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Abstract

In this study, we devised a new concept for the precise nanofabrication of Au-Si fibrous
nanostructures using megahertz femtosecond laser irradiation in air and atmospheric
pressure conditions. The weblike fibrous nanostructures of Au thin layer on silicon
substrate, which are proposed for the application of solar cells, exhibit a specific
improvement of the optical properties in visible wavelength. Varying numbers of laser
interaction pulses were used to control the synthesis of the nanofibrous structures.
Electron microscopy analysis revealed that the nanostructures are formed due to the
aggregation of polycrystalline nanoparticles of the respective constituent materials
with diameters varying between 30 and 90 nm. Measurement of the reflectance through
a spectroradiometer showed that the coupling of incident electromagnetic irradiation
was greatly improved over the broadband wavelength range. Lower reflectance intensity
was obtained with a higher number of laser pulses due to the bulk of gold nanoparticles
being agglomerated by the mechanism of fusion. This forms interweaving fibrous nanostructures
which reveal a certain degree of assembly.

PACS

81.05.Zx; 81.07.-b

Keywords:

Laser material processing; Nanomaterials; Photovoltaic

Background

Manufacturing solar cells with an easy processing and inexpensive material has become
the most important challenge for the future. Several articles focused on the enhancement
of the spectral absorbance by modification of materials, improvement in electron-hole
transport [1], and the usage of alternative wide-band-gap semiconductor materials [2]. Nanostructured material-based solar cells have attracted interest due to their characteristics
and processing benefits. Silicon and metal nanowires, nanotubes, and nanorods which
enable solar cells in decoupling light absorption from the direction of carrier transport
have been studied by many researchers [3-6]. Minsung and Koichi demonstrated tin-catalyzed silicon nanowire solar cells fabricated
by the hydrogen radical-assisted deposition method on a C-Si wafer, while Baxter and
Aydil employed ZnO as a wide-band-gap semiconductor to construct dye-sensitized solar
cells which exhibited an energy conversion efficiency of 0.5% with an internal quantum
efficiency of 70%. Also, Huynh et al. studied polymer matrix solar cells using CdSe
nanorods, achieving an efficiency of 1.7% [5]. The benefit of nanowires, nanotubes, and nanorods is the improvement of current
densities because the diffusion length of minority carriers is much shorter than the
thickness of the material required for optimal light absorption [7]. The application of nanofibrous structures in solar cells is the most promising method
among other alternative approaches. Due to the high optical properties of nanoparticles,
further research is also being carried out on nanoparticle-based dye-sensitized solar
cells (DSSCs) [8-10].

Basically, metal nanoparticles exhibit remarkable properties departing from the bulk
material counterparts due to their large surface area to volume ratio, high surface
energy, and spatial confinement. For instance, gold nanoparticles exhibit a strong
absorption peak near the 520-nm wavelength which cannot be observed in the bulk material
due to surface plasmon oscillation modes of the conduction electrons in the nanoparticles
[11]. Properties such as quantum confinement, surface plasmon resonance, enhanced catalytic
activity, and superparamagnetism, among others, have been observed in nanomaterials
to be varied as gold nanoparticle [7]. Laser scribing, laser patterning [12], and laser-induced ablation from a solid target are known as an alternative physical
method for nanofabrication. Compaan et al. employed laser to scribe grooves of very
narrow widths and superior profiles onto thin-film PV [13]. Rajeev et al. tried to increase metal absorption using a four-beam interference
pattern creating hole-array structures to the surface [8]. Nakayama et al. investigated the effects of plasmon scattering on absorption and
photocurrent collection in prototype GaAs solar cells decorated with size-controlled
Ag nanoparticles by masked deposition through anodic aluminum oxide (AAO) templates
and examined the size effects of hemispherical metal nanoparticle arrays [9]. Kume also investigated light emission from surface plasmon polaritons (SPPs) mediated
by a metallic nanoparticle system consisting of Ag nanoparticles placed very close
to an Al surface and prepared by depositing an Ag film on an Al film [10]. Novotný et al. [14] investigated the effect of the impact of a UV laser beam on thermally evaporated
black gold and gold thin films with respect to their optical and structural properties.
They observed that the absorptivity of the black gold film decreased with an increase
in the number of laser pulses. The most recent effort includes using plasmonic metal
nanoparticles to improve the efficiency of quantum dot solar cells and thin film solar
cells [15,16].

The main difference between our nanofiber and other nanowire, nanotube, and nanorod
structures in solar cell application is the ‘weblike and well-organized morphology
structure’. Nanowire, nanotube, and nanorod morphology provides direct conduction
paths for electrons from the point of injection to the collection electrode and allows
for the decoupling of light absorption from the direction of carrier transport along
the longitudinal direction only, while the weblike and network structure of nanofibers
has inherent anisotropy with a large variety of morphology. Moreover, the dense network
of nanofibers can provide a greater surface area of around 104 times that that of untreated surfaces. In the present study, a femtosecond laser
has been used to generate a nanofibrous structure on gold-silicon wafer. Different
numbers of laser cycles were used to synthesize the nanofibrous structure with various
dwell times. A spectroradiometer was used to measure reflectance to investigate the
coupling of incident electromagnetic irradiation over the broadband wavelength range.
The new structure revealed a higher reduction in visible light reflection when compared
to an unstructured gold-silicon substrate.

Methods

A thin gold film of 200-nm thickness was initially deposited onto a 0.02-Ω cm p-type
silicon (100) wafer using an evaporator (e-beam) in the AMPEL Nanofabrication laboratory
at the University of British Columbia (UBC). Four sets of these gold-silicon samples
of 10 mm × 10 mm size were precisely cut using a dice saw and used for the present
experiment. In order to obtain a large number of nanoparticles for analysis without
damaging the surface of the target, laser cycles were gradually increased (2, 3, 4,
and 5 cycles). The laser source is an all-diode-pumped, direct-diode-pumped Yb-doped
fiber oscillator/amplifier system capable of producing variable pulse energies up
to 10 mJ with a pulse frequency range between 200 kHz and 25 MHz. Average power varies
between 0 and 20 W. In order to ablate the target material and create nanoparticles,
the laser beam scanned the surface of the gold-sputtered silicon wafer in a 40 × 40
dot-array pattern. The laser beam dwell time at each dot point can be set at 0.5,
0.75, or 1.0 ms. The laser-irradiated samples were then characterized by scanning
electrical microscopy (SEM), transmission electron microscopy (TEM), and energy-dispersive
X-ray (EDX) analyses. A spectrophotometer (Ocean Optics, Dunedin, FL, USA) was used
to measure the reflectance of the laser-irradiated samples by illumination with a
wavelength in the range of 200 to 2,200 nm.

Results and discussion

Characterization of nanoparticle aggregation

Figure 1 shows a TEM image of a gold-silicon nanofiber, accompanied with EDX analysis results.
The figure shows that nanofibers consist of agglomerated silicon oxide nanoparticles
with individual gold nanoparticles or a small cluster of gold nanoparticles dispersed
in the cloud of silicon oxide nanoparticle agglomerates. It is also evident from the
image that the diameter of gold particles is a fraction of that of silicon oxide particles.

Figure 1.TEM and EDX analyses. TEM and EDX analyses show that a dense cloud of gold atoms (plume) firstly assembled
in different laser spots of the gold target.

The basic mechanism of femtosecond laser synthesis of nanoparticles could be explained
in terms of the dynamic formation mechanism postulated by Sivakumar et al. [17] and Tan and Venkatakrishnan [18]. In brief, a dense cloud of atoms (plume) accumulated around the laser spot of the
gold target during the course of ablation. This core was made up of a number of small
gold atoms aggregated randomly due to the density fluctuation to form embryonic nanoparticles.
Even when the ablation process had been terminated, at the end of the cycle, the aggregation
continued, per se at a significantly slower growth rate with every new cycle until all atoms in the
vicinity of the embryonic nanoparticles were depleted.

The significant difference in the melting/evaporation point of gold and silicon can
be used to explain the large difference in particle size [19]. The evaporation/melting point of gold is much higher than that of silicon. As the
cloud of plasma cools, the temperature of gold aggregation reduces to its melting
point and particles solidify far before silicon particles reach the melting point.
Therefore, silicon particles have much longer time to grow, leading to a much larger
size.

The laser system used for this work has megahertz pulse frequency, so the energy of
each laser pulse is in the order of nanojoules. It will generally need several pulses
to create a dense plasma with a temperature high enough to evaporate both gold and
silicon. Because of the large difference in evaporation points of gold and silicon,
it is reasonable to speculate that gold and Si nanoparticles are initiated at different
times, with silicon particles appearing first, at lower laser scanning cycles, and
at a shorter dwell time.The formation of gold-silicon aggregated nanoparticles was
observed starting at the second laser beam scanning cycle. Figure 2 shows nanofibers generated at a single laser beam scanning. With a single scanning
cycle, short fibers mixed with large molten droplets were observed. The formation
of fibrous aggregated nanoparticles was not evident.As the number of scanning cycles
increases, the amount of molten droplets reduces and the aggregates grow longer, finally
forming unique and uniform fibrous structures. Figure 3D shows typical weblike fibrous nanostructures formed due to the agglomeration of
the bulk quantity of nanoparticles created during laser ablation at 5 cycles and 0.75-ms
dwell time. Moreover, the fibrous nanostructures have relatively uniform diameters
(around 50 nm) and do not have a wide range of variation in size distribution. In
particular, the nanoparticles merge to form smooth chains.

Figure 3.SEM images of morphology transition with different cycles. (A) Less than 2 cycles, (B) up to 2 cycles, (C) 4 cycles, and (D) 5 cycles.

The most interesting phenomenon we observed is that the growth of silicon fibrous
nanostructure begins first, followed by gold nanoparticle formation, until an equal
quantity of these nanoparticles (approximately 50% of Si and Au) is formed at the
third and fourth cycles. After that, the gold nanoparticle content drops. The gold
content was measured by EDX analysis, as shown in Figure 4. Figure 5 shows the gold content at various laser machining parameters. The percentage of gold
is obtained from EDX analysis results in Figure 4. Figure 5 shows that the gold content increases with the increase of laser beam dwell time.
However, there is an optimum number of machining cycles at which the gold content
reaches the highest. The reduction of gold content to a higher number of machining
cycle may be due to the removal of the entire gold thin film [16] and the subsequent penetration of the laser beam to the Si substrate. As the gold
thin film was completely consumed, the generated nanoparticle agglomerates entirely
consist of silicon. Therefore, the overall detected gold content reduces.

Light reflectance

The nanofibrous structure can significantly influence optical properties, which can
differ considerably with those of the bulk materials. This type of structure enhances
optical absorption due to surface plasmon excitation in the metal nanoparticle [10]. The micro-nanoscale surface roughness of the treated substrate could also increase
light absorption due to the multiple reflections in micro-cavities and the variation
of light incident angles. Metal surfaces with roughness on the scale of the optical
wavelength are found to have a strong coupling of the incident light and become discolored
as a result of selective surface plasmon absorption.In order to investigate the samples'
enhanced absorption behavior in the visible region, a spectroradiometer was employed
with a broad wavelength range of 250 to 1,200 nm. The measured integrating reflectance
spectra are illustrated in Figure 6, where the red curve represents the reflectance of the unirradiated gold-silicon
sample showing a high reflective intensity around 4,000 a.u.

The dark red curve represents the untreated sample, while the olive green, purple,
light blue, and orange curves represent the reflection spectrum of the fibrous nanostructure
layer with 2, 3, 4, and 5 cycles over visible wavelength, respectively, at different
dwell times. The fibrous nanostructure increases the surface area by more than an
order of magnitude which causes the radiation to pass through a longer distance before
being reflected back. Therefore, a photon incident on a structured surface is likely
to undergo more than one reflection before leaving the surface. Comparing the reflection
spectrum to that of pure silicon nanofibers obtained from a previous experiment repeated
on silicon wafer [20], we can conclude that the fibrous structure is the main attribute for light enhancement.
The embedded gold particles will further enhance such multi-reflection, by increasing
the intensity of reflection. This is evident from Figure 6A. At 2 scanning cycles and 0.25 ms of dwell time, the quantity of nanofiber is the
lowest, but the percentage content of gold reaches the highest. Therefore, the enhancement
effect is the most noticeable. It was observed that the reflectance decreased as the
scanning cycle increased. As the scanning cycle increased, more fibrous nanostructures
were generated and the thickness of the deposition increased, hence more effective
in reflecting illumination. As the gold content reaches the highest at 2 or 3 cycles,
we expect that the reflectance will drop to the lowest at these parameters. However,
the results show that the reflectance reduces consistently with the increase of the
number of cycles. This is attributed to the enhanced light absorptance of nanostructured
silicon [20]. At higher number of cycles, the gold content reduces; however, the total quantity
of the nanofiber increases. Therefore, the overall light absorptance of the treated
substrate improves as the number of cycles increases. From these results, we can conclude
that gold nanoparticles moderately enhance the light absorptance of silicon nanofiber.
The enhancement is more effective when the quantity of silicon nanofibers is relatively
low. If the deposition thickness of nanofiber is limited, embedding gold nanoparticles
can be a method for enhancing light absorptance.

Moreover, the spectra exhibit a characteristic lower peak with the tail portion of
the broadband extending towards the UV wavelength range. The width of the 519-nm peak
is broadened and the height is lowered to a greater extent by introducing more laser
shots. This spectral change indicates that the diameters of the nanoparticles are
reduced more under irradiation of the laser with higher dwell time and more laser
shots [20]. Moreover, when nanoparticles are sufficiently close together, interaction between
neighboring particles arises. In simple words, when the longer dwell time creates
a greater quantity of unique and homogenous distribution of the nanofibrous structures,
the dipole created by the electric field of light induces a surface polarization charge,
which effectively acts as a restoring force for free electrons.

Conclusions

In summary, a simple and inexpensive method was implemented for synthesizing metal-semiconductor
nanofibrous structures by using femtosecond laser material processing. The gold-silicon
content ratio can be controlled by the number of interactive laser pulses. The highly
improved coupling efficiency between light and the bulk quantity of gold nanoparticles
may be attributed to the excitation of confined plasmon modes on the structured metal
surfaces. These Au-Si solar cell nanofibrous structures may be a promising candidate
for future photovoltaic application.

Competing interests

The authors declare that they have no competing interests.

Authors' contributions

At the time of this work, ASM was a Ph.D. candidate at Ryerson University. He conducted
the experiment, developed the theory, and drafted the manuscript. KV was ASM's supervisor.
He conceived the idea of this research work and planned the experiment. BT was ASM's
co-supervisor. She contributed to the interpretation of experimental results and the
theory development. She also revised the manuscript. All authors read and approved
the final manuscript.

Acknowledgements

This work was funded by the Natural Science and Engineering Research Council of Canada
and the Ministry of Research and Innovation of Ontario, Canada.