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Deley studied for a degree in Pharmacy at the University of Sunderland and graduated in 1995. It was an appearance on LWT's Blind Date as a contestant that put him in the public eye, having been spotted by leading industry manager at the time Jan Simmonds.

He found his home as the anchor presenter for the cable & satellite channel Trouble live twice weekly on. He also co-presented It's in the Jeans, a series of 12 shows taking a light-hearted look at how teenagers relate to the opposite sex, as well as chart show Blast, entertainment show The T-Spot and music magazine programme iPop. Throughout the summer of 2000 he made broadcasting history by presenting T-Nation which was the first live broadcast television show from the biggest store in Europe, Topshop on Oxford Street.

Deley toured the country with the Smash Hits Roadshow from 1998 to 2000, interviewing bands for exclusive backstage footage, gossip and news. In 1999 and 2000 he hosted the roadshow itself.

For BBC One, he presented and reported on monetary and consumer issues affecting children and teenagers for Short Change. He was the main anchor presenter from 1998 to 2005. He also appeared on programmes for BBC Choice (now BBC Three) as one of the main presenters on Hype and Hype on the Road. On BBC One, he has also been the main presenter on a youth science programme, Why 5, which ran for two series. He was also the presenter of CBBC's 'Sorcerer's Apprentice'.

In July 2011 it was announced that Deley would be anchoring Channel 4's live coverage of the IAAF World Athletics Championships from Daegu, South Korea. Deley began on 27 August but struggled to win the audience as many viewers complained about his stilted delivery and the mixing up of his colleagues' names.[3][4] He was replaced as the main presenter on 30 August by former T4 presenter Rick Edwards, who had previously been presenting the evening highlights programme.[5]