High purity plastics greatly improve the propagation of radiation-induced light

November 8th, 2013 in Physics / Condensed Matter

Highly-purified Polystyrene

Highly-purified Polystyrene

Japanese researchers have reported major improvements in the propagation of light generated by radiation in highly purified plastics. The research was published in the issue of Applied Physics Letters on October 16, 2013.

Plastics that emit light when exposed to radiation are widely used in particle and nuclear physics experiments, and have been integral to radiation measurements in decontamination operations such as that in Fukushima Prefecture. A better understanding of the behavior of light emitted by plastics because of radiation will enable improved measurements of radiation or radioactivity.

This research team manufactured high-purity (>99.9%) polystyrene plastic that exhibits a much greater propagation distance for ultraviolet light than that of general-use polystyrene. Additionally, in-depth analysis of the ultraviolet light propagation revealed that values for the refractive index that were based on the longer-wavelength sodium D-line (589nm) were inaccurate. Instead, the team calculated a highly reliable and much more accurate "effective refractive index" that considers the wavelength distribution of light generated by the radiation.

These findings will contribute significantly at the fundamental level to the design of light propagation in radiation measurement devices, and will have far-reaching effects from particle physics experiments to optical fibers (e.g., scintillation fibers or wavelength shifters) that are used in high-performance radiation measurements and decontamination cleanup.

Research Methods and Findings

Basic data that characterizes the propagation of light generated by radiation includes the light attenuation length (defined as the distance in which the light intensity decreases by 0.36), the reflectivity, and the refractive index. The attenuation length of ultraviolet light in normal polystyrene plastic is only 1mm. The research team produced highly-purified polystyrene (>99.9%) to study in greater detail the behavior of light produced by radiation. The attenuation length of the highly purified polystyrene was much longer (41.6mm) than that found in general-use polystyrene. Additionally, the group devised a mathematical function that goes beyond the standard index based on the sodium D-line and describes an "Effective Refractive Index" (Neff=1.67) that considers the entire spectrum of light generated by radiation. By doing so, they can increase the accuracy in radiation measurements. This function is generally applicable to other materials that generate light.

Spillover Effects

This research has provided a better understanding of the behavior of light in plastics, and a more comprehensive understanding of the nature of light produced by radiation. In particular, applications using plastic optical fibers have dramatically improved the reliability of data based on outputted values, as well as in the initial values that are used in simulations to replicate the behavior of lightpropagation. Thus, higher performance can now be realized for the measurement of radiation or radioactivity.