Water SA

Water SA publishes refereed, original work in all branches of water science, technology, engineering and policy. This includes: water resource development; the hydrological cycle; surface hydrology; geohydrology, hydropedology and hydrometeorology; limnology; freshwater and estuarine ecology; salinisation; treatment and management of municipal and industrial water and wastewater; treatment and disposal of sewage sludge; environmental pollution control; environmental and drinking water quality; drinking water treatment; water services, including domestic water supply and sanitation services; agricultural water; aquaculture in terms of its impact on the water resource; water policy and governance; water economics; water as a social good. Water SA is intended to serve both international and Southern African readers and authors. Contributions which are not of broad international interest must make a contribution to Southern Africa (defined for this purpose to include the countries of South Africa, Swaziland, Lesotho, Namibia, Botswana, Zimbabwe and Mozambique). Submissions of predominantly local interest outside of Southern Africa will not be considered.

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In shallow estuaries, artificial substrates provide a means of assessing the response of the diatom community to water chemistry. The shallow St Lucia Estuary was historically connected to the Mfolozi River at the mouth. This connection was severed during the early 1950s due to sediment input from the agriculturally impacted Mfolozi River. A connection has recently been re-established and the potential impact of dissolved inorganic nutrients from the Mfolozi River needs to be determined, as it may alter the ecological integrity of the St Lucia Estuary which forms part of a UNESCO World Heritage Site. This study found that the epilithic algal biomass and diatom species composition grown on glass slides were good indicators of nutrient enrichment in the estuary. Over a 28-day study period an above-average rainfall event resulted in an increase of nutrient-enriched freshwater flow into the estuary. No significant biomass differences were recorded in either the natural phytoplankton or microphytobenthos communities because of high variability. By contrast, the epilithic algal biomass accumulation on the glass slides was highest following the freshwater input. Statistical analyses indicated that the accumulation of the epilithic community on the glass slides was mostly affected by DIN and salinity. Diversity index scores for both the natural phytoplankton and microphytobenthos were variable, while the epilithic diatom index scores consistently declined from Day 7 (H’ = 1.2) to Day 28 (H’ = 0.7). These data indicate that epilithic algae grown on glass slides can be used as an effective monitoring tool to detect nutrient-induced changes as a supplementary method in this highly variable estuary.

Although the impervious layer under a hydraulic structure is rarely flat, the effect of the impervious layer’s slope, under the hydraulic structure, on seepage characteristics has not been studied to date. Therefore, this study investigated the effect of the downhill and uphill impervious layer’s slope (downhill/uphill foundation slopes) on the uplift pressure, seepage discharge and exit gradient under hydraulic structures. In order to reach this goal, a numerical model has been developed in which the general equation of fluid flow in non-uniform; anisotropic soil is solved by the finite volume method on a structured grid. The model validation was performed using the measured data from experimental tests. The results of the model validation indicated that the model calculates the seepage discharge and uplift pressure with a maximum error of less than 3.79% and 3.25%, respectively. The results also indicated that by increasing the downhill foundation slope (DFS) the uplift force decreases, but the exit gradient and seepage discharge increase. Moreover, by increasing the uphill foundation slope (UFS), the uplift force increases but the exit gradient and seepage discharge decrease. In addition, the results demonstrate that by increasing the length of the cut-off wall the effect of the DFS on decreasing and UFS on increasing the uplift pressure force becomes more severe. However, the effect of the DFS on increasing the seepage discharge and UFS on decreasing the seepage discharge becomes milder as the length of the cut-off wall increases. By increasing the DFS, from zero to −15%, the exit gradient increases 19.75% and 14.4% for 1 m and 6 m cut-off lengths, respectively.

The disposal of wastewater containing polyaromatic hydrocarbons (PAHs) has been observed to be a very costly process, hence mitigation for many industrial plants continues to be a challenge. The purpose of this study was to examine the potential use of C18 as a modifier in membrane technology; thus, C18 was incorporated into poly (vinylidene fluoride) (PVDF) membranes. According to the specific composition ratios, the phase inversion process was used for dispersion of the C18 into PVDF, which was subsequently dispersed in 1-methyl-2-pyrrolidone (NMP). The resulting membranes were characterised with Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The mechanical properties of the membranes were analysed using dynamic mechanical analysis (DMA), whereas the thermal behaviour was studied with a thermogravimetric analyser (TGA). Furthermore, the functionality of the synthesised membrane was further evaluated by its adsorption potentials using high performance liquid chromatography equipped with an ultraviolet detector. The SEM micrographs showed successful incorporation of the C18 within the polymeric membrane (PVDF) backbone. The TGA showed that the thermal decomposition of the synthesised membranes was observed at 495 and 610°C for PVDF bare and PVDF/C18, respectively. In addition, the HPLC results obtained indicated that the C18 modified membrane was more effective in adsorbing PAHs when compared to the bare PVDF membrane. The salient features of this study therefore suggest that C18 could be used as a potential modifier for the development of PVDF membranes.

Unsaturated soil hydraulic conductivity is a main parameter in agricultural and environmental studies, necessary for predicting and managing water and solute transport in soils. This parameter is difficult to measure in agricultural fields; thus, a simple and practical estimation method would be preferable, and quantitative methods (analytical and numerical) to predict the field parameters should be developed. Field experiments were conducted to collect water quality data to model the unsaturated hydraulic conductivity of a sandy loam soil. A mini disk infiltrometer (MDI) was used to measure soil infiltration rate. Input variables included electrical conductivity and the sodium adsorption ratio of irrigation water. Suction rate (pressure head), soil bulk density, and soil moisture content acted as inputs, with unsaturated soil hydraulic conductivity as output. The performance of Gaussian process regression (GPR) was analysed, with multiple linear regression (LR) and multi-layer perceptron (MLP) models used for comparison. Three performance criteria were compared: correlation coefficient (r), root mean square error (RMSE), and mean absolute error (MAE). The simulations employed the Waikato environment for knowledge analysis (WEKA) open source tool. The results indicate that the GPR with Pearson VII function-based universal kernel (PUK kernel), cache size 250007, Omega 1.0 and Sigma 1.0 performs better than other kernels when evaluating test split data, with a correlation coefficient of 0.9646. The RMSEs for GPR (PUK kernel), MLP, and LR were 1.16 × 10−04, 1.87 × 10−04, and 2.22 × 10−04 cm·s−1, respectively. Predictive data mining algorithms (DMA) enable an estimate of unknown values based on patterns in a database. Therefore, the present methodology can be put to use in predictive tools to manage water and solute transport in soils, as the GPR model provides much greater accuracy than the LR and MLP models in predicting the unsaturated hydraulic conductivity of a sandy loam soil.

Grain legumes have potential to contribute to food and nutritional security in water-scarce areas. Information on their yield, water use and water productivity (WP) would be useful for their promotion. The aim of the study was to make a comparative assessment of adaptation, yield, water use and WP of an African indigenous grain legume (bambara groundnut) and two major grain legumes (dry bean and groundnut) under rainfed, deficit and optimum irrigation conditions. Field trials were conducted during the 2015/16 and 2016/17 summer seasons in KwaZulu-Natal, South Africa, using a split-plot design arranged in completely randomised blocks with three replications. Data collected included stomatal conductance, leaf area index, timing of key phenological stages and yield. Water use was calculated as a residual of the soil water balance. Water productivity was obtained as the quotient of grain yield and water use. Crops adapted to limited soil water availability through stomatal regulation and reduction in canopy size and duration. Yield, yield components and WP varied significantly (P < 0.05) among crop species. During 2015/16, groundnut had the highest yield and WP (10 540 kg·ha−1 and 0.99 kg·m−3, respectively). During 2016/17, the highest yield and WP were observed in dry bean, 2 911 kg·ha−1 and 0.75 kg·m−3, respectively. For both seasons, dry bean had the lowest water use (143–268 mm) across all water treatments. Dry bean and groundnut out– performed bambara groundnut with respect to yield, harvest index and WP. For any promotion of bambara groundnut as an alternative crop, there is need for crop improvement to improve yield and WP.

The legume Acacia mearnsii invades South Africa’s fynbos riparian zones and may alter the nitrogen (N) dynamics and supply in these areas that typically support few native N fixers. Nitrogen uptake by A. mearnsii may also be influenced by water availability, potentially affecting riparian-specific performance and impact estimations. We expected to find functional differences between the invasive legume and the two co-occurring but non-leguminous native species Brabejum stellatifolium and Metrosideros angustifolia. We also wanted to examine whether in-situ water availability affected N source or uptake in the invasive species. We found A. mearnsii was indeed functioning differently from non-N-fixing native species, and had considerably higher foliar %N. Interestingly, 15N abundance and uptake were associated with site hydrology, meaning water availability should be scrutinised when assuming N-fixing in A. mearnsii using δ15N. Nonetheless, higher water availability toA. mearnsii in fynbos riparian ecosystems did increase foliar N uptake. This has implications for prioritizing clearing of sites with increased nutrient deposition, such as dense stands in relatively moist riparian zones.