Interpretive Summary: Understanding how biochemistry changes during the life-cycle of fruit and vegetables, especially during the postharvest period is important for comprehending how our storage practices affect both useful and detrimental changes in commodities as well as developing new ways to help predict and maintain quality. Broad, untargeted sampling of fruit chemicals simultaneously allows a systemic interpretation of metabolism in response to postharvest environment as well as genotype. Comprehensive interpretation of metabolism under these conditions can be used to develop new technology including storage or supply-chain management and early selection tools that can accelerate fruit breeding.