Thin, Tough, pH-Sensitive Hydrogel Films with Rapid
Load RecoveryNaficySinaSpinksGeoffrey M.WallaceGordon G.2014Stimuli-responsive hydrogels are
used as the building blocks of
actuators and sensors. Their application has been limited, however,
by their lack of mechanical strength and recovery from loading. Here,
we report the preparation of pH-sensitive hydrogels as thin as 20
μm. The hydrogels are made of a polyether-based polyurethane
and poly­(acrylic acid). A simple method was employed to create hydrogels
with thicknesses in the range of 20–570 μm. The hydrogel
films volume changed by a factor of ∼2 when the pH was switched
around the transition point (pH 4). Tensile extensibilities of up
to ∼350% were maintained at each pH, and the average Young’s
modulus and tensile strength were in the range of 580–910 and
715–1320 kPa, respectively, depending on the pH. Repeated tensile
loading and unloading to 100% extension showed little permanent damage,
unlike analogous double-network hydrogels, and with immediate recovery
(up to 75–85% of the first loading cycle), unlike hybrid ionic–covalent
interpenetrating network hydrogels.