"I love the unpredictability," the 44-year-old said about the dating show before Jimmy transitioned into a new conversation. "What's the worst date you ever went on?" he asked.

"So I went on a date in my twenties with this guy who was really super handsome. I was like really into it. And he picked me up for dinner, we went and had dinner, it was lovely. I was like this is going really well. And he drove me home and, you know, I kind of signalled that I was in for a kiss," the Oscar-winning actress said. "He pulled over by my house, and we started kissing, and it was really good," she went on, "and then he pulled away and whispered, 'Make out with my nose.'"

The Long Shot star burst into laughter as she continued. But with tears forming in her eyes, she added, "I'm yet to meet another person who likes to have somebody make out with their nose."

So did she actually go through with it?

"He was like really into it. I started giggling. It was, like, good, so I didn't want to mess it up, so I gave him a little peck on the nose," she said.

"And he was like, 'No...'" she said in a deep, sexy voice. "'Make out with it...'"

Charlize and Jimmy couldn't contain themselves before the talk show host quipped, "The Bachelorette gets a rose, you got a nose."