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QL works perfectly for me in win8 in chrome/firefox, I haven't tested IE but know it can't work in metro IE as that doesn't support plugins.

The nvidia drivers that windows update automatically installs (currently 306.97) work perfectly on my 460 gtx, they give full openGL support. they are the same drivers that you get if you go to the nvidia driver website and select the current WHQL build.

You could also try with QLPrism - works like a charm for me now.
In the past I had many connection problems (ql would disconnect mid-game, and had to do a net_restart to solve it), but it seems that bug has been solved now
HTH