Preliminary experimental data for particle number ratios in the collisions of Au+Au at the BNL AGS (11A GeV/c) and Pb+Pb at the CERN SPS (160A GeV/c) are analyzed in a thermodynamically consistent hadron gas model with excluded volume. Large values of temperature, T = 140 185 MeV, and baryonic chemical potential, µb = 590 270 MeV, close to the boundary of the quark-gluon plasma phase are found from fitting the data. This seems to indicate that the energy density at the chemical freezeout is tremendous which would be indeed the case for the point-like hadrons. However, a self-consistent treatment of the van der Waals excluded volume reveals much smaller energy densities which are very far below a lowest limit estimate of the quark-gluon plasma energy density. PACS number(s): 25.75.-q, 24.10.Pa

Phase diagram of strongly interacting matter is discussed within the exactly solvable statistical model of the quark-gluon bags. The model predicts two phases of matter: the hadron gas at a low temperature T and baryonic chemical potential muB, and the quark-gluon gas at a high T and/or muB. The nature of the phase transition depends on a form of the bag mass-volume spectrum (its pre-exponential factor), which is expected to change with the muB/T ratio. It is therefore likely that the line of the 1st} order transition at a high muB/T ratio is followed by the line of the 2nd order phase transition at an intermediate muB/T, and then by the lines of "higher order transitions" at a low muB/T.