Special Issue Information

Dear Colleagues,

Exergy analysis is a powerful thermodynamic technique for assessing and improving the efficiency of processes, devices and systems, as well as for enhancing environmental and economic performance. As a multidisciplinary concept, exergy applications are observed in various fields, including mechanical and chemical engineering as well as economics, management, physics and biology. Consequently, exergy analysis is used increasingly by industries and governments throughout the world, particularly with the aim of improving energy sustainability. Research and review articles on all facets of exergy and its applications, and on exergy-related topics, are sought for this special issue.

Abstract: In this study, a four stroke four cylinder direct injection CI engine was run using three different injection pressures. In all measurements, the fuel quantity per cycle, the pre injection and main injection timing, the boost pressure and the engine speed were kept constant. The motor tests were performed under 130, 140 and 150 MPa rail pressure. During the theoretical part of the study, combustion, emission, energy and exergy analysis were made using the test results. An increase in the injection pressure increases combustion efficiency. The results show that combustion efficiency is not enough by itself, because the increase in the power need of the injection pump, decreases the thermal efficiency. The increase in the combustion temperature, increases the cooling loss and decreases the exergetic efficiency. In addition, the NOx emissions increased by 12% and soot emissions decreased 44% via increasing injection pressure by 17%. The thermal and exergetic efficiencies are found inversely proportional with injection pressure. Exergy destruction is found independent of the injection pressure and its value is obtained as ~6%.

Abstract: A comprehensive thermodynamic study is conducted of a diesel based Combined Heat and Power (CHP) system, based on a diesel engine and an Organic Rankine Cycle (ORC). Present research covers both energy and exergy analyses along with a multi-objective optimization. In order to determine the irreversibilities in each component of the CHP system and assess the system performance, a complete parametric study is performed to investigate the effects of major design parameters and operating conditions on the system’s performance. The main contribution of the current research study is to conduct both exergy and multi-objective optimization of a system using different working fluid for low-grade heat recovery. In order to conduct the evolutionary based optimization, two objective functions are considered in the optimization; namely the system exergy efficiency, and the total cost rate of the system, which is a combination of the cost associated with environmental impact and the purchase cost of each component. Therefore, in the optimization approach, the overall cycle exergy efficiency is maximized satisfying several constraints while the total cost rate of the system is minimized. To provide a better understanding of the system under study, the Pareto frontier is shown for multi-objective optimization and also an equation is derived to fit the optimized point. In addition, a closed form relationship between exergy efficiency and total cost rate is derived.

Abstract: Performance degradation assessment of rolling element bearings is vital for the reliable and cost-efficient operation and maintenance of rotating machines, especially for the implementation of condition-based maintenance (CBM). For robust degradation assessment of rolling element bearings, uncertainties such as those induced from usage variations or sensor errors must be taken into account. This paper presents an information exergy index for bearing performance degradation assessment that combines singular value decomposition (SVD) and the information exergy method. Information exergy integrates condition monitoring information of multiple instants and multiple sensors, and thus performance degradation assessment uncertainties are reduced and robust degradation assessment results can be obtained using the proposed index. The effectiveness and robustness of the proposed information exergy index are validated through experimental case studies.

Abstract: An overview is presented of the recent developments in the application of large eddy simulation (LES) for prediction and analysis of local entropy generation in turbulent reacting flows. A challenging issue in such LES is subgrid-scale (SGS) modeling of filtered entropy generation terms. An effective closure strategy, recently developed, is based on the filtered density function (FDF) methodology with inclusion of entropy variations. This methodology, titled entropy FDF (En-FDF), is the main focus of this article. The En-FDF has been introduced as the joint velocity-scalar-turbulent frequency-entropy FDF and the marginal scalar-entropy FDF. Both formulations contain the chemical reaction and its entropy generation effects in closed forms. The former constitutes the most comprehensive form of the En-FDF and provides closure for all of the unclosed terms in LES transport equations. The latter is the marginal En-FDF and accounts for entropy generation effects, as well as scalar-entropy statistics. The En-FDF methodologies are described, and some of their recent predictions of entropy statistics and entropy generation in turbulent shear flows are presented.

Abstract: This paper presents a theoretical and practical analysis of the application of the thermoeconomic method. A furnace for heating air is evaluated using the methodology. The furnace works with solar energy, received from a parabolic trough collector and with electricity supplied by an electric power utility. The methodology evaluates the process by the first and second law of thermodynamics as the first step then the cost analysis is applied for getting the thermoeconomic cost. For this study, the climatic conditions of the city of Queretaro (Mexico) are considered. Two periods were taken into account: from July 2006 to June 2007 and on 6 January 2011. The prototype, located at CICATA-IPN, Qro, was analyzed in two different scenarios i.e., with 100% of electricity and 100% of solar energy. The results showed that thermoeconomic costs for the heating process with electricity, inside the chamber, are less than those using solar heating. This may be ascribed to the high cost of the materials, fittings, and manufacturing of the solar equipment. Also, the influence of the mass flow, aperture area, length and diameter of the receiver of the solar prototype is a parameter for increasing the efficiency of the prototype in addition to the price of manufacturing. The optimum design parameters are: length is 3 to 5 m, mass flow rate is 0.03 kg/s, diameter of the receiver is around 10 to 30 mm and aperture area is 3 m2.

Abstract: The paper discusses methods of evaluating thermodynamic properties of landscape cover based on multi-spectral measurements by the Landsat satellites. Authors demonstrate how these methods could be used for studying functionality of landscapes and for spatial interpolation of Flux NET system measurements.

Abstract: A solar-aided coal-fired power plant realizes the integration of a fossil fuel (coal or gas) and clean energy (solar). In this paper, a conventional 600 MW coal-fired power plant and a 600 MW solar-aided coal-fired power plant have been taken as the study case to understand the merits of solar-aided power generation (SAPG) technology. The plants in the case study have been analyzed by using the First and Second Laws of Thermodynamics principles. The solar irradiation and load ratio have been considered in the analysis. We conclude that if the solar irradiation was 925 W/m2 and load ratio of the SAPG plant was 100%, the exergy efficiency would be 44.54% and the energy efficiency of the plant (46.35%). It was found that in the SAPG plant the largest exergy loss was from the boiler, which accounted for about 76.74% of the total loss. When the load ratio of the unit remains at 100%, and the solar irradiation varies from 500 W/m2 to 1,100 W/m2, the coal savings would be in the range of 8.6 g/kWh to 15.8 g/kWh. If the solar irradiation were kept at 925 W/m2 while the load ratio of the plant changed from 30% to 100%, the coal savings could be in the range of 11.99 g/kWh to 13.75 g/kWh.

Abstract: The use of exergy to correlate energy-utilization efficiencies and energy research investments is described. Specifically, energy and exergy losses are compared with energy research and development expenditures, demonstrating that the latter correlates with energy losses, even though it would be more sensible to allocate energy research and development funding in line with exergy losses, as they represent the actual deviation of efficiency from the ideal. The methodology is outlined and illustrated with two case studies. The case studies consider the province of Ontario, Canada and the United States. The investigation utilizes data on the energy utilization in a country or region, including flows of energy and exergy through the main sectors of the economy. The results are expected to be of use to government and public authorities that administer research and development funding and resources and should help improve the effectiveness of such investments.

Abstract: Parametric studies of the effects of slip irreversibility in concentrating solar power (CSP)-powered bio-digester assemblies are investigated. Complexities regarding the identification of the appropriate electro-kinetic phenomena for certain electrolyte phases are reviewed. The application of exergy analysis to the design of energy conversion devices, like solar thermal collectors, for the required heat of formation in a downdraft waste food bio-digester, is discussed. Thermal management in the silicon-based substrate of the energy system is analyzed. The rectangular-shaped micro-channels are simulated with a finite-volume, staggered coupling of the pressure-velocity fields. Entropy generation transport within the energy system is determined and coupled with the solution procedure. Consequently, the effects of channel size perturbation, Reynolds number, and pressure ratios on the thermal performance and exergy destruction are presented. A comparative analysis of the axial heat conduction for thermal management in energy conversion devices is proposed.

Abstract: Theoretically, the concepts of energy, entropy, exergy and embodied energy are founded in the fields of thermodynamics and physics. Yet, over decades these concepts have been applied in numerous fields of science and engineering, playing a key role in the analysis of processes, systems and devices in which energy transfers and energy transformations occur. The research reported here aims to demonstrate, in terms of sustainability, the usefulness of the embodied energy and exergy concepts for analyzing electric devices which convert energy, particularly the electromagnet. This study relies on a dualist view, incorporating technical and environmental dimensions. The information provided by energy assessments is shown to be less useful than that provided by exergy and prone to be misleading. The electromagnet force and torque (representing the driving force of output exergy), accepted as both environmental and technical quantities, are expressed as a function of the electric current and the magnetic field, supporting the view of the necessity of discerning interrelations between science and the environment. This research suggests that a useful step in assessing the viability of electric devices in concert with ecological systems might be to view the magnetic flux density B and the electric current intensity I as environmental parameters. In line with this idea the study encompasses an overview of potential human health risks and effects of extremely low frequency electromagnetic fields (ELF EMFs) caused by the operation of electric systems. It is concluded that exergy has a significant role to play in evaluating and increasing the efficiencies of electrical technologies and systems. This article also aims to demonstrate the need for joint efforts by researchers in electric and environmental engineering, and in medicine and health fields, for enhancing knowledge of the impacts of environmental ELF EMFs on humans and other life forms.

Abstract: In this paper we undertake the theoretical analysis of a two-stage semiconductor thermoelectric module (TEM) which contains an arbitrary and different number of thermocouples, n1 and n2, in each stage (pyramid-styled TEM). The analysis is based on a dimensionless entropy balance set of equations. We study the effects of n1 and n2, the flowing electric currents through each stage, the applied temperatures and the thermoelectric properties of the semiconductor materials on the exergetic efficiency. Our main result implies that the electric currents flowing in each stage must necessarily be different with a ratio about 4.3 if the best thermal performance and the highest temperature difference possible between the cold and hot side of the device are pursued. This fact had not been pointed out before for pyramid-styled two stage TEM. The ratio n1/n2should be about 8.

Abstract: Energy storage systems are increasingly gaining importance with regard to their role in achieving load levelling, especially for matching intermittent sources of renewable energy with customer demand, as well as for storing excess nuclear or thermal power during the daily cycle. Compressed air energy storage (CAES), with its high reliability, economic feasibility, and low environmental impact, is a promising method for large-scale energy storage. Although there are only two large-scale CAES plants in existence, recently, a number of CAES projects have been initiated around the world, and some innovative concepts of CAES have been proposed. Existing CAES plants have some disadvantages such as energy loss due to dissipation of heat of compression, use of fossil fuels, and dependence on geological formations. This paper reviews the main drawbacks of the existing CAES systems and presents some innovative concepts of CAES, such as adiabatic CAES, isothermal CAES, micro-CAES combined with air-cycle heating and cooling, and constant-pressure CAES combined with pumped hydro storage that can address such problems and widen the scope of CAES applications, by energy and exergy analyses. These analyses greatly help us to understand the characteristics of each CAES system and compare different CAES systems.

Abstract: For ecological economic evaluation based on the unified biophysical matrix this research illustrates an updated emergy synthesis in terms of embodied cosmic exergy instead of embodied solar energy, which successes the foundation of systems ecological theory but changes the starting point for the estimation from simply the sun to the cosmos. According to the modified definition implicating explicit scarcity and strict additivity based on the fundamental thermodynamics laws, the updated emergy approach overcomes the confusable and intractable deficiencies of traditional one and shows firmer theoretical basis as well as better applicability. As a case study for the regional socio-economic ecosystem, a cosmic emergy based ecological economic evaluation of the Beijing urban ecosystem during the period 1978-2004 is presented. The local and external resources supporting the concerned ecosystem are accounted and analyzed in a common unit, i.e., cosmic Joule, according to which a series of indicators are applied to reveal its evolutional characteristics through five aspects as emergy structure, emergy intensity, emergy welfare, environmental impacts, and degree of exploitation and economic efficiency. During the analyzed period, the major emergy source sustaining the operation of the ecosystem had changed from the renewable resources exploited locally to the nonrenewable resources purchased from outside. Emergy intensity for the Beijing urban ecosystem kept rising owing to the continuous investment of resources, which not only improved the living standard but also intensified the environmental pressure. Moreover, the increase of exploitation degree was accompanied with the decline of economic efficiency, while the rising emergy investment ratio implicates that Beijing was at the risks of resources shortage and high dependence on external resources

Abstract: A multi-criteria approach is presented for the assessment of alternative means for covering the energy needs (electricity and heat) of an industrial unit, taking into consideration sustainability aspects. The procedure is first described in general terms: proper indicators are defined; next they are grouped in order to form sub-indices, which are then used to determine the composite sustainability index. The procedure is applied for the evaluation of three alternative systems. The three systems are placed in order of preference, which depends on the criteria used. In addition to conclusions reached as a result of the particular case study, recommendations for future work are given.

Abstract: In this paper exergy analysis is used to assess the performance of the three most common air conditioning plant schemes: all-air, dual-duct and fan-coil systems. The results are presented in terms of flow diagrams to provide a clear picture of the exergy flow across the systems. The most relevant outcomes are that the air cooling and dehumidification is the process most responsible for the exergy loss and that the exergy efficiency of the overall systems is rather low; thus the quest for more appropriate technologies. Solar-assisted air-conditioning is also discussed, outlining the possibilities and the constraints.

Abstract: Exergy is demonstrated to be a useful measurable parameter reflecting the state of the ecosystem, and allowing estimation of the severity of its anthropogenous damage. Exergy is shown to have advantages such as good theoretical basis in thermodynamics, close relation to information theory, rather high correlation with others ecosystem goal functions and relative ease of computation. Nowadays exergy is often used in ecological assessment. This paper reviews the application of exergy in ecology in the fields of ecological modeling and natural ecosystem monitoring. Special attention is paid to the use of exergy for aquatic ecosystem studies, particularly, assessment of the lake Baikal ecosystem state.

Abstract: Industrial Ecology involves the transformation of industrial processes from linear to closed loop systems: matter and energy flows which were initially considered as wastes become now resources for existing or new processes. In this paper, Thermoeconomics, commonly used for the optimization and diagnosis of energy systems, is proposed as a tool for the characterization of Industrial Ecology. Thermoeconomics is based on the exergy analysis (Thermodynamics) but goes further by introducing the concepts of purpose and cost (Economics). It is presented in this study as a systematic and general approach for the analysis of waste flow integration. The formulation is based on extending the thermoeconomic process of the cost formation of wastes in order to consider their use as input for other processes. Consequently, it can be applied to important Industrial Ecology issues such as identification of integration possibilities and efficiency improvement, quantification of benefits obtained by integration, or determination of fair prices based on physical roots. The capability of the methodology is demonstrated by means of a case study based on the integration of a power plant, a cement kiln and a gas-fired boiler.

Abstract: Fluid flow, heat transfer and entropy generation characteristics of micro-pipes are investigated computationally by considering the simultaneous effects of pipe diameter, wall heat flux and Reynolds number in detail. Variable fluid property continuity, Navier-Stokes and energy equations are numerically handled for wide ranges of pipe diameter (d = 0.50–1.00 mm), wall heat flux (q''= 1000–2000 W/m2) and Reynolds number (Re = 1 – 2000), where the relative roughness is kept constant at e/d = 0.001 in the complete set of the scenarios considered. Computations indicated slight shifts in velocity profiles from the laminar character at Re = 500 with the corresponding shape factor (H) and intermittency values (γ) of H = 3.293→3.275 and γ = 0.041→0.051 (d = 1.00→0.50 mm). Moreover, the onset of transition was determined to move down to Retra = 1,656, 1,607, 1,491, 1,341 and 1,272 at d = 1.00, 0.90, 0.75, 0.60 and 0.50 mm, respectively. The impacts of pipe diameter on friction mechanism and heat transfer rates are evaluated to become more significant at high Reynolds numbers, resulting in the rise of energy loss data at the identical conditions as well. In cases with low pipe diameter and high Reynolds number, wall heat flux is determined to promote the magnitude of local thermal entropy generation rates. Local Bejan numbers are inspected to rise with wall heat flux at high Reynolds numbers, indicating that the elevating role of wall heat flux on local thermal entropy generation is dominant to the suppressing function of Reynolds number on local thermal entropy generation. Cross-sectional total entropy generation is computed to be most influenced by pipe diameter at high wall heat flux and low Reynolds numbers.

Abstract: The transport equation of entropy is introduced in large eddy simulation to perform exergy analysis of turbulent combustion systems. The sources of exergy destruction can be evaluated by analyzing entropy generation terms, which appear in unclosed forms in this equation. The closure is based on the filtered density function (FDF) methodology. The primary advantage of FDF is that chemical reaction and its entropy generation effects appear in closed forms. This methodology involves a stochastic model, which is being developed to account for the subgrid scale transport of entropy.

Abstract: This work applies the second-law analysis of thermodynamics to quantify the exergy destruction of the components of screw liquid chiller, and to identify the potential for each component to contribute to improve the overall energy efficiency of the system. Three screw liquid chiller units were built to demonstrate the feasibility of the model presented herein. Unit A was a 100 RT water-cooled screw liquid chiller. Unit B was modified from Unit A by switching the old condenser for a new one with a greater heat transfer, and Unit C was modified from Unit B by exchanging the compressor for a more efficient one. The results indicate that the compressor has the largest potential to improve energy efficiency, followed in order by the condenser, and then the evaporator. The second law analysis may help engineers to focus on the components with higher exergy destruction and quantify the extent to which modifying such components can influence, favorably or unfavorably, the performance of other components of the screw liquid chiller.

Abstract: Exergy analysis is a powerful and systematic tool for the improvement of energy systems, with many possible applications in both conversion and utilization of energy. Here we present selected applications, with a special attention to renewable energy systems (solar), covering both design and operation/control. After these applications to non-reactive systems, potential ways of reducing the large irreversibilities connected to reactive systems (combustion) are considered, with special reference to chemically-recuperated gas turbine cycles and topping high-temperature fuel cells.

Abstract: The benefits are demonstrated of using exergy to understand the efficiencies of electrical power technologies and to assist improvements. Although exergy applications in power systems and electrical technology are uncommon, exergy nevertheless identifies clearly potential reductions in thermodynamic losses and efficiency improvements. Various devices are considered, ranging from simple electrical devices to generation systems for electrical power and for multiple products including electricity, and on to electrically driven. The insights provided by exergy are shown to be more useful than those provided by energy, which are sometimes misleading. Exergy is concluded to have a significant role in assessing and improving the efficiencies of electrical power technologies and systems, and provides a useful tool for engineers and scientists as well as decision and policy makers.

Abstract: It is known that mechanical work, and in turn electricity, can be produced from a difference in the chemical potential that may result from a salinity gradient. Such a gradient may be found, for instance, in an estuary where a stream of soft water is flooding into a sink of salty water which we may find in an ocean, gulf or salt lake. Various technological approaches are proposed for the production of energy from a salinity gradient between a stream of soft water and a source of salty water. Before considering the implementation of a typical technology, it is of utmost importance to be able to compare various technological approaches, on the same basis, using the appropriate variables and mathematical formulations. In this context, exergy balance can become a very useful tool for an easy and quick evaluation of the maximum thermodynamic work that can be produced from energy systems. In this short paper, we briefly introduce the use of exergy for enabling us to easily and quickly assess the theoretical maximum power or ideal reversible work we may expect from typical salinity gradient energy systems.

Abstract: All real processes generate entropy and the power/exergy loss is usually determined by means of the Gouy-Stodola law. If the system only exchanges heat at the environmental temperature, the Gouy-Stodola law gives the correct loss of power. However, most industrial processes exchange heat at higher or lower temperatures than the actual environmental temperature. When calculating the real loss of power in these cases, the Gouy-Stodola law does not give the correct loss if the actual environmental temperature is used. The first aim of this paper is to show through simple steam turbine examples that the previous statement is true. The second aim of the paper is to define the effective temperature to calculate the real power loss of the system with the Gouy-Stodola law, and to apply it to turbine examples. Example calculations also show that the correct power loss can be defined if the effective temperature is used instead of the real environmental temperature.

Abstract: This paper reviews how ideas have evolved in this field from the pioneering work of CARNOT right up to the present. The coupling of thermostatics with thermokinetics (heat and mass transfers) and entropy or exergy analysis is illustrated through study of thermomechanical engines such as the Carnot heat engine, and internal combustion engines. The benefits and importance of stagnation temperature and irreversibility parameters are underlined. The main situations of constrained (or unconstrained) optimization are defined, discussed and illustrated. The result of this study is a new branch of thermodynamics: Finite Dimensions Optimal Thermodynamics (FDOT).

Abstract: In the present paper, the thermoeconomic optimization of an endoreversible solardriven heat engine has been carried out by using finite-time/finite-size thermodynamic theory. In the considered heat engine model, the heat transfer from the hot reservoir to the working fluid is assumed to be the radiation type and the heat transfer to the cold reservoir is assumed the conduction type. In this work, the optimum performance and two design parameters have been investigated under three objective functions: the power output per unit total cost, the efficient power per unit total cost and the ecological function per unit total cost. The effects of the technical and economical parameters on the thermoeconomic performance have been also discussed under the aforementioned three criteria of performance.

Abstract: An experimental design is presented for an optical method of measuring spatial variations of flow irreversibilities in laminar viscous fluid motion. Pulsed laser measurements of fluid velocity with PIV (Particle Image Velocimetry) are post-processed to determine the local flow irreversibilities. The experimental technique yields whole-field measurements of instantaneous entropy production with a non-intrusive, optical method. Unlike point-wise methods that give measured velocities at single points in space, the PIV method is used to measure spatial velocity gradients over the entire problem domain. When combined with local temperatures and thermal irreversibilities, these velocity gradients can be used to find local losses of energy availability and exergy destruction. This article focuses on the frictional portion of entropy production, which leads to irreversible dissipation of mechanical energy to internal energy through friction. Such effects are significant in various technological applications, ranging from power turbines to internal duct flows and turbomachinery. Specific problems of a rotational stirring tank and channel flow are examined in this paper. By tracking the local flow irreversibilities, designers can focus on problem areas of highest entropy production to make local component modifications, thereby improving the overall energy efficiency of the system.