GLYCOLURILS IN α-UREIDO- AND α-AMINOALKYLATION REACTIONS. 3. N-(HYDROXYMETHYL)GLYCOLURILS IN REACTIONS WITH ALIPHATIC AMINES AND AMINO ACIDS

А. Н. Кравченко, И. Е. Чикунов, К. А. Лысенко, В. В. Баранов

Abstract

The condensation of aliphatic alkylamines and achiral amino acids with 1,5-butano-2,4,6,8-tetra-(hydroxymethyl)- and 2,4,6,8-tetra(hydroxymethyl)glycolurils was used to prepare and characterize polycyclic condensed compounds (including some previously unknown examples) containing glycoluril and alkylamine fragments. X-ray structural study of the obtained compounds was used to identify n(N)→s(C–H) anomeric interaction.