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The duo stole the smooch (and the spotlight) after walking the red carpet for Affleck's new flick, and we can't say that we blame Ben for making a move: Mrs. Affleck was looking red-hot in her Monique Lhuillier gown and Bulgari clutch.

The red carpet never seemed so steamy.

Argo is set for release Oct. 12.

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Your information may be shared with other NBCUniversal businesses and used to better tailor our services and advertising to you. For more details about how we use your information, see our Privacy Policy. If you are located outside of the U.S., your information may be transferred to, processed and used in the U.S.