2015-03-31T22:10:17ZEngineering properties of historic brick – variability considerations as a function of stationary versus nonstationary kiln typehttp://hdl.handle.net/10197/3609
Engineering properties of historic brick – variability considerations as a function of stationary versus nonstationary kiln type
Laefer, Debra F.; Boggs, Justin; Cooper, Nicole
Brick produced prior to the mid-twentieth century exhibit high levels of variability in appearance, geometry, and mechanical properties. Understanding historic brick variability is important for accurate performance prediction of existing structures, and for the selection of appropriate replacement units. A lack of uniformity amongst historic brick can be caused by the molding and firing methods, as well as the composition of their raw materials. This paper focuses on one aspect of production-induced disparities: kiln type. Tremendous variance can be shown from this alone, between both kiln type and even within a single firing. Although kilns of past eras were constantly improved for energy efficiency, their products continued to be highly inconsistent in appearance and performance. This paper presents the mechanics of heat distribution in kilns and demonstrates its direct impact on the variability of engineering properties due to
inconsistent heat application.
2004-01-01T00:00:00ZAssessment and code considerations for the combined effect of seismic base-isolation and viscoelastic dampershttp://hdl.handle.net/10197/3608
Assessment and code considerations for the combined effect of seismic base-isolation and viscoelastic dampers
Erkal, Aykut; Tezcan, Semih S.; Laefer, Debra F.
To propose an initial formulation for the passive control section of the Turkish Earthquake Code, the impact of base isolation and viscoelastic dampers on a four-story reinforced concrete (RC) frame building was considered under various one-dimensional earthquake excitations. Both statically equivalent seismic load methods (comparing Turkish Earthquake code with Uniform Building Code) and linear time history analyses were applied to the RC building based on a portion of the 1999 Kocaeli Earthquake ground motion record (modified to possess predominant spectral periods of T1=0.13 sec and T2=1.43 sec). Effective peak ground acceleration was set to 0.40g representing hard and soft soil conditions, respectively. Time history variations of upper column displacements and bending moments were compared, as well as story drift ratios. Reductions of the fixed-base case displacements and column bending moments were obtained of up to 73% under base-isolation, up to 25% with viscoelastic dampers, and up to 83% (with a unified response reduction factor) when both devices were both present.
2011-01-01T00:00:00ZSemi-analytical determination of natural frequencies and mode shapes of multi-span bridge deckshttp://hdl.handle.net/10197/3563
Semi-analytical determination of natural frequencies and mode shapes of multi-span bridge decks
Rezaiguia, Abdelouahab; Laefer, Debra F.
The determination of the natural frequencies and mode shapes of structures requires an analytical, semi-analytical or numerical method. This paper presents a new semi-analytical approach to determine natural frequencies and mode shapes of a multi-span, continuous, orthotropic bridge deck. The suggested approach is based on the modal method, which differs from other approaches in its decomposition of the admissible functions defining the mode shapes. Implementation of this technique is simple and enables avoidance of cumbersome mathematical calculations. In this paper, application of the semi-analytic approach to a three-span, orthotropic roadway bridge deck is compared in the first 16 modes of previously published fully analytical results and to a finite element method analysis. The simplified implementation matches within 2 % in all cases, with the additional benefit of including intermodal coupling. The approach can be extended to similar bridges with more than three spans.
2009-12-01T00:00:00ZDynamic analysis of a beam resting on an elastic half-space with inertial propertieshttp://hdl.handle.net/10197/3525
Dynamic analysis of a beam resting on an elastic half-space with inertial properties
Laefer, Debra F.; Guenfoud, S.; Bosakov, S. V.
This work gives a semi-analytical approach for the dynamic analysis of beams and plates rest-ing on an elastic half-space with inertial properties. Such calculations have been associated with significant mathematical challenges, often leading to unrealizable computing processes. Therefore, this paper presents a detailed analysis of Green’s function defining surface displacements of such a space in the contact zone with structures, which allows determination of reactive forces and other physical responses. The obtained solutions can be applied to (i) study dynamic interaction between soil and structures, (ii) determine transient wave fields caused by a seismic source, and (iii) assess numerical computations with different numerical methods programs. Natural frequencies, natural shapes, and the dynamic response of a beam due to external harmonic excitation are determined. Eigenfrequencies and Eigenshapes are presented. Validation with a Boussinesq problem illustrates the inertia effect on the results of the dynamic analysis.
2009-08-01T00:00:00ZExpansive fracture agent behaviour for concrete
crackinghttp://hdl.handle.net/10197/3441
Expansive fracture agent behaviour for concrete
cracking
Laefer, Debra F.; Ceribasi, Seyit; Wortman, John; Abrozevitch-Cooper, Nicole; Huynh, Minh-Phuoc; Midgette, J.
Increasing concerns regarding litigation and terrorism provide a strong dual motivation to decrease high explosives usage in the construction industry. This paper provides parameter considerations and initial guidelines for the application of expansive fracture agents, typically used for concrete and soft rock removal. This approach may be especially appropriate near environmentally and historically sensitive sites. Thirty-three unreinforced blocks (approximately a cubic meter each) of varying strengths composed of sand, cement, and flyash were tested under various temperature environments, with differing expansive agents, confinement levels, and post-cracking treatments. Cracking characteristics such as crack initiation and crack expansion were analyzed. Although the performance of expansive cement was dependent upon a highly complex set of variable interactions, higher ambient temperatures, higher agent mixture temperatures, and chemical configuration designed for colder temperatures decreased the time to first crack and hastened the extent of cracking. Conversely, higher strength material required more time to first crack, as well as an extended time to achieve a 25.4 mm wide crack. Manual interference with the normal material volume expansion slowed the cracking process but did not truncate it, while the manufacturer’s recommendation to introduce water post-cracking actually reduced and slowed the extent of cracking.
2010-06-01T00:00:00ZAssessment of excavation-induced building damagehttp://hdl.handle.net/10197/3428
Assessment of excavation-induced building damage
Laefer, Debra F.; Cording, Edward J.; Long, James L.; Son, Moorak; Ghahreman, Bidjan
Ground movements during excavation have the potential for major impact on nearby buildings, utilities and streets. Increasingly ground movements are controlled at the source. They are assessed by linking the ground loss at the excavation wall to the volume change and displacements in the soil mass, and then to the lateral strains and angular distortion in structural bays or units, and are related to damage using a damage criterion based on the state of strain at a point. Numerical and physical models of excavation-induced building damage were used to vary parameters and develop procedures for assessing distortion and damage. Examples of building distortion and damage are presented for brick bearing wall structures of the 1800’s and early 1900’s, as well as later frame structures, that illustrate how geometry, era of construction, stiffness, and condition influence building response to ground movement.
Paper presented at the ER2010, Earth Retention Conference 3, August 1-4, 2010, Bellevue, Washington
2010-08-01T00:00:00ZUnderstanding microcrystalline waxes for the seismic protection of art objectshttp://hdl.handle.net/10197/3427
Understanding microcrystalline waxes for the seismic protection of art objects
Crowley, Anne; Laefer, Debra F.
Use of microcrystalline waxes for the protection of ceramic art objects from seismic events is an inexpensive and relatively popular technique. This paper presents performance results for three commercial, microcrystalline waxes based on anchoring requirements of resisting seismic-induced tensile and shear forces, while exhibiting a ductile failure mode to prevent objects from suddenly detaching themselves from their display units and becoming sufficiently mobile to fall off stands or collide with other art objects. As many of the testing techniques described in this paper are not easily accessible to the average museum conservator, and some of the products may not be readily available, emphasis is placed on establishing an expected range of strengths, and correlations are suggested for predicting the general performance of any microcrystalline wax in a specific application arrangement, based on easily performed, simplified tests that were found to be able to predict tensile capacity within 10%. Distinctive performance trends were found amongst various products with capacity being as much as 183 kPa in tension and 42kPas in shear. The pre-application of a methylacrylate copolymer to the bonding surface consistently improved performance, while increasing wax thickness did not.
2008-01-01T00:00:00ZDynamic increment for shear force due to heavy vehicles crossing a highway bridgehttp://hdl.handle.net/10197/3426
Dynamic increment for shear force due to heavy vehicles crossing a highway bridge
González, Arturo; Cantero, Daniel; O'Brien, Eugene J.
Most of the current research on dynamic amplification factors caused by traffic flow on a bridge has focused on bending moment effects. Although bending stresses often govern the requirements of the bridge section, sufficient shear capacity must be provided too. Shear stresses near the support are strongly influenced by damaged expansion joints and/or differential settlements between the bridge deck and the approach road. The latter is taken into account in this theoretical investigation to evaluate the dynamics associated with the shear load effect caused by heavy trucks and how it relates to the length of the bridge span.
2011-12-01T00:00:00ZLateral image degradation in terrestrial laser scanninghttp://hdl.handle.net/10197/3408
Lateral image degradation in terrestrial laser scanning
Laefer, Debra F.; Fitzgerald, M.; Maloney, Eoghan M.; Coyne, David; Lennon, Donal; Morrish, Sean
The use of aerial laser scanning to detect change in infrastructure and buildings after major disasters has become increasingly common in recent years to help prioritize interventions. More recent efforts are being invested to apply laser scanning in the assessment and structural health monitoring of buildings to simplify and quicken building damage surveys by the automatic detection of defects and deformations. Technology application must, however, be done in cognizance of equipment constraints regarding scan angle, sampling size, and beam width. This article reports a series of laboratory and field experiments designed to begin to quantify and minimise the possible errors for effective defect detection via terrestrial laser scanning during surveying. Varying geometric positions that cause either over- or under-prediction of crack thickness and length as a function of both standoff distance and angle of obliquity between the scanner and the defect are presented. These may over-predict horizontal crack thickness by 15 mm and failing to detect others. To help minimise such errors, a standoff distance of 12–15 m with a maximum obliquity of 45˚ between the scanner and target object are recommended.
2009-05-01T00:00:00ZThree-dimensional spatial information systems : state of the art reviewhttp://hdl.handle.net/10197/3407
Three-dimensional spatial information systems : state of the art review
Schön, Bianca; Laefer, Debra F.; Bertolotto, Michela; Morrish, Sean
A spatial information system (SIS) is critical to the hosting, querying, and analyzing of spatial data sets. The increasing availability of three-dimensional (3D) data (e.g. from aerial and terrestrial laser scanning) and the desire to use such data in large geo-spatial platforms have been dual drivers in the evolution of integrated SISs. Within this context, recent patents demonstrate efforts to handle large data sets, especially complex point clouds. While the development of feature-rich geo-systems has been well documented, the implementation of support for 3D capabilities is only now being addressed. This paper documents the underlying technologies implemented for the support for 3D features in SISs. Examples include ESRI’s ArcGIS geo-database with its support for two-and-a-half dimensions (2.5D) in its Digital Elevation Model (DEM) and Triangular Irregular Network (TIN), the more recent development of the Terrain feature class, and support for 3D objects and buildings with its multi-patch feature class. Recent patents and research advances aim to extract DEMs and TINs automatically from point cloud data. In this context, various data structuring innovations are presented including both commercial and open source alternatives.
2009-01-01T00:00:00ZTheoretical solutions for strength-scaled unreinforced masonry for scaled soil-structure
experimentationhttp://hdl.handle.net/10197/3399
Theoretical solutions for strength-scaled unreinforced masonry for scaled soil-structure
experimentation
Laefer, Debra F.; Erkal, Aykut; Cording, Edward J.; Long, James H.; Truong-Hong, Linh
Reduced-scale masonry testing offers advantages of lower costs and shorter schedules compared to full-scale testing, but achieving results reflective of full-scale behavior requires development and fulfilment of appropriate scaling relationships. In many model-scale experiments, geometric scaling occurs but kinematic and/or dynamic similitude is not fully satisfied. This paper describes the theoretical basis and evolution of the equations necessary to achieve kinematic similitude for soil-structure testing at one-gravity for unreinforced masonry. Critical considerations relate to preventing the soil from being overloaded. By adopting a standard linear relationship of increased soil stiffness with depth, the controlling principle becomes the application of restricted, scaled loads throughout the entirety of the structure-soil system. As such, material strength and stiffness must be scaled accordingly to respond appropriately under the reduced stress. An example is provided for an adjacent excavation experiment with related empirical verification and computational quantification.
2010-07-01T00:00:00ZProcessing of terrestrial laser scanning point cloud data for computational modelling of building facadeshttp://hdl.handle.net/10197/3398
Processing of terrestrial laser scanning point cloud data for computational modelling of building facades
Laefer, Debra F.; Truong-Hong, Linh; Fitzgerald, M.
With the rapidly increasing availability of laser scanning data and the growing pressure to use it as the basis for computational models, there has been heighten interest in quickly, cost-effectively, and accurately processing the resulting point cloud data sets so that they are compatible for importation into computational models. This paper presents traditional strategies for solid model generation and examines in detail innovations and continuing limitations of recent patents, newly published research, and some currently available commercial programs for the transformation of laser scanning point cloud data into solid models appropriate for finite element method meshing and various meshing strategies particularly well-suited for point cloud data.
2011-01-01T00:00:00ZManufacturing, assembly, and testing of scaled, historic masonry for one-gravity, pseudo-static, soil-structure experimentshttp://hdl.handle.net/10197/3397
Manufacturing, assembly, and testing of scaled, historic masonry for one-gravity, pseudo-static, soil-structure experiments
Laefer, Debra F.; Long, James H.; Cording, Edward J.; Erkal, Aykut; Truong-Hong, Linh
In many model-scale experiments, geometric scaling is upheld but kinematic and/or dynamic similitude is not because of the difficulty in manufacturing and assembling small models. This paper describes scaling, manufacturing, assembly, and testing of 1/10th scaled historic masonry materials for one-gravity, pseudo-static, soil-structure testing. Prototype selection, manufacturing limitations, constructibility constraints, and testing decisions are presented, alongside details related to model construction. Compressive, tensile, and shear capacities of one-tenth scale prototype values, as well as failure mechanisms, were achieved by adopting traditional brick extrusion and firing methods, in conjunction with modifying mortar products developed for historic restoration. When scaled-masonry structures were subjected to adjacent excavation, damage levels and patterns and levels were consistent with full-scale, field observations.
2011-12-01T00:00:00ZCo-conditioning of the anaerobic digested sludge of a municipal wastewater treatment plant with alum sludge : benefit of phosphorus reduction in reject waterhttp://hdl.handle.net/10197/3275
Co-conditioning of the anaerobic digested sludge of a municipal wastewater treatment plant with alum sludge : benefit of phosphorus reduction in reject water
Yang, Y.; Zhao, Y.Q.; Babatunde, A.O.; Kearney, P.
In this study, alum sludge was introduced into co-conditioning and dewatering with an anaerobic digested activated sludge to examine the role of the alum sludge in improving the dewaterbility of the mixed sludge and also in immobilizing phosphorus in the reject water. Experiments have demonstrated that the optimal mix ratio for the two sludges is 2:1 (anaerobic digested sludge: alum sludge; volume basis), and this can bring about 99% phosphorus reduction in the reject water through the adsorption of phosphorus by Al in the sludge. The phosphorus loading in wastewater treatment plants is itself derived from the recycling of reject water during the wastewater treatment process. Consequently, this co-conditioning and dewatering strategy can achieve a significant reduction in phosphorus loading in wastewater treatment plants. In addition, the use of the alum sludge can beneficially enhance the dewaterbility of the resultant mixed sludge by decreasing both the SRF and the CST, due to the alum sludge acting as a skeleton builder. Experiments have also demonstrated that the optimal polymer (Superfloc C2260) dose for the anaerobic digested sludge was 120 mg/l while the optimal dose for the mixed sludge (mix ratio 2:1) was 15 mg/l, highlighting a huge saving in polymer addition. Therefore, from the technical perspective, the co-conditioning and dewatering strategy can be viewed as a “win-win” situation. However, for its full-scale application, integrated cost-effective analysis of process capabilities, sludge transport, increased cake disposal, additional administration, polymer saving etc. should be factored in.
2007-12-01T00:00:00ZOn the role of gypsum (CaSO_4.2H_2O) in conditioning and dewatering of a waterworks sludgehttp://hdl.handle.net/10197/3269
On the role of gypsum (CaSO_4.2H_2O) in conditioning and dewatering of a waterworks sludge
Zhao, Y.Q.; Allen, Stephen; Sun, Guangzhi
Problems concerning the management and utilization of sludge derived from water treatment processes are still not fully solved. A common approach is direct discharge to a landfill site. This study provides experimental data to demonstrate the effectiveness of a combination of gypsum (CaSO4x2H2O) and an organic polymer in alum sludge conditioning and dewatering. Experimental results demonstrated that the filterability of dually conditioned alum sludge was significantly improved by the addition of gypsum at a 1:1 ratio (WT/WT) to original sludge solids. Dewatering tests showed that a further decrease of almost seven percentage of sludge cake equilibrium moisture content was achieved by the involvement of gypsum compared to the situation of single polymer conditioning. The importance of this study lies in the possible application of dewatered alum sludge to land use or as a filter medium in constructed wetland for wastewater treatment, providing a positive solution to the problem of alum sludge disposal.
2004-01-01T00:00:00ZOptimising the performance of a lab-scale tidal flow reed bed system treating agricultural wastewaterhttp://hdl.handle.net/10197/3263
Optimising the performance of a lab-scale tidal flow reed bed system treating agricultural wastewater
Zhao, Y.Q.; Sun, Guangzhi; Lafferty, C.; Allen, Stephen
A gravel-based tidal flow reed bed system was operated with three different strategies in order to investigate its optimal performance for the treatment of high strength agricultural wastewaters. According to the three strategies, individual reed beds of the system were saturated and unsaturated with the wastewaters for different periods while steady hydraulic and organic loadings were maintained. Experiment results demonstrated that the system produced highest pollutant removal efficiencies with relatively short saturated period and long unsaturated period, highlighting the importance of O2 transfer into reed bed matrices during the treatment of high strength wastewaters. Significant removals of some major organic and inorganic pollutants were achieved with all the three operation strategies. Nitrification was not the major route of NH4-N removal when the system was under high organic loading. Due to the filtration of suspended solids and accumulation of biomass, gradual clogging of the reed bed matrices took place. The clogging caused concerns over the long-term efficiency of the current tidal flow reed bed system.
2004-01-01T00:00:00ZFrom "fills" to filter : insights into the reuse of dewatered alum sludge as a filter media in a constructed wetlandhttp://hdl.handle.net/10197/3262
From "fills" to filter : insights into the reuse of dewatered alum sludge as a filter media in a constructed wetland
Babatunde, A.O.; Zhao, Y.Q.; Yang, Y.; Kearney, P.
Dewatered alum sludge, a by-product of drinking water treatment plants, hitherto consigned to landfills was used to develop a novel bio-filter in form of a constructed wetland. Performance results have demonstrated the benefits of the alum sludge cakes in a lab-scale system in enhancing phosphorus (P) removal from an animal farm wastewater. Although P and organic matter were concurrently removed in the system, there was a probable “one off” release of organics from the system, and this coincided with an increase in inlet P concentration from 39.2 mg-P/l to 163.0 mg-P/l. A conceptual model was then proposed to explain and discuss this.
2007-07-01T00:00:00ZDewatered alum sludge : a potential adsorbent for phosphorus removalhttp://hdl.handle.net/10197/3261
Dewatered alum sludge : a potential adsorbent for phosphorus removal
Yang, Y.; Tomlinson, D.; Kennedy, S.; Zhao, Y.Q.
Alum sludge refers to the by-product from the processing of drinking water in Water Treatment Works. In this study, groups of batch experiments were designed to identify the characteristics of dewatered alum sludge for phosphorus adsorption. Air-dried alum sludge (moisture content 10.2%), which was collected from a Water Treatment Works in Dublin, was subjected for artificial P-rich wastewater adsorption tests using KH2PO4 as a model P source. Adsorption behaviours were investigated as a function of amount and particle size of alum sludge; pH of solution; and adsorption time. The results have shown that pH plays a major role not only in the adsorption process but also in the adsorption capacity. With regard to adsorption capacity, this study reveals the Langmuir adsorption isotherm being the best fit with experimental data (R2=0.98-0.99). The maximum adsorption capacities range from 0.7 to 3.5mg-P/g when the pH of the synthetic P solution was varied from 9.0 to 4.3, accordingly. The outcome of this study indicated that alum sludge is suitable for use as an adsorbent for removal of phosphate from wastewater.
2006-06-01T00:00:00ZPhosphorus removal in laboratory-scale unvegetated vertical subsurface flow constructed wetland systems using alum sludge as main substratehttp://hdl.handle.net/10197/3260
Phosphorus removal in laboratory-scale unvegetated vertical subsurface flow constructed wetland systems using alum sludge as main substrate
Babatunde, A.O.; Zhao, Y.Q.
This research has two eventual goals: (1) To optimize performance of subsurface constructed wetlands for removal of phosphorus (P) (2) To demonstrate that dewatered alum sludge (a by-product), can be reused as a constructed wetland substrate. To achieve these, alum sludge from a water treatment plant was characterized and used as main substrate in four experimental vertical sub-surface flow constructed wetland systems treating dairy farm wastewater. Results show that the alum sludge has suitable hydraulic characteristics (uniformity coefficient = 3.6) for use as a substrate, and in the batch studies, up to 48.6mg-P was removed by 1g of the alum sludge at a P concentration of 360mg-P/l and a dosage of 5g/l. Results from the experimental systems highlight the significant P removal ability of the alum sludge. However, the inclusion of pea gravel at the infiltrative surface of some of the systems had a negative effect on the P removal performance. Sequential P-fractionation results show that there was no significant increase in the easily extractable P, but for total P, there was significant increase, although this was found to decrease with depth. This study shows that the novel use of dewatered alum sludge can bring about high P removal in vertical subsurface flow constructed wetland systems.
2009-07-01T00:00:00ZOn the necessity of sludge conditioning with non-organic polymer : AOP approachhttp://hdl.handle.net/10197/3259
On the necessity of sludge conditioning with non-organic polymer : AOP approach
Zhao, Y.Q.; Keogh, C.; Tony, Maha A.
Organic polymers have long been used as sludge conditioners to improve its dewaterability in sludge management practice. Although polymers can bring about a great dewatering performance of the sludge, their potential health related risk remains unknown regarding their residual in dewatered sludge cakes in the environment when the sludge is finally disposed as landfill especially in long term point of view. For this regard, as an initiative action, Fenton (Fe2+/H2O2) and its related reagents were tested in this study as potential alternative an alum sludge conditioners for the purpose of eliminating the perceived long term risk associated with polymer residual in the environment.
2009-07-01T00:00:00ZSome experience in measuring pore water suction in Dublin glacial tillhttp://hdl.handle.net/10197/3257
Some experience in measuring pore water suction in Dublin glacial till
Long, Michael (Michael M.); Menkiti, Christopher O.; Follet, Ben
Several recent articles and discussions in GIN, by Penman (2002), Thomann et al. (2003),
Ridley (2003) and Sellers et al. (2003) highlight the importance of pore water pressure
and suctions and in particular the difficulties associated with measuring suction. This
article outlines some recent experience in measuring suctions, which were developed in
cut slopes in a very stiff glacial till during the Dublin Port Tunnel (DPT) project in
Ireland. A particular feature of the project was the execution of a fully instrumented 12m
deep trial excavation (Menkiti et al., 2004).
Initially some background to the project and to the problem will be given. Then some
details of the specification, installation technique and some examples of the
measurements obtained will be outlined. Finally some conclusions will be made on the lessons learned and recommendations will be made for future similar applications.
2004-09-01T00:00:00ZAn investigation of two peat slope failures in the Wicklow mountainshttp://hdl.handle.net/10197/3256
An investigation of two peat slope failures in the Wicklow mountains
Boylan, Noel; Long, Michael (Michael M.)
Although peat slope failures have occurred in Ireland for many thousands of years their causal
factors and the triggering mechanisms involved are poorly understood. A particular barrier to
quantitative assessment of the risk of failures is the lack of knowledge of the geotechnical
properties of peat and its role in failures. In order to advance the understanding of these issues
case history data is invaluable. This paper describes a case study from the Wicklow
mountains where a desk and remote sensing based study was used to identify peat slope
failures. Subsequently detailed field studies were carried out at two failure locations. It was
found that although the full causal factors at the time of failure are unknown, a common
factor was that the failure took place in a zone of highly decomposed and relatively low fibre
content peat. A revision of the standard test method for fibre content for use in peat soils is
proposed.
2010-12-01T00:00:00ZTwo strategies for phosphorus removal from reject water of municipal wastewater treatment plant using alum sludgehttp://hdl.handle.net/10197/3255
Two strategies for phosphorus removal from reject water of municipal wastewater treatment plant using alum sludge
Yang, Y.; Zhao, Y.Q.; Babatunde, A.O.; Kearney, P.
In view of the well recognized need of reject water treatment in MWWTP (municipal wastewater treatment plant), this paper outlines two strategies for P removal from reject water using alum sludge, which is produced as by-product in drinking water treatment plant when aluminium sulphate is used for flocculating raw waters. One strategy is the use of the alum sludge in liquid form for co-conditioning and dewatering with the anaerobically digested activated sludge in MWWTP. The other strategy involves the use of the dewatered alum sludge cakes in a fixed bed for P immobilization from the reject water that refers to the mixture of the supernatant of the sludge thickening process and the supernatant of the anaerobically digested sludge. Experimental trials have demonstrated that the alum sludge can efficiently reduce P level in reject water. The co-conditioning strategy could reduce P from 597-675 mg P/L to 0.14-3.20 mg P/L in the supernatant of the sewage sludge while the organic polymer dosage for the conditioning of the mixed sludges would also be significantly reduced. The second strategy of reject water filtration with alum sludge bed has shown a good performance of P reduction. The alum sludge has P-adsorption capacity of 31 mg-P/g-sludge, which was tested under filtration velocity of 1.0 m/h. The two strategies highlight the beneficial utilization of alum sludge in wastewater treatment process in MWWTP, thus converting the alum sludge as a useful material, rather than a waste for landfill.
2009-12-01T00:00:00ZA comparative study between the NGI direct simple shear apparatus and the Mikasa direct shear apparatushttp://hdl.handle.net/10197/3254
A comparative study between the NGI direct simple shear apparatus and the Mikasa direct shear apparatus
Hanzawa, Hideo; Nutt, Nigel; Lunne, Tom; Tang, Y.X.; Long, Michael (Michael M.)
A comparative study of the NGI Direct Simple Shear Test (DSST) and the Mikasa Direct Shear Test (DST) is reported. Samples from Norwegian Drammen clay and Japanese Ariake clay were subjected to both types of test. An evaluation of these test results and a theoretical consideration on the different shearing mechanisms has shown that although the DST give generally higher stiffness and strength than the DSST, these differences can mainly be accounted for by the different shearing mechanisms and shearing rates. Sample disturbance due to transportation and
handling may also be the reason for some of the difference. Tests on undisturbed and
remoulded Drammen clay consolidated to stresses much higher than the in situ
effective overburden stress give almost identical results. Thus the effects of sample
disturbance and in situ structure in the clay were eradicated.
2007-02-01T00:00:00ZA novel alum-sludge based constructed wetland system to reduce pollution effects of agricultural runoff : first resultshttp://hdl.handle.net/10197/3229
A novel alum-sludge based constructed wetland system to reduce pollution effects of agricultural runoff : first results
Babatunde, A.O.; Zhao, Y.Q.
This paper is a research brief highlighting the development of a novel alum sludge based constructed wetland system, aimed at reducing the pollution effects of agricultural run-offs. Alum sludge is a by-product of drinking water treatment plants where aluminium sulphate is used as coagulant. The alum sludge cakes were used as the main support matrix in the constructed wetland system, having been shown to have a greater capacity to retain contaminants, especially phosphorus, through sorption phenomena, ionic exchange and other physico-chemical processes. The dewatered alum sludge cakes proved beneficial in enhancing and sustaining phosphorus removal in the system, while the removal of organics is thought to be enhanced by the tidal flow mechanism employed. Overall removal of 82.3 + 3.5% (BOD5) and 85.5 + 2.1 % (COD) were achieved in the system
2007-01-01T00:00:00ZAssessment of an MASW technique incorporating discrete particle modellinghttp://hdl.handle.net/10197/3228
Assessment of an MASW technique incorporating discrete particle modelling
Donohue, Shane; Long, Michael (Michael M.)
A Discrete Particle Scheme (DPS) consisting of interacting circular particles is
utilised to examine the Multichannel Analysis of Surface Waves (MASW) technique.
Synthetic earth models of various complexity are generated using the DPS and analysed
by the MASW dispersion and inversion techniques. For normally dispersive cases,
dominated by the fundamental mode, the MASW profiles closely match the true synthetic
shear wave velocity (Vs) profiles. When tested on a model that contains a low velocity
layer, the accuracy is reduced.
MASW field tests at a highly uniform site in Norway (Onsøy) and a site with
distinctive layer boundaries in Ireland (Ballinasloe) result in highly repeatable profiles of
Vs. Resolution of dispersion curves at low frequencies (<10Hz) is a problem at the
Ballinasloe test site, which limits the depth of penetration of the technique. MASW
inversion results compare excellently with downhole seismic cone tests at the Onsøy test
site and reasonably with a seismic refraction survey at the Ballinasloe site.
2008-06-01T00:00:00ZConstructive approaches towards water treatment works sludge management : an international review of beneficial re-useshttp://hdl.handle.net/10197/3227
Constructive approaches towards water treatment works sludge management : an international review of beneficial re-uses
Babatunde, A.O.; Zhao, Y.Q.
Till date, virtually all known drinking water processing systems generate an enormous amount of residual sludge, and what else to do with this rapidly increasing 'waste' stream in an economic and environmentally sustainable manner remains a significant environmental issue. Perhaps, the realization of this fact has led to series of concerted efforts aimed at beneficial re-uses in an effort to close the loop between efficient water treatment and sustainable sludge management. This paper therefore presents a comprehensive review of available literature on attempts at beneficial reuses of water treatment plant sludge, in an effort to provide a compendium of recent and past developments, and update our current state of knowledge. Four broad categories of uses, which included over eleven possible ways in which waterworks sludges can be reused were identified and examined. Obvious advantages of such reuse options were highlighted and knowledge gaps identified. Future issues that will assist in the development of sustainable waterworks sludge management options with a multi-prong approach were equally discussed.
2007-03-01T00:00:00ZFluoride removal from drinking water by adsorption using bone char as a biosorbenthttp://hdl.handle.net/10197/3226
Fluoride removal from drinking water by adsorption using bone char as a biosorbent
Ma, W.; Ya, F.; Wang, R.; Zhao, Y.Q.
As a biomass material, bone char was investigated for the feasibility to be used as a cost-effective biosorbent for fluoride removal from drinking water in groundwater environment. Based on the batch tests with natural tourmalin and active alumina being the reference adsorbents, BF (referring to bone char) has demonstrated a higher fluoride adsorption capacity. This capacity was found being increased with the increase of fluoride concentration. Furthermore, BF based column adsorption experiments indicated that the fluoride removal could be significantly affected by flow rate and bed height. A mass transfer model developed in this study can be used to optimize the bed configuration and operation parameters. Experimental results and predicted data by the model have shown a good consistent. A full-scale BF fixed-bed to treat fluoride-containing groundwater in Northeast China has been successfully operated since 2002.
2008-04-01T00:00:00ZA hierarchy for land application of organic wastes : influence of urban stakeholdershttp://hdl.handle.net/10197/3225
A hierarchy for land application of organic wastes : influence of urban stakeholders
Taffese Tanto, Mebrate; Magette, W. L.
Paper presented at RAMIRAN 2010 14th Ramiran international conference : Treatment and Use of Organic Residues in Agriculture - Challenges and Opportunities towards Sustainable Management, Lisbon, 12-15 September 2010
2010-09-01T00:00:00ZPurification capacity of a highly loaded laboratory scale tidal flow reed bed system with effluent recirculationhttp://hdl.handle.net/10197/3199
Purification capacity of a highly loaded laboratory scale tidal flow reed bed system with effluent recirculation
Zhao, Y.Q.; Sun, Guangzhi; Allen, Stephen
The purification capacity of a laboratory scale tidal flow reed bed system with final effluent recirculation at a ratio of 1:1 was investigated in this study. In particular, the four-stage reed bed system was heavily loaded with strong agricultural wastewater. Under the hydraulic and organic loading rates of 0.43 m3/m2.d and 1055 gCOD/m2.d, respectively, the average removal efficiencies obtained for COD, BOD5, SS, NH4-N and P were 77%, 78%, 66%, 62% and 38%, respectively. Even with the high loading rates, about 30% of NH4-N was converted into NO2-N and NO3-N from the mid-stage of the system where nitrification took place. The results suggest that the multi-stage reed bed system could be employed to treat strong wastewater under high loading, especially for the substantive mass removal of solids, organic matter and ammoniacal-nitrogen. Tidal flow combined with effluent recirculation is a favourable operation strategy to achieve this objective.
2004-09-01T00:00:00ZRemoval of ammoniacal-nitrogen from an artificial landfill leachate in downflow reed bedshttp://hdl.handle.net/10197/3198
Removal of ammoniacal-nitrogen from an artificial landfill leachate in downflow reed beds
Connolly, Roseanne; Zhao, Y.Q.; Sun, Guangzhi; Allen, Stephen
The fate of ammoniacal-nitrogen (NH4-N) was studied in a lab-scale downflow reed bed system treating an artificial landfill leachate. Individual reed beds were submerged by the leachate, then drained and rinsed by tap water. It was discovered that NH4-N was removed by a two-staged process, adsorption onto the reed bed media followed by nitrification into nitrite-nitrogen (NO2-N) and nitrate-nitrogen (NO3-N). A drop of NH4-N level of the leachate was observed when the reed beds were submerged. By rinsing of the beds, part of the NH4-N adsorbed inside the bed matrices was re-released into the rinse water. The presence of NO2-N and NO3-N in the rinse water demonstrated that nitrification process took place while the NH4-N was being retained inside the bed matrices. For artificial leachates with NH4-N levels of 150±5 mg/l, an average removal rate of 43.8% in a three-hour treatment was achieved; mass balance analysis indicated that processes of adsorption, and transformation into NO2-N and NO3-N accounted for 63.7%, 4.3% and 24.4% of the NH4-N removal, respectively. This study also demonstrated that in general greater recirculation rate of effluent around the downflow reed beds gives higher NH4-N removal.
2004-10-29T00:00:00ZKinetics of aqueous photocatalytic oxidation of fulvic acids in a photocatalysis-ultrafiltration reactor (PUR)http://hdl.handle.net/10197/3183
Kinetics of aqueous photocatalytic oxidation of fulvic acids in a photocatalysis-ultrafiltration reactor (PUR)
Fu, J.F.; Ji, Min; Zhao, Y.Q.; Wang, Lizhang
The photocatalysis of natural organic matter, fulvic acid (FA), by P25 TiO2 in terms of UV254 and TOC concentrations was investigated in this study. The experiments were conducted in a lab-scale photocatalysis-ultrafiltration reactor (PUR) with TiO2 suspension. Groups of experiments were designed to examine the effects of pH of bulk solution, TiO2 concentration and additives strength as well as light intensity on the degradation of FA. Results from this study revealed that the degradable behaviour of FA can be reasonably described by first-order kinetics. In addition, it was demonstrated that low pH value, increased additives concentration and relative high light intensity were all beneficial parameters for TOC removal. By inspecting the relationship between rate constant (k) and influencing factors, an overall FA oxidation rate kinetic model was established. The utility of the model was demonstrated by the agreement of predictive and experimental results.
2006-06-01T00:00:00ZSettling behaviour of polymer flocculated water-treatment sludge I : analyses of settling curveshttp://hdl.handle.net/10197/3182
Settling behaviour of polymer flocculated water-treatment sludge I : analyses of settling curves
Zhao, Y.Q.
Settling behaviour of polymer conditioned water-treatment sludge was investigated in this study for the purpose of a better understanding of a so-called “CML30 method”, which was developed in previous study to evaluate the optimum polymer dosage in sludge conditioning. The “CML30 method” is on the basis of a 30 min settling test in 100 ml measuring cylinders. In this study, the series of settling tests in 100, 500 and 1000 ml measuring cylinders were respectively performed and the settling curves (interfacial height to dose and time) were the main focuses for presentation and analyses in great detail in this paper. According to the experimental data presented in this study, settling behaviour may be controlled by both the growth of large sized floc and progressively decreased viscosity. The “speed-up” phenomenon in small polymer dose range obviously enhances the settlement and plays a critical role for the settling set in a 100 ml measuring cylinder at a special dose and at the settling time interval 5-30 min. It is such special observation that leads to the success of so-called ad hoc “CML30 method”. However, sludge settling behaviour could be controlled by the formation of networked structure which is involved in excess polymer during the large range (say over 10 mg/l for the case tested) of polymer doses. The higher liquid viscosity values derived from excess polymer will increase the drag force for the resistance of the settlement. In addition, wall effects are likely to interplay with the internal networked structure in large dosed region.
2004-02-01T00:00:00ZSettling behaviour of polymer flocculated water-treatment sludge II : effects of floc structure and floc packinghttp://hdl.handle.net/10197/3181
Settling behaviour of polymer flocculated water-treatment sludge II : effects of floc structure and floc packing
Zhao, Y.Q.
On the basis of experiments carried out using an image analysis system and static zone settlement, the alum sludge floc structure and the floc packing status with varied polymer dosages were examined in greater detail to reveal the link with the settling behaviour manifested in the “CML30 method”. The results of image analysis lead to the findings of the floc size with a pattern in initially great increase with low polymer dose and finally a plateau being reached at higher amount of polymer addition. Meanwhile, a polymer dosage in the range of 2.0 – 20.0 mg/l (for sludge SS = 4,595 mg/l) can result in the increase of the floc fractal dimension (DF) up to an average value of 1.72 (raw sludge DF being 1.06), indicating greater compactness of the floc solids. These floc features control the settling behaviour of the “CML30 method”, especially in small polymer dosages. However, in large polymer doses, the controlling factor is derived from the floc 'packing' status (referring to the inter – floc contact manner). This 'packing' status may associate with viscosity of settling medium (supernatant) and the excess polymer in bulk solution. All these affect the sludge floc networked structure in overdosing range.
2004-03-01T00:00:00ZAn alternative arrangement of gravel media in tidal flow reed beds treating pig farm wastewaterhttp://hdl.handle.net/10197/3179
An alternative arrangement of gravel media in tidal flow reed beds treating pig farm wastewater
Sun, Guangzhi; Zhao, Y.Q.; Allen, Stephen
The effect of using coarse grain in the upper layer of a gravel-based reed bed is investigated. The aim for testing the “anti-sized” arrangement of gravel media is to seek a solution for the practical problem of medium clogging in reed beds that frequently takes place during the treatment of high strength wastewaters. Results from parallel operations of an anti-sized and a conventional “mono-sized” reed bed reveal that the former has the advantage of greater pollutant removal efficiencies. A specific clogging tendency rate is defined to quantitatively describe the clogging behaviour. Calculation of the clogging tendency rate reveals that the anti-sized reed bed has a clear advantage over the mono-sized bed because of improved ability to counteract clogging. Greater pore space in the upper layer of the anti-sized bed allows the suspended solids to be filtered and penetrate farther into the bed matrix, thereby allowing the solid-storage capacity of the matrix to be used more effectively and prolonging the operational life time of the bed. As such, the anti-sized arrangement of reed bed media may provide a viable solution for the problem of clogging.
2007-01-01T00:00:00ZEffectiveness of a drinking-water treatment sludge in removing different phosphorus species from aqueous solutionhttp://hdl.handle.net/10197/3178
Effectiveness of a drinking-water treatment sludge in removing different phosphorus species from aqueous solution
Razali, Melanie; Zhao, Y.Q.; Bruen, Michael
Drinking-water treatment sludge (DWTS) produced at water treatment plants is an inescapable by-product and has long been treated as a waste for landfill. In this study, a series of batch adsorption tests were conducted using a wide range of phosphorus (P) species to determine the adsorption capacities of freshly dewatered aluminium salt based DWTS. The adsorption process is highly dependant on the pH of the suspension and is good at low pHs with adsorption capacities in the order of orthophosphate>polyphosphate>organic phosphate when these three P species were simulated according to their level in typical municipal wastewater. At pH 4.0, the adsorption capacity for orthophosphate was 10.2 mg-PO43-/g DWTS, polyphosphate was 7.4 mg-PO43-/g DWTS and organic phosphate was 4.8 mg-PO43-/g DWTS. Subsequently, a continuous flow column test with dewatered Al-based DWTS as filter medium was conducted at a hydraulic loading of 2.79 m3/m2.d and an extremely high P loading of 210.5 PO43-/m2.d. The sludge bed remained stable and removed over 80% P in a 30 day period and the bed did not reach saturation point for over 60 days. This proves the potential of the sludge as a filter material in various forms of P immobilization, thus converting it from a waste to a useful material in pollutant control.
2007-07-01T00:00:00ZCharacteristics and mechanisms of phosphate adsorption on dewatered alum sludgehttp://hdl.handle.net/10197/3177
Characteristics and mechanisms of phosphate adsorption on dewatered alum sludge
Yang, Y.; Zhao, Y.Q.; Babatunde, A.O.; Wang, L.; Ren, Y.X.; Han, Y.
The adsorption characteristics of phosphate adsorption on the dewatered alum sludge were identified as a function of pH and ion strengths in solution. In addition, adsorption mechanisms were investigated by conducting batch tests on both the hydrolysis and P-adsorption process of the alum sludge, and making a comparative analysis to gain newer insights into understanding the adsorption process. Results show that the adsorption capacity decreased from 3.5 to 0.7 mg-P/g-sludge when the solution pH was increased from 4.3 to 9.0, indicating that adsorption capacity is largely dependent upon the pH of the system. The results of the competitive adsorption between phosphate and typical anions found in wastewater, such as SO42- and Cl-, onto alum sludge reveal that alum sludge can selectively adsorb phosphate ions. The insignificant effect of SO42- and Cl- on P-adsorption capacity indicates that phosphate adsorption is through a kind of inner-sphere complex reaction. During the adsorption process, the decrease of phosphate concentration in solution accompanied with an increase in pH values and concentrations of SO42-, Cl- and TOC (total organic carbon) suggests that phosphate replaced the functional groups from the surface of alum sludge which infers that ligand exchange is the dominating mechanism for phosphate removal. At the same time, the simultaneous decreases in PO43- and total aluminium concentration in solution indicate that chemical reaction and precipitation are other mechanisms of phosphate removal.
2006-09-01T00:00:00ZReuse of aluminium-based water treatment sludge to immobilize a wide range of phosphorus contamination : equilibrium study with different isotherm modelshttp://hdl.handle.net/10197/3176
Reuse of aluminium-based water treatment sludge to immobilize a wide range of phosphorus contamination : equilibrium study with different isotherm models
Zhao, Y.Q.; Razali, Melanie; Babatunde, A.O.; Yang, Y.; Bruen, Michael
The adsorption equilibrium of a wide range of phosphorus species by an aluminium-based water treatment sludge (Al-WTS) was examined in this study. Four kinds of adsorption-isotherm models, namely Langmuir, Freundlich, Temkin and Dubinin-Radushkevich, were used to fit the adsorption equilibrium data. In order to optimise the adsorption-isotherm model, correlation coefficient (R2) and four error functions were employed to facilitate the evaluation of fitting accuracy. Experiments have demonstrated that the Al-WTS may be an excellent raw material to adsorb P in polluted aqueous environment with adsorption ability in the order of KH2PO4 (ortho-P) > Na(PO3)6 (poly-P) > C10H14N5O7P·H2O (organic-P). More importantly, this study provides an entire comparison of the four isotherms in describing the P adsorption behaviour. By considering both the standard least-square based R2 and the results of four error functions analysis, this study reveals that the Freundlich isotherm appears to be the best model to fit the experimental equilibrium data. Langmuir and Temkin isotherms are also good models in current experimental conditions while Dubinin-Radushkevich isotherm poorly described the adsorption behaviour. The error analysis in this study provides vital evidence to reflect its role in facilitating the optimisation in adsorption isotherm study. Obviously, R2 seems inadequate in optimising multi-isotherm models due to its inherent bias resulting from the least-squares linearisation.
2007-10-01T00:00:00ZOptimising photoelectrocatalytic oxidation of fulvic acid using response surface methodologyhttp://hdl.handle.net/10197/3175
Optimising photoelectrocatalytic oxidation of fulvic acid using response surface methodology
Fu, J.F.; Zhao, Y.Q.; Wu, Qiuli
In this paper, statistics-based experimental design with response surface methodology (RSM) was employed to investigate the effect of operation conditions on photoelectrocatalytic oxidation of fulvic acid (FA) using a Ti/TiO2 electrode in a photoreactor. Initially, the Box-Behnken design was employed including the three key variables (initial pH, potassium peroxodisulphate (K2S2O8) and bias potential). Thereafter, the mutual interaction and effects between these parameters and optimum conditions were obtained in greater detail by means of SAS and Matlab software. The results of this investigation reveal that: (1) the regression analysis with R2 value of 0.9754 shows a close fit between the experimental results and the model predictions; (2) three-dimension response surface plot can provide a good manner for visualizing the parameter interactions; and (3) the optimum pH, K2S2O8 and bias potential is found to be 3.8, 88.40mg/L, 0.88V respectively and the highest FA removal efficiency of 57.1% can be achieved.
2007-06-01T00:00:00ZInvolvement of gypsum (CaSO4.2H2O) in water treatment sludge dewatering : a potential benefit in disposal and reusehttp://hdl.handle.net/10197/3174
Involvement of gypsum (CaSO4.2H2O) in water treatment sludge dewatering : a potential benefit in disposal and reuse
Zhao, Y.Q.
This research assessed the use of gypsum (CaSO4.2H2O) as a skeleton builder for sludge dewatering since polymer conditioning of sludge affected only the rate of water release, not the extent of dewatering. The use of gypsum as a physical conditioner, in association with a polymer, could improve sludge filterability. More significantly, gypsum serves as a skeleton builder, forming a permeable and rigid lattice structure that can remain porous under high positive pressure during the compression step after the cake growth of the filtration, thereby maintaining the size of the micro-passages through which water is expressed. Experiments using a high pressure cell apparatus showed that a further decrease of two to seven percent of the equilibrium moisture content of the sludge cake was achieved, for sludge thicknesses for dewatering of 1 to 10 cm, by the addition of gypsum with 60% of the original sludge solids when compared to the single polymer conditioning. The importance of the addition of gypsum in alum sludge dewatering is not only the improvement in the extent of dewatering, but also the potential application of transforming dewatered alum sludge from ‘waste’ for landfill to useful ‘fertilizer’ or to be used as filter medium/adsorbent for wastewater treatment engineering.
2006-01-01T00:00:00ZAnti-sized reed bed system for animal wastewater treatment : a comparative studyhttp://hdl.handle.net/10197/3173
Anti-sized reed bed system for animal wastewater treatment : a comparative study
Zhao, Y.Q.; Sun, Guangzhi; Allen, Stephen
Two separate sets of reed bed systems were operated in parallel for the purpose to study a comparative behaviour of high strength animal wastewater treatment. Each system consisted of five-stage gravel-based reed beds. The only difference between the two systems lies in the gravel arrangement within the beds. One system employed single sized gravel as bed medium (termed as mono-sized bed) while the other used two layers of gravel with coarse grain as the upper layer (termed as anti-sized bed). It was demonstrated that both the systems have the strong capacity for animal wastewater treatment but no significant difference with regard to pollutants‟ removal efficiency. However, anti-sized system showed a clear advantage in its ability to retard the clogging phenomenon exhibited during the system operation and avoid the impairment of its long-term functioning and sustainability. Clogging development was monitored via daily record of evolution of water level after the reed bed fill-up step in tidal flow operation strategy. According to present study, anti-sized reed bed experienced more than 2-fold operating period without clogging as compared with mono-sized reed bed in their parallel operation. In addition, a conceptual model to predict the clogging time was attempted and its utility was demonstrated via the data of this study.
2004-07-01T00:00:00ZEnhanced removal of organic matter and ammoniacal-nitrogen in a column experiment of tidal flow constructed wetland systemhttp://hdl.handle.net/10197/3172
Enhanced removal of organic matter and ammoniacal-nitrogen in a column experiment of tidal flow constructed wetland system
Sun, Guangzhi; Zhao, Y.Q.; Allen, Stephen
This study investigated the efficiency of a four-stage tidal flow constructed wetland system for the removal of organic matter and ammoniacal-nitrogen from diluted piggery wastewater. The results demonstrated that the operation of tidal flow enhanced the transfer of oxygen into wetland matrices. The overall oxygen consumption rate in the tidal flow system (357 gO2/m2∙d) was considerably higher than the rate obtainable in conventional wetlands. Most oxygen consumption (99%) was due to the decomposition of organic matter. The total supply of oxygen into the wetlands (473 gO2/m2∙d) exceeded the demand for the treatment. The percentage removal of BOD5 and NH4-N was improved by effluent recirculation at a ratio of 1:1. Immobilization by microbial cells and adsorption were found to be the main routes for the removal of ammoniacal-nitrogen. Significant nitrification could not take place under the treatment condition of the experiment.
2005-01-26T00:00:00ZA study of dual polymer conditioning of aluminum-based drinking water treatment residualhttp://hdl.handle.net/10197/3171
A study of dual polymer conditioning of aluminum-based drinking water treatment residual
Ma, W.; Zhao, Y.Q.; Kearney, P.
Conditioning of an alum-based water treatment sludge by single and dual polymers was investigated in this study. Capillary suction time (CST), specific resistance to filtration (SRF) and settling rate of conditioned sludge were used to evaluate the sludge dewatering characteristics. Sludge dewaterability resulting from single and dual polymer conditioning were compared for the purpose of exploring the validity and effectiveness of dual polymer conditioning strategy. Unlike activated sludge derived from wastewater treatment, results from this study have demonstrated that conditioning of the alum sludge by the combined use of an cationic polymer (FO-4140) followed by an anionic polymer (LT-25) does not exhibit considerable advantage in further improvement of sludge dewaterability with comparison of single polymer conditioning. This study supports the view that for alum-based water treatment sludge, inter particle bridging seems to be the dominative mechanism and the charge neutralization plays a less important role in the conditioning process. In addition, an intrinsic relationship between CST and SRF was deducted and tested via the experimental data obtained from the study.
2007-01-01T00:00:00ZAlum sludge-based constructed wetland system for enhanced removal of P and OM from wastewater : concept, design and performance analysishttp://hdl.handle.net/10197/3170
Alum sludge-based constructed wetland system for enhanced removal of P and OM from wastewater : concept, design and performance analysis
Babatunde, A.O.; Zhao, Y.Q.; Zhao, X.H.
The concept, design and performance analysis of a four-stage novel constructed wetland system (CWs) capable of enhanced and simultaneous removal of phosphorus (P) and organic matter (OM) from wastewaters is described. Alum sludge, a largely available by-product of drinking water facilities using aluminium salts as coagulant was used as the media. Under a hydraulic loading rate of 1.27 m3/m2.d and a range of organic loading rate of 279.4–774.7 g-BOD5/m2.d and 361.1–1028.7 g-COD/m2.d, average removal efficiencies (mean ±SD) of 90.6 ±7.5% for BOD5 and 71.8 ±10.2% for COD were achieved, respectively. P removal was exceptional with average removal efficiency of 97.6 ±1.9% achieved for soluble reactive P at a mean influent concentration of 21.0 ±2.9 mg/l. Overall, the system holds great promise as a novel CWs for simultaneous removal of P and OM, and at the same time, it transforms alum sludge from a waste into a useful material.
2010-08-01T00:00:00ZUse of dewatered alum sludge as a substrate in reed bed treatment systems for wastewater treatmenthttp://hdl.handle.net/10197/3160
Use of dewatered alum sludge as a substrate in reed bed treatment systems for wastewater treatment
Zhao, Y.Q.; Babatunde, A.O.; Razali, Melanie; Harty, F.
In this paper, two laboratory scale simulated reed beds were investigated for the purpose of assessing the feasibility and effectiveness of using dewatered alum sludge as a possible substrate for wastewater treatment reed bed systems. One horizontal subsurface flow set-up and one vertical flow set-up were used. The horizontal flow system was planted with Phragmites australis while the vertical flow system was left unplanted. Thus, the latter was more akin to a sand filter system, but was examined with the potential use as a planted vertical reed bed system. The influent source used was farmyard wastewater. It is expected that the present study will provide the basis for long-term and large-scale trials in realising the concept of integrating “waste” into treatment processes. Results obtained so far have shown that the dewatered alum sludge holds great promise as a low-cost resource media for use in reed bed treatment systems. Appreciable and stable performance was obtained during the continuous operation at high hydraulic, organic and phosphorus loadings. In particular, both wetlands achieved over 90% phosphorus removal, reflecting the significant advantage of this novel approach over conventional reed bed treatment systems. However, extensive research into possible surface clogging and possible release of some substances from the sludge to the treated effluent is necessary to ensure reliability of the system. This will help make the alum sludge based reed bed environmentally and economically justifiable.
2008-01-01T00:00:00ZRe-use of dewatered aluminium-coagulated water treatment residual to immobilize phosphorus : batch and column trials using a condensed phosphatehttp://hdl.handle.net/10197/3143
Re-use of dewatered aluminium-coagulated water treatment residual to immobilize phosphorus : batch and column trials using a condensed phosphate
Babatunde, A.O.; Zhao, Y.Q.; Yang, Y.; Kearney, P.
The aluminium content in dewatered aluminium-coagulated water treatment residual (DAC-WTR) can lead to a high phosphorus (P) removal capacity. Therefore, DAC-WTR has been used as adsorbent/soil amendment to remove P in several studies, focusing mostly on orthophosphates (ortho-P). This study is concerned with extending such reuse of DAC-WTR to remove P using a condensed phosphate as the model P source. Using a 48-hr equilibration time and a 1.18mm (mean particle size); (1) P removal was found to increase with increasing DAC-WTR dosage, but specific uptake of P per mass of DAC-WTR was decreased (2) A maximum adsorption capacity of 4.52mg-P/g of DAC-WTR was obtained at a pH of 4.0.
In the continuous flow test, P removal efficiency decreased from 90 to 30% when loading was increased from 3.9 to 16.5g-P/m2.d. An average 45% removal efficiency was obtained after an intentional P loading surge. At the end of the continuous flow test, an operating removal capacity of 2.66 mg-P/g of DAC-WTR was determined which was 83.3% of the adsorption maxima obtained in the batch tests. There was no excessive loss of solids during the continuous flow test and aluminium content in the effluent remained below 0.1mg-Al3+/l. These results have demonstrated that dewatered DAC-WTR can further be used as a low-cost adsorbent media for condensed phosphate removal.
2008-03-01T00:00:00ZConstructed wetlands for environmental pollution control : a review of developments, research and practice in Irelandhttp://hdl.handle.net/10197/3142
Constructed wetlands for environmental pollution control : a review of developments, research and practice in Ireland
Babatunde, A.O.; Zhao, Y.Q.; O'Neill, M.; O'Sullivan, B.
For the purpose of synthesizing a compendium of efforts aimed at environmental pollution control through the use of constructed wetlands systems (CWs) in Ireland, a detailed review of CWs was undertaken. Emphasis was placed on the diverse range of development, practice and researches on CWs technology, placing them in the overall context of the need for low-cost and sustainable wastewater treatment systems. The potential use of CWs in protecting estuarine quality within the current legislative framework is considered, as well as the emerging concept of integrated constructed wetlands (ICWs). In addition, an assessment of the efficiency of CWs in operation in Ireland towards abating environmental pollution was done, and compared with CWs operating in other European countries. The need for sufficient and appropriate data to assist in further development of CWs and modelling studies, and instilling confidence in the public is also highlighted.
2008-01-01T00:00:00ZGeotechnical properties of Dublin boulder clayhttp://hdl.handle.net/10197/3141
Geotechnical properties of Dublin boulder clay
Long, Michael (Michael M.); Menkiti, Christopher O.
Geotechnical characteristics of Dublin Boulder Clay (DBC) based on detailed site
investigation and site experience from some recent large projects in Dublin are presented.
This paper attempts to synthesise available information in parallel with recent work by
Skipper et al (2005), who provide an updated understanding of the geology of the DBC.
Having assessed the effects of sampling disturbance, the paper characterises the various
formations and sub-units of the DBC. The interpreted material behaviour is related to
observed engineering performance. It was found from the behaviour of earth retained
structures that intact, clayey, DBC formations are 2 to 3 times stiffer than assessed from
high quality laboratory tests on block samples. DBC is shown to be significantly stiffer
than other well-characterised tills. Relatively inexpensive Multi Channel Surface Wave
techniques (MASW) can give very reliable estimates of in situ small strain stiffness. High
undrained triaxial compression strengths were measured and it appears that simple UU
tests on high quality specimens give good results. Significant strength anisotropy was
suggested by undrained triaxial extension strengths that were only 30% to 50% of the
triaxial compression strengths. Field horizontal permeability values of the intact clayey
till units have a representative mean of about 10-9 m/s and when compared to laboratory
values suggest that the material may exhibit some degree of anisotropy of permeability.
Overall, the measured engineering parameters for the DBC are favourable for many
construction projects. Further work is required in order to understand the in situ
horizontal stress profile and the stiffness anisotropy of the till.
KEYWORDS: Glacial soils, In situ testing, laboratory tests, site investigation, strength,
stiffness.
2007-09-01T00:00:00ZConditioning of aluminium-based water treatment sludge with Fenton’s reagent : effectiveness and optimising study to improve dewaterabilityhttp://hdl.handle.net/10197/3140
Conditioning of aluminium-based water treatment sludge with Fenton’s reagent : effectiveness and optimising study to improve dewaterability
Tony, Maha A.; Zhao, Y.Q.; Fu, J.F.; Tayeb, Aghareed M.
Alternative conditioning of aluminium-based drinking water treatment sludge using Fenton reagent (Fe2+/H2O2) was examined in this study. Focuses were placed on effectiveness and factors to affect such novel application of Fenton process. Experiments have demonstrated that considerable improvement of alum sludge dewaterability evaluated by capillary suction time (CST) can be obtained at the relative low concentrations of Fenton reagent. A Box-Behnken experimental design based on the response surface methodology was applied to evaluate the optimum of the influencing variables, i.e. iron concentration, hydrogen peroxide concentration and pH. The optimal values for Fe2+, H2O2, and pH are 21 mg g-1 DS-1(dry solids), 105 mg g-1 DS-1 and 6, respectively, at which the CST reduction efficiency of 48±3 % can be achieved, this agreed with that predicted by an established polynomial model in this study.
2008-06-01T00:00:00ZResponse surface optimization of phosphorus species adsorption onto powdered alum sludgehttp://hdl.handle.net/10197/3139
Response surface optimization of phosphorus species adsorption onto powdered alum sludge
Fu, J.F.; Zhao, Y.Q.; Razali, Melanie; Bruen, Michael
The purpose of this study is to optimize adsorption conditions of powdered alum sludge (PAS) as low-cost adsorbent for the removal of three P-species (ortho-P, poly-P and organic-P) from wastewater using the response surface methodology (RSM). Initially, RSM in the basis of a three-variable Box-Behnken design was used to determine the effect of pH (from 4 to 7), PAS mass (from 0.1 to 0.5 g) and PAS particle size (from 125 to 420 μm) on the response levels (removal efficiencies of the three P-species). Three response surface quadratic models in terms of three factors were then obtained from an analysis of the experimental data using a SAS computer package. Thereafter, the effect of each of the parameters on P removal for each of the three species was examined using the three-dimensional response surface. All three parameters (pH, PAS mass and PAS particle size) had a significant effect on the removal of each of the P species. Finally, optimal conditions for P species removal were determined at which the P-removals of 99.8 % (for ortho-P), 94.9 % (for poly-P) and 94.8 % (for organic-P) were achieved, respectively. The results derived from the verification experiments agreed with that predicted by the models, confirming the suitability of the established models and the success of RSM in optimizing the PAS adsorption conditions.
2008-06-01T00:00:00Z