B2B will let you parse and read unstructured data such as PDF, EXCEL, HTML etc... and it has the capability to read binary data such as Messages, EBCDIC File etc... and has a very large list of supported formates.

B2B Data Transformation Studio is the Developer tool, by which the parsing of (reading) the unstructured data is done. B2B mostly gives the output as an XML file.

B2B Data Transformation is integrated with Informatica PowerCenter using a Transformation "Unstructured Data Transformation", This transformation can receive the output of B2B Data Transformation studion and load into any Target supported by Powercenter.

To add to DISoln answer above...
Using B2B DataTransfromation (or UDO – Unstructured Data Option in PowerCenter ) indeed you can handle any file type (complex XMLs, office documents, PDFs and industry standards).
in order to load the information into a relational table UDO also allows you to define “Relational Hirarchy” which will automatically transform hierarchical definition of the XML you will create in UDO (from the source PDF) to a relational representation that PowerCenter can consume easily.

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