1 Answer
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If you are on different servers, you need to use your full Diaspora IDs. Type something like nameofyourfriend@joindiaspora.com into the search field at the top, and it should find his account after a while. (Or he can do the same with your full ID.)

Another option (if you cannot find him for some reason): On the right side there is a link titled Share this link via email, blog, or favorite social network!. Just send him this link and he should be able to connect to you by visiting it.