There are two profiles in your configuration, and this is typically what you want for playing FPS/TPS games (for having different sensitivity for ADS). First profile is active for hip fire, and second one for ADS (when right mouse button is pressed). The problem here is that you have a lot of button...

This is not a supported use case, controller emulations are only tested with consoles.
There is are at least two controller emulation that should work on computer: EMUJOYSTICKPS3 and EMUG27PC.
Since you want to emulate a controller, try the EMUJOYSTICKPS3 firmware.