Official Marvel site have also confirmed both Redford and VanCamp's characters in their article.

Quote:

Following in the footsteps of the record-breaking Marvel Studios’ release, “Marvel’s The Avengers,” production on the highly anticipated release, Marvel’s “Captain America: The Winter Soldier” has commenced in Los Angeles, California, with production also including locations in Cleveland, Ohio, and Washington D.C. Directing the film is the team of Anthony and Joe Russo (“Welcome to Collinwood”) from a screenplay written by Christopher Markus (“Captain America: The First Avenger”) & Stephen McFeely (“Captain America: The First Avenger”). “Captain America: The Winter Soldier” returns Chris Evans (“Captain America: The First Avenger,” “Marvel’s The Avengers”) as the iconic super hero character Steve Rogers/Captain America, along with Scarlett Johansson (“Marvel’s The Avengers,” “Iron Man 2”) as Black Widow and Samuel L. Jackson (“Marvel’s The Avengers,” “Iron Man 2”) as Nick Fury. In addition, film icon Robert Redford has joined the all-star cast as Agent Alexander Pierce, a senior leader within the S.H.I.E.L.D. organization. “Captain America: The Winter Soldier” is set for release in the U.S. on April 4, 2014.
“Captain America: The Winter Soldier” will pick-up where “Marvel’s The Avengers” left off, as Steve Rogers struggles to embrace his role in the modern world and teams up with Natasha Romanoff, a.k.a. Black Widow, to battle a powerful yet shadowy enemy in present-day Washington, D.C.

Looking a bit closer at what he's wearing, I don't think it's the main outfit, but rather one he uses for spy missions. In essence, I think that's the MCU version of Cap's Super-Soldier suit from the comics (if we're going by the fingerless gloves being worn in the image).

Here is a minor nit. Why are they not maintaining consistency of the SHIELD logo with Agents of SHIELD?

Well, we don't know when the SHIELD TV show takes place. There was a new logo introduced in The Avengers (although the old one could still be seen on some things, e.g. the truck Loki rode in), but if it takes place before that then it makes sense they're using the old logo.

I'm actually surprised Jeffrey Ford has signed on to co-edit yet another MCU film. First it was Captain America: The First Avenger, then The Avengers, Iron Man 3 and now Captain America: The Winter Soldier.

Feige must really like his work...

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