Energy storage technologies are of great interest to electric utilities, energy service companies, and automobile manufacturers (for electric vehicle application). The ability to store large amounts of energy would allow electric utilities to have greater flexibility in their operation because with this option the supply and demand do not have to be matched instantaneously. The availability of the proper battery at the right price will make the electric vehicle a reality, a goal that has eluded the automotive industry thus far. Four types of storage technologies (listed below) are discussed in this section, but most emphasis is placed on storage batteries because it is now closest to being commercially viable. The other storage technology widely used by the electric power industry, pumped-storage power plants, is not discussed as this has been in commercial operation for more than 60 years in various countries around the world.

Flywheel storage

Compressed air energy storage

Superconducting magnetic energy storage

Battery storage

Flywheel Storage

Flywheels store their energy in their rotating mass, which rotates at very high speeds (approaching 75,000 rotations per minute), and are made of composite materials instead of steel because of the composite’s ability to withstand the rotating forces exerted on the flywheel. In order to store enegy the flywheel is placed in a sealed container which is then placed in a vacuum to reduce air resistance. Magnets embedded in the flywheel pass near pickup coils. The magnet induces a current in the coil changing the rotational energy into electrical energy.

Flywheels are still in research and development, and commercial products are several years away.

Compressed Air Energy Storage

As the name implies, the compressed air energy storage (CAES) plant uses electricity to compress air which is stored in underground reservoirs. When electricity is needed, this compressed air is withdrawn, heated with gas or oil, and run through an expansion turbine to drive a generator. The compressed air can be stored in several types of underground structures, including caverns in salt or rock formations, aquifers, and depleted natural gas fields. Typically the compressed air in a CAES plant uses about one third of the premium fuel needed to produce the same amount of electricity as in a conventional plant. A 290-MW CAES plant has been in operation in Germany since the early 1980s with 90% availability and 99% starting reliability. In the U.S., the Alabama Electric Cooperative runs a CAES plant that stores compressed air in a 19-million cubic foot cavern mined from a salt dome. This 110-MW plant has a storage capacity of 26 h. The fixed-price turnkey cost for this first-of-a-kind plant is about $400/kW in constant 1988 dollars.

The turbomachinery of the CAES plant is like a combustion turbine, but the compressor and the expander operate independently. In a combustion turbine, the air that is used to drive the turbine is compressed just prior to combustion and expansion and, as a result, the compressor and the expander must operate at the same time and must have the same air mass flow rate. In the case of a CAES plant, the compressor and the expander can be sized independently to provide the utility-selected “optimal” MW charge and discharge rate which determines the ratio of hours of compression required for each hour of turbine-generator operation. The MW ratings and time ratio are influenced by the utility’s load curve, and the price of off-peak power.

For example, the CAES plant in Germany requires 4 h of compression per hour of generation. On the other hand, the Alabama plant requires 1.7 h of compression for each hour of generation. At 110-MW net output, the power ratio is 0.818 kW output for each kilowatt input. The heat rate (LHV) is 4122 BTU/kWh with natural gas fuel and 4089 BTU/kWh with fuel oil. Due to the storage option, a partial-load operation of the CAES plant is also very flexible. For example, the heat rate of the expander increases only by 5%, and the airflow decreases nearly linearly when the plant output is turned down to 45% of full load. However, CAES plants have not reached commercial viability beyond some prototypes.

Superconducting Magnetic Energy Storage

A third type of advanced energy storage technology is superconducting magnetic energy storage (SMES), which may someday allow electric utilities to store electricity with unparalled efficiency (90% or more). A simple description of SMES operation follows. The electricity storage medium is a doughnut-shaped electromagnetic coil of superconducting wire. This coil could be about 1000 m in diameter, installed in a trench, and kept at superconducting temper- ature by a refrigeration system. Off-peak electricity, converted to direct current (DC), would be fed into this coil and stored for retrieval at any moment. The coil would be kept at a low-temperature supercon- ducting state using liquid helium.

The time between charging and discharging could be as little as 20 ms with a round-trip AC–AC efficiency of over 90%.

Developing a commercial-scale SMES plant presents both economic and technical challenges. Due to the high cost of liquiud helium, only plants with 1000-MW, 5-h capacity are economically attractive. Even then the plant capital cost can exceed several thousand dollars per kilowatt. As ceramic superconductors, which become superconducting at higher temperatures (maintained by less expensive liquid nitrogen), become more widely available, it may be possible to develop smaller scale SMES plants at a lower price.

Battery Storage

Even though battery storage is the oldest and most familiar energy storage device, significant advances have been made in this technology in recent years to deserve more attention. There has been renewed interest in this technology due to its potential application in non-polluting electric vehicles. Battery systems are quiet and non-polluting, and can be installed near load centers and existing suburban substations. These have round-trip AC–AC efficiencies in the range of 85%, and can respond to load changes within 20 ms. Several U.S., European, and Japanese utilities have demonstrated the application of lead–acid batteries for load-following applications. Some of them have been as large as 10 MW with 4 h of storage.

The other player in battery development is the automotive industry for electric vehicle application. In 1991, General Motors, Ford, Chrysler, Electric Power Research Institute (EPRI), several utilities, and the U.S. Department of Energy (DOE) formed the U.S. Advanced Battery Consortium (USABC) to develop better batteries for electric vehicle (EV) applications. A brief introduction to some of the available battery technologies as well some that are under study is presented in the following (Source:http://www.eren. doe.gov/consumerinfo/refbriefs/fa1/html).

Battery Types

Chemical batteries are individual cells filled with a conducting medium-electrolyte that, when connected together, form a battery. Multiple batteries connected together form a battery bank. At present, there are two main types of batteries: primary batteries (non-rechargeable) and secondary batteries (rechargeable). Secondary batteries are further divided into two categories based on the operating temperature of the electrolyte. Ambient operating temperature batteries have either aqueous (flooded) or nonaqueous elec- trolytes. High operating temperature batteries (molten electrodes) have either solid or molten electrolytes. Batteries in EVs are the secondary-rechargeable-type and are in either of the two sub-categories. A battery for an EV must meet certain performance goals.

These goals include quick discharge and recharge capability, long cycle life (the number of discharges before becoming unserviceable), low cost, recycla- bility, high specific energy (amount of usable energy, measured in watt-hours per pound [lb] or kilogram [kg]), high energy density (amount of energy stored per unit volume), specific power (determines the potential for acceleration), and the ability to work in extreme heat or cold. No battery currently available meets all these criteria.

Lead–Acid Batteries

Lead–acid starting batteries (shallow-cycle lead–acid secondary batteries) are the most common battery used in vehicles today. This battery is an ambient temperature, aqueous electrolyte battery. A cousin to this battery is the deep-cycle lead–acid battery, now widely used in golf carts and forklifts. The first electric cars built also used this technology. Although the lead–acid battery is relatively inexpensive, it is very heavy, with a limited usable energy by weight (specific energy). The battery’s low specific energy and poor energy density make for a very large and heavy battery pack, which cannot power a vehicle as far as an equivalent gas-powered vehicle. Lead–acid batteries should not be discharged by more than 80% of their rated capacity or depth of discharge (DOD). Exceeding the 80% DOD shortens the life of the battery. Lead–acid batteries are inexpensive, readily available, and are highly recyclable, using the elaborate recycling system already in place. Research continues to try to improve these batteries.

A lead–acid nonaqueous (gelled lead acid) battery uses an electrolyte paste instead of a liquid. These batteries do not have to be mounted in an upright position. There is no electrolyte to spill in an accident. Nonaqueous lead–acid batteries typically do not have as high a life cycle and are more expensive than flooded deep-cycle lead–acid batteries.

Nickel Iron and Nickel Cadmium Batteries

Nickel iron (Edison cells) and nickel cadmium (nicad) pocket and sintered plate batteries have been in use for many years. Both of these batteries have a specific energy of around 25 Wh/lb (55 Wh/kg), which is higher than advanced lead–acid batteries. These batteries also have a long cycle life. Both of these batteries are recyclable. Nickel iron batteries are non-toxic, while nicads are toxic. They can also be discharged to 100% DOD without damage. The biggest drawback to these batteries is their cost. Depend- ing on the size of battery bank in the vehicle, it may cost between $20,000 and $60,000 for the batteries. The batteries should last at least 100,000 mi (160,900 km) in normal service.

Nickel Metal Hydride Batteries

Nickel metal hydride batteries are offered as the best of the next generation of batteries. They have a high specific energy: around 40.8 Wh/lb (90 Wh/kg). According to a U.S. DOE report, the batteries are benign to the environment and are recyclable. They also are reported to have a very long cycle life. Nickel metal hydride batteries have a high self-discharge rate: they lose their charge when stored for long periods of time. They are already commercially available as “AA” and “C” cell batteries, for small consumer appliances and toys. Manufacturing of larger batteries for EV applications is only available to EV manufacturers. Honda is using these batteries in the EV Plus, which is available for lease in California.

Sodium Sulfur Batteries

This battery is a high-temperature battery, with the electrolyte operating at temperatures of 572°F (300°C). The sodium component of this battery explodes on contact with water, which raises certain safety concerns. The materials of the battery must be capable of withstanding the high internal temper- atures they create, as well as freezing and thawing cycles. This battery has a very high specific energy: 50 Wh/lb (110 Wh/kg). The Ford Motor Company uses sodium sulfur batteries in their Ecostar, a converted delivery minivan that is currently sold in Europe. Sodium sulfur batteries are only available to EV manufacturers.

Lithium Iron and Lithium Polymer Batteries

The USABC considers lithium iron batteries to be the long-term battery solution for EVs. The batteries have a very high specific energy: 68 Wh/lb (150 Wh/kg). They have a molten-salt electrolyte and share many features of a sealed bipolar battery. Lithium iron batteries are also reported to have a very long cycle life. These are widely used in laptop computers. These batteries will allow a vehicle to travel distances and accelerate at a rate comparable to conventional gasoline-powered vehicles. Lithium polymer batteries eliminate liquid electrolytes. They are thin and flexible, and can be molded into a variety of shapes and sizes.

Neither type will be ready for EV commercial applications until early in the 21st century.

Zinc and Aluminum Air Batteries

Zinc air batteries are currently being tested in postal trucks in Germany. These batteries use either aluminum or zinc as a sacrificial anode. As the battery produces electricity, the anode dissolves into the electrolyte. When the anode is completely dissolved, a new anode is placed in the vehicle. The aluminum or zinc and the electrolyte are removed and sent to a recycling facility. These batteries have a specific energy of over 97 Wh/lb (200 Wh/kg). The German postal vans currently carry 80 kWh of energy in their battery, giving them about the same range as 13 gallons (49.2 liters) of gasoline. In their tests, the vans have achieved a range of 615 mi (990 km) at 25 miles per hour (40 km/h)..

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