The first figure is Jean Grey, although I couldn't say from what particular line, but, given the five points of articulation, it looks like an earlier Toy Biz figure to me. The second figure, which is obviously Spider-man, looks like a toy from one of the movie lines, based on his costume design, although, again, I couldn't say with any certainty exactly which one. Not terribly helpful, I know.

Thanks for your help Although I am aware it's Jean Grey and Spider-Man I didn't quite make that clear in the first post. It's more the line they are from! I have been searching but finding out info for a specific Spider-Man is proving rather difficult. The Jean Grey figure is beginning to bug me tho! Again any help is appreciated. Thanks.