EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B). HIGH
CONCENTRATIONS MAY LEAD TO CENTRAL NERVOUS SYSTEM EFFECTS (DROWSINESS,
DIZZINESS, NAUSEA, HEADACHES, PARALYSIS, AND BLURRED VISION) AND/OR
DAMAGE. OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED
WITH LIVER ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS
WELL AS REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC
OVEREXPOSURE, HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS
SYSTEM DAMAGE.

FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION.

FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS AND ALERT,
GIVE 2 TO 4 CUPFULS OF WATER OR MILK. CALL A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
TREAT SYMPTOMATICALLY AND SUPPORTIVELY.

SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
ISOLATE THE HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED
PERSONNEL. CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE
COMBUSTIBLE MATERIALS SUCH AS SAWDUST.

SECTION 7 - HANDLING AND STORAGE

HANDLING:
WASH THOROUGHLY AFTER HANDLING. AVOID PROLONGED OR REPEATED CONTACT WITH
SKIN. USE WITH ADEQUATE VENTILATION.

ENGINEERING CONTROLS:
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR
OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS.

RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.

SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION.

EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.

OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.

HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.

HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE.

HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.

STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.

SECTION 11 - TOXICOLOGICAL INFORMATION

PRODUCT LD50: ND

PRODUCT LC50: ND

CHEMICAL NAME LD50 LC50

PARA-NONYL PHENOL 1300 MG/KG N.E.
(RAT, ORAL)

XYLENE 4300 MG/KG 5000 PPM (RAT, INHALATION, 4HR)
(RAT, ORAL)

TOLUENE 636 MG/KG >26700 PPM (RAT, INHALATION,
(RAT, ORAL) 1 HR)

ETHYLBENZENE 3500 MG/KG N.E.
(RAT, ORAL)

n-BUTANOL 2500 MG/KG (RAT) >8000 PPM (RAT, INHALATION,
4HR)

SECTION 12 - ECOLOGICAL INFORMATION

ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.

SECTION 13 - DISPOSAL INFORMATION

DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER STORM DRAINS OR SEWER SYSTEMS.

SECTION 14 - TRANSPORTATION INFORMATION

DOT PROPER SHIPPING NAME: PAINT RELATED MATERIAL

DOT TECHNICAL NAME: N.A.

DOT HAZARD CLASS: 3

DOT UN/NA NUMBER: UN1263

PACKING GROUP: III

HAZARD SUBCLASS: N.A.

RESP. GUIDE PAGE: 128

SECTION 15 - REGULATORY INFORMATION

CERCLA - SARA HAZARD CATEGORY:

THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES"
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD, REACTIVE
HAZARD

SARA SECTION 313:

LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT
ARE SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF
THE SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART
372:

CHEMICAL NAME CAS NUMBER

XYLENE 1330-20-7

TOLUENE 108-88-3

ETHYLBENZENE 100-41-4

n-BUTANOL 71-36-3

TOXIC SUBSTANCES CONTROL ACT:

LISTED BELOW ARE THE SUBSTANCES (IF ANY) CONTAINED IN THIS PRODUCT THAT
ARE SUBJECT TO THE REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM
THE UNITED STATES:
IT IS THE POLICY OF RUST-OLEUM CORPORATION TO USE ONLY TSCA COMPLIANT
MATERIALS IN ITS PRODUCTS.

U.S. STATE REGULATIONS: AS FOLLOWS

NEW JERSEY RIGHT-TO-KNOW:
THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE
COMPONENTS IN THIS PRODUCT.

CHEMICAL NAME CAS NUMBER

LIMESTONE 1317-65-3

POLYETHYLENE POLYAMINE ADDUCT MIXTURE

POLYOXYPROPYLENEDIAMINE 9046-10-0

PENNSYLVANIA RIGHT-TO-KNOW:
THE FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN THE PRODUCT AT
GREATER THAN 3%.

CHEMICAL NAME CAS NUMBER

LIMESTONE 1317-65-3

POLYETHYLENE POLYAMINE ADDUCT MIXTURE

POLYOXYPROPYLENEDIAMINE 9046-10-0

CALIFORNIA PROPOSITION 65:

WARNING!

THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN BY THE STATE OF CALIFORNIA TO
CAUSE CANCER.

WARNING!

THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.

INTERNATIONAL REGULATIONS: AS FOLLOWS

CANADIAN WHMIS:
THIS MSDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.

LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED

RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE
AS OF THE DATE OF THIS MATERIAL SAFETY DATA SHEET. HOWEVER, BECAUSE THE
CONDITIONS OF HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR
CONTROL, WE ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR
PROPERTY DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM
CORPORATION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE
ACCURACY OR RELIABILITY OF THE DATA OR RESULTS OBTAINED FROM THEIR USE.
ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION.
THE INFORMATION AND RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE
OFFERED FOR THE USERS' CONSIDERATION AND EXAMINATION. IT IS THE
RESPONSIBILITY OF THE USER TO DETERMINE THE FINAL SUITABILITY OF THIS
INFORMATION AND TO COMPLY WITH ALL APPLICABLE INTERNATIONAL, FEDERAL,
STATE, AND LOCAL LAWS AND REGULATIONS.