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In Pokémon XD: Gale of Darkness

In Pokémon XD, Exinn is found in the Mayor's house, not allowing Michael to explore the house. She is distracted by playing the Music Disc containing the Rumba of Love on the stereo in the room. When Michael finds the Mayor's Note lying on the floor next to the Mayor's bed, he is suddenly interrupted by the 'secretary', who reveals herself to be a Cipher Peon. Once beaten, she flees the house and is not seen again.

In Pokémon Colosseum, an unnamed woman also appears in the Mayor's house as his secretary. It is unknown if she actually is Exinn, since there is no evidence in either game to support or deny the possibility.