Of the recently developed univariate and multivariate near-IR FT-Raman methods for estimating cellulose crystallinity, the former method was applied to a variety of lignocelluloses: softwoods, hardwoods, wood pulps, and agricultural residues/fibers. The effect of autofluorescence on the crystallinity estimation was minimized by solvent extraction or chemical treatment...

Population size estimates for stream fishes are important for conservation and management, but sampling costs limit the extent of most estimates to small portions of river networks that encompass 100s?10 000s of linear kilometres. However, the advent of large fish density data sets, spatial-stream-network (SSN) models that benefit from nonindependence among samples,...

A new method is proposed for estimation of cellulose crystallinity (CrI) based on 93 cm?1 Raman band in spectra of cellulose I materials. In this method (93-Raman), CrI was determined based on regression that was developed using the ratios of peak-heights of the 93 and 1096 cm?1 Raman bands (I93/I1096). For calibration...

Influences of fiber orientation and milling on wood cellulose crystallinity were studied using jack pine wood. The fiber orientation effects were measured by sampling rectangular wood blocks in radial, tangential, and cross-sectional orientations. The influence of milling was studied by analyzing the unsieved and sieved milled wood fractions (all

Precise, unbiased estimates of population size are an essential tool for fisheries management. For a wide variety of salmonid fishes, redd counts from a sample of reaches are commonly used to monitor annual trends in abundance. Using a 9-year time series of georeferenced censuses of Chinook salmon (Oncorhynchus tshawytscha) redds from central Idaho,...

Syringyl (S) lignin content and the syringyl-to-guaiacyl (S/G) lignin ratio are important characteristics of wood and lignocellulosic biomass. Although numerous methods are available for estimating S lignin units and the S/G ratio, in this work, a new method based on Raman spectroscopy that uses the 370 cm?1 Raman band-area intensity (370-area)...

Two simple methods based on the 370 cm-1 Raman band intensity were developed for estimation of syringyl-to-guaiacyl (S/G) ratio in woods. The methods, in principle, are representative of the whole cell wall lignin and not just the portion of lignin that gets cleaved to release monomers, for example, during certain S/G chemical analyses. As such,...

Wildfires can lead to severe environmental consequences by releasing large amounts of particulate matter (PM) and precursors of ozone (Sandberg et al., 1999; Riebau and Fox, 2001). The Southeast has the most burned area among various U.S. regions (Stanturf et al., 2002) and has regionally some of the highest levels of PM and ozone in the nation. Fires have been found...

Although X-ray diffraction (XRD) has been the most widely used technique to investigate crystallinity index (CrI) and crystallite size (L200) of cellulose materials, there are not many studies that have taken into account the role of sample moisture on these measurements. The present investigation focuses on a variety of celluloses and cellulose...

Estimating the thermal response of streams to a warming climate is important for prioritizing native fish conservation efforts. While there are plentiful estimates of air temperature responses to climate change, the sensitivity of streams, particularly small headwater streams, to warming temperatures is less well understood. A substantial body of literature correlates...

Urban heat island (UHI) is one major anthropogenic modification to the Earth system that transcends its physical boundary. Using MODIS data from 2003 to 2012, we showed that the UHI effect decayed exponentially toward rural areas for majority of the 32 Chinese cities. We found an obvious urban/ rural temperature ?cliff?, and estimated that the footprint of UHI effect (...

Population viability analysis (PVA) uses concepts from theoretical ecology to provide a powerful tool for quantitative estimates of population dynamics and extinction risks. However, conventional statistical PVA requires long-term data from every population of interest, whereas many species of concern exist in multiple isolated populations that are only monitored...

Large rivers constitute small portions of drainage networks but provide important migratory habitats and fisheries for salmon and trout when and where temperatures are sufficiently cold. Management and conservation of cold?water fishes in the current era of rapid climate change requires knowing how riverine thermal environments are evolving and the potential for...

Smoke from wildland fires is one of the sources of atmospheric anthropogenic aerosols. it can dramatically affect regional and global radiative balance. Ross et al. (1998) estimated a direct radiative forcing of nearly -20 Wm-2 for the 1995 Amazonian smoke season (August and September). Penner et al. (1992) indicated that the magnitude of the...

Despite widespread efforts to avert wildfire by reducing the density of flammable vegetation, little is known about the effects of this practice on the reproductive biology of forest birds. We examined nest-site selection and nest survival of the Black-chinned Hummingbird (Archilochus alexandri) in New Mexico riparian forests treated or not for fuel...

This study analyzes spatial and temporal variability of emissions from wildland fires across the contiguous US. The emissions are estimates based on a recently constructed dataset of historical fire records collected by multiple US governlnental agencies. Both wildfire and prescribed fires have the highest emissions over the Pacific coastal states. Prescribed fire...

Drought provides a favourable environment for the ignition and spread of intense wildfires. This study examines the opposite relationship between the two natural disasters, that is, the role of wildfires in the development of drought. The case of the 1988 northern U.S. wildfires is investigated. Emissions of smoke particles from the wildfires and the resulting optical...

The technique of selective 13C-enrichment of specific carbons in lignin combined with 13C-NMR differential spectrometry between spectra of 13C-enriched and unenriched lignins (Ä13C-NMR) provides definitive information on the structure of the lignin macromolecule. Improvements were made on, (1) specific 13C-enrichment of almost all carbons involved in inter-unit bonds...

Simulations are performed to understand the importance of smoke from biomass burning in tropical South America to regional radiation and climate. The National Center for Atmospheric Research (NCAR) regional climate model coupled with the NCAR column radiative model is used to estimate smoke direct radiative forcing and consequent atmospheric perturbations during a...