Angelina Jolie's 20 Hottest Moments

Whether dazzling audiences with her breathtaking breakout in 'Gia,' assuming her rightful place as "Sexiest Woman Alive" on Esquire's November 2004 cover or walking the red carpet with Brad Pitt, Angelina Jolie never ceases to awe with her beauty.

In a pictorial homage, Moviefone looks back at 20 of Angie's most jaw-dropping, eye-defying, downright sexiest moments ever.