tag:blogger.com,1999:blog-189086392018-05-29T00:35:32.373-07:00Tiny Gadget InspectorNews and information about Tiny Gadgets from a team of independent tech geeks.Rafa Minuhttp://www.blogger.com/profile/00633308632116989582noreply@blogger.comBlogger15125tag:blogger.com,1999:blog-18908639.post-41476839559596484852011-01-29T04:56:00.000-08:002011-01-31T05:15:41.836-08:00Hydrogen-Nanobead-Based Synthetic Gas<div class="separator" style="clear: both; text-align: center;"><a href="http://www.cellaenergy.com/" imageanchor="1" style="clear: right; float: right; margin-bottom: 1em; margin-left: 1em;"><img border="0" height="172" src="http://4.bp.blogspot.com/_KUfXolaT_Dk/TUQMt7XyLAI/AAAAAAAAAt0/-gEGeUW9hNY/s200/CellaEnergy_logo.jpg" width="200" /></a></div><b><a href="http://www.cellaenergy.com/">Cella Energy</a></b> claims to have invented a hydrogen-based synthetic fuel that could replace gasoline in cars, and lead to US$1.50 per gallon gasoline. Hydrogen is the most abundant element in the Universe, but the challenge on our planet has been making and storing hydrogen safely. We can use hydrogen in fuel cell systems where the only emissions are water. We can also convert regular gasoline cars or aircraft jet-engines to hydrogen with minimal modifications. If we burn hydrogen instead of fossil fuels in internal combustion engines or in jet-engines there are no carbon emissions.<br /><br />This new technology has been&nbsp;researched&nbsp;entirely in the UK, and is based on complex hydrides that are highly unstable, usually degrading rapidly in air. In simpler words, it is a nanotech-driven method that encapsulates hydrogen at usable concentrations in micro-capsules, allowing it to be handled and burned in conventional engines without the need to store it in dangerous high-pressure tanks or super-cooled environments. <br /><br />According to Cella’s website:<br /><blockquote>Cella Energy have developed a method using a low-cost process called coaxial electrospinning or electrospraying that can trap a complex chemical hydride inside a nano-porous polymer that speeds up the kinetics of hydrogen desorption, reduces the temperature at which the desorption occurs and filters out many if not all of the damaging chemicals. It also protects the hydrides from oxygen and water, making it possible to handle it in air.</blockquote><br />Fundamental to the widespread introduction of hydrogen technologies is a low-cost, practical way of storing hydrogen. This is particularly challenging for transport applications, which places stringent requirements on cost, safety, volume and weight. Hydrogen storage is also vital for the smart-grid to operate effectively.<br /><br /><center><br /><iframe title="YouTube video player" class="youtube-player" type="text/html" width="560" height="345" src="http://www.youtube.com/embed/KVPtLrKis0M" frameborder="0" allowFullScreen></iframe><br /></center><br /><br /><b>Features and Benefits of the hydrogen-based synthetic fuel:</b><br /><br /><ul><li>low-pressure</li><li>safe</li><li>ambient temperatures</li><li>rapid desorption of hydrogen</li><li>pure hydrogen</li><li>can be handled safely in the open air</li><li>increases revenue for customer</li><li>fast introduction into market</li><li>saves money and time on packaging</li><li>end customer can travel further without refuelling</li></ul><br /><br /><hr /><b>More Info:</b><br /><ul><li><b><span class="Apple-style-span" style="font-weight: normal;"><a href="http://www.cellaenergy.com/">http://www.cellaenergy.com/</a></span></b></li><li><b><span class="Apple-style-span" style="-webkit-text-decorations-in-effect: underline; color: #0000ee; font-weight: normal;"><a href="http://www.gizmag.com/breakthrough-promises-150-per-gallon-synthetic-gasoline-with-no-carbon-emissions/17687/">http://www.gizmag.com/</a></span></b></li></ul><b> </b><div class="blogger-post-footer"><script type="text/javascript"><!--
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The work is described in <i>Nature Nanotechnology</i>, published online December 20, 2009. <br />The Brookhaven team, led by physicist Oleg Gang, has been refining techniques to use strands of artificial DNA as a highly specific kind of Velcro or glue to link up <a href="http://www.bnl.gov/bnlweb/pubaf/pr/PR_display.asp?prID=921">nanoparticles</a>. Such DNA-based self-assembly holds promise for the rational design of a range of new materials for applications in molecular separation, electronics, energy conversion, and other fields. But none of these structures has had the ability to change in a programmable manner in response to molecular stimuli — until now.<br /><table align="center"><tbody><tr><td><div class="pic_center" style="width: 600px;"><a href="http://www.bnl.gov/bnlweb/pubaf/pr/photos/2009%5C12%5CNanostructures-300.jpg" target="_blank"><img alt="Illustrations show how a 3-D crystal made from nanoparticles changes between two distinct states" border="0" src="http://www.bnl.gov/bnlweb/pubaf/pr/photos/2009%5C12%5CNanostructures-600px.jpg" /></a><div class="captionNoPad"><a href="http://www.bnl.gov/bnlweb/pubaf/pr/photos/2009%5C12%5CNanostructures-300.jpg" target="_blank"><img alt="Click on the image to download a high-resolution version." border="0" src="http://www.bnl.gov/common/images/enlarge.gif" style="float: right; margin-left: 10px;" /></a>These illustrations show how a 3-D crystal made from nanoparticles changes between two distinct states via an intermediate structure (top row, middle) when looped (left) versus unlooped (right) double-stranded DNA chains are used to link the particles. The scientists were able to measure the distance between the particles in each structure by recording x-ray scattering patterns (bottom row). Switching from looped to unlooped DNA increased the interparticle distance by about 6 nanometers.<br /></div></div></td></tr></tbody></table>“Now we’re using a special type of DNA-linking device — a kind of ‘smart glue’ — that affects how the particles connect to make structures that are switchable between different configurations,” says Gang. This reliable, reversible switching could be used to regulate functional properties — for example, a material’s fluorescence and energy transfer properties — to make new materials that are responsive to changing conditions, or to alter their functions on demand.<br />Such responsiveness to changes in environmental conditions and the ability to adopt new forms are hallmarks of living systems. In that way, these new nanomaterials more closely mimic biological systems than any previous nanostructures. Though far from any form of truly “artificial life,” these materials could lead to the design of nanoscale machines that, at a very simple level, mimic cellular processes such as converting sunlight into useful energy, or sensing the presence of other molecules. Responsive materials would also have benefits in the field of optics or to produce regulated porous materials for molecular separations, Gang says.<br />The scientists achieved the goal of responsiveness by creating structures where the distance between nanoparticles could be carefully controlled with nanometer accuracy.<br />“Many physical characteristics of nanomaterials, such as optical and magnetic properties, are strongly dependent on the distance between nanoparticles,” Gang explains.<br />In their previous studies, the scientists used single strands of DNA attached to individual nanoparticles as linker molecules. When the free ends of these DNA strands had complementary genetic code, they would bind to attach the particles. Constraining the interactions by anchoring some of the particles on a surface allowed the scientists to reliably form a variety of structures from two-particle clusters (called dimers) to more complex 3-D nanoparticle crystals.<br />In the new work, the scientists have added more complicated double-stranded DNA structures. Unlike the single strands, which coil in uncontrollable ways, these double-stranded structures are more rigid and therefore constrain the interparticle distances.<br />Additionally, some of the strands making up the double-stranded DNA molecules have complicated structures such as loops, which pull the bound particles closer together than when both strands are exactly parallel. By varying the type of DNA device, between looped and unlooped strands, and measuring the interparticle distances using precision techniques at Brookhaven’s National Synchrotron Light Source (NSLS) and at the Center for Functional Nanomaterials (CFN), the scientists demonstrated that they could effectively control the distance between the particles and switch the system from one state to another at will.<br />The approach resulted in two-configuration, switchable systems both in dimers and nanocrystals, with a distance change of about 6 nanometers — about 25 percent of the interparticle distance. By comparing kinetics in the two systems, they found that the switching between states is faster in the simpler, two-particle system. The dimers also retain their ability to return to their initial state more precisely than the 3-D crystals, suggesting that molecular crowding may be an issue to further investigate in the 3-D materials.<br />“Our hope is that the ability to induce post-assembly reorganization of these structures by adding DNA or other molecules as external stimuli, and our ability to observe these changes with nanometer resolution, will help us understand these processes and find ways to apply them in new kinds of nanomachinery in which the system’s functionality is determined by the nanoparticles and their relative organization,” says Gang.<br />Future studies will make use of precise imaging capabilities, such as advanced electron microscopy tools at the CFN and higher-resolution x-ray techniques that will become available at Brookhaven’s new light source, NSLS-II, now under construction.<br />Gang’s collaborators on this work include Brookhaven colleagues Mudalige Kumara, Dmytro Nykypanchuk and William Sherman, as well as Mathew Maye, a former Brookhaven chemist now at Syracuse University. The research was funded by the DOE Office of Science, by a Laboratory Directed Research and Development grant, and by a Goldhaber Distinguished Fellowship. Brookhaven Science Associates, which manages Brookhaven Lab, has filed patent applications related to this work. For information about these patents and licensing opportunities, contact Kimberley Elcess, <a href="mailto:elcess@bnl.gov">elcess@bnl.gov</a>, 631 344-4151.<br />Upon publication, the paper will be available at: <a href="http://dx.doi.org/10.1038/NNANO.2009.378" target="_blank">http://dx.doi.org/10.1038/NNANO.2009.378</a>.<br /><i>The Center for Functional Nanomaterials at Brookhaven National Laboratory is one of the five DOE Nanoscale Science Research Centers (NSRCs), premier national user facilities for interdisciplinary research at the nanoscale. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE’s Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge and Sandia and Los Alamos national laboratories. For more information about the DOE NSRCs, please visit <a href="http://nano.energy.gov/" target="_blank">http://nano.energy.gov</a>.</i><br /><strong>Related Links</strong><br /><ul><li><a href="http://www.bnl.gov/bnlweb/pubaf/pr/PR_display.asp?prID=921">DNA-Based Assembly Line for Precision Nano-Cluster Construction</a></li><li><a href="http://www.bnl.gov/bnlweb/pubaf/pr/PR_display.asp?prID=07-127">DNA Technique Yields 3-D Crystalline Organization of Nanoparticles</a></li><li><a href="http://www.bnl.gov/bnlweb/pubaf/pr/PR_display.asp?prID=07-94">New DNA-Based Technique For Assembly of Nano- and Micro-sized Particles</a></li><li><a href="http://www.bnl.gov/bnlweb/pubaf/pr/PR_display.asp?prID=06-112">Nanoparticle Assembly Enters the Fast Lane</a></li></ul><div class="blogger-post-footer"><script type="text/javascript"><!--
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See Part 15, Subpart B, of the Federal Register (CFR 47, Parts 0-19).</div></td></tr></tbody></table></td></tr></tbody></table></td></tr></tbody></table><br /><hr /><br /><table border="0" cellpadding="0" cellspacing="0" width="100%"><tbody><tr><td rowspan="2" align="center" valign="top" width="50%"><img src="http://gumstix.com/store/catalog/images/prd_waysmall200ax.jpg" usemap="#Map" border="0" height="271" width="300" /><br /></td> <td rowspan="2" valign="top"><img src="http://gumstix.com/store/catalog/images/spacer.gif" height="1" width="20" /></td> <td height="201" valign="top"><table align="center" border="0" cellpadding="5" cellspacing="0" width="350"> <tbody><tr> <td class="descrp-largbld" height="50">way small and way versatile!</td> </tr> <tr> <td><table border="0" cellpadding="3" cellspacing="0" width="100%"> <tbody><tr> <td class="descrp" align="right" valign="top" width="115"><strong>Motherboard:</strong></td> <td class="descrp" valign="top" width="217"> gumstix basix motherboard</td> </tr> <tr> <td class="descrp" align="right" valign="top"><strong>Processor:</strong></td> <td class="descrp" valign="top">Intel XScale® PXA255 </td> </tr> <tr> <td class="descrp" align="right" valign="top"><strong>Speed:</strong></td> <td class="descrp" valign="top">200MHz</td> </tr> <tr> <td class="descrp" height="20" valign="top"><div align="right"><strong>Memory:</strong></div></td> <td class="descrp" height="20" valign="top">64MB RAM and 4MB Flash</td> </tr> <tr class="descrp"> <td height="20" valign="top" width="115"><div align="right"><strong>Connection:</strong></div></td> <td height="20" valign="top" width="217"> <p>2 serial ports<br />USB client - mini-B socket</p></td> </tr> <tr> <td class="descrp" height="20" valign="top"><div align="right"><strong>Software:</strong></div></td> <td class="descrp" height="20" valign="top">Latest Linux 2.6 and <a href="http://docwiki.gumstix.org/Software#Which_software_has_been_pre-loaded_onto_the_flash_of_the_gumstix_platform_.28basix_and_connex.29.3F" target="_blank">more</a></td> </tr> <tr class="descrp"> <td height="20" valign="top"><div align="right"><strong>Power:</strong></div> </td> <td height="20" valign="top">Standard 3.5V - 6V input<br />(power adapter included)</td></tr></tbody></table></td></tr></tbody></table></td></tr></tbody></table><br /><hr />Gumstix is a technology company that designs, builds and sells full function miniature computers and related Linux systems for customers in over 60 countries worldwide.<hr /><span style="font-weight: bold;">More Info:</span>:<br /><a href="http://www.gumstix.com/">Gumstix</a><div class="blogger-post-footer"><script type="text/javascript"><!--
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While ground-breaking, it is visible until today that this technology came out of a (research and market) environment with a lot of fascination for spearhead efficiencies and little regard for cost and the ratio between cost and efficiency. Despite continued incremental improvements, silicon-wafer based cells are fundamentally limited by high materials cost and poor capital efficiency. Because silicon wafers do not absorb light very strongly, silicon cells intrinsically require large amounts of semiconductor material. And because wafers are fragile, their handling is intricate and limits achievable process throughput, with the result being poor cost efficiency.<br /><br /></li><li>The Second Wave came about a decade ago with the arrival of the first commercial thin-film solar cells. This established that new non-silicon semiconductor materials could dramatically reduce the materials cost of solar cells, with the absorber of such cells being two orders of magnitude thinner than that of silicon wafer cells. However, it turned out that this was not enough to make a fundamental difference in the cost efficiency of solar panels overall: the challenge resided in yield and throughput limits of vacuum based thin-film deposition techniques, which resulted in high process cost. As a result, none of the many thin-film efforts based on vacuum deposition was ever able to produce products more than only marginally less expensive than ever-improving silicon cells.<br /><br /></li><li>The Third Wave of Solar Power brings together several fundamental technology innovations that build on the unmet potential of the Second Wave while more than addressing its limitations. The result of these patented and patent-pending innovations is a dramatic improvement in the cost-efficiency, yield, and throughput of the production of thin-film solar cells.</li></ol><a onblur="try {parent.deselectBloggerImageGracefully();} catch(e) {}" href="http://3.bp.blogspot.com/_UNVmFaf_we4/RunC2IXLllI/AAAAAAAAAC8/-gIBPujVE4s/s1600-h/nano_solar_cells.jpg"><img style="margin: 0pt 0pt 10px 10px; float: right; cursor: pointer;" src="http://3.bp.blogspot.com/_UNVmFaf_we4/RunC2IXLllI/AAAAAAAAAC8/-gIBPujVE4s/s200/nano_solar_cells.jpg" alt="Molecules" id="BLOGGER_PHOTO_ID_5109829487441974866" border="0" /></a><br />The ability to architect and assemble materials on a nanometer scale now makes it possible to optimize solar cells at the very length scale at which the relevant photovoltaic semiconductor quantum-physics occurs.<br /><br />Molecular self-assembly techniques for instance now give us the unprecedented capability of designing and creating nanostructured materials with novel properties. <br />Such techniques generally rely on formulas that control the precise, bottom-up chemical assembly of molecules into geometric structures composed of many molecules, e.g. in the 1nm to 100nm range.<br /><br /><br /><center><object height="350" width="425"><param name="movie" value="http://www.youtube.com/v/4riNlqZHCTQ"><param name="wmode" value="transparent"><embed src="http://www.youtube.com/v/4riNlqZHCTQ" type="application/x-shockwave-flash" wmode="transparent" height="350" width="425"></embed></object></center><br /><br /><br /><span style="font-weight: bold;">More Info</span>:<br /><a href="http://www.nanosolar.com/rolltoroll.htm">Nanosolar</a><div class="blogger-post-footer"><script type="text/javascript"><!--
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