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I seem to remember there was only one ferry when I was there. Erturk I think. I bought the tickets from their office right on the front at Cesme. It goes around 5pm. It only takes one hour or less and it's not a big ferry. You have to walk about 5 minutes along the harbour at Cesme to find it and likewise when you get to Chios it's a few minutes' walk into the town. Can't remember the cost; it wasn't much but I was just a foot passenger.