Andrei Lugovoi and Dmitry Kovtun flew from Moscow to London on 16 October 2006. They checked into the Best Western hotel on Shaftesbury Avenue, the inquiry heard. They are accused of trying to poison Litvinenko for the first time later that day – and of succeeding two weeks later when they slipped radioactive polonium into his tea.

Giving evidence, the hotel’s manager, Goran Krgo, said he spotted Lugovoi and Kovtun the moment they arrived. “I remember these guests quite vividly,” he told the inquiry on Wednesday.

Asked to elaborate, he said: “We found them to be quite comical on account of how they were dressed and the excessive jewellery they were wearing.”

Krgo said he advised the two men to go to a nearby cafe since their rooms weren’t ready. They came back and checked in, reappearing in the lobby half an hour later, having swapped casual clothes for business gear.

“Kovtun was wearing a silver polyester suit and Lugovoi a dark grey check. They had colourful ties. We were laughing. The girl working behind the desk was amused and making comments.”

Krgo added: “The colours didn’t match. The suits were either too big or too small. They didn’t look like people used to wearing suits. They looked more like a donkey with a saddle.”

Det. Insp Craig Mascall of the Metropolitan police said forensic experts later found large quantities of polonium in both Lugovoi and Kovtun’s hotel rooms. In Lugovoi’s room, 107, the highest reading came from the bathroom plughole, leading to the suspicion he may have thrown the polonium away. Polonium was also found in Kovtun’s room, 308, on a chair and coat-hanger.

Later that afternoon, the pair met Litvinenko in the fourth-floor boardroom of Erinys, an oil and gas exploration company, in Mayfair.

Experts found “substantial contamination” here too, on chairs and a green fabric cover. On one corner of the table there was “full scale deflection” – an off-the-scale reading of alpha radiation.

The inquiry was told that there was no indication Litvinenko had been contaminated before his meeting with Lugovoi and Kovtun. The three men went for a meal at the Itsu sushi bar in Piccadilly, where polonium was also detected. Litvinenko threw up once that evening but survived this first botched assassination attempt, the inquiry heard.

More polonium was found in Pescatori, an Italian restaurant where Lugovoi and Kovtun ate that evening, clocking up a bill of £214.20. They had dinner with Alexander Shadrin, a Russian emigre.

They rounded off the night with a visit to Dar Marrakesh, a Moroccan restaurant. Polonium even turned up on the shisha pipe which Lugovoi smoked on its terrace.

Bozo assassins Andrei Lugovoi and Dmitry Kovtun

Call records showed that hours after trying to murder Litvinenko Lugovoi called “female A”, a woman whom he had “met informally” during one of numerous trips in 2006 to London. “Female A” declined to see him, Mascall said.

The following morning, Lugovoi and Kovtun left their hotel a day early and checked into the Parkes Hotel in Knightsbridge. Polonium was found in their new rooms.

The inquiry also heard that the Russian authorities deliberately blocked an attempt by British experts to examine the two aircraft used by Lugovoi and Kovtun to fly to and from London on 16 and 18 October 2006. The pair flew with the Russian carrier Transaero. Russia’s public health minister, Gennady Onischenko, assured the British embassy in Moscow that no radiation contamination was found on either plane.

Experts, however, managed to test the second London-Moscow plane at Heathrow airport. They discovered polonium traces on the seats – 26E and 26F – where Kovtun and Luovoi had been sitting. The Russian authorities then cancelled a scheduled flight to London of the other plane. It has since never come back to UK airspace.

A photograph taken by UK border police was released to the inquiry, showing Lugovoi and Kovtun arriving at Gatwick airport on 16 October.

Giving evidence, Det Con Spencer Scott said he stopped both men at immigration control. He said: “I thought they were of interest.”

He questioned them for 20 minutes. “They were very evasive as to why they were going to the UK,” he said, adding they “gave one-word answers”.

Scott said he let them enter the country after confirming that their business meeting was genuine. “I was given advice I should allow them to go through,” he said.

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