Jessica Drew was genetically enhanced and given super-powers by the criminal organization HYDRA, for whom she became an assassin as Spider-Woman. She later reformed and became a SHIELD agent and is currently a member of the Avengers and an Agent of SWORD.

Okay, Jessica Jones had a crush on him, now I gotta track down where Jessica Drew said it. Ms. Marvel admitted she liked him in the Siege Spiderman one shot, damn, all the Mavel ladies have the hots for Spidey. I want to say she said it in the issues right before Siege started, dang it, this is going to drive me nuts.

@Fresh03:List of Spider-Man supporting charactersPeter Parker's love interestsLiz Allan — Peter's high school crush, although they never get together. Liz instead marries Peter's friend, Harry Osborn.Betty Brant — Peter dates the Daily Bugle secretary, but they break up due to her blaming Spider-Man for the death of her brother. Betty Brant later marries Daily Bugle reporter Ned Leeds.Gwen Stacy — Peter's first real girlfriend, whom the Green Goblin kills by throwing her off a bridge. The Controversial 2004 storyline, "Sins Past" has Gwen cheating on Peter and becoming pregnant by Norman Osborn, secretly giving birth to twins, who, told by Norman that Spider-Man had killed their mother, attempt to kill Spider-Man in revenge as adults. In House of M, Gwen is still alive and married to Peter.Debra Whitman — a fellow Empire State University student and secretary whom Peter dates for a period of time, though his frequent disappearances complicate their relationship. She is eventually diagnosed with mild schizophrenia, ironically exacerbated by her "delusional" belief that Peter is Spider-Man. With Peter's help, she overcomes that idea. Soon afterward, she leaves New York after another man, Biff Rifkin, confesses his feelings for her.April Maye - a reporter from the Daily Globe, a NY newspaper and competitor to the Daily Bugle. April had something of a love-hate relationship with Peter for a while. Introduced in Amazing Spider-Man #194.Black Widow - a storyline in Marvel Team-Up had Natasha brainwashed and living by the name of Nancy Rushman. Spider-Man found her and had a strong attraction to her at the time.Michele Gonzales — Michele is the hot-tempered sister of Peter's roommate Vin Gonzales, and his temporary roommate while Vin serves time for his involvement in the Spider-Tracer Killings frame-up. Michelle attempts to kick Peter out (who is actually the Chameleon in disguise) but is instead seduced by him and become infatuated with him.[1] She is almost constantly angry, and questioning her or drawing attention to the size of her buttocks really set her off. [2] However, she is also a kind person, by trying to help her clients get their lives back on track.Jean DeWolff - NYPD Captain Jean DeWolff had a complex yet largely unrealized attraction to Spider-Man, as revealed shortly after her death.Jessica Drew, a.k.a Spider-Woman (Jessica Drew) — a British convert moved to the United States when she was younger. She had a crush on Peter when she knew that Peter was Spider-Man.Lisa Skye — a largely unknown girl who goes on a date with Peter. This story takes place in one of the Marvel Comics Hostess advertisements and may not have been in continuity. In the first issue of Spider-Man's Tangled Web, Peter dates a girl named Skye, but it's unknown if this is Lisa.Marcy Kane — another Empire State University graduate student who Peter dates briefly. Prior to dating Peter, she was the lover of the Jack of Hearts. Kane is later revealed to be an alien (Contraxian) who is on Earth looking for solutions to her homeworld's problems.Angelica Jones a.k.a. Firestar — a former sidekick of Spider-Man who later became a one-time crush of Peter before he married Mary Jane Watson.Felicia Hardy, a.k.a. Black Cat — The relationship between Spider-Man and Black Cat is short-lived after Spider-Man learns that Felicia Hardy is only interested in him as Spider-Man and not as Peter Parker.Sarah Rushman — Peter dates Sarah during a time when he believes Mary Jane to be dead; however, she turns out to be the S.H.I.E.L.D.-brainwashed mutant Marrow.Carlie Cooper - She is an officer of the NYPD's Crime Scene Unit and ex-best friend of Harry Osborn's ex-girlfriend, Lily Hollister. Peter recognized Carlie as a good match and friend, but, as always, Spider-man's work shakes the things.Norah Winters — Norah is a feisty journalist who works with Peter at Front Line. She has made some flirtatious remarks at times, and has been dating Randy Robertson.[3]Ms. Marvel — Carol Danvers, the superhero Ms. Marvel, has worked with Spider-Man on occasion and even agreed to go on a date with him in accordance with his helping her on a mission. She later fulfills her promise.[3] Spider-Man had admitted to himself he finds her attractive in her outfit. At the end of the near disastrous date, the two bonded together over a love of junk food. After she was possessed by the symbiote for a time, Venom hints to Spider-Man that his feelings for Ms. Marvel are mutual.Hebe — The goddess of youth, cupbearer for the gods, and Hercules's ex-wife. While helping out the homeless at the F.E.A.S.T. Center, Aunt May sets her up on a blind date with Peter Parker.[4] The blind date however is crashed by Hercules, and ends with Hebe and Hercules reconciling, and Spider-Man getting the New Avengers to join Hercules' battle against Hera.[5]Susan Storm, a.k.a. Invisible Woman — In Untold Tales of Spider-Man Annual 1996, Invisible Girl goes on a date with Spider-Man. Their date is ruined by Namor to whom Johnny has lied that Spider-Man kidnapped Sue.[edit] Other continuityKitty Pryde — In the Ultimate Marvel Universe, Kitty Pryde of the X-Men had a crush on Spider-Man and would eventually become his girlfriend.Sophia Sanduval — A mutant known as Chat from the Marvel Adventures Spider-Man who appeared in issue 53 and is best friends with this version's Emma Frost. She is one of the few people who knew Spider-Man's identity and has developed a crush on him. She and Peter begin dating, meanwhile Emma (with her own crush on Peter) shakes their relationship.Jean Grey — When X-Men save the life of Spider-Man by using some freshly drawn enzymes from Morbius and Professor Xavier's equipment Spidey shows his gratitude by kissing Jean.[6]Silver Sable — In the What If? storyline What If Spider-man had married the Black Cat?, after Black Cat is accidentally killed by the Paladin, Silver Sable and Spider-Man enter into a romantic relationship due to their shared grief over the loss of their loved ones; Uatu the Watcher leaves it ambiguous whether this relationship will work out or not.Emma Frost — In Marvel Adventures Spider-man, Emma reveals that she has a crush on Peter and tried to separate Chat and Spidey by erasing Chat's memory due to jealousy. http://en.wikipedia.org/wiki/List_of_Spider-Man_supporting_characters