No, there is no direct bus from Madrid to Ljubljana. However, there are services departing from Madrid and arriving at Ljubljana Dalmatinova ulica via Venice Mestre Train Station. The journey, including transfers, takes approximately 35h 25m.

What companies run services between Madrid, Spain and Ljubljana, Slovenia?

Eurowings, Adria Airways and 11 other airlines fly from Madrid to Ljubljana hourly. Alternatively, you can take a bus from Madrid to Ljubljana via Mestre and Venice Mestre Train Station in around 35h 25m.

Based in Madrid, Renfe is a state-owned train operator, that connects cities across Spain and neighbouring countries including Portugal, France, Germany, Switzerland, and the Netherlands. Renfe’s extensive network means most destinations offer multiple trains a day, with the most popular routes normally offering a train each hour. Locally known as AVE, the high-speed trains can reach speeds of up to 350km/h, making travel between major cities very efficient. Comfort is key in a Renfe train, with seats with footrests in all three classes of travel: Standard, Club and First. Each seat has an individual light, a pull-down table and an electrical outlet for in Club and First classes. There is free WiFi for first class passengers and for those with a + Renfe card.

Loosely translated as the French National Railway Corporation, the SNCF is France’s state-owned railway company. It covers the country’s extensive rail network, as well as the TGV and Thalys, France’s two high-speed railway networks. With over 14,000 trains operating daily, it is a fast and efficient way of travelling around the country. The railway network consists of about 32,000km in total, of which 1800km are high-speed lines and 14,500km are electrified.

The primary train operator in Italy, Trenitalia was created in the year 2000. Trenitalia offers national rail connections in Italy as well as international connections to Austria, France, Germany and Switzerland. The company operates regional and long-distance trains, as well as high-speed trains called Frecce that travel on specialised tracks on speeds of up to 360km/h. Trenitalia tickets are available online, in stations across the country or from many travel agents that offer bookings.

One of Europe’s leading bus companies, Flixbus serves over 1400 destinations, in 26 countries including Germany, France, Italy, Austria, the Netherlands, Croatia, Spain, and across Scandinavia and central and eastern Europe. Founded in 2012, Flixbus’ extensive network connects cities with approximately 200,000 trips, with buses often departing every 30 minutes. One of the most affordable ways to get around Europe (and expanding soon into the US), a Flixbus journey is cost-effective, well-connected, comfortable and safe.

A Spanish subsidiary of National Express, ALSA provides bus and coach services across Spain and neighbouring countries including Portugal, France, Germany, the Netherlands, Italy, Poland and Malta. Founded in 1923, ALSA values service and the customer experience. Buses are equipped with communal TV screens showing movies, individual behind-seat screens, ALSA radio, app for books and music, and free WiFi so you’re never bored on your journey. ALSA services are accessible to people with disabilities, and guide dogs are welcome on all journeys. Flexibility is another highlight of an ALSA journey, with three types of tickets on offer - Frequent Traveller Pass, Share Pass and ALSA Pass, along with discounts for senior citizens, students and children.

Bus from Madrid to Padova

Want to know more about travelling around Slovenia

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Ljubljana is the capital and largest city of Slovenia. During antiquity, it was the site of a Roman city called Emona. It was under Habsburg rule from the Middle Ages until the dissolution of the Austro-Hungarian Empire in 1918.
- Wikipedia

Things to do in Ljubljana

Prešeren Square (Slovenian: Prešernov trg) is the central square in Ljubljana, the capital of Slovenia. It is part of the old town's pedestrian zone and a major meeting point, where festivals, Ljubljana carnival, concerts, sports, political, and protest events take place. It was renovated in 2007.

The Triple Bridge (Slovenian: Tromostovje, in older sources also Tromostje) is a group of three bridges across the Ljubljanica River. It connects the Ljubljana's historical, medieval, town on one bank, and the modern city of Ljubljana, capital of Slovenia, on the other.

The Dragon Bridge (Slovenian: Zmajski most, historically also Zmajev most) is a road bridge located in Ljubljana, the capital of Slovenia. It crosses the Ljubljanica River. between Kopitar Street (Kopitarjeva ulica) and Ressel Street (Resljeva cesta), to the north of the Ljubljana Central Market at Vodnik Square. It was built in the beginning of the 20th century, when Ljubljana was part of the Austro-Hungarian Monarchy. As one of the best examples of reinforced concrete bridges and of the Vienna Secession style, the bridge is today protected as a technical monument. It is intended primarily for motorised traffic.

Tivoli City Park (Slovenian: Mestni park Tivoli) or simply Tivoli Park (Park Tivoli) is the largest park in Ljubljana, the capital of Slovenia. It is located on the western outskirts of the Center District, stretching to the Šiška District to the north, the Vič District to the south, and the Rožnik District to the west. Several notable buildings and art works stand in the park. Since 1984, the park has been protected as part of Tivoli–Rožnik Hill–Šiška Hill Nature Park. It is home to a variety of bird species.

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Find all the transport options for your trip from Madrid to Ljubljana right here. Rome2rio displays up to date schedules, route maps, journey times and estimated fares from relevant transport operators, ensuring you can make an informed decision about which option will suit you best. Rome2rio also offers online bookings for selected operators, making reservations easy and straightforward.