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I am not saying that to be flip - Dreamweaver is a terrible place to learn PHP. It has some of the worst code I have ever seen, and was never meant to be a teaching example. So when you start by following Dreamweaver's model you put yourself at a disadvantage right away.

This little book will help you learn the PHP and MySQL part of things correctly. As you come to understand how those parts work together (instead of just trying to model your programming on Dreamweaver) you will be way ahead in your programming, I promise.http://www.sitepoint.com/books/phpmysql4/

It's a great investment - a little money, a little time, and a lot of knowledge. Best of luck with your project. ~Ray