This is a schematic representation of the coated product and applications.
CREDIT
ORNL

A moth’s eye and lotus leaf were the inspirations for an antireflective water-repelling, or superhydrophobic glass coating that holds significant potential for solar panels, lenses, detectors, windows, weapons systems and many other products.

The discovery by researchers at the Department of Energy’s Oak Ridge National Laboratory, detailed in a paper published in the Journal of Materials Chemistry C, is based on a mechanically robust nanostructured layer of porous glass film. The coating can be customized to be superhydrophobic, fog-resistant and antireflective.

“While lotus leaves repel water and self-clean when it rains, a moth’s eyes are antireflective because of naturally covered tapered nanostructures where the refractive index gradually increases as light travels to the moth’s cornea,” said Tolga Aytug, lead author of the paper and a member of ORNL’s Materials Chemistry Group. “Combined, these features provide truly game-changing ability to design coatings for specific properties and performance.”

To be superhydrophobic, a surface must achieve a water droplet contact angle exceeding 150 degrees. ORNL’s coating has a contact angle of between 155 and 165 degrees, so water literally bounces off, carrying away dust and dirt. This property combined with the suppression of light reflection from a glass surface is critical for improved performance in numerous optical applications, Aytug said.

The base material–a special type of glass coating–is also highly durable, which sets it apart from competing technologies, according to Aytug, who described the process.

“We developed a method that starts with depositing a thin layer of glass material on a glass surface followed by thermal processing and selective material removal by etching,” he said. “This produces a surface consisting of a porous three-dimensional network of high-silica content glass that resembles microscopic coral.”

The fact the coating can be fabricated through industry standard techniques makes it easy and inexpensive to scale up and apply to a wide variety of glass platforms.

Where solar panels are concerned, the suppression of reflected light translates into a 3-6 percent relative increase in light-to-electricity conversion efficiency and power output of the cells. Coupled with the superhydrophobic self-cleaning ability, this could also substantially reduce maintenance and operating costs of solar panels. In addition, the coating is highly effective at blocking ultraviolet light.

Other potential applications include goggles, periscopes, optical instruments, photodetectors and sensors. In addition, the superhydrophobic property can be effective at preventing ice and snow buildup on optical elements and can impede biofouling in marine applications.

Aytug emphasized that the impact abrasion resistance of the coating completes the package, making it suitable for untold applications.

The work was supported by the Laboratory Directed Technology Innovation Program. STEM research was supported by the DOE Office of Science Basic Energy Sciences. A portion of the research was conducted at the Center for Nanophase Materials Sciences, a DOE Office of Science User Facility. Photovoltaic device measurements were done at the University of Utah.