconds) all three rams are retreated to depressurize the cavity to prevent expansionof the parison when the cavity is opened and to depressurize the polymers remaining in the nozzle and entrance to prevent exudation from the nozzle while the cavity is open. This exudation leads to premature flow of polymers into the cavity during thenext cycle which can lead to smearing of polymer C on the surfaces of the container.

1500 milliseconds marks the end of the injection phase of the machine cycle for this example. Subsequent to the end of the injection phase of the cycle, manifold valves 84, 85 are actuated and the ram cylinders 71 are recharged with theirpolymers by the plasticators 82. The injection mold is opened by retreating the hydraulic press 44 to withdraw the core pin 10 from the cavity 20. The parison just formed is transferred to one of the blow mold cavities 30A, 30B and the container whichwas blow molded simultaneously with the injection cycle is ejected from the blow mold in which it was finished.

FIG. 16 shows a nozzle 50 appropriate for injection of a parison having a three layer wall. Polymer B, which forms the outside surface layer, is delivered by the ram 70B to an annular exit distribution channel 54B which distributes the polymercircumferentially of the nozzle structure. Polymer B advances along a conical passage 56B to an annular exit orifice 58B at the exit of the nozzle which leads to the injection cavity. Similarly, polymer C, which forms the core layer, is delivered byram 70C to annular distribution channel 54C and thence along conical passage 56C to annular orifice 58C. Polymer A, which forms the inside surface layer, is delivered by the ram 70A to a passage 56A which exits through an exit orifice into the center ofthe concentric flows issuing from orifices 58B and 58C. A nozzle shut off valve 59 can be moved axially to arrest flow of polymer A.

FIGS. 17 and 18 compare the parison 60 as injection molded with the finished container. The neck portion 62 remains virtually unchanged during blow molding. The parison is held by the chilled neck portion while the hot and soft parison isblown. Thus, the neck 62 including the flange 64 is essentially formed in the injection mold. The remainder of the parison walls including the wall which forms the parison's bottom portion 61 which in turn forms the parison's closed end 63 are thinnedas the parison is stretched during blow molding.

FIG. 18 shows that the core layer C extends throughout the flange 64, but does not penetrate the flange edge. This is accomplished in large part by selection of the delay time in starting the ram for the core polymer. The flange 64 will beemployed in a double seam seal when a metal end is crimped, by well known techniques, onto the container mouth to close the filled container. Since the flange represents a significant area, it is important that the core layer extend well into theflange. The programmed flows of the various polymers also ensure that the core layer is not exposed at the sprue mark at the central exterior of the container.

FIG. 19 is an enlargement of the container wall within the circle of FIG. 18. Layer A is the inside surface layer formed from polymer A in the foregoing description. Layer B is the outside surface layer, formed from polymer B. Layer C is thecore or barrier layer formed from polymer C. The thinnest layer is the relatively expensive barrier polymer C. The relative thickness of the three layers is controlled by controlling the relative flow rates of the three polymers by microprocessor controlof the displacement rates of the rams. A preferred wall structure is a layer of a blend of high density polyethylene and polypropylene on each face of a core barrier layer of ethylene vinyl alcohol copolymer (EVOH).

FIG. 20 shows how the oxygen barrier quality of EVOH decreases abruptly at high levels of moisture. Where the EVOH layer is thin, only a small quantity of water will cause a large increase in oxygen permeability. For this reason, the EVOH layermust adequately be protected against the intrusion of moisture.

Polyolefins do not adhere well to EVOH. Adhesion can be improved by adding adhesion promotors to the polyolefin, the EVOH or both. Another approach is to provide an intermediate layer of an adherent polymeric material which adheres to thepolyolefin and the EVOH. Such materials include modified polyolefins sold under the name Plexar by the Chemplex Company of Rolling Meadows, Ill. These comprise a blend of a polyolefin and a graft copolymer of high density polyethylene and anunsaturated fused ring carboxylic acid anhydride. The polyolefin component of the blend can be polyethylene or preferably is an olefin copolymer such as ethylene vinyl acetate. Schroeder application Ser. No. 973,943 filed Dec. 28, 1978 U.S. Pat. No. 4,254,169 teaches the use of these materials to bond to EVOH. The materials themselves are disclosed in U.S. Pat. Nos. 4,087,587 and 4,087,588. We have found these modified polyolefins to be suitable as interlayers to improve adhesion betweenthe polyolefin surface layers and the EVOH core layer.

Another suitable material for use as an interlayer to improve adhesion between the EVOH polyolefins are maleic anhydride grafted polyolefins sold under the name Admer by Mitsui Petrochemical Industries of Tokyo, Japan.

The use of interlayers on each side of the EVOH oxygen barrier layer results in a five layer container. To produce such a container, the three passage nozzle of FIG. 16 is replaced with a five passage nozzle of similar construction. Where theinside and outside surface layers are of the same polymer one ram can be used for both those layers. The flow from that ram is divided and proportioned with part supplying the central axial passageway to form the inside surface layer and the balancesupplying the outermost nozzle annular orifice. The two additional nozzle orifices are located just inside and just outside the nozzle orifice for the EVOH barrier layer. The two additional annular nozzle orifices can be supplied with the interlayerpolymer from a single ram, the flow being divided and proportioned. Thus, a three ram machine can produce a five layer parison. Greater control can be exercised over the polymer flows by using a machine with an independently controllable ram for eachlayer. A nozzle shut off valve can be employed to selectively control the polymer flows. The three layers of interlayer polymer and the barrier polymer can be treated as a single core layer. A five layer wall is shown in FIG. 21 wherein layers A and Bare the inside and outside surface layers of polyolefin, layer C is the barrier layer of EVOH, and two layers D are the interlayer material.

EXAMPLE I

Five layer containers having a capacity of about 51/2 ounces, of 202.times.307 size, weighing about 11 g were made using a five orifice nozzle on a three ram machine. The inside and outside surface layers were polypropylenepolyethylene blockcopolymer (Hercules Profax 7631). The adhesive interlayers were ethylene vinyl acetate copolymer blended with a graft copolymer of high density polyethylene and a fused ring carboxylic acid anhydride (Plexar 1615-2). The oxygen barrier was EVOH(Kuraray EVAL EP-F, available from Kuraray Co. Ltd., Osaka, Japan). The layers were well adhered. The barrier extended to the flange lip and was completely encapsulated.

EXAMPLE II

Five layer containers similar to those of Example I were made wherein the inside and outside surface layers were polypropylene (EXXON E612); the interlayer material was Plexar III, a blend of ethylene vinyl acetate copolymer and a graftcopolymer; and the barrier was EVAL EP-F. The layers were well adhered. The barrier layer extended to the lip of the flange and was completely encapsulated.

EXAMPLE III

Five layer containers similar to those of Example I were made wherein the inside and outside surface layers were a 50--50 blend of polypropylene (EXXON E612) and high density polyethylene (Chemplex 5701); the interlayer material was Plexar III;and the barrier layer was EVAL EP-F. The layers were well adhered. The barrier layer extended to the lip of the flange and was completely encapsulated.

EXAMPLE IV

Five layer containers similar to those of Example I were made wherein the inside and outside surface layers were a copolymer of propylene and ethylene (Hercules Profax 7631); the interlayer material was maleic anhydride grafted polyolefin (mitsuiAdmer QB 530); and the barrier layer was EVAL EP-F. The layers were well adhered. The barrier layer extended to the lip of the flange and was completely encapsulated.

In the making of the containers of Examples I-IV the injection schedule began feeding the inside and outside surface layer polymer than the polymer for the adhesive interlayer was started and substantially simultaneously the barrier layer polymerwas started. The flows of the adhesive interlayer polymer and the barrier layer polymer were terminated before the outside surface layer polymer flow was terminated.