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To add some­one to your Con­tacts list click the + sign and search for them by their name or num­ber, then click Add to Con­tacts. You can only call some­one (use the phone icon) in your con­tacts list if they’re shown as on­line. Click the video cam­era icon to start a video call. They’ll also need to click the video cam­era icon in Skype so you can see them, too.