One litre of liquid water has a mass of almost exactly one kilogram, due to the gram being defined in 1795 as one cubic centimetre of water at the temperature of melting ice. Subsequent redefinitions of the metre and kilogram mean that this relationship is no longer exact by definition.[4]

From 1901 to 1964, the litre was defined as the volume of one kilogram of pure water at maximum density and standard pressure. The kilogram was in turn specified as the mass of a platinum/iridium cylinder held at Sèvres in France and was intended to be of the same mass as the 1 litre of water referred to above. It was subsequently discovered that the cylinder was around 28 parts per million too large and thus, during this time, a litre was about 1.000028 dm3. Additionally, the mass-volume relationship of water (as with any fluid) depends on temperature, pressure, purity and isotopic uniformity. In 1964, the definition relating the litre to mass was abandoned in favour of the current one. Although the litre is not an official SI unit, it is accepted by the CGPM (the standards body that defines the SI) for use with the SI. CGPM defines the litre and its acceptable symbols.

A litre is equal in volume to the millistere, an obsolete non-SI metric unit customarily used for dry measure.

Litres are most commonly used for items (such as fluids and solids that can be poured) which are measured by the capacity or size of their container, whereas cubic metres (and derived units) are most commonly used for items measured either by their dimensions or their displacements. The litre is often also used in some calculated measurements, such as density (kg/L), allowing an easy comparison with the density of water.

One litre of water has a mass of almost exactly one kilogram when measured at its maximal density, which occurs at about 4 °C. Similarly: 1 millilitre of water has a mass of about 1 g; 1,000 litres of water has a mass of about 1,000 kg (1 tonne). This relationship holds because the gram was originally defined as the mass of 1 mL of water; however, this definition was abandoned in 1799 because the density of water changes with temperature and, very slightly, with pressure.

It is now known that density also depends on the isotopic ratios of the oxygen and hydrogen atoms in a particular water sample. Modern measurements of Vienna Standard Mean Ocean Water, which is pure distilled water with an isotopic composition representative of the average of the world’s oceans, show it has a density of 0.999975 ±1×10−6 kg/L at its point of maximum density (3.984 °C) under one standard atmosphere (760 torr, 101.325 kPa) of pressure.[5]

The litre, though not an official SI unit, may be used with SI prefixes. The most commonly used derived unit is the millilitre, defined as one-thousandth of a litre, and also often referred to by the SI derived unit name ‘cubic centimetre’. It is a commonly used measure, especially in medicine and cooking. Other units may be found in the table below, where the more often used terms are in bold. However, some authorities advise against some of them; for example, in the United States, NIST advocates using the millilitre or litre instead of the centilitre.[6]

One litre is slightly more than one U.S. liquid quart and slightly less than one imperial quart or one U.S. dry quart. A mnemonic for its volume relative to the imperial pint is ‘a litre of water is a pint and three quarters’.

A litre is the volume of a cube with sides of 10 cm, which is slightly less than a cube of sides 4 inches (or one-third of a foot). One cubic foot would contain exactly 27 such cubes (four inches on each side), making one cubic foot approximately equal to 27 litres. One cubic foot has an exact volume of 28.316846592 litres, which is within 5% of the 27-litre approximation.

A litre of water has a mass almost exactly equal to one kilogram. An early definition of the kilogram was set as the mass of one litre of water. Because volume changes with temperature and pressure, and pressure uses units of mass, the definition of a kilogram was changed. At standard pressure, one litre of water has a mass of 0.999975 kg at 4 °C, and 0.997 kg at 25 °C.[7]

Originally, the only symbol for the litre was l (lowercase letter L), following the SI convention that only those unit symbols that abbreviate the name of a person start with a capital letter. In many English-speaking countries, however, the most common shape of a handwritten Arabic digit 1 is just a vertical stroke; that is, it lacks the upstroke added in many other cultures. Therefore, the digit ‘1’ may easily be confused with the letter ‘l’. Further, on some typewriters, particularly older ones, the unshifted L key had to be used to type the numeral 1. Even in some computer typefaces, the two characters are barely distinguishable. This caused some concern, especially in the medical community.

As a result, L (uppercase letter L) was adopted as an alternative symbol for litre in 1979. The United StatesNational Institute of Standards and Technology now recommends the use of the uppercase letter L,[8] a practice that is also widely followed in Canada and Australia. In these countries, the symbol L is also used with prefixes, as in mL and µL, instead of the traditional ml and µl used in Europe. In the UK and Ireland as well as the rest of Europe, lowercase l is used with prefixes, though whole litres are often written in full (so, ‘750 ml’ on a wine bottle, but often ‘1 litre’ on a juice carton). In 1990, the CIPM stated that it was still too early to choose a single symbol for the litre.

Prior to 1979, the symbol ℓ (script small l, U+2113), came into common use in some countries; for example, it was recommended by South African Bureau of Standards publication M33 and Canada in the 1970s. This symbol can still be encountered occasionally in some English-speaking countries, and its use is ubiquitous in Japan and South Korea. Fonts covering the CJK characters usually include not only the script small ℓ but also four precomposed characters: ㎕, ㎖, ㎗ and ㎘ (U+3395 to U+3398) for the microlitre, millilitre, decilitre and kilolitre. Such usage in printed works is in conflict with the recommendations published by the BIPM on the advice of the major international standards organisations (including ISO, NIST, NPL, IAU, IUPAC and IUPAP) who state in the SI Brochure that unit symbols should be ‘printed in Roman (upright) type regardless of the type used in the surrounding text’.[9][10]

The litre was introduced in France in 1795 as one of the new ‘republican units of measurement’ and defined as one cubic decimetre.[12] One litre of liquid water has a mass of almost exactly one kilogram, due to the gram being defined in 1795 as one cubic centimetre of water at the temperature of melting ice.[4] The original decimetre length was 44.344 lignes, which was revised in 1798 to 44.3296 lignes. This made the original litre 1.000974 of today's dm3. It was against this litre that the kilogram was constructed.

In 1879, the CIPM adopted the definition of the litre, with the symbol l (lowercase letter L).

In 1901, at the 3rd CGPM conference, the litre was redefined as the space occupied by 1 kg of pure water at the temperature of its maximum density (3.98 °C) under a pressure of 1 atm. This made the litre equal to about 1.000028 dm3 (earlier reference works usually put it at 1.000027 dm3).

In 1964, at the 12th CGPM conference, the original definition was reverted to, and thus the litre was once again defined in exact relation to the metre, as another name for the cubic decimetre, that is, exactly 1 dm3.[13]

In 1979, at the 16th CGPM conference, the alternative symbol L (uppercase letter L) was adopted. It also expressed a preference that in the future only one of these two symbols should be retained, but in 1990 said it was still too early to do so.[14]

The microlitre (µL) has been known in the past as the lambda (λ), but this usage is now discouraged.[16]

In European countries where the metric system was established well before the adoption of the SI standard, there is still carry-over of usage from the precursor cgs and MKS systems.[citation needed] In the SI system, use of prefixes for powers of 1,000 is preferred and all other multiples discouraged. However, in countries where these other multiples were already established, their use remains common. In particular, use of the centi (10−2), deci (10−1), deca (10+1) and hecto (10+2) prefixes are still common. For example, in many European countries, the hectolitre is the typical unit for production and export volumes of beverages (milk, beer, soft drinks, wine, etc.) and for measuring the size of the catch and quotas for fishing boats; decilitres are common in Switzerland and Scandinavia and sometimes found in cookbooks; centilitres indicate the capacity of drinking glasses and of small bottles. In colloquial Dutch in Belgium, a 'vijfentwintiger' and a 'drieëndertiger' (literally 'twenty-fiver' and 'thirty-threer') are the common beer glasses, the corresponding bottles mention 25 cL or 33 cL. Bottles may also be 75 cL or half size at 37.5 cL for 'artisanal' brews or 70 cL for wines or spirits. Cans come in 25 cL, 33 cL and 50 cL a.k.a. 0.5 L. Family size bottles as for soft drinks or drinking water use the litre (0.5 L, 1 L, 1.5 L, 2 L) as well as beer barrels (50 L or the half-sized 25 L). The quantities of some non-liquid food products (e.g. ice cream) are also expressed in mL or L (typically 1000 mL) instead of the mass units. This happens because such goods contain much air and have very low density, thus their unit prices using litres are perceived less shocking. This unit is most common for all other household size containers of liquids from thermocans to buckets to bath tubs; as well as for fuel tanks and consumption for heating or by vehicles.

In countries where the metric system was adopted as the official measuring system after the SI standard was established, common usage more closely follow contemporary SI conventions. For example, in Canada, where the metric system is now in widespread use, consumer beverages are labelled almost exclusively using litres and millilitres. Hectolitres sometimes appear in industry, but centilitres and decilitres are rarely, if ever, used. Larger volumes are usually given in cubic metres (equivalent to 1 kL), or thousands or millions of cubic metres. The situation is similar in Australia, although kilolitres, megalitres and gigalitres are commonly used for measuring water consumption, reservoir capacities and river flows.

For larger volumes of fluids, such as annual consumption of tap water, lorry (truck) tanks, or swimming pools, the cubic metre is the general unit. It is also generally for all volumes of a non-liquid nature.

Fluid flow rates may be measured in litres per unit time interval (second, minute, hour, etc.).

Table 6 (Non-SI units accepted for use with the International System). Retrieved 2008-08-24

National Institute of Standards and Technology (11 November 2000). "Appendix C: General tables of units of measurement". NIST Handbook 44: Specifications, Tolerances, and Other Technical Requirements for Weighing and Measuring Devices. National Institute of Standards and Technology. Retrieved 2006-10-09.

Taylor, B.N. and Thompson, A. (Eds.). (2008a). The International System of Units (SI). United States version of the English text of the eighth edition (2006) of the International Bureau of Weights and Measures publication Le Système International d’ Unités (SI) (Special Publication 330). Gaithersburg, MD: National Institute of Standards and Technology. Retrieved 2008-08-18.