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You can find Toxic on route 17 in pokemon Black/White .
Okay Goto to route 1 to the fishing spot . Surf down there then go left then you will have to face some rangers and after beating them you enter route 17 then surf left and you will find a pokeball with toxic .
check http://www.youtube.com/watch?v=cSDjNLjlmPs
for a better idea . Watch from 5.00 .