You’ll get something like this. Note that the workflow in my case is “Blank Workflow with Custom Step”. Change this to the one you are trying to profile.

Issue 1: Cannot see the workflow step.

If you cannot see the workflow step, that means that there is a mismatch between the Microsoft.Xrm.Sdk.Workflow.dll version and/or your custom workflow step version. Go the folder with the Plugin Registration tool and check the version of the Microsoft.Xrm.Sdk.Workflow.dll version. The important thing is if the major version or minor version of the Microsoft.Xrm.Sdk.Workflow.dll assembly in Plugin Registration tool folder, is different from the one in the Workflow XAML, you will not see the step displayed.