The synthesis of chiral compounds is one of the major tasks of today's organic chemists. Besides of auxilliary-based methods, the application of catalysts plays a major role for example in the industrial production of drugs. In this context not only the chiral induction but also the removal of the chiral catalyst is very important. Up to now only a few examples of helically chiral ligands for transition metal catalysis are published. This PHD-thesis studies the usage of helically chiral poly(methacrylates) as ligands for molybdenum, rhodium and palladium in different test reactions. These innovative multiple site catalysts combine the advantages of homogenous catalysts and polymer-bound reagents. Additionally to the preparation of a outstandingly active phosphin-palladium-catalyst for allylic substitution even at -20 °C, this pioneering work explores the novel qualities of this ligand class regarding design, optimization and utilization which are bound to the polymeric state.