Sorry, don't think so. But it would be a nice addition. I like the PDF exporter a lot for its simplicity and nice output, but there is still room for improvement. An automated table of contents is one thing I'd like to see, running headers (for chapter titles or a copyright notice for example) is another.

It's indeed currently not possible with the PDF exporter. The LaTeX exporter currently includes title pages, tables of content etc., the PDF exporter might do so in future versions. We have those on our list :)