Pitt arrived in the Canadian city on a break from filming "World War Z," his zombie battle flick that's had locations in London and Glasgow. Jolie served as arm candy while she preps the release of her directorial debut, "Blood and Honey."

Plenty of other A-listers have hit the festival, or will in the coming days, including Tilda Swinton, George Clooney, Ryan Gosling, Seth Rogen and Ewan McGregor. Click the photo link above to check out the scene.