A Boy Like That/I Have A Love from West Side Story is featured in The First Time, the fifth episode of Season Three. It is sung by Rachel and Santana.

The song is performed in The April Rhodes Civic Pavilion, while rehearsals for the school production of West Side Story. It is split into two parts within the episode. The first part is edited into the scene between Blaine and Sebastian, showing Sebastian's personality, implying he can't be trusted and that Blaine can't fall into Sebastian's trap. The second part is entwined to where Tina talks about losing her virginity to Mike, talking about how it was the right time because it was with somebody that she really loved. Rachel realizes that Finn is the right person to lose her virginity to, because she loves him very much and she knows, he loves her just as much as she does.