Hi,
Primarily this problem comes due to wrong insertion of message center no, or in rare case software corruption. So call the your network operator and ask them to give the message center no, and insert that no. manually in message settings...
Hope this has helped you...
Thanks...

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Quicker SMS is a software which allows you to send SMS on your PC. You can type SMS on your keyboard quicker than do it on your BlackBerry phone. Especially, it is very useful when you want to send group SMS to your friends. It is an effective tool to improve your efficiency and save your time.Visit http://www.joege.com to get latest version.

At the same time, Quicker SMS can receive new SMS from your BlackBerry phone whenever the phone is connected with it. You can save SMS from your friends on the disk permanently and forward to others easily. It supports importing all contacts in your BlackBerry phone. So you can select contacts quickly when you want to send SMS. When new SMS is coming, it will be showed on the main screen of the phone(see picture below). This function can works without PC client porgram(in trial version, this function works forever and it is free).
Key features

Send SMS to many friends from your address book by one click.

Send timed SMS to friends in the future.

Show new SMS notification dialog on PC desktop from your BlackBerry phone when it connects with Quicker SMS.

Show new SMS notification dialog on BlackBerry’s main screen(This feature can be used without PC client program. It likes MsgShow、PeekaWho. When new SMS is coming, phone number, name(if phone number is in your contacts) and full SMS content will be showed in notification dialog.).

take out your battery, sim and memory stick..
then turn it off for 5 minutes, then turn in on without inserting the memory stick.
after that try sending sms again, if it delivered,then try it with memory stick.
if u can send sms,then its ok..but if cant then your memory sticks got a problem.my suggestion is to format the memory stick..