An aqueous liquid cleansing and moisturising composition comprising a surface active agent selected from anionic, nonionic, zwitterionic and cationic surface active agents and mixtures thereof; an benefit agent having a weight average particle size in the range 50 to 500 microns; and a thickening agent. The thickening agent is added to the benefit agent in amount from 1 to 50% wt, based on the benefit agent.

3. A composition according to claim 1 wherein the composition is structured with a structurant selected from the group consisting of swelling clays; cross-linked polyacrylates; acrylates and copolymers thereof; polyvinylpyrrolidone andcopolymers thereof; polyethylene imines; salts; sucrose esters; and gellants.

5. A composition according to claim 1 comprising 0.1 to 15 wt % of the benefit agent.

6. A composition according to claim 1 wherein the benefit agent functions as a carrier to deliver efficacy agents to skin treated with the composition.

7. A composition according to claim 1 comprising 1 to 35 wt % of the surface active agent.

8. A composition according to claim 1 further comprising a cosurfactant selected from the group consisting of betaines, amidobetaines and sulphobetaines.

9. A process for preparing a composition according to claim 1, comprises:

(a) forming a base composition comprising at least one surface active agent selected from the group consisting of anionic, nonionic, zwitterionic and cationic surface active agents and mixtures thereof and less than one percent by weight solidsoap;

(b) adding a thickening agent to the benefit agent in an amount from 1 to 50 wt. %, based on the benefit agent; and

(c) mixing the base formulation of step (a) with the benefit agent.

10. A method of depositing a benefit agent from an aqueous liquid cleansing and moisturizing composition, the method comprising providing the said benefit agent in a composition comprising:

(b) a benefit agent having a weight average particle size in the range 50 to 500 microns;

(c) a thickening agent, wherein the thickening agent is added to the benefit agent in amount from 1 to 50% wt., based on the benefit agent; and

(d) less than one percent by weight solid soap.

Description:

The present invention relates to detergent compositions suitable for care and personal washing of the skin. In particular, it relates tocompositions which are formulated to give mild cleansing and conditioning of the skin.

Compositions formulated to cleanse the skin are well known. It is also known to formulate products which provide both a cleansing and a moisturising benefit.

One of the problems which may be encountered with such dual purpose compositions is that, whilst cleansing may be effective, there is an insufficient level of moisturising.

We have found a way of formulating such compositions such that they can deliver effective moisturising, conditioning or protection of the skin.

In WO 94/01085 and 94/01084 the advantage of depositing large particles of petrolatum from soap based compositions is recognised.

However, according to WO 94/03152, concerned with shower gels comprising, a non-soap detergent, silicone oil added to condition the skin and cationic polymers, the maximum average droplet size of the silicone oil that can be used is 2 microns, ifproduct stability is to be maintained.

We have now found that larger particles, by particle is meant a solid particle or liquid droplet, of benefit agent can be incorporated into non-soap based compositions and effective delivery of the benefit agent can be achieved if the benefitagent is thickened.

Thus, according to the invention there is provided an aqueous liquid cleansing and moisturising composition comprising:

b) an benefit agent having a weight average particle size in the range 50 to 500 microns; and

c) a thickening agent,

wherein the thickening agent is added to the benefit agent in amount from 1 to 50 wt % based on the benefit agent.

The composition is suitable for cleansing and "moisturising", "conditioning" or "protection" of the skin. The benefit agent is included in the composition to moisturise, condition and/or protect the skin. By "benefit agent" is meant a substancethat softens the skin (stratum corneum) and keeps it soft by retarding the decrease of its water content and/or protects the skin.

The benefit agent may be incorporated in a carrier in the compositions of the invention, particularly if it is likely to suffer detrimental interactions with other components of the composition. Benefit agents for which such detrimentalinteractions may occur include lipids; alkyl lactates; sunscreens; esters such as isopropyl palmitate and isopropyl myristate; and vitamins. The carrier can, for example, be a silicone or hydrocarbon oil which is not solubilised/micellised by thesurface active phase and in which the benefit agent is relatively soluble.

The benefit agent is preferably present in amount of from 0.1 to 15 wt %, most preferably from 0.2 to 10 wt %, more. preferably from 0.5 to 7 wt %.

An advantage of the composition according to the invention is that, during use, it deposits benefit agent onto the skin at a level which results in a perceivable benefit. Without being bound by theory, it is believed the benefit agent isdispersed into large pools during dilution of the composition in use and these pools deposit readily onto the skin.

In WO 94/01084 and WO 94/01085 the composition are structured by the presence of at least 5% insoluble solid fatty acid soap. However, it is believed that such high levels of solid phase material may adversely affect the amount of benefit agentdeposited onto the skin. Thus, in the present invention it is preferred that the composition is substantially free of solid soap, by which is meant the level of solid soap is below 1 wt %.

Whilst some materials can function as both a benefit agent and a thickener therefor it will be appreciated that the benefit and thickening function cannot be provided by the same component. However, it will be understood that where thecomposition comprises two or more benefit agents one of said benefit agents could also function as a thickening agent.

Preferably the amount of thickening agent is from 4 to 25% wt based on the level of benefit agent.

Although the compositions of the invention may be self-structuring preferably they will also comprise a structurant, i.e. a material added to increase the viscosity at zero shear. Suitable materials include swelling clays, for example laponite;fatty acids and derivatives hereof and, in particular fatty acid monoglyceride polyglycol ethers; cross-linked polyacrylates such as Carbopol (.TM.) (polymers available from Goodrich); acrylates and copolymers thereof, polyvinylpyrrolidone and copolymersthereof; polyethylene imines; salts such as sodium chloride and ammonium sulphate; sucrose esters; gellants; and mixtures thereof.

Of the clays particularly preferred are synthetic hectorite (laponite) clay used in conjunction with an electrolyte salt capable of causing the clay to thicken. Suitable electrolytes include alkali and alkaline earth salts such as halides,ammonium salts and sulphates.

The compositions according to the invention may also comprise a thickening agent in addition to the thickening agent added to the benefit agent, i.e. a material which maintains the viscosity of the composition as the shear rate thereof isincreased during use. Suitable materials include cross-linked polyacrylates such as Carbopol (.TM.) (polymers available from Goodrich); fatty acids and derivatives thereof and, in particular, fatty acid monoglyceride polyglycol ethers; natural gumsincluding alginates, guar, xanthan and polysaccharide derivatives including carboxy methyl cellulose and hydroxypropyl guar; propylene glycols and propylene glycol oleates; salts such as sodium chloride and ammonium sulphate; glycerol tallowates; andmixtures thereof.

Further examples of structurants and thickeners are given in the International Cosmetic Ingredient Dictionary, Fifth Edition, 1993, published by CTFA (The Cosmetic, Toiletry & Fragrance Association), incorporated herein by reference.

The surface active agent Can be selected from any known surfactant suitable for topical application to the human body. Mild surfactants, i.e. surfactants which do not damage the stratum corneum, the outer layer of skin, are particularlypreferred.

One preferred anionic detergent is fatty acyl isethionate of formula:

where R is an alkyl or alkenyl group of 7 to 21 carbon atoms and M is a solubilising cation such as sodium, potassium, ammonium or substituted ammonium. Preferably at least three quarters of the RCO groups have 12 to 18 carbon atoms and may bederived from coconut, palm or a coconut/palm blend.

Another preferred anionic detergent is alkyl ether sulphate of formula:

where R is an alkyl group of 8 to 22 carbon atoms, n ranges from 0.5 to 10, especially from 1.5 to 8, and M is a solubilising cation as defined above.

Mixtures of any of the foregoing surface active agents may also be used.

The surface active agent is preferably present at a level of from 1 to 35 wt %, preferably 3 to 30 wt %.

It is also preferable that the composition includes from 0.5 to 15 wt % of a cosurfactant agent with skin-mildness benefits. Suitable materials are zwitterionic detergents which have an alkyl or alkenyl group of 7 to 18 carbon atoms and complywith an overall structural formula: ##STR1## where R.sup.1 is alkyl or alkenyl of 7 to 18 carbon atoms; R.sup.2 and R.sup.3 are each independently alkyl, hydroxyalkyl or carboxyalkyl of 1 to 3 carbon atoms;

m is 2 to 4;

n is 0 or 1;

X is alkylene of 1 to 3 carbon atoms optionally substituted with hydroxyl, and

Y is --CO.sub.2.sup.- or --SO.sub.3.sup.-.

Zwitterionic detergents within the above general formula include simple betaines of formula: ##STR2## and amido betaines of formula: ##STR3## where m is 2 or 3.

In both formulae R.sup.1, R.sup.2 and R.sup.3 are as defined previously. R.sup.1 may, in particular, be a mixture of C.sub.12 and C.sub.14 alkyl groups derived from coconut so that at least half, preferably, at least three quarter of the groupsR.sup.1 has 10 to 14 carbon atoms. R.sup.2 and R.sup.3 are preferably methyl.

A further possibility is a sulphobetaine of formula: ##STR4## where m is 2 or 3, or variants of these in which --(CH.sub.2).sub.3 SO.sub.3.sup.- is replaced by ##STR5## R.sup.1, R.sup.2 and R.sup.3 in these formulae are as defined previously.

Furthermore, the benefit agent may also function as a carrier to deliver efficacy agents to skin treated with the compositions of the invention. This route is particularly useful for delivering efficacy agents which are difficult to deposit ontothe skin or those which suffer detrimental interactions with other components in the composition. In such cases the carrier is a often a silicone or hydrocarbon oil which is not solubilised/micellised by the surface active phase and in which theefficacy agent is relatively soluble. Examples of such efficacy agents include anti-viral agents; hydroxycaprylic acids; pyrrolidone; carboxylic acids; 2,4,4'-trichloro-2'-hydroxydiphenyl ether (Irgasan DP300); 3,4,4'-trichlorocarbanilide; salicylicacid; benzoyl peroxide; perfumes; essential oils; germicides and insect repellants such as N,N-dimethyl m-toluamide (DEET); and mixtures thereof.

Compositions of the invention may be formulated as products for washing the skin, for example bath or shower gels, hand washing compositions, facial washing liquids; pre-and post-shaving products; rinse-off, wipe-off and leave-on skin-careproducts.

The compositions of the invention will generally be pourable liquids or semi-liquids eg pastes and will preferably have a viscosity in the range 1000 to 100,000 mPas measured at a shear rate 10 s.sup.-1 and 25.degree. C. in a HaakeRotoviscometer RV20.

The compositions of the invention will preferably exhibit a Newtonian viscosity at a shear stress of 0.01 Pa, at 25.degree. C., of at least 5,000 Pas, preferably greater than 10,000 Pas.

The above-mentioned characteristic viscosity measurements may be determined exactly (as in the case of the non-zero shear viscosities) using, for example a Carrimed CSL 100 low stress rheometer or obtained from an extrapolation according to theCross Model, (see J of the Chemical Engineer, 1993, paper entitled "Rheology for the Chemical Engineer" by H. Barnes) as in the case of zero shear rate.

In this example, the effect of thickening a silicone oil benefit agent with silica on the deposition of silicone oil onto the skin was examined.

The following method was used to determine the amount of benefit agent deposited onto full thickness porcine skin (5 .times.15 cm) treated with compositions according to the invention.

The skin was prehydrated and then 0.5 ml of the product applied to it. The product was lathered for 10 seconds and then rinsed for 10 seconds under running water.

Thereafter the skin was wiped once with a paper towel to remove excess water.

2 minutes after drying a strip of adhesive tape was pressed onto the skin for 30 seconds by applying a constant load of 100 g.cm.sup.-2. The adhesive tape employed was J-Lar Superclear (.TM.) tape having a width of 2.5 cm. In total ten stripsof tape were applied to adjacent sites on the skin.

In this test procedure silicone which has deposited on the skin will subsequently be transferred to the tape along with some of the outer layer of the skin.

The amounts of silicon and skin adhering to the tape are determined by means of X-ray fluorescence spectroscopy.

The tape strips are placed in an X-ray fluorescence spectrometer with the adhesive side facing the beam of this machine. A mask is applied over the tape to define a standardised area in the middle of the tape which is exposed to the X-ray beam. The sample chamber of the machine is placed under vacuum before making measurements and the spectrometer is then used to measure the quantities of silicon and sulphur. The sulphur is representative of the amount of skin which has transferred to thetape.

The amounts of silicon and sulphur observed with a clean piece of adhesive tape are subtracted from the experimental measurements. The experimental measurements for the average levels of sulphur and silicon are expressed as a ratio of silicon tosulphur. From this ratio it is possible to determine silicone oil-deposition per unit area of skin.

A base shower gel formulation having the following composition was prepared.

The composition was prepared by dispersing the polyacrylate in excess water. Thereafter sorbic acid and trisodium citrate dihydrate were added to the resulting polymer dispersion. The three surface active agents were mixed and the resulting mixadded to the polymer dispersion. Thereafter minors were added. The viscosity of the resulting composition was measured at a shear rate of 10 s.sup.-1 at 25.degree. C. and thickener added until the required viscosity obtained.

Two Harvard 44 syringe pumps were used to infuse the base formulation and the benefit agent, silicone oil. Silicone oil was present at a level of 5 wt % based on the total composition. One syringe was filled with the base formulation and theother with silicone oil. The syringes were then inserted into the syringe pump and the infusion rate set at 5:95 oil:base. The oil and base were forced through a static in-line mixer and a composition with oil particles of the required size obtained. The size of the particles can be controlled by the diameter of the static mixer, the flow rate and length of the mixer tube. The size of the particles can be determined using a Malvern Mastersizer.

Silicone deposition from the compositions according to the invention was measured by the test procedure described above and compared with that from a similar composition (A) comprising a silicone oil emulsion having a viscosity of 60000 mPas at10 s.sup.-1 and 25.degree. C.

The results demonstrate the advantage, in terms of deposition of silicone, using a composition comprising a thickened silicone oil over a composition comprising a unthickened silicone oil.

Example II

Example I was repeated except that the benefit agent used was IPP (isopropylpalmitate). The IPP was thickened with three different thickeners at a level of 10% by weight based on the IPP.

The following method was used to determine the amount of IPP deposited onto full thickness porcine skin (5.times.15 cm pieces) treated with compositions according to the invention. The skin was treated and washed with the compositions accordingto the invention by the same method as described for example I. Thereafter the skin was extracted with ethanol three times (3 ml per extract) and the extract made up to 10 g and submitted for Gas Chromatography analysis to determine the amount of IPPdeposited.

The results demonstrate the increased deposition of IPP obtained when the IPP is thickened.

Example III

In this example the benefit agent used was lauryl lactate.

The following method was used to determine the amount of lauryl lactate deposited onto skin treated with compositions according to the invention containing lauryl lactate.

Porcine full thickness skin was prehydrated and then 0.20 g of the product and 0.8 g of water applied to it. The skin was washed for 30 seconds and then rinsed for 10 seconds under running water.

Thereafter the skin was wiped once with a paper towel to remove excess water. 30 seconds after drying 5 strips of Desquame tape were applied to the skin sequentially for 10 seconds.

The strips were then removed from the skin and hydrolysed in 2 ml of NaOH (0.5M) at 60.degree. C. for 60 minutes. They were then neutralised with 2 ml HCl (0.5M) and in Sorensens phosphate buffer (pH 7.0). The total lauryl lactate and theprotein content of the tapes, representative of the lauryl lactate transferred to the skin, was determined using Sigma diagnostic assay Kits 735/10 and 690. A solution containing the assay and treated strips was prepared and the absorbance at 540 nmmeasured in a UV spectrometer.

In a separate set of experiments, but with the same base formulation as described above, the effect of a range of thickening agents (all at a level of 5% wt based on the lauryl lactate) on the deposition of lauryl lactate was examined. Thelauryl lactate or thickened lauryl lactate was added to the base formulation at a level of 5wt %.