Share This

Rice University researchers Madhuri Thakur, left, and Sibani Lisa Biswal are testing anodes made of treated porous silicon that can be spread on a current collector and holds up to 10 times the amount of lithium than graphite anodes in current lithium-ion batteries. The robust anodes have achieved more than 600 charge-discharge cycles.

Credit: Jeff Fitlow/Rice University

Researchers at Rice University have refined silicon-based lithium-ion technology by literally crushing their previous work to make a high-capacity, long-lived and low-cost anode material with serious commercial potential for rechargeable lithium batteries.

Related Articles

The team led by Rice engineer Sibani Lisa Biswal and research scientist Madhuri Thakur reported in Nature's open access journal Scientific Reports on the creation of a silicon-based anode, the negative electrode of a battery, that easily achieves 600 charge-discharge cycles at 1,000 milliamp hours per gram (mAh/g). This is a significant improvement over the 350 mAh/g capacity of current graphite anodes.

That puts it squarely in the realm of next-generation battery technology competing to lower the cost and extend the range of electric vehicles.

The new work by Rice through the long-running Lockheed Martin Advanced Nanotechnology Center of Excellence at Rice (LANCER) is the next and biggest logical step since the partners began investigating batteries four years ago.

"We previously reported on making porous silicon films," said Biswal, an assistant professor of chemical and biomolecular engineering. "We have been looking to move away from the film geometry to something that can be easily transferred into the current battery manufacturing process. Madhuri crushed the porous silicon film to form porous silicon particulates, a powder that can be easily adopted by battery manufacturers."

Silicon can hold 10 times more lithium ions than the graphite commonly used in anodes today. But there's a problem: Silicon more than triples its volume when completely lithiated. When repeated, this swelling and shrinking causes silicon to quickly break down.

Many researchers have been working on strategies to make silicon more suitable for battery use. Scientists at Rice and elsewhere have created nanostructured silicon with a high surface-to-volume ratio, which allows the silicon to accommodate a larger volume expansion. Biswal, lead author Thakur and co-author Michael Wong, a professor of chemical and biomolecular engineering and of chemistry, tried the opposite approach; they etched pores into silicon wafers to give the material room to expand. By earlier this year, they had advanced to making sponge-like silicon films that showed even more promise.

But even those films presented a problem for manufacturers, Thakur said. "They're not easy to handle and would be difficult to scale up." But by crushing the sponges into porous grains, the material gains far more surface area to soak up lithium ions.

Biswal held up two vials, one holding 50 milligrams of crushed silicon, the other 50 milligrams of porous silicon powder. The difference between them was obvious. "The surface area of our material is 46 square meters per gram," she said. "Crushed silicon is 0.71 square meters per gram. So our particles have more than 50 times the surface area, which gives us a larger surface area for lithiation, with plenty of void space to accommodate expansion." The porous silicon powder is mixed with a binder, pyrolyzed polyacrylonitrile (PAN), which offers conductive and structural support.

"As a powder, they can be used in large-scale roll-to-roll processing by industry," Thakur said. "The material is very simple to synthesize, cost-effective and gives high energy capacity over a large number of cycles."

"This work shows just how important and useful it is to be able to control the internal pores and the external size of the silicon particles," Wong said.

In recent experiments, Thakur designed a half-cell battery with lithium metal as the counter electrode and fixed the capacity of the anode to 1,000 mAh/g. That was only about a third of its theoretical capacity, but three times better than current batteries. The anodes lasted 600 charge-discharge cycles at a C/2 rate (two hours to charge and two hours to discharge). Another anode continues to cycle at a C/5 rate (five-hour charge and five-hour discharge) and is expected to remain at 1,000 mAh/g for more than 700 cycles.

"This successful endeavor between Rice University and Lockheed Martin Mission Systems and Sensors will provide a significant improvement in battery technology by the development of this inexpensive manufacturing technique for silicon anode material," said Steven Sinsabaugh, a Lockheed Martin Fellow who works with LANCER and a co-author of the paper along with Lockheed Martin researcher Mark Isaacson. "We're truly excited about this breakthrough and are looking forward to transitioning this technology to the commercial marketplace."

"The next step will be to test this porous silicon powder as an anode in a full battery," Biswal said. "Our preliminary results with cobalt oxide as the cathode appear very promising, and there are new cathode materials that we'd like to investigate."

Story Source:

The above story is based on materials provided by Rice University. Note: Materials may be edited for content and length.

More From ScienceDaily

More Matter & Energy News

Featured Research

Mar. 3, 2015 — Researchers have developed a new way of rapidly screening yeasts that could help produce more sustainable biofuels. The new technique could also be a boon in the search for new ways of deriving ... full story

Mar. 3, 2015 — Major cities in the UK are falling behind their international counterparts in terms of their use of smart technologies, according to a new study. The research has found that smart cities in the UK, ... full story

Mar. 3, 2015 — Scientists have explored friction at the microscopic level. They discovered that the force generating friction is much stronger than previously thought. The discovery is an important step toward ... full story

Mar. 3, 2015 — Micro-drones are already being put to use in a large number of areas: These small aircraft face extensive requirements when performing aerial observation tasks or when deployed in the field of ... full story

Mar. 3, 2015 — Recent research contributes to the effort to determine the nature of dark matter, one of the most important mysteries in physics. As indirect evidence provided by its gravitational effects, dark ... full story

Mar. 3, 2015 — Physicists have shown for the first time that electrons in graphene can be moved along a predefined path. This movement occurs entirely without loss and could provide a basis for numerous ... full story

Mar. 3, 2015 — Magnetic vortex structures, so-called skyrmions, could in future store and process information very efficiently. They could also be the basis for high-frequency components. For the first time, a team ... full story

Mar. 2, 2015 — For the first time, researchers have produced a 3-D image revealing part of the inner structure of an intact, infectious virus, using a unique X-ray laser. The virus, called Mimivirus, is in a ... full story

Featured Videos

Forensic Holodeck Creates 3D Crime Scenes

Reuters - Innovations Video Online (Mar. 3, 2015) — A holodeck is no longer the preserve of TV sci-fi classic Star Trek, thanks to researchers from the Institute of Forensic Medicine Zurich, who have created what they say is the first system in the world to visualise the 3D data of forensic scans. Jim Drury saw it in operation.
Video provided by Reuters

Solar Plane Passes New Test Ahead of World Tour

AFP (Mar. 2, 2015) — A solar-powered plane made a third successful test flight in the United Arab Emirates on Monday ahead of a planned round-the-world tour to promote alternative energy. Duration: 01:05
Video provided by AFP

Electric Hydrofoiling Watercraft Delivers Eco-Friendly Thrills

Reuters - Innovations Video Online (Mar. 2, 2015) — The Quadrofoil is a high-tech electric personal watercraft that its makers call a &apos;sports car for the water&apos;. When it hits 10 km/h, the Slovenian-engineered Quadrofoil is lifted above the water onto four wing-like hydrofoils where it &apos;flies&apos; above the surface with minimal water resistance. Matthew Stock reports.
Video provided by Reuters

Related Stories

June 10, 2014 — Researchers have developed a three-dimensional, silicon-decorated, cone-shaped carbon-nanotube cluster architecture for lithium ion battery anodes that could enable charging of portable electronics ... full story

May 15, 2014 — Using a material found in Silly Putty and surgical tubing, a group of researchers have developed a new way to make lithium-ion batteries that will last three times longer between charges compared to ... full story

July 16, 2012 — Researchers have found a way to make multiple high-performance anodes from a single silicon wafer. The process uses simple silicon to replace graphite as an element in rechargeable lithium-ion ... full story

ScienceDaily features breaking news and videos about the latest discoveries in health, technology, the environment, and more -- from major news services and leading universities, scientific journals, and research organizations.